Diffuse Emission of CO2 from Showa-Shinzan, Hokkaido, Japan: A Sign of Volcanic Dome Degassing   总被引：1，自引：0，他引：1  

Pedro A. Hernández  Kenji Notsu  Hiromu Okada  Toshiya Mori  Masanori Sato  Francisco Barahona  Nemesio M. Pérez 《Pure and Applied Geophysics》2006,163(4):869-881

Two soil CO₂ efflux surveys were carried out in September 1999 and June 2002 to study the spatial distribution of diffuse CO₂ degassing and estimate the total CO₂ output from Showa-Shinzan volcanic dome, Japan. Seventy-six and 81 measurements of CO₂ efflux were performed in 1999 and 2002, respectively, covering most of Showa-Shinzan volcano. Soil CO₂ efflux data showed a wide range of values up to 552 g m^-2 d^-1. Carbon isotope signatures of the soil CO₂ ranged from -0.9‰ to -30.9‰, suggesting a mixing between different carbon reservoirs. Most of the study area showed CO₂ efflux background values during the 1999 and 2002 surveys (B = 8.2 and 4.4 g m^-2 d^-1, respectively). The spatial distribution of CO₂ efflux anomalies for both surveys showed a good correlation with the soil temperature, indicating a similar origin for the extensive soil degassing generated by condensation processes and fluids discharged by the fumarolic system of Showa-Shinzan. The total diffuse CO₂ output of Showa-Shinzan was estimated to be about 14.0–15.6 t d^-1 of CO₂ for an area of 0.53 km².  相似文献   

The LMDZ4 general circulation model: climate performance and sensitivity to parametrized physics with emphasis on tropical convection   总被引：3，自引：11，他引：3  

Frédéric Hourdin  Ionela Musat  Sandrine Bony  Pascale Braconnot  Francis Codron  Jean-Louis Dufresne  Laurent Fairhead  Marie-Angèle Filiberti  Pierre Friedlingstein  Jean-Yves Grandpeix  Gerhard Krinner  Phu LeVan  Zhao-Xin Li  François Lott 《Climate Dynamics》2006,27(7-8):787-813

The LMDZ4 general circulation model is the atmospheric component of the IPSL–CM4 coupled model which has been used to perform climate change simulations for the 4th IPCC assessment report. The main aspects of the model climatology (forced by observed sea surface temperature) are documented here, as well as the major improvements with respect to the previous versions, which mainly come form the parametrization of tropical convection. A methodology is proposed to help analyse the sensitivity of the tropical Hadley–Walker circulation to the parametrization of cumulus convection and clouds. The tropical circulation is characterized using scalar potentials associated with the horizontal wind and horizontal transport of geopotential (the Laplacian of which is proportional to the total vertical momentum in the atmospheric column). The effect of parametrized physics is analysed in a regime sorted framework using the vertical velocity at 500 hPa as a proxy for large scale vertical motion. Compared to Tiedtke’s convection scheme, used in previous versions, the Emanuel’s scheme improves the representation of the Hadley–Walker circulation, with a relatively stronger and deeper large scale vertical ascent over tropical continents, and suppresses the marked patterns of concentrated rainfall over oceans. Thanks to the regime sorted analyses, these differences are attributed to intrinsic differences in the vertical distribution of convective heating, and to the lack of self-inhibition by precipitating downdraughts in Tiedtke’s parametrization. Both the convection and cloud schemes are shown to control the relative importance of large scale convection over land and ocean, an important point for the behaviour of the coupled model.  相似文献   

Trace Metal Solid State Speciation in Aerosols of the Northern Levantine Basin,East Mediterranean   总被引：3，自引：0，他引：3  

Mustafa Koçak  Nilgun Kubilay  Barak Herut  Malcolm Nimmo 《Journal of Atmospheric Chemistry》2007,56(3):239-257

