大气污染物排放量与颗粒物环境空气质量的空间非协同耦合研究——以武汉市为例     

张金亭  赵玉丹  田扬戈  何青青  庄艳华  彭韵羲  洪松 《地理科学进展》2019,38(4):612-624

针对区域大气污染物排放量与空气质量在时空分布上存在不完全协同、匹配的现象,论文选择SO₂、NO_X、PM_2.5、CO和VOCs作为大气污染物指标,选择气溶胶光学厚度(Aerosol Optical Depth, AOD)表征颗粒物环境空气质量,以武汉市为例,综合应用耦合模型和空间错位指数模型研究2类指标之间的空间非协同耦合规律。主要结论如下：① 武汉市大气污染物排放量与颗粒物空气质量具有不同空间分布特征,大气污染物排放量呈现由城市中心城区向远城区递减的趋势,其中SO₂、PM_2.5和VOCs的排放具有明显的中心聚集现象,而NO_X和CO聚集现象不显著,且与道路分布明显相关;AOD分布具有明显的空间差异性,总体上呈由西北向东南依次递减的趋势。② 武汉市大气污染物排放与颗粒物空气质量的空间非协同耦合规律：越靠近城市中心城区,空间协同耦合现象越显著,空间错位现象越弱;越远离主城区,空间非协同耦合现象越显著,空间错位现象越显著;SO₂排放量与AOD在武汉市远城区的空间错位指数均大于0.7,且耦合度指数小于0.3,呈现较强的非协同耦合特征,NO_X、VOCs、PM_2.5的排放量与AOD在武汉中心城区的空间错位指数均小于0.5,且耦合度指数大于0.5,协同耦合现象较为显著。③ 基于时空非协同耦合分析城市大气环境污染治理建议：针对污染物与AOD空间错位不显著的城市中心城区,以本地减排治理为主;针对污染物与AOD空间错位显著的远城区,应在污染溯源分析的基础上进行区域协调综合治理。  相似文献   

Extraction of Lithium from Salt Lake Brine using N523-TBP Mixture System   总被引：1，自引：1，他引：0       下载免费PDF全文

SHI Dong  LI Li-juan  LI Jin-feng  JI Lian-min  SONG Fu-gen  PENG Xiao-wu  ZHANG Li-cheng  ZHANG Yu-ze  LI Hui-fang  SONG Xue-xue  NIE Feng  ZENG Zhong-min  LIU Zhi-qi  GUO Fan 《盐湖研究》2019,27(2):95-110

In this work,problems encountered by tri-butyl phosphate( TBP) in the industrialization of lithium extraction from salt lake brine were discussed in detail. The behavior of N,N-bi-( 2-ethylhexyl) acetamide( N523) during lithium extraction was investigated,and its disadvantages were analyzed in the view of practical application. An N523-TBP mixture extraction system was proposed to alleviate or avoid the defects that N523 and TBP met when they were used separately. The optimal composition of this mixture extraction system was determined to be 20% N523-30% TBP-50% kerosene.The effects of brine acidity,Fe/Li molarity ratio,phase ratio and chloride ion concentration on lithium extraction efficiency were discussed. The operation conditions in single-stage extraction were optimized as brine acidity = 0. 05 mol/L,Fe/Li molarity ratio = 1. 3,and phase ratio = 2. The high concentration of chloride ions in brine was beneficial for the extraction of lithium. The structure of the extracted complex was proposed as( LiFeCl_4·n N523·m TBP)·( 2-n) N523·( 2-m) TBP( m + n = 2) by chemical analysis and slope-fitting methods. The extraction thermodynamic functions were calculated preliminarily,and the results suggested that the extraction process was an exothermic( ΔH 0) and spontaneous( ΔG 0) reaction,and the degree of disorder increased( ΔS 0) during the extraction process. This work will give some guidance to the lithium industry of Qinghai in both the fundamental theory and practical application.  相似文献   

