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Several significant international incidents in Asian exclusive economic zones (EEZs) have underscored the ambiguity and lack of agreement regarding the regime governing foreign military activities in coastal States’ EEZs. A group of senior officials and analysts participated in their personal capacities in a dialogue from 2002–2005 that discussed the issues with a view to improving mutual understanding of the regime and finding areas of agreement. The Tokyo meeting in September 2005 reached consensus on some voluntary, non-binding guidelines that are presented here. The guidelines are based selectively on the 1982 UNCLOS, State practice and emerging ‘soft’ law, and attempt to balance the interests of coastal States and user States. It is hoped that they may serve as the basis for discussion and eventual agreements between governments. 相似文献
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东亚地区春季二氧化硫的输送与转化过程研究I.模式及其验证 总被引：5，自引：0，他引：5
结合新近评估的东亚地区污染源资料,作者利用一个耦合的区域化学输送模式系统以探讨东亚地区春季期间气象过程、气相与液相化学过程、非均相化学过程、气溶胶过程和干湿沉降过程对二氧化硫输送及转化过程的影响,并研究二氧化硫和硫酸盐气溶胶的空间分布及变化特征.模拟的二氧化硫和硫酸盐气溶胶的浓度值与2001年春季飞机和地面获取的观测值进行了比较.比较结果显示,模拟值与观测值具有很好的一致性,模式系统很好地反映了二氧化硫和硫酸盐气溶胶的分布特征和变化规律,再现了许多观测到的重要特征,为进一步分析模拟结果奠定了基础. 相似文献
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Summary Magnetic and crystallographic properties of solid solutionsxFeTiO3. (1–x) Fe2O3 of hematite (Fe2O3) and ilmenite (FeTiO3), which have rhombohedral crystal structure, are examined in detail for the whole range of 0 x 1. Samples examined are mineral grains separated out from natural rocks and artificially synthesized ones. The minerals of the hematite-ilmenite series for 0.55<x are ferromagnetic and their Curie-point decreases in proportion to increase inx, becoming 0 C aroundx=0.8. Those for 0.55 >x >0 are feeble ferromagnetic, probably being anti-ferromagnetic just same as hematite. Finally probable cause of the ferromagnetism forx>0.55 is briefly discussed. It seems that presence of ferromagnetic ilmenite must always be taken into consideration whenever magnetism of rocks is studied in relation to various geophysical phenomena.
Zusammenfassung Die magnetischen und krystallographischen Eigenschaften der festen LösungenxFeTiO3. (1–x) Fe2O3 von Hämatit (Fe2O3) und Ilmenit (FeTiO3), die eine rhombohedrale Krystallstruktur haben, wurden im ganzen Bereich von 0 x 1 ausführlich untersucht. Die untersuchten Proben waren aus Naturgesteinen getrennten sowie aus zusammengesetzten künstlichen Mineralkörner. Die Minerale der Hämatit-Ilmenitschen Reihe von 0.55<x sind ferromagnetisch, und ihr Curie-Punkt nimmt proportional mit der Zunahme vonx ab, und fallsx ungefähr 0.8 erreicht, wird er 0 C. Die Minerale von 0.55 >x >0 sind hingegen schwach ferromagnetisch, und vielleicht sind sie genau wie das Hämatit antiferromagnetisch. Zum Schlusse wurde die wahrscheinliche Ursache des Ferromagnetismus im Umfang von x>0.55 kurz besprochen. Es scheint, dass man das Vorhandensein von ferromagnetischem Ilmcnit immer dann in Betracht ziehen muss, wenn man den Gesteinmagnetismus in Bezug auf die verschiedenen geophysikalischen Phänomene untersucht.
