Factors influencing the oxidation,reduction, methylation and demethylation of mercury species in coastal waters     

Lindsay Whalin  Eun-Hee Kim  Robert Mason 《Marine Chemistry》2007

The objective of this study was to examine the redox reactions and other transformations of mercury (Hg) species in surface waters, and the factors determining the rates of these reactions. For the redox studies completed at the Chesapeake Biological Laboratory (CBL), two isotopes (¹⁹⁹Hg^II and ²⁰²Hg⁰) were added into different types of filtered water (fresh to seawater) to examine the oxidation and reduction reactions. Further studies of both the redox reactions and methylation/demethylation reactions of Hg were conducted with unfiltered water on board research vessels during cruises in May and July 2005 on the Chesapeake Bay and shelf. While CH₃¹⁹⁹Hg^II was added to allow the examination of demethylation, ²⁰¹Hg^II was used to examine both reduction and methylation, and ²⁰²Hg⁰ was used to examine oxidation. Overall, the results showed that both Hg oxidation and reduction were simultaneously occurring and were photochemically mediated in the waters investigated. In contrast to the previously assumed “unreactive” nature of Hg⁰, the studies found that the magnitude of the rate constant for Hg⁰ oxidation was greater than that for reduction, indicating its importance in estuarine and coastal waters. In addition, both experiments at CBL and on board ship showed that Hg^II reduction was similar in magnitude, suggesting that biotic processes were relatively unimportant. While no measurable methylation occurred during the incubation period during the on board studies, concentration of CH₃¹⁹⁹Hg^II decreased over the time during the experiments. It appeared that the demethylation processes were not dominantly photochemically driven, but could be microbially mediated. Further studies are needed in order to help better understand Hg redox and transformations in natural water systems.  相似文献   

Geochemical tables: H. J. Rösler and H. Lange. Elsevier, Amsterdam, 1972, 468 pp., 216 tables, 136 fig., Dfl. 80.00     

B. Mason 《Marine Chemistry》1973,1(4):330

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Surface-layer flow in complex terrain: Comparison of models and full-scale observations   总被引：2，自引：0，他引：2  

John L. Walmsley  Ib Troen  Demetrius P. Lalas  Paul J. Mason 《Boundary-Layer Meteorology》1990,52(3):259-281

Four models of surface boundary-layer flow in complex terrain are compared with observations made at Blashaval Hill, North Uist, Scotland. The field experiment is described by Mason and King (1985). Three of the models are derived from the two-dimensional theory of Jackson and Hunt (1975) and are described in Mason and King (1985), Walmsley et al. (1986) and Troen and Petersen (1989). The fourth is a mass-consistent code based on Traci et al. (1979). The model results are in good agreement with each other and are generally within the observed range of variation ( ~ ± 16%) in normalized wind speed. For most wind direcions (7 of 11), model results of normalized wind speed at the summit were within 7% of the observed mean values. For some wind directions, calculations using the Guidelines of Walmsley et al. (1989) suggested that variations in surface roughness were important. This led us to apply one of our models incorporating nonuniform surface roughness. The lack of significant improvement for cases when water lay upstream of Blashaval Hill is attributed to compensating changes at summit and reference sites and to very local effects on the wind data. Sensitivity to topography lying to the west and northwest of Blashaval was also investigated. Results suggested an influence from those distant topographic features for some wind directions. When those features were incorporated, maximum errors in normalized wind speed at the summit were reduced from 18 to 13%.  相似文献   

The Vivian Thompson Stereo-planigraph     

Kenneth  Mason 《The Photogrammetric Record》1975,8(45):371-371

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A 500 hPa synoptic wildland fire climatology for large Canadian forest fires, 1959–1996     

W. R. Skinner  M. D. Flannigan  B. J. Stocks  D. L. Martell  B. M. Wotton  J. B. Todd  J. A. Mason  K. A. Logan  E. M. Bosch 《Theoretical and Applied Climatology》2002,71(3-4):157-169

Summary In Canada, the average annual area of burned forest has increased from around 1 million ha in the 1970’s to over 2.5 million ha in the 1990’s. A previous study has identified the link between anomalous mid-tropospheric circulation at 500 hPa over northern North America and wildland fire severity activity in various large regions of Canada over the entire May to August fire season. In this study, a northern North American study region of the hemispheric gridded 5° latitude by 10° longitude 500 hPa dataset is identified and analysed from 1959 to 1996 for a sequence of six monthly periods through the fire season, beginning in April and ending in September. Synoptic types, or modes of upper air behavior, are determined objectively by the eigenvector method employing K-means cluster analysis. Monthly burned areas from the Canadian Large Fire Database (LFDB) for the same period, 1959 to 1996, are analysed in conjunction with the classified monthly 500 hPa synoptic types. Relationships between common monthly patterns of anomalous upper flow and spatial patterns of large fire occurrence are examined at the ecozone level. Average occurrence of a monthly synoptic type associated with very large area burned is approximately 18% of the years from 1959 to 1996. The largest areas burned during the main fire (May to August) season occur in the western Boreal and Taiga ecozones – the Taiga Plains, Taiga Shield, Boreal West Shield and Boreal Plains. Monthly burned areas are also analysed temporally in conjunction with a calculated monthly zonal index (Zi_m) for two separate areas defined to cover western and eastern Canada. In both western and eastern Canada, high area burned is associated with synoptic types with mid-tropospheric ridging in the proximity of the affected region and low Zi_m with weak westerlies and strong meridional flow over western Canada. Received April 3, 2001 Revised July 13, 2001  相似文献   