An established three stage sequential leach scheme was applied to a series of selected high volume aerosol samples (n = 35) collected from the Turkish Eastern Mediterranean coastline (Erdemli). Samples were selected according to their air mass back trajectory history to reflect the contrasting mixtures of aerosol material present in the Eastern Mediterranean marine aerosol. Two populations were adopted, those samples which were classed as “anthropogenic” and those which were “Saharan” dominated aerosol populations. Applying the three stage leach it was possible to define the proportion for each of the considered metals (Al, Fe, Cu, Pb, Cd, Zn and Mn) present in the (a) “exchangeable” (b) “carbonate / oxide” and (c) “refractory” phases, representing novel solid state aerosol speciation data for this marine system. Clear trends were established, conforming with data from previous studies with mainly crustal derived metals (Al and Fe) being present in the refractory phases (Al > 88%; Fe > 84%) and those influenced by anthropogenic sources being dominating in the exchangeable phase, although for these metals the variability was comparatively high (12–64%; 19–85%; 40–100% for Zn, Pb and Cd, respectively). For the majority, greater exchangeable fractions were present the lower the crustal source contribution to the aerosol population, whereas the “refractory” fraction exhibited contrasting behaviour. This was illustrated by the novel application of the mixing diagram, presenting each of the three speciation stages against the corresponding percent anthropogenic contribution to each collected sample. Zn, Pb and Cd all illustrated progressive decrease in the percent exchangeable with increasing crustal contribution to the aerosol population. The percent exchangeable was discussed in terms of its use to represent the upper limit of the bioavailable fraction of metal associated with the aerosol, post deposition. The mixing diagram approach enabled the prediction of the residual fractions for Cd, Pb and Zn (41 ± 4%; 62 ± 4% and 82 ± 5%, respectively,) in Saharan end-member material.  相似文献   

Decoupling of arsenic and iron release from ferrihydrite suspension under reducing conditions: a biogeochemical model     

André Burnol  Francis Garrido  Philippe Baranger  Catherine Joulian  Marie-Christine Dictor  Françoise Bodénan  Guillaume Morin  Laurent Charlet 《Geochemical transactions》2007,8(1):12

High levels of arsenic in groundwater and drinking water are a major health problem. Although the processes controlling the release of As are still not well known, the reductive dissolution of As-rich Fe oxyhydroxides has so far been a favorite hypothesis. Decoupling between arsenic and iron redox transformations has been experimentally demonstrated, but not quantitatively interpreted. Here, we report on incubation batch experiments run with As(V) sorbed on, or co-precipitated with, 2-line ferrihydrite. The biotic and abiotic processes of As release were investigated by using wet chemistry, X-ray diffraction, X-ray absorption and genomic techniques. The incubation experiments were carried out with a phosphate-rich growth medium and a community of Fe(III)-reducing bacteria under strict anoxic conditions for two months. During the first month, the release of Fe(II) in the aqueous phase amounted to only 3% to 10% of the total initial solid Fe concentration, whilst the total aqueous As remained almost constant after an initial exchange with phosphate ions. During the second month, the aqueous Fe(II) concentration remained constant, or even decreased, whereas the total quantity of As released to the solution accounted for 14% to 45% of the total initial solid As concentration. At the end of the incubation, the aqueous-phase arsenic was present predominately as As(III) whilst X-ray absorption spectroscopy indicated that more than 70% of the solid-phase arsenic was present as As(V). X-ray diffraction revealed vivianite Fe(II)₃(PO₄)₂.8H₂O in some of the experiments. A biogeochemical model was then developed to simulate these aqueous- and solid-phase results. The two main conclusions drawn from the model are that (1) As(V) is not reduced during the first incubation month with high Eh values, but rather re-adsorbed onto the ferrihydrite surface, and this state remains until arsenic reduction is energetically more favorable than iron reduction, and (2) the release of As during the second month is due to its reduction to the more weakly adsorbed As(III) which cannot compete against carbonate ions for sorption onto ferrihydrite. The model was also successfully applied to recent experimental results on the release of arsenic from Bengal delta sediments.  相似文献   

Sources of dissolved REE in mountainous streams draining granitic rocks, Sierras Pampeanas (Córdoba, Argentina)   总被引：1，自引：0，他引：1  

M. Gabriela García  Karina L. Lecomte  Andrea I. Pasquini  Stella M. Formica  Pedro J. Depetris 《Geochimica et cosmochimica acta》2007,71(22):5355-5368

Stream waters draining granitic terrains from the highest part (850 to 2200 m a.s.l.) of Sierras Pampeanas (Córdoba, Argentina, ∼32°S, ∼65°W) were sampled in order to define sources and distribution of dissolved rare earth elements (REE), and to describe the geochemical processes that govern their mobility. The contribution of the regional granite to the dissolved REE pool in stream water is limited due to the physical conditions predominating in the area (i.e., steep slopes and semiarid climate). Therefore, precipitation is considered a seasonally significant source controlling REE concentration in stream water. Dissolved REE concentrations are inversely correlated with monthly precipitation and rainfall frequency. During the rainy season (i.e., the austral summer) REE concentrations in stream water are lower than during the dry season (i.e., austral winter). Such low concentrations reflect the balance between the REE input from precipitation and their removal by adsorption. In contrast, during the dry season, the longer residence time of water within fractures and colluvium determines an increased REE concentration in the base flow. Lower pH values also contribute to raise REE concentration through desorption from mineral surfaces.  相似文献   

Post-collisional transition from calc-alkaline to alkaline magmatism during transcurrent deformation in the southernmost Dom Feliciano Belt (Braziliano–Pan-African, Uruguay)     