Résumé On étudie les proprietés magnétiques et cristallographiques des solutions solides rhombohédralesxFeTiO3. (1–x) Fe2O3 de l'hématite (Fe2O3) et de l'ilménite (FeTiO3) pour l'étendue totale de 0 x 1. Les échantillons examinés sont des minéraux séparés par des grains naturels et des grains artificiellement synthétisés. On montre que les minéraux de la série hématite-ilménite sont ferromagnétiques pourx>0.55 et que leur point de Curie diminue en proportion à l'acroissement de x: il est atteind à 0 C quandx est environ 0.8. Les minéraux pour 0.55 >x >0 sont faiblement ferromagnétiques, étant probablement antiferromagnétiques comme l'hématite pure. Finalement, on discute briévement l'origine probable du ferromagnétisme des solutions solides dans l'étenduex>0.55. Il semble que la présence de l'ilménite ferromagnétique doit Être considérée lorsqu'on étudie le magnétisme des roches par rapport aux divers phénomènes géophysiques.相似文献
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Takehiko Yagi Yoshiaki Ida Yosiko Sato Syun-Iti Akimoto 《Physics of the Earth and Planetary Interiors》1975,10(4):348-354
The pressure dependence of the three lattice parameters and unit cell volume of fayalite (Fe2SiO4 olivine) was determined by X-ray diffraction under hydrostatic pressures up to 70 kbar. In order to eliminate stress inhomogeneity within a composite material consisting of a specimen mixed with an internal-pressure standard, a liquid (1 : 1 mixture of ethanol and methanol) was used as a pressure-transmitting medium. The isothermal bulk modulus calculated on the basis of the second-order Birch-Murnaghan equation of state gives the values K0 = 1.19 ± 0.10 Mbar and K0′ = 7 ± 4, and if we assume K0′ = 5: K0 = 1.24 ± 0.02 Mbar. Three axes of fayalite were found to be compressible in the following order, b >c >a. Comparisons with the results obtained under non-hydrostatic compression are made. 相似文献
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Modeling of Regional High Ozone Episode Observed at Two Mountain Sites (Mt. Tai and Huang) in East China 总被引：3，自引：0，他引：3
Zifa Wang Jie Li Xiquan Wang Pakpong Pochanart Hajime Akimoto 《Journal of Atmospheric Chemistry》2006,55(3):253-272
A high O3 episode was observed during 23–25 May 2004 at two high-mountain sites reflecting the regional pattern of air pollutants over East China. This episode lasted about three days with the maximum hourly O3 mixing ratios reaching 111 and 114 ppbv at Mt. Tai and Huang, respectively. Backward trajectories and meteorological analysis indicated that regional transport, associated with a weak high pressure system over the East China Sea, might play an important role in the formation of this high ozone episode. The nested air quality prediction modeling system (NAQPMS) was applied to investigate the formation and evolution of this high O3 event. The comparison of model results with observations showed that NAQPMS successfully reproduced the main observed patterns of O3 and meteorological parameters during the simulated period. The model results with emission over the Yangtze Delta and the East Central China switched on/off clearly showed that ozone and its precursors transported from the Yangtze Delta and the East Central China enhanced the high ozone episode at two sites, with a contribution of 20%–50% during the episode. In addition, based on process analysis with the model, chemical production and regional transport appeared to be the main causes of high ozone episode involving a large amount of high-ozone air masses and precursors transported from the surrounding areas. The horizontal transport is more active during the period of high ozone episode than that during the non-episode at Mt. Tai as well as Mt. Huang. 相似文献
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Phase equilibria in a natural garnet lherzolite nodule (PHN 1611) from Lesotho kimberlite and its chemical analogue have been studied in the pressure range 45–205 kbar and in the temperature range 1050–1200°C. Partition of elements, particularly Mg2+Fe2+, among coexisting minerals at varying pressures has also been examined. High-pressure transformations of olivine(α) to spinel(γ) through modified spinel(β) were confirmed in the garnet lherzolite. The transformation behavior is quite consistent with the information previously accumulated for the simple system Mg2SiO4Fe2SiO4. At pressures of 50–150 kbar, a continuous increase in the solid solubility of the