The ClBrI composition of 3.23 Ga modified seawater: implications for the geological evolution of ocean halide chemistry     

D.M.DeR. Channer  C.E.J. de Ronde  E.T.C. Spooner 《Earth and Planetary Science Letters》1997,150(3-4)

Fluid inclusion leachates obtained from vug and vein quartz samples from an Archean (3.23 Ga) Fe-oxide hydrothermal deposit in the west-central part of the Barberton greenstone belt, South Africa, were analyzed by ion chromatography for chloride, bromide, and iodide. The deposit, known as the ironstone pods, formed by seafloor hydrothermal activity and fluid discharge. Quartz is dominated by type I liquid-vapor, aqueous inclusions with a bimodal salinity distribution (0–0.25 M_Cl⁻ and 0.9–1.8 M_Cl⁻). Bulk analytical salinities range from 0.45 to 0.99 M_Cl⁻ represent averages of type I inclusions. Bulk fluid inclusion bromide and iodide concentrations are 1.44–3.32 mM and 0.01–0.12 mM, respectively. For comparison, modern seawater has halogen contents of 590 mM chloride, 0.9 mM bromide, and 0.5 μM total iodine. In the fluids from the ironstone pods, bromide and iodide are enriched relative to chloride, when compared with modern seawater.Approximate Br⁻Cl⁻ and I⁻Cl⁻ ratios of 3.2 Ga Barberton seawater are 2.5 × 10⁻³ and 40 × 10⁻⁶, respectively. Dispersion to higher values was caused principally by reaction with organic sediments whose trends are similar to those seen for modern vent fluids at unsedimented and sedimented ridges, relative to modern seawater. These halide ratios are greater than those of modern seawater, suggesting a change in the halide ratios of seawater over geological time. The analytical data are consistent with a model in which marine organic sedimentation has fractionated bromine and iodine out of seawater relative to chloride, thereby causing the halide ratios of seawater to decrease from high early and mid-Archean values towards their present day values.  相似文献   

Greenhouse Gas Emissions from Hydroelectric Reservoirs in Tropical Regions   总被引：2，自引：1，他引：2  

Luiz Pinguelli Rosa  Marco Aurelio dos Santos  Bohdan Matvienko  Ednaldo Oliveira dos Santos  Elizabeth Sikar 《Climatic change》2004,66(1-2):9-21

This paper discusses emissions by power-dams in the tropics. Greenhouse gas emissions from tropical power-dams are produced underwater through biomass decomposition by bacteria. The gases produced in these dams are mainly nitrogen, carbon dioxide and methane. A methodology was established for measuring greenhouse gases emitted by various power-dams in Brazil. Experimental measurements of gas emissions by dams were made to determine accurately their emissions of methane (CH₄) and carbon dioxide (CO₂) gases through bubbles formed on the lake bottom by decomposing organic matter, as well as rising up the lake gradient by molecular diffusion.The main source of gas in power-dams reservoirs is the bacterial decomposition (aerobic and anaerobic) of autochthonous and allochthonous organic matter that basically produces CO₂ and CH₄. The types and modes of gas production and release in the tropics are reviewed.  相似文献   

Countergradient Fluxes of Conserved Variables in the Clear convective and Stratocumulus-topped Boundary Layer: The role of the Entrainment Flux     

Stephan R. de Roode  Harm J. J. Jonker  Peter G. Duynkerke  Bjorn Stevens 《Boundary-Layer Meteorology》2004,112(1):179-196

Large-eddy simulations of a clear convective boundary layer (CBL)and a stratocumulus-topped boundary layer are studied. Bottom-upand a top-down scalars were included in the simulations, and theprinciple of linear superposition of variables was applied toreconstruct the fields of any arbitrary conserved variable.This approach allows a systematic analysis of countergradient fluxesas a function of the flux ratio, which is defined as the ratio betweenthe entrainment flux and the surface flux of the conserved quantity.In general, the turbulent flux of an arbitrary conserved quantityis counter to the mean vertical gradient if the heights where thevertical flux and the mean vertical gradient change sign do notcoincide. The regime where the flux is countergradient is thereforebounded by the so-called zero-flux and zero-gradient heights. Becausethe vertical flux changes sign only if the entrainment flux has anopposite sign to the surface flux, countergradient fluxes arepredominantly found for negative flux ratios. In the CBL the fluxratio for the virtual potential temperature is, to a good approximation,constant, and equal to -0.2. Only if the moisture contribution to thevirtual potential temperature is negligibly small will the flux ratio forthe potential temperature be equal to this value. Otherwise, theflux ratio for the potential temperature can have any arbitrary(negative) value, and, as a consequence, the fluxes for thepotential temperature and the virtual potential temperature willbe countergradient at different heights. As a practical application ofthe results, vertical profiles of the countergradient correction termfor different entrainment-to-surface-flux ratios are discussed.  相似文献   

