Predicting Soil-Water and Soil-Air Transport Properties and Their Effects on Soil-Vapor Extraction Efficiency   总被引：1，自引：0，他引：1  

Tjalfe G. Poulsen  Per Moldrup  Toshiko Yamaguchi  Per Schjønning  Jens Aage Hansen 《Ground Water Monitoring & Remediation》1999,19(3):61-70

Accurate prediction of water and air Iran sport parameters in variably saturated soil is necessary for modeling of soil-vapor extraction (SVE) at soil sites contaminated with volatile organic chemicals (VOCs). An expression for predicting saturated water permeability (k_l,s) in undisturbed soils from the soil total porosity and the field capacity soil-water content was developed by fitting a tortuous-tube fluid flow model to measured water permeability and gas diffusivity data. The new k_l,s expression gave accurate predictions when tested against independent k_l,s data. The k_l,s expression was implemented in the Campbell relative water permeability model to yield a predictive model for water permeability in variably saturated, undisturbed soil. The water permeability model, together with recently developed predictive equations for gas permeability and gas diffusivity, was used in a two-dimensional numerical SVE model that also included non-equilibrium mass transfer of VOC from a separate phase (nonaqueous phase liquid [NAPL]) to the air phase. SVE: calculations showed that gas permeability is likely the most important factor controlling VOC migration and vapor extraction efficiency. Water permeability and gas diffusivity effects became significant at water contents near and above field capacity. The NAPL-air mass transfer coefficient also had large impacts on simulated vapor extraction efficiency. The calculations suggest that realistic SVE models need to include predictive expressions for both conveciive, diffusive. and phase-partitioning processes in natural, undisturbed soils.  相似文献   

Molecular analysis of petroleum derived compounds that adsorb onto gas hydrate surfaces     

Anna E. Borgund  Sylvi Høiland  Tanja Barth  Per Fotland  Kjell M. Askvik 《Applied Geochemistry》2009

Field observations have shown that some streams of water, gas and crude oil do not form gas hydrate plugs during petroleum production even when operating within thermodynamic conditions for hydrate formation. Also, when studied under controlled laboratory conditions, some oils are found to form hydrate dispersed systems whereas others form plugs. Oils with low tendency to form hydrate plugs are believed to contain natural hydrate plug inhibiting components (NICs) that adsorb onto the hydrate surface, making them less water-wet and preventing the particles from agglomerating into large hydrate clusters. The molecular structure of the NICs is currently unknown. In this work, hydrate adsorbing components were extracted from crude oils using freon hydrates as an extraction phase. The fractions were found to be enriched in polar material, and more polar material is associated with hydrates generated in biodegraded crude oils than in non-biodegraded oils. Various fractionation schemes and analytical techniques have been applied in the search for molecular characterisation. The average molecular weights were found to be approximately 500 g/mole. GC–MS chromatograms show a large UCM (Unresolved Complex Mixture). Thus, GC–MS has a limited potential for identification of compounds. A commercial biosurfactant was used as a model compound in the search for similar structures in the extracts. The results from analysis of the hydrate adsorbing components suggest that the type and structure are more important for hydrate morphology than the amount of material adsorbed.  相似文献   

Improving the Coastal Mean Dynamic Topography by Geodetic Combination of Tide Gauge and Satellite Altimetry     

Ole Baltazar Andersen  Karina Nielsen  Per Knudsen  Chris W. Hughes  Rory Bingham  Luciana Fenoglio-Marc 《Marine Geodesy》2013,36(6):517-545

Abstract

The ocean mean dynamic topography (MDT) is the surface representation of the ocean circulation. The MDT may be determined by the ocean approach, which involves temporal averaging of numerical ocean circulation model information, or by the geodetic approach, wherein the MDT is derived using the ellipsoidal height of the mean sea surface (MSS), or mean sea level (MSL) minus the geoid as the geoid. The ellipsoidal height of the MSS might be estimated either by satellite or coastal tide gauges by connecting the tide gauge datum to the Earth-centred reference frame. In this article we present a novel approach to improve the coastal MDT, where the solution is based on both satellite altimetry and tide gauge data using new set of 302 tide gauges with ellipsoidal heights through the SONEL network. The approach was evaluated for the Northeast Atlantic coast where a dense network of GNSS-surveyed tide gauges is available. The typical misfit between tide gauge and satellite or oceanographic MDT was found to be around 9?cm. This misfit was found to be mainly due to small scale geoid errors. Similarly, we found, that a single tide gauge places only weak constraints on the coastal dynamic topography.  相似文献   

Chemical composition and acute toxicity in the water after in situ burning--a laboratory experiment     

Faksness LG  Hansen BH  Altin D  Brandvik PJ 《Marine pollution bulletin》2012,64(1):49-55