Climate change impacts on U.S. Coastal and Marine Ecosystems   总被引：1，自引：0，他引：1  

Donald Scavia  John C. Field  Donald F. Boesch  Robert W. Buddemeier  Virginia Burkett  Daniel R. Cayan  Michael Fogarty  Mark A. Harwell  Robert W. Howarth  Curt Mason  Denise J. Reed  Thomas C. Royer  Asbury H. Sallenger  James G. Titus 《Estuaries and Coasts》2002,25(2):149-164

Increases in concentrations of greenhouse gases projected for the 21st century are expected to lead to increased mean global air and ocean temperatures. The National Assessment of Potential Consequences of Climate Variability and Change (NAST 2001) was based on a series of regional and sector assessments. This paper is a summary of the coastal and marine resources sector review of potential impacts on shorelines, estuaries, coastal wetlands, coral reefs, and ocean margin ecosystems. The assessment considered the impacts of several key drivers of climate change: sea level change; alterations in precipitation patterns and subsequent delivery of freshwater, nutrients, and sediment; increased ocean temperature; alterations in circulation patterns; changes in frequency and intensity of coastal storms; and increased levels of atmospheric CO₂. Increasing rates of sea-level rise and intensity and frequency of coastal storms and hurricanes over the next decades will increase threats to shorelines, wetlands, and coastal development. Estuarine productivity will change in response to alteration in the timing and amount of freshwater, nutrients, and sediment delivery. Higher water temperatures and changes in freshwater delivery will alter estuarine stratification, residence time, and eutrophication. Increased ocean temperatures are expected to increase coral bleaching and higher CO₂ levels may reduce coral calcification, making it more difficult for corals to recover from other disturbances, and inhibiting poleward shifts. Ocean warming is expected to cause poleward shifts in the ranges of many other organisms, including commercial species, and these shifts may have secondary effects on their predators and prey. Although these potential impacts of climate change and variability will vary from system to system, it is important to recognize that they will be superimposed upon, and in many cases intensify, other ecosystem stresses (pollution, harvesting, habitat destruction, invasive species, land and resource use, extreme natural events), which may lead to more significant consequences.  相似文献   

Late Pliocene to late Pleistocene environments preserved at the Palisades Site, central Yukon River, Alaska     

Paul Matheus  James BegétOwen Mason  Carol Gelvin-Reymiller 《Quaternary Research》2003,60(1):33-43

The Palisades Site is an extensive silt-loam bluff complex on the central Yukon River preserving a nearly continuous record of the last 2 myr. Volcanic ash deposits present include the Old Crow (OCt; 140,000 yr), Sheep Creek (SCt; 190,000 yr), PA (2.02 myr), EC (ca. 2 myr), and Mining Camp (ca. 2 myr) tephras. Two new tephras, PAL and PAU, are geochemically similar to the PA and EC tephras and appear to be comagmatic. The PA tephra occurs in ice-wedge casts and solifluction deposits, marking the oldest occurrence of permafrost in central Alaska. Three buried forest horizons are present in association with dated tephras. The uppermost forest bed occurs immediately above the OCt; the middle forest horizon occurs below the SCt. The lowest forest bed occurs between the EC and the PA tephras, and correlates with the Dawson Cut Forest Bed. Plant taxa in all three peats are common elements of moist taiga forest found in lowlands of central Alaska today. Large mammal fossils are all from common late Pleistocene taxa. Those recovered in situ came from a single horizon radiocarbon dated to ca. 27,000 ¹⁴C yr B.P. The incongruous small mammal assemblage in that horizon reflects a diverse landscape with both wet and mesic environments.  相似文献   

The making of Stars 'R' Us!     

Serena Viti  Wendy Brown  Martin McCoustra  Helen Fraser  Nigel Mason  Robert Massey 《Astronomy& Geophysics》2004,45(6):6.22-6.24

The team behind a successful project to broaden the understanding of astrochemistry – Serena Viti, Wendy Brown, Martin McCoustra, Helen Fraser, Nigel Mason and Robert Massey – recount how they went about it and what benefits resulted.  相似文献   

Riparian perspectives of international cooperation in the Eastern Nile Basin     

Simon A. Mason 《Aquatic Sciences - Research Across Boundaries》2005,67(1):1-2

No Abstract.  .  相似文献   

A mixed finite-element method for solving the poroelastic Biot equations with electrokinetic coupling     

C. C. Pain  J. H. Saunders  M. H. Worthington  J. M. Singer  W. Stuart-Bruges  G. Mason  A. Goddard 《Geophysical Journal International》2005,160(2):592-608

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