塔北地区寒武系白云岩储层裂缝充填特征与有效性     

彭军  林攀  夏青松  李斌  韩浩东 《地球科学与环境学报》2019,(1):40-53

塔里木盆地寒武系白云岩储层具有年代老、埋深大、成岩作用强烈的特征,原生孔隙几乎被破坏殆尽,有效裂缝的发育程度是决定储层优劣的关键因素。根据岩芯描述、薄片鉴定、FMI成像测井、扫描电镜、阴极发光、电子探针以及流体包裹体分析等研究手段,开展了塔里木盆地北部地区(简称"塔北地区")寒武系白云岩储层的裂缝充填特征及有效性分析。塔北地区整体裂缝发育,天山南地区与塔河地区裂缝在产状、线密度、形态以及充填特征上存在差异。天山南地区裂缝线密度与有效性均低于塔河地区,充填矿物主要为自形白云石与石英,其次为方解石、石膏与黄铁矿。充填白云石分为3期,对应的温度区间分别为70℃～90℃、90℃～110℃及110℃以上,均为地层内的成岩流体成因;充填石英分两期,第一期为黏土矿物转化蚀变形成,第二期可能为热液成因。塔河地区裂缝线密度高,有效性较好,溶蚀作用发育,是有利的勘探地区,其充填物以热液矿物组合形式出现,主要为方解石,其次为石膏、鞍状白云石、黏土矿物、沥青等,重晶石以交代白云石的形式出现。充填方解石分为4期,对应的温度区间分别为70℃～100℃、100℃～130℃、130℃～180℃及180℃以上,前3期充填为不同埋深时期地层内成岩流体成因,最后一期充填为自下部运移而来的高温热液流体成因。  相似文献   

海绵城市建设下的生态效应分析——以常德市穿紫河流域为例     

王夏青  孙思远  杨萍  邹小燕  易巧梅  彭保发  许建伟 《地理学报》2019,74(10):2123-2135

海绵城市建设被认为是解决城市内涝、水污染和水资源短缺、热岛效应等问题的有效途径之一。中国自2015年起共确立30个海绵城市建设试点城区,为今后海绵城市建设在全国范围的推广提供示范。基于实地调研、查阅资料并对比分析穿紫河流域海绵城市建设前后的水文、植被和气候等自然要素变化。结果表明：常德市城市内涝有效缓解,但在暴雨发生时局部仍出现积水和内涝现象;穿紫河水质总体上由劣Ⅴ类转变为Ⅲ类,但在冬季周期性恶化及污染物富集;穿紫河流域生物多样性显著增加,同时也表现出植物种类单一、具有环境净化功能的植物种类较少、生态系统不完整和管理不善等问题;常德市夏季的热岛效应有一定程度缓解。常德市2004-2019年的海绵城市建设显著提升了穿紫河流域的生态效应,为该地区的社会经济发展和人居环境改善提供了重要的生态基础,也为合理评价其他试点城区海绵城市建设效果提供借鉴。  相似文献   

Growth inhibition and oxidative stress in two species of marine diatoms exposed to 1-phenylethanol     

DOU Xiang  MENG Fanping  DUAN Weiyan  LIU Qunqun  LI Hao  DU Shuhao  PENG Xiaoling 《中国海洋湖沼学报》2019,(4)

1-phenylethanol(1-PEA)is a flavor extensively used in the production of co smetics,beverages,and food.The release of 1-PEA into coastal environments has aroused great concern.However,its potential effects on marine organisms are still unknown.In order to provide a better understanding of the ecological risks of 1-PEA in marine environments,this study determined the toxic effects of 1-PEA on two marine diatoms(Phaeodactylum tricornutum and Skeletonema costatum).The diatoms were grown in culture medium containing different concentrations of 1-PEA for 96 h.The contents of chlorophyll a,chlorophyll c,glutathione(GSH),malondialdehyde(MDA),and the activities of superoxide dismutase(SOD),catalase(CAT)and glutathione peroxidase(GPx),were measured at the end of the exposure period.1-PEA was shown to significantly inhibit the growth of diatoms,with 96-h EC_(50) values of 257.14 mg/L and 126.46 mg/L in P.tricornutum and S.costatum,respectively.In P.tricornutum,the levels of SOD,CAT,GPx,GSH,and MDA were stimulated only when 1-PEA concentrations were close to or greater than the 96-h EC_(50)value.However,in S.costatum,the activities of SOD and CAT,and the syntheses of two chlorophylls were inhibited even at an exposure concentration below the 96-h EC_(50) value.Taken together,these findings indicate a potential ecological risk by discharging 1-PEA into coastal areas and its species-specific toxic effects on marine organisms.  相似文献   

基于EEMD和ARIMA的海温预测模型研究          下载免费PDF全文

张莹  谭艳春  彭发定  廖杏杰  余昱昕 《海洋学研究》2019,37(1):9-14

类型丰富、时空分辨率高的海洋探测数据,为信号分解和机器学习算法的应用提供了可能。本文针对如何建立有效的海温预测模型这一问题,使用高时空分辨率的海表温度(SST)融合产品,引入信号处理领域的集合经验模态分解(EEMD)和机器学习领域的自回归积分滑动平均模型(ARIMA)。首先利用最适于分解自然信号的EEMD方法,将海温数据分解成多个确定频率的序列;再利用ARIMA分别对各个频率的序列进行预测,最后将各个序列的预测结果进行组合。该方法在丰富数据的支撑下,比以往直接使用海温数据所建立的预测模型精度更高,为更好地进行海温预测提供了新方法。  相似文献   