The chemical composition and toxicity of a water soluble fraction (WSF) of oil versus the underlying water after in situ burning (ISB), has been studied in a laboratory experiment. A system for allowing water sampling after ISB was developed. Seawater samples and oil were collected prior to and immediately after ISB, and chemical analysis was conducted. The chemical characterization of the water showed that the disappearance of water soluble oil components during ISB was insignificant. Acute toxicity tests with the marine copepod Calanus finmarchicus and Microtox® bioassay was performed to establish LC₅₀/EC₅₀ values of the water. The results were compared with regular WAF systems with unburned weathered oil, and indicated no increase in toxicity in the underlying water after ISB.  相似文献   

From Fish to Jellyfish in the Eutrophicated Limfjorden (Denmark)     

Hans Ulrik Riisgård  Per Andersen  Erik Hoffmann 《Estuaries and Coasts》2012,35(3):701-713

The heavily eutrophicated Limfjorden (Denmark) provides a good illustration of the value of long-term monitoring, especially if this is combined with an experimental, interdisciplinary research approach. Here, we first give a short overview of the environmental status of Limfjorden, including the historical development of nutrient overloading and subsequent oxygen depletion in near-bottom water, and how the annual landings of edible bottom-dwelling fish species (plaice, flounder, eel and others) caught in Limfjorden have decreased from about 2,500 t in the early 1920s to only about 20 t in recent years where the fish have been replaced by an increasing number of especially the moon jellyfish, Aurelia aurita, which mainly preys on zooplankton. Next, we evaluate the ecological consequences of the present high number of jellyfish, based on data from recent years’ research on the abundance of jellyfish, their population dynamics and predation impact. In Limfjorden, the benthic polyp stage of A. aurita ensures a large number of small ephyrae in the early spring and subsequently a large population of adult medusae that control the zooplankton during summer and autumn. The holopelagic invasive ctenophore Mnemiopsis leidyi, which was observed in Limfjorden for the first time in 2007, is a second carnivore adding additional predation pressure of the indigenous A. aurita so that copepods and other mesozooplankton organisms may be virtually absent, as observed in 2008 and 2009 where ciliates made up a substantial part of the zooplankton biomass. Marine environmental management programmes should be aware of the increasing importance of both indigenous and new invasive jellyfish species that may show mass occurrence in especially eutrophicated and over-fished areas.  相似文献   

Spatial and temporal controls on historical channel responses – study of an atypical case: Someşu Mic River,Romania     

Ioana Perşoiu  Maria Rădoane 《地球表面变化过程与地形》2011,36(10):1391-1409

In this paper the spatial and temporal responses of the Some?u Mic River (Romania) to natural and anthropogenic controls over the past 150 years are analysed, based on a series of morphometric parameters extracted from five successive sets of topographic maps and one set of orthophotos. Prior to the intensive hydrotechnical interventions of the last four decades, the river was characterized by a complex alternation of different channel types, resulting in a mixture of alluvial and mixed sinuous – meandering – sinuous anabranched – meandering anabranched reaches, each a few hundred metres to a few kilometres long. The main cause for this spatial behaviour was the local geology. Its effects were intensified by a larger scale slope, slightly higher than along a longitudinal profile with normal concavity, as a consequence of the presence of a 400 m elevation knick‐point located in the catchment area. A generalized maintenance of river in the floodplain perimeter during the entire interval of study (centennial scale), with local planform adjustments and lack of median scale avulsion in lateral tilting areas and along the anabranched reaches, channel lengthening and meander development during hydrological stable periods and channel shortening and increasing of natural cutoffs during periods with higher incidence of floods (decadal scale), and the incapacity of local morphologic changes resulted from human interventions to completely counterbalance general trends (decadal scale), supports the idea of decreasing the amplitude and frequency of important floods, after the end of the Little Ice Age. Channel metamorphosis by canalization, diminishing/elimination of overflows and medium‐scale avulsions by changes in flow regimes (dams) and the presence of dykes in the floodplain perimeter, channel narrowing (43%) and incision (at least after 1945) downstream from dams, and probably because of in‐channel gravel mining are the main anthropically induced changes along the Some?u Mic River. Even if human impact is important, both at the drainage basin scale and along the Some?u Mic River, it has only local impacts, subordinated to climate. The low level of human impact on this river could be the consequence of the higher general slope downstream from 400 m elevation knick‐point, which probably forces the positioning of its effects under an important internal threshold of the fluvial system. This boundary condition defines Some?u Mic River as an atypical river. This study supports the idea that climate has a more important role in the post‐Little Ice Age (LIA) rivers' behaviour than currently accepted. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Distribution of arsenic and its mobility in shallow aquifer sediments from Ambikanagar, West Bengal, India   总被引：1，自引：0，他引：1  