pyroxene component in garnet was demonstrated in the lherzolite system by means of microprobe analyses. At 45–75 kbar and 1200°C, the Fe2+/(Mg + Fe2+) value becomes greater in the ascending order orthopyroxene, Ca-rich clinopyroxene, olivine and garnet. At 144–146 kbar and 1200°C, garnet exhibits the highest Fe2+/(Mg + Fe2+) value; modified spinel(β) and Ca-poor clinopyroxene follow it. When the modified spinel(β)-spinel(γ) transformation occurred, a higher concentration of Fe2+ was found in spinel(γ) rather than in garnet. As a result of the change in the Mg2+Fe2+ partition relation among coexisting minerals, an increase of about 1% in the Fe2SiO4 component in (Mg,Fe)2SiO4 modified spinel and spinel was observed compared with olivine.These experimental results strongly suggest that the olivine(α)-modified spinel(β) transformation is responsible for the seismic discontinuity at depths of 380–410 km in the mantle. They also support the idea that the minor seismic discontinuity around 520 km is due to the superposition effect of two types of phase transformation, i.e. the modified spinel(β)-spinel(γ) transformation and the pyroxene-garnet transformation. Mineral assemblages in the upper mantle and the upper half of the transition zone are given as a function of depth for the following regions: 100–150, 150–380, 380–410, 410–500, 500–600 and 600–650 km. 相似文献
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Recent experiments on the olivine-spinel phase transformation in Ni2SiO4 have provided the following fundamental results: (1) the interphase structural orientation relationships with between the olivine and spinel phases upon transformation; and (2) the growth of 300 μm spinel single crystal from single crystals of olivine. In the light of these observations, transformation mechanisms proposed have been compared. We conclude that neither a nucleation and growth model nor a martensite model is verified by the experimental results. The former model lacks consistency in terms of the interphase relationships, and the latter cannot offer a dislocation-multiplication mechanism for the growth process. 相似文献
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Yugo Kanaya Yasuhiro Sadanaga Jun Hirokawa Yoshizumi Kajii Hajime Akimoto 《Journal of Atmospheric Chemistry》2001,38(1):73-110
An instrument for measuringtropospheric OH/HO2 radicals by laser-inducedfluorescence developed in our laboratory is presentedin detail. It is based on FAGE (fluorescence assay bygas expansion) technique and OH is both excited anddetected at 308 nm corresponding to its A-X(0,0) band.The alignment of the laser beam, the design of thesample gas inlet, and the devices for the fluorescencedetection are optimized so as to reduce the backgroundsignal while keeping the OH sensitivity as high aspossible. A thermalized position of the expanding gasbeam is probed in our system and we did not observe asevere decrease of the HOx sensitivities under humidconditions. An optical fiber is used for deliveringthe laser light to the fluorescence detection cellmounted outside at a high position. Thus the laserbeam alignment is by far simplified and is made highlyreproducible, once settled properly. For thecalibration, two methods are employed: a system withlaser absorption measurements of OH and a system ofsimultaneous photolysis of H2O and O2. Thecalibration factors are compared well within thecombined uncertainty. Using the latter system, theconversion efficiency of HO2 to OH by NO additionis measured to be around 90%. The detection limitsfor OH and HO2 (S/N = 2) are estimated to be3.3 × 106 and 3.6 × 106cm–3 at noon,respectively, with an integration time of 1 min. Theresults of test observations at our institute are alsopresented. 相似文献
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Accurate measurements of cell parameters were performed on the ilmenite phases of ZnSiO3 and MgGeO3 using an X-ray diffraction method under hydrostatic conditions. The linear changes in cell parameter are represented by 1?a/a 0=(1.06±0.04)×10?4 P(kbar) and 1?c/c 0=(2.11±0.04)×10?4 P for ZnSiO3, and 1?a/a 0=(1.37±0.03)×10?4 P and 1?c/c 0=(2.05±0.04)×10?4 P for MgGeO3. A least-squares calculation using the first-order Birch-Murnaghan equation gives K T =2.16±0.02 Mbar and K T =1.87±0.02 Mbar for ZnSiO3 and MgGeO3, respectively. Elastic systematics assuming K T V m =constant give a predicted value K T =2.14 Mbar for the ilmenite phase of MgSiO3. 相似文献