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61.
A number of samples from the A0, A2, B and C horizons have been collected from podzolic soils in the Lake Gosciaz catchment in central Poland. The catchment is very uniform consisting of 2–6-m-high sand dunes with sparse stands of pine and a grass undervegetation. Radiocarbon dates of fossil soils covered by dune sand, within the same type of environment as the Lake Gosciaz catchment, indicate that the main dune-forming phase is of Older Dryas age. Magnetic measurements have been carried out on bulk samples and on particle size fractions from the different soil horizons. With respect to our mineral magnetic study it can be concluded that the soils are very uniform over the entire catchment. Relatively high concentrations of magnetic grains are found in the humus layer, particularly in the <4 μm size fraction, as indicated by the highest X, Xfd, SIRM and HIRM values. The most likely mechanism for the magnetic enhancement in these podzolic top soils is continued burning processes. Low magnetic concentrations in the A2 horizon are due to eluviation and chelation. Local conditions can lead to a range of magnetic minerals precipitating in the B horizon.  相似文献   
62.
In the 1920's the Swedish geologist Lennart von Post found evidence of irregular early Holocene isostatic uplift in the region northwest of Lake Vänern in western Sweden. von Post based his conclusions on levellings of ancient shore lines. These were indirectly dated by pollen stratigraphical investigations in basins situated at approximately the same altitudes as the shore lines. To test von Post's hypothesis, we have adopted a different methodological approach. The sediments in twelve small lake basins, within five minor areas in this region, have been investigated with respect to when they became isolated from ancient Lake Vänern. Initially all the lake thresholds were levelled. Altitudes range between 165 and 96 m above sea level. By combining the results of mineral magnetic and diatom stratigraphical analyses it has been possible to determine the level in the sediment when the basin became isolated. The 14C age of this isolation level has been inferred from AMS dates based on the NaOH-soluble fraction of bulk sediment, partly with very low organic content. Altogether, 36 radiocarbon datings have been carried out, ranging from 10080 to 8800 14C years BP. Pollen analyses, and subsequent correspondence analysis (CA) of all pollen spectra, were carried out around the isolation level in each basin as a complement to the AMS datings.If the region had been subject to irregular isostatic uplift, lakes at the same altitude in the five areas should have been isolated at different times. The AMS determined isolation ages, corrected according to CA of the pollen stratigraphy and compensated for the relatively higher rebound of the northerly situated sites support von Post's conclusion, from the beginning of this century, that the region northwest of Lake Vänern has been subjected to irregular isostatic uplift.  相似文献   
63.
Moss samples (Pleurozium schreberi) exposed to traffic‐related emission of Pd, Pt and Rh were analysed in this study. Successful elimination of interferences was achieved in the determination of Pd, Pt and Rh mass fractions in these samples using inductively coupled plasma‐tandem mass spectrometry (ICP‐MS/MS). Based on the results, a reliable determination of Pd, Pt and Rh mass fractions in microwave‐digested moss samples was obtained using ammonia (10% NH3 in He) in the collision/reaction cell when 103Rh was measured either on‐mass (103→103) or with mass‐shift (103→171) and mass‐shifts for 108Pd (108→159) and 195Pt (195→229) were used. The ICP‐MS/MS procedure was validated using BCR‐723 (road dust) as a reference material. In addition, a good agreement between the ICP‐MS/MS results and the results obtained with cloud point extraction and quadrupole ICP‐MS was observed for the moss samples.  相似文献   
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In the North Atlantic the Icelandic, the North Sea, and the Newfoundland cod stocks are currently overexploited. Overexploitation also characterised the Northeast Arctic cod stock, but effective management measures introduced in 1990 and the years thereafter have brought this stock within safe biological limits. The Northeast Arctic cod stock is transboundary and shared between Norway and Russia. As guidelines for a sound management strategy of this cod stock in the future, reference points for management are discussed. As a point of departure, a management strategy which fulfils the objectives for fishery policy stated by Norway is analysed. These objectives, focusing on sustainable harvesting, increased profitability and the role of the fishery as employer of labour in rural districts are fundamental in most of the world's fishery nations.The “optimal” strategy is defined as the one which fulfils these in the best way possible. The natural variations are discussed and the biological and economic yield's dependence upon the rate of exploitation are analysed. The analysis shows that the size of the spawning stock should be no less than 500 000 tonnes and that highest yield is obtained through a rate of exploitation of around 17–30% (equivalent to a fishing mortality of about 0.20–0.40). A spawning stock size of 500 000 tonnes should therefore serve as a “limit reference point” and a fishing mortality of about 0.20–0.40 should serve as a “target reference point” in the management of Northeast Arctic cod.The method described may be applied to other demersal stocks to help establish target and limit reference points in order to conduct a sound management.  相似文献   
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Data on the acceleration of an oscillating cylinder in water are analysed by a Kalman extended filter. A hydrodynamical forcing model based upon Morison's equation appears to be reasonable and drag estimation appears simple using simulated data. Estimation based upon real data gives an average drag coefficient decreasing with the oscillation amplitude. An assymetric drag coefficient variation over the oscillation period is estimated.  相似文献   
69.