Pedro Oyhantabal  Siegfried Siegesmund  Klaus Wemmer  Robert Frei  Paul Layer 《Lithos》2007,98(1-4):141-159

In the southernmost Dom Feliciano Belt of Uruguay, highly fractionated calc-alkaline granites, mildly alkaline granites, shoshonitic volcanics, and peralkaline intrusions and volcanics are spatially and temporal associated with the evolution of shear zones. Four representative magmatic unites of this diverse association were petrographic and geochemically investigated: the Solís de Mataojo Complex, a medium to high K2O calc-alkaline granite with signature typical of mature continental arcs and post-collisional settings; the Maldonado granite, highly fractionated calc-alkaline to alkaline, with characteristics that are transitional between both types of series; the Pan de Azúcar Pluton, with characteristics typical of post-collisional alkaline granites and the Las Flores shoshonitic basalts.

Geochemistry and geotectonic setting point out that slab breakoff was most likely the mechanism associated with the generation of high-K calc-alkaline magmas (Solís de Mataojo and Maldonado) shortly after collision. Extension associated to the formation of molassic basins and emplacement of dolerites and basalt flows with shoshonitic affinity (Las Flores) 15and finally a shift to magmas with alkaline signatures (Pan de Azúcar) simultaneous with a second transpressional phase were probably linked with lithospheric thinning through delamination. This evolution took place between 615 and 575 Ma, according to available data. Contrary to previous proposals, which considered this magmatism to represent the root of a continental magmatic arc, a post-collisional environment, transitional from orogenic to anorogenic, during transcurrent deformation is proposed.  相似文献   

Nutrient dynamics in Mediterranean temporary streams: A case study in Pardiela catchment (Degebe River, Portugal)   总被引：1，自引：0，他引：1  

Ana Isabel Lilleb  Manuela Morais  Pedro Guilherme  Rita Fonseca  Antnio Serafim  Ramiro Neves 《Limnologica》2007,37(4):337-348

Most of the streams in the Mediterranean region are temporary, following predictable seasonal of flooding and drying, with a transition from lotic conditions to shallow lentic conditions. The goal of our study was to assess the nitrogen and phosphorus dynamics in channel-bed processes of temporary streams between floods. Results show that, during winter, temperatures ranged between 9.5 and 11.2 °C and oxygen concentration ranged from 8.0 to 9.5 mg L⁻¹, whereas, during summer, temperatures varied between 21.2 and 26.8 °C and oxygen between 1.2 and 5.3 mg L⁻¹, with oxygen depletion in the pools during the night. The nitrate concentrations were far more abundant during winter (February), while ammonium concentration increased after stream fragmentation into pools (especially in July when oxygen depletion conditions favoured ammonification). Results on sediment profiles showed that the most active sediment layers for NH₄-N are the top 2–3 cm, corresponding to the sediment depositional sites of the stream. Phosphate concentrations had larger variability, yet concentrations decreased from winter to spring and increased again in summer, when the shallow water pools were formed. Sediment profiles at the sediment depositional sites showed that PO₄-P was more dynamic in the first 6 cm.

In Mediterranean temporary streams, nutrient dynamics vary seasonally, as the system transits from lotic conditions to shallow lentic conditions, evidencing the regeneration of nutrients from organic and inorganic matter during the flow cessation period.  相似文献   

An immersed boundary method for compressible multiphase flows: application to the dynamics of pyroclastic density currents     

Mattia de’ Michieli Vitturi  Tomaso Esposti Ongaro  Augusto Neri  Maria Vittoria Salvetti  François Beux 《Computational Geosciences》2007,11(3):183-198

  相似文献   

The Population of KPC-Scale Flat-Spectrum Radio Sources     

Pedro Augusto  Peter N. Wilkinson  Ian W.A. Browne 《Astrophysics and Space Science》1998,261(1-4):261-264

In this paper we present a subsample of 55 flat-spectrum radio sources dominated by (∼ 100 mas) kpc-scale structure, selected from a parent sample of 1665 VLA sources. Most are core-jets and 23 are CSO/MSO candidates. Properties of the subsample are discussed. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Non-Linear Gravitational Clustering Using the Zel'dovich Approximation     

Michael Joseph Carr  Pedro Pina Avelino  Paulo Mauricio de Carvalho 《Astrophysics and Space Science》1998,261(1-4):335-336

As an alternative to computationally expensive N-body simulations for gravitional clustering, the Zel'dovich approximation (ZA) was studied in 3D, 2D and 1D. Plots of the density contrast were compared against linear theory and the exact solution. The ZA was found to perform very well in the linear regime, better than linear theory, and to give a good approximation well into the non-linear regime. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献