Assessment of predictions of the response of the Hualien containment model during forced vibration tests     

J. Enrique Luco  Francisco C. P. de Barros 《Soil Dynamics and Earthquake Engineering》2004,24(12):1013-1035

Blind predictions for the response of the 1/4-scale reinforced concrete Hualien (Taiwan) containment model during forced vibration tests are compared with the observed data. The predictions obtained by the CLASSI approach reflect the experimental conditions prior to and after backfill of the soil surrounding the embedded foundation. The experimental data show a strong and unexpected coupling between the response in the NS and EW directions which is not present in the results for the axisymmetric theoretical models. Also, significant differences can be seen between the experimental responses in the two orthogonal horizontal directions which minimize cross-axis coupling. Although these differences are not accounted for in the theoretical models, the discrepancies between predictions and observations are within the uncertainty of the structural and geotechnical data. The obtained differences between predictions and observations give an excellent measure of the prediction error that can be expected in this type of analysis from uncertainty in the data. A detailed assessment of the initial structural and geotechnical data based on extensive comparisons with the results of previous identification studies is also presented. Finally, comparisons between the observed response and calculations based on revised models for the structure and the soil show that current methods of analysis can account accurately for the observed response.  相似文献   

Non-linear channel–shoal dynamics in long tidal embayments     

G. P. Schramkowski  H. M. Schuttelaars  H. E. de Swart 《Ocean Dynamics》2004,54(3-4):399-407

The dynamics of finite-amplitude bed forms in a tidal channel is studied with the use of an idealized morphodynamic model. The latter is based on depth-averaged equations for the tidal flow over a sandy bottom. The model considers phenomena on spatial scales of the order of the tidal excursion length. Transport of sediment mainly takes place as suspended load. The reference state of this model is characterized by a spatially uniform M₂ tidal current over a fixed horizontal bed. The temporal evolution of deviations from this reference state is governed by amplitude equations: these are a set of non-linear equations that describe the temporal evolution of bed forms. These equations are used to obtain new morphodynamic equilibria which may be either static or time-periodic. Several of these bottom profiles show strong similarity with the tidal bars that are observed in natural estuaries. The dependence of the equilibrium solutions on the value of bottom friction and channel width is investigated systematically. For narrow channels (width small compared to the tidal excursion length) stable static equilibria exist if bottom friction is slightly larger than r_cr. For channel widths more comparable to the tidal excursion length, multiple stable steady states may exist for bottom friction parameter values below r_cr. Regardless of channel width, stable time-periodic equilibria seem to emerge as the bottom friction is increased.Responsible Editor: Jens Kappenberg  相似文献   

A model for grain-size sorting over tidal sand ridges     

M. Walgreen  H.E. de Swart  D. Calvete 《Ocean Dynamics》2004,54(3-4):374-384

A model was developed and analyzed to quantify the effect of graded sediment on the formation of tidal sand ridges. Field data reveal coarse (fine) sediment at the crests (in the troughs), but often phase shifts between the mean grain-size distribution and the bottom topography occur. Following earlier work, this study is based on a linear stability analysis of a basic state with respect to small bottom perturbations. The basic state describes an alongshore tidal current on a coastal shelf. Sediment is transported as bed load and dynamic hiding effects are accounted for. A one-layer model for the bed evolution is used and two grain size classes (fine and coarse sand) are considered. Results indicate an increase in growth and migration rates of tidal sand ridges for a bimodal mixture, whilst the wavelength of the ridges remains unchanged. A symmetrical externally forced tidal current results in a grain-size distribution which is in phase with the ridges. Incorporation of an additional external M₄ tidal constituent or a steady current results in a phase shift between the grain-size distribution and ridge topography. These results show a general agreement with observations. The physical mechanism responsible for the observed grain-size distribution over the ridges is also discussed.Responsible Editor: Jens Kappenberg  相似文献   

