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41.
Abstract

Carbonyl sulphide (OCS) is an important precursor of sulphate aerosols and consequently a key species in stratospheric ozone depletion. The SPectromètre InfraRouge d'Absorption à Lasers Embarqués (SPIRALE) and shortwave infrared (SWIR) balloon-borne instruments have flown in the tropics and in the polar Arctic, and ground-based measurements have been performed by the Qualité de l'Air (QualAir) Fourier Transform Spectrometer in Paris. Partial and total columns and vertical profiles have been obtained to study OCS variability with altitude, latitude, and season. The annual total column variation in Paris reveals a seasonal variation with a maximum in April–June and a minimum in November–January. Total column measurements above Paris and from SWIR balloon-borne instrument are compared with several MkIV measurements, several Network for the Detection of Atmospheric Composition Change (NDACC) stations, aircraft, ship, and balloon measurements to highlight the OCS total column decrease from tropical to polar latitudes. OCS high-resolution in situ vertical profiles have been measured for the first time in the altitude range between 14 and 30?km at tropical and polar latitudes. OCS profiles are compared with Atmospheric Chemistry Experiment (ACE) satellite measurements and show good agreement. Using the correlation between OCS and N2O from SPIRALE, the OCS stratospheric lifetime has been accurately determined. We find a stratospheric lifetime of 68?±?20 years at polar latitudes and 58?±?14 years at tropical latitudes leading to a global stratospheric sink of 49?±?14?Gg?S?y?1.  相似文献   
42.
Geographic Information Systems (GIS) consists of various tools to perform spatial analyses in a wide variety of disciplines, including radiometric analysis to characterize the distribution of natural radionuclide concentrations. Recently, open-source GIS has become popular among geospatial users because it can be freely used, and powerful tools are constantly developed to enhance software capabilities. Gamma-ray spectroscopy was used to measure the concentrations of these natural radionuclides by dragging a Delta Underwater Gamma System (DUGS) among the sediment in the Berg River estuary located in Velddrif, South Africa. In this study, QGIS was used to visually illustrate and interpret the distribution of natural radionuclides, that is, potassium (K40), thorium (Th232), and uranium (U238). These concentrations can be used to investigate various geographical and geological phenomena, which include sediment processes. The data were then interpreted to derive sediment characteristics. Various features of tidal estuaries were demonstrated by the results.  相似文献   
43.
Extreme temperatures are key drivers controlling both biotic and abiotic processes, and may be strongly modified by topography and land cover. We modelled mean and extreme temperatures in northern Fennoscandia by combining digital elevation and land cover data with climate observations from northern Finland, Norway and Sweden. Multivariate partitioning technique was utilized to investigate the relative importance of environmental variables for the variation of the three temperature parameters: mean annual absolute minima and maxima, and mean annual temperature. Generalized additive modeling showed good performance, explaining 84–95 % of the temperature variation. The inclusion of remotely sensed variables improved significantly the modelling of thermal extremes in this system. The water cover variables and topography were the most important drivers of minimum temperatures, whereas elevation was the most important factor controlling maximum temperatures. The spatial variability of mean temperatures was clearly driven by geographical location and the effects of topography. Partitioning technique gave novel insights into temperature-environment relationship at the meso-scale and thus proved to be useful tool for the study of the extreme temperatures in the high-latitude setting.  相似文献   
44.
45.
The recent numerical simulations of Tittemore and Wisdom (1988, 1989, 1990) and Dermottet al. (1988), Malhotra and Dermott (1990) concerning the tidal evolution through resonances of some pairs of Uranian satellites have revealed interesting dynamical phenomena related to the interactions between close-by resonances. These interactions produce chaotic layers and strong secondary resonances. The slow evolution of the satellite orbits in this dynamical landscape is responsible for temporary capture into resonance, enhancement of eccentricity or inclination and subsequent escape from resonance. The present contribution aims at developing analytical tools for predicting the location and size of chaotic layers and secondary resonances. The problem of the 3:1 inclination resonance between Miranda and Umbriel is analysed.  相似文献   
46.