敛痔散医院制剂质量标准初步研究          下载免费PDF全文

彭军良  胡小苏  姚向阳 《应用海洋学学报》2019,35(11):145-147

目的：研究敛痔散医院制剂质量的初步标准。方法：薄层色谱法定性鉴别敛痔散中的血竭,HPLC法定性鉴别敛痔散中的黄芩;HPLC法和酸碱滴定法分别定量测定敛痔散中盐酸小檗碱和氧化锌。结果：血竭和黄芩均可检出;盐酸小檗碱在0.0239～2.49μg范围内线性关系良好,平均回收率为93.23%,RSD%为7.2%;氧化锌在取样0.02525～0.25204g范围内线性关系良好,平均回收率为101.36%,RSD%为1.0%。结论：本研究为建立规范的质量标准奠定了坚实基础。  相似文献   

复方清痹片糖衣片改薄膜衣片质量标准研究          下载免费PDF全文

刘会  唐伟  彭艳梅 《应用海洋学学报》2019,35(11):142-144

目的：研究复方清痹片糖衣片改薄膜衣片的质量标准。方法：将原由滑石粉、糖浆、川蜡等辅料包糖衣片改为由胃溶型薄膜包衣预混剂包薄膜衣片,对薄膜衣片质量标准进行研究,对赤芍、防己、黄柏、甘草等进行薄层鉴别研究,并对赤芍中芍药苷进行含量测定方法学研究。结果：赤芍、防己、黄柏、甘草薄层鉴别斑点清晰,专属性强;芍药苷在2.9858～29.8584μg/ml之间有良好的线性关系,平均回收率98.33%,RSD%为1.70%。结论：糖衣片改薄膜衣片工艺可行,质量控制可靠、准确,可用于复方清痹片的质量控制。  相似文献   

Growth inhibition and oxidative stress in two species of marine diatoms exposed to 1-phenylethanol     

DOU Xiang  MENG Fanping  DUAN Weiyan  LIU Qunqun  LI Hao  DU Shuhao  PENG Xiaoling 《海洋湖沼学报（英文）》2019,(4):1342-1352

1-phenylethanol (1-PEA) is a flavor extensively used in the production of cosmetics, beverages, and food. The release of 1-PEA into coastal environments has aroused great concern. However, its potential effects on marine organisms are still unknown. In order to provide a better understanding of the ecological risks of 1-PEA in marine environments, this study determined the toxic effects of 1-PEA on two marine diatoms (Phaeodactylum tricornutum and Skeletonema costatum). The diatoms were grown in culture medium containing different concentrations of 1-PEA for 96 h. The contents of chlorophyll a, chlorophyll c, glutathione (GSH), malondialdehyde (MDA), and the activities of superoxide dismutase (SOD), catalase (CAT) and glutathione peroxidase (GPx), were measured at the end of the exposure period. 1-PEA was shown to significantly inhibit the growth of diatoms, with 96-h EC50 values of 257.14 mg/Land 126.46 mg/L in P. tricornutum and S. costatum, respectively. In P. tricornutum, the levels of SOD, CAT, GPx, GSH, and MDA were stimulated only when 1-PEA concentrations were close to or greater than the 96-h EC50 value. However, in S. costatum, the activities of SOD and CAT, and the syntheses of two chlorophylls were inhibited even at an exposure concentration below the 96-h EC50 value. Taken together, these findings indicate a potential ecological risk by discharging 1-PEA into coastal areas and its species-specific toxic effects on marine organisms.  相似文献   

不规则三角网数字水深模型缓冲面快速构建的滚动球加速优化算法     

董箭  张志衡  彭认灿  李改肖  王沫 《测绘学报》2019,48(5):654-667

针对TIN_DDM缓冲面构建与应用中存在的数据类型特殊、算法效率与模型精度不匹配的问题,本文将滚动球模型应用扩展至TIN_DDM缓冲面的构建过程。在分析滚动球模型构建精度局限的基础上,建立了滚动球半径关联的滚动球模型整体精度控制方法;结合大数据量TIN_DDM缓冲面多次构建的应用效率需求,阐明了关键采样点与滚动球半径对TIN_DDM缓冲面构建效率的影响规律;设计了TIN_DDM缓冲面构建关键采样点的判定准则,建立了关键采样点与滚动球半径的数值关联关系;提出了一种基于滚动球加速优化模型的TIN_DDM缓冲面快速构建算法,算法时间复杂度为O(n)。试验结果表明:本文算法可实现任意缓冲半径条件下TIN_DDM缓冲面的多次快速构建,且算法精度控制在2σ内。  相似文献