Joyanto Routh  Per Hjelmquist 《Applied Geochemistry》2011,26(4):505-515

Sediments from a core retrieved during installation of a shallow drinking water well in Ambikanagar (West Bengal, India) were analyzed for various physical and chemical parameters. The geochemical analyses included: (1) a 4-step sequential extraction scheme to determine the distribution of As between different fractions, (2) As speciation (As³⁺ vs. As⁵⁺), and (3) C, N and S isotopes. The sediments have a low percentage of organic C and N (0.10-0.56% and 0.01-0.05%, respectively). Arsenic concentration is between 2 and 7 mg kg⁻¹, and it is mainly associated with the residual fraction, less susceptible to chemical weathering. The proportion of As³⁺ in these sediments is high and ranges from 24% to 74%. Arsenic in the second fraction (reducible) correlates well with Mn, and in the residual fraction As correlates well with several transition elements. The stable isotope results indicate microbial oxidation of organic matter involving SO₄ reduction. Oxidation of primary sulfide minerals and release of As from reduction of Fe-(oxy)hydroxides do not seem important mechanisms in As mobilization. Instead, the dominance of As³⁺ and presence of As⁵⁺ reducing microorganisms in this shallow aquifer imply As remobilization involving microbial processes that needs further investigations.  相似文献   

Model of outgrowths in the spiral galaxies NGC 4921 and NGC 7049 and the origin of spiral arms     

Per Carlqvist 《Astrophysics and Space Science》2013,343(2):689-712

NGC 4921 and 7049 are two spiral galaxies presenting narrow, distinct dust features. A detailed study of the morphology of those features has been carried out using Hubble Space Telescope archival images. NGC 4921 shows a few but well-defined dust arms midway to its centre while NGC 7049 displays many more dusty features, mainly collected within a ring-shaped formation. Numerous dark and filamentary structures, called outgrowths, are found to protrude from the dusty arms in both galaxies. The outgrowths point both outwards and inwards in the galaxies. Mostly they are found to be V-shaped or Y-shaped with the branches connected to dark arm filaments. Often the stem of the Y appears to consist of intertwined filaments. Remarkably, the outgrowths show considerable similarities to elephant trunks in H ii regions. A model of the outgrowths, based on magnetized filaments, is proposed. The model provides explanations of both the shapes and orientations of the outgrowths. Most important, it can also give an account for their intertwined structures. It is found that the longest outgrowths are confusingly similar to dusty spiral arms. This suggests that some of the outgrowths can develop into such arms. The time-scale of the development is estimated to be on the order of the rotation period of the arms or shorter. Similar processes may also take place in other spiral galaxies. If so, the model of the outgrowths can offer a new approach to the old winding problem of spiral arms.  相似文献   

Godzilla from a Zoological Perspective     

Per Christiansen 《Mathematical Geology》2000,32(2):231-245

The 1998 TriStar movie Godzilla proved to be a major blockbuster, although not the financial success that was initially anticipated and movie critics have been rather unforgiving. Apart from a radically different external morphology compared to the classic Japanese movie monster, the new Godzilla character apparently was made different from the old version on a number of key points to make him more biologically probable. However, calculations show that his limbs and limb muscles must have been severely undersized to move his huge bulk around at even a leisurely pace, and most other biological problems with the old Godzilla, e.g., growth rates and reptilian physiology at such a massive size, have remained unaltered. The old Godzilla was actually the more plausible from a biomechanical point of view.  相似文献   

Sputtering in the outflows of cool stars     

Carl Covatto  Per A. Aannestad 《Monthly notices of the Royal Astronomical Society》2000,318(1):67-72

Radiation pressure acts to accelerate dust grains and, by transfer of momentum through collisions with the gas, drives the outflows of late-type stars. Some of these dust–gas collisions may be energetic enough to remove atoms from the dust grains. From an assumed initial size distribution for the dust grains, the method of Krüger et al. is used to study the evolution of a sample of spherical amorphous carbon grains under conditions typical of a late-type star. The size distribution of dust grains is presented for various sets of model parameters. One set of models assumes an initial Mathis, Rumpl & Nordsieck (MRN) distribution for the dust grains. The high-luminosity ( L ∗), high-effective temperature ( T _eff) set of parameters has a terminal velocity ( v _term) that is near, but above , the upper limit of observed outflow velocities for carbon stars (∼30 km s⁻¹ for the assumed ̇ of 5×10⁻⁶ M_⊙ yr⁻¹). The low L ∗, T _eff model has a v _term that lies near, but below , the upper limit of observed velocities. A significant amount of sputtering occurs in the high L ∗, T _eff model with ∼40 per cent of the grain mass sputtered. About ∼1 per cent of the dust mass is sputtered in the low L ∗, T _eff. Another set of models assumes that the dust forms with a log-normal distribution. Here, v _term is nearly the same for the high L ∗, T _eff model as for the low L ∗, T _eff model. This is a result of the large amount of dust mass loss (∼75 per cent) by sputtering in the high L ∗, T _eff model.  相似文献