The inter-annual variability in phytoplankton summer blooms in the upper reaches of the Schelde estuary was investigated between 1996 and 2005 by monthly sampling at 10 stations. The large inter-annual variations of the chlorophyll a concentration in the freshwater tidal reaches were independent from variations in chlorophyll a in the tributary river Schelde. Summer mean chlorophyll a concentrations were significantly negatively correlated with flushing rate (Spearman correlation: r = −0.67, p = 0.05, n = 9) but not with temperature, irradiance and suspended particulate matter or dissolved silica (DSi) concentrations. During dry summers, low flushing rates permitted the development of dense phytoplankton populations in the upper part of the estuary, while during wet summers high flushing rates prevented the development of dense phytoplankton blooms. Flushing rate was also found to be important for the phytoplankton community composition. At low flushing rates, the community was dominated by diatoms that developed within the upper estuary. At high flushing rates, chlorophytes imported from the tributary river Schelde became more important in the phytoplankton community. The position of the chlorophyll a maximum shifted from the head of the estuary when flushing rates were low, to more downstream when flushing rates were high. Although DSi concentrations tended to be lower during years of high phytoplankton (mainly diatom) biomass, the relation with flushing rate was not significant.  相似文献   
47.
Geotechnical and Geological Engineering - The aggregates consist approximately 85% of the total volume in asphalts pavements, and their properties influence directly their behavior. Therefore, it...  相似文献   
48.
Investigating the characteristics of model-forecast errors using various statistical and object-oriented methods is necessary for providing useful guidance to end-users and model developers as well. To this end, the random and systematic errors (i.e., biases) of the 2-m temperature and 10-m wind predictions of the NCAR-AirDat weather research and forecasting (WRF)-based real-time four-dimensional data assimilation (RTFDDA) and forecasting system are analyzed. This system has been running operationally over a contiguous United States (CONUS) domain at a 4-km grid spacing with four forecast cycles daily from June 2009 to September 2010. In the result an exceptionally useful forecast dataset was generated and used for studying the error properties of the model forecasts, in terms of both a longer time period and a broader coverage of geographic regions than previously studied. Spatiotemporal characteristics of the errors are investigated based on the 24-h forecasts between June 2009 and April 2010, and the 72-h forecasts between May and September 2010. It was found that the biases of both wind and temperature forecasts vary greatly seasonally and diurnally, with dependency on the forecast length, station elevation, geographical location, and meteorological conditions. The temperature showed systematic cold biases during the daytime at all station elevations and warm biases during the nighttime above 1,000 m above sea level (ASL), while below 600 m ASL cold biases occurred during the nighttime. The forecasts of surface wind speed exhibited strong positive biases during the nighttime, while the negative biases were observed in the spring and summer afternoons. The surface wind speed was mostly over-predicted except for the stations located between 1,000 and 2,100 m ASL, for which negative biases were identified for most forecast cycles. The highest wind-speed errors were found over the high terrain and near sea-level stations. The wind-direction errors were relatively large at the high-terrain elevation in the Rocky and Appalachian mountain ranges and the western coastal areas and the error structure exhibited notable diurnal variability.  相似文献   
49.
50.
Coordinated observations involving ion composition, thermal plasma, energetic particle, and ULF magnetic field data from GEOS 1 and 2 often reveal the presence of electromagnetic ion cyclotron and magnetosonic waves, which are distinguished by their respective polarization characteristics and frequency spectra. The ion cyclotron waves are identified by a magnetic field perturbation that lies in a plane perpendicular to the Earth's magnetic field B0 and propagate along B0. They are associated with the abundance of cold He+ in the presence of anisotropic pitch angle distributions of ions having energies E > 20 keV, and were observed at frequencies near the He+ gyrofrequency. The magnetosonic waves are characterized by a magnetic field perturbation parallel to B0 and thus seem to be propagating perpendicular to the Earth's magnetic field. They often occur at harmonics (not always including the fundamental) at the proton gyrofrequency and are associated with phase-space-density distributions that peak at energies E ~ 5–30