Fluxes of dissolved forms of iron and manganese across the sediment–water interface were studied in situ in the Gulf of Finland and the Vistula Lagoon (Baltic Sea), and in the Golubaya Bay (Black Sea) from 2001 to 2005. Fluxes were measured using chamber incubations, and sediment cores were collected and sliced to assess the porewater and solid phase metal distribution at different depths. Measured and calculated benthic fluxes of manganese and iron were directed out of sediment for all sites and were found to vary between 70–4450 and 5–1000 µmole m− 2 day− 1 for manganese and iron, respectively. The behavior of the studied metals at various redox conditions in the near-bottom water and in the sediment was the main focus in this study. Our results show the importance of bottom water redox conditions for iron fluxes. We measured no fluxes at oxic conditions, intermediate fluxes at anoxic conditions (up to 200 μmole m− 2 day− 1) and high fluxes at suboxic conditions (up to 1000 μmole m− 2 day− 1). Total dissolved iron fluxes were generally dominated by iron(II). Contribution of iron(III) to the total iron flux did not exceed 20%. Obtained fluxes of manganese at all studied regions showed a linear correlation (r2 = 0.97) to its concentration in the porewater of the top sediment layer (0–5 mm) and did not depend on dissolved oxygen concentrations of bottom water. Organically complexed iron and manganese were in most cases not involved in the benthic exchange processes.  相似文献   
70.
Rates of transformation, recycling and burial of nitrogen and their temporal and spatial variability were investigated in deep-sea sediments of the Porcupine Abyssal Plain (PAP), NE Atlantic during eight cruises from 1996 to 2000. Benthic fluxes of ammonium (NH4) and nitrate (NO3) were measured in situ using a benthic lander. Fluxes of dissolved organic nitrogen (DON) and denitrification rates were calculated from pore water profiles of DON and NO3, respectively. Burial of nitrogen was calculated from down core profiles of nitrogen in the solid phase together with 14C-based sediment accumulation rates and dry bulk density. Average NH4 and NO3-effluxes were 7.4 ± 19 μmol m−2 d−1 (n = 7) and 52 ± 30 μmol m−2 d−1 (n = 14), respectively, during the period 1996–2000. During the same period, the DON-flux was 11 ± 5.6 μmol m−2 d−1 (n = 5) and the denitrification rate was 5.1 ± 3.0 μmol m−2 d−1 (n = 22). Temporal and spatial variations were only found in the benthic NO3 fluxes. The average burial rate was 4.6 ± 0.9 μmol m−2 d−1. On average over the sampling period, the recycling efficiency of the PON input to the sediment was 94% and the burial efficiency hence 6%. The DON flux constituted 14% of the nitrogen recycled, and it was of similar magnitude as the sum of burial and denitrification. By assuming the PAP is representative of all deep-sea areas, rates of denitrification, burial and DON efflux were extrapolated to the total area of the deep-sea floor (>2000 m) and integrated values of denitrification and burial of 8 ± 5 and 7 ± 1 Tg N year−1, respectively, were obtained. This value of total deep-sea sediment denitrification corresponds to 3–12% of the global ocean benthic denitrification. Burial in deep-sea sediments makes up at least 25% of the global ocean nitrogen burial. The integrated DON flux from the deep-sea floor is comparable in magnitude to a reported global riverine input of DON suggesting that deep-sea sediments constitute an important source of DON to the world ocean.  相似文献   
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