Neuralizing target superresolution algorithms   总被引：1，自引：0，他引：1  

Collins  M. de Jong  M. 《Geoscience and Remote Sensing Letters, IEEE》2004,1(4):318-321

Tatem et al. (2001) have designed a Hopfield network-based algorithm for superresolving discrete targets that are larger than the sample spacing of an image. The algorithm iteratively minimizes a criterion function that contains a sigmoidal activation term. We have altered their algorithm to bring it in line with Hopfield's original network by reducing the pseudotemperature of the sigmoid. We found that smaller values of the pseudotemperature lead to faster convergence to a solution and resulting solutions that are more accurate.  相似文献   

Reversibility of radiocaesium sorption on illite     

Arjan de Koning  Rob N.J Comans 《Geochimica et cosmochimica acta》2004,68(13):2815-2823

Adsorption of trace amounts of radiocaesium on NH₄-, K-, and Na-saturated Fithian illite and subsequent desorption by 1 M NH₄ showed that a substantial amount of radiocaesium (44%, 46%, and 91% for NH₄-, K-, and Na-illite, respectively) cannot be desorbed after only 5 min of adsorption. Our results suggest that this instantaneous fixation is caused by the collapse of the frayed edges of the clay mineral and the relatively high concentration of radiocaesium building up in solution in the batch desorption experiments. Consequently, commonly applied high-NH₄ extractions underestimate truly exchangeable amounts of radiocaesium in soils and sediments containing illitic clay minerals. The rate of desorption of trace amounts of radiocaesium from the solids using high NH₄ or Cs concentrations has a half-life of about 2 yr, reflecting radiocaesium desorption from (partially) collapsed interlayers. Extraction of radiocaesium from illite after 5 min of contact time with a Cs-selective adsorbent or a 1 × 10^-6 M CsCl solution shows that 100% of the bound radiocaesium is readily available. The desorption rate in the presence of a Cs-selective adsorbent has a half-life of about 0.2 yr. Desorption of radiocaesium from illite using different ammonium concentrations shows that radiocaesium partitioning follows reversible ion-exchange theory if the NH₄ concentration is below 1 × 10^-4 M, and sufficient time (weeks) is allowed for the reaction to proceed. Thus, radiocaesium sorption reversibility in the natural environment is much higher than generally assumed, and equilibrium solid/liquid partitioning may be assumed for the long-term modelling of radiocaesium mobility in the natural environment. In the particular case of anoxic freshwater sediments with very high NH₄ concentrations in the pore waters (up to several mmol.L^-1), collapse of the frayed edges of illite may occur, influencing radiocaesium partitioning. If collapse occurs before radiocaesium adsorbs to illite, high caesium sorption reversibility as measured by high-NH₄ extraction can be expected because further collapse of the frayed edges during the extraction procedure will be limited. This effect has indeed been observed earlier in the extraction of radiocaesium from anoxic freshwater sediments with high-NH₄ solutions and was as yet unexplained.  相似文献   

Beryllium-10 in Australasian tektites: Constraints on the location of the source crater     

P. Ma  K. Aggrey  C. Tonzola  C. Schnabel  P. de Nicola  J.T. Wasson  L. Brown  R. Middleton 《Geochimica et cosmochimica acta》2004,68(19):3883-3896

By using accelerator mass spectrometry we have measured the ¹⁰Be concentrations of 86 Australasian tektites. Corrected to the time of tektite production ∼0.8 My ago, the ¹⁰Be concentrations (10⁶ atom/g) range from 59 for a layered tektite from Huai Sai, Thailand, to 280 for an australite from New South Wales, Australia. The average value is 143 ± 50. When tektites are sorted by country, their average measured ¹⁰Be concentrations increase slowly with increasing distance from Southeast Asia, the probable location of the tektite producing event, from 59 ± 9 for 6 layered tektites from Laos to 136 ± 20 for 20 splash-form tektites from Australia. The lowest ¹⁰Be concentrations for tektites fall on or within a contour centered off the shore of Vietnam, south of the Gulf of Tonkin (107°E; 17°N), but also encompassing two other locations in the area of northeastern Thailand previously proposed for the site of a single tektite-producing impact. The ¹⁰Be concentrations of layered tektites show only a weak anticorrelation (R ∼ −0.3) with the numbers of relict crystalline inclusions.Loosely consolidated, fine-grained terrestrial sediments or recently consolidated sedimentary rocks are the most likely precursor materials. Dilution of sediments with other kinds of rock raises problems in mixing and is not supported by petrographic data. Sedimentary columns that have the right range of ¹⁰Be concentrations occur off the coasts of places where sedimentation rates are high relative to those in the deep sea. A single impact into such a region, 15 to 300 m thick, could have propelled near-surface, high-¹⁰Be material farthest—to Australia—while keeping the deeper-lying, low-¹⁰Be layers closer to home. We do not rule out, however, other proposed mechanisms for tektite formation.  相似文献   

Magnetic fabrics and rock magnetism of Proterozoic dike swarm from the southern São Francisco Craton, Minas Gerais State, Brazil     

Maria Irene Bartolomeu Raposo  Alexandre O. Chaves  Paulo Lojkasek-Lima  Manoel Souza D'Agrella-Filho  Wilson Teixeira   《Tectonophysics》2004,378(1-2):43-63

Magnetic fabric and rock magnetism studies were performed on 32 mafic dikes of a Proterozoic dike swarm from the southern São Francisco Craton (SFC; Minas Gerais State, SE Brazil). Magnetic anisotropies were determined by applying anisotropy of low-field magnetic susceptibility (AMS) and anisotropy of remanent magnetization (ARM). The latter was performed imposing both anhysteretic (total (AAR) and partial pAAR)) and isothermal remanence magnetizations (AIRM). Partial anhysteretic remanence anisotropy was performed based on remanent coercivity spectra from a pilot specimen of each site. In most sites, AMS is dominantly carried by ferromagnetic minerals, however, in some sites, the paramagnetic contribution exceeds 70% of bulk susceptibility. Rock magnetism and thin section analysis allow classifying the dikes as non-hydrothermalized and hydrothermalized. Magnetic measurement shows that the mean magnetic susceptibility is usually lower than 5×10⁻³ (SI). Ti-poor titanomagnetites up to pure magnetite pseudo-single-domain (PSD) grain sizes carry the majority of magnetic fabrics for non-hydrothermalized dikes whereas coarse to fine grained Ti-poor titanomagnetites carry the majority of magnetic fabrics for hydrothermalized dikes.Three primary AMS fabrics are recognized which are coaxial with ARM fabric, except for two dikes, from both non-hydrothermalized and hydrothermalized dikes. Normal AMS fabric surprisingly is not dominant (31%). The parallelism between AMS, pAAR_0–30, pAAR_30–60 and pAAR_60–90 fabrics in the hydrothermalized dikes indicates that magnetic grains formed due to late-stage crystallization or to remobilization of iron oxides due to hydrothermal alteration after dike emplacement have acquired a mimetic fabric coaxial with the primary fabric given by coarse-grained early crystallized Ti-poor titanomagnetites. This fabric is interpreted as magma flow in which the analysis of K_max inclination permitted the inference that the dikes were fed by horizontal or subhorizontal fluxes (K_max<30°). Intermediate AMS fabric is the most important (41%) in the investigated swarm. It is interpreted as due to vertical compaction of a static magma column with the minimum stress along the dike strike. ARM determinations for these sites also remained intermediate except for two dikes. In one of them, AIRM fabric resulted in normal AMS fabric while for the other AAR fabric resulted in inverse AMS fabric. A combination of AMS and ARM fabrics suggest that magmatic fabric for both dikes were overprinted by some late local event, probably related to Brasiliano orogenic processes after dike emplacement. InverseInverse AMS fabric is a minority (four dikes). ARM determinations also remained inverse suggesting a primary origin for inverse AMS fabric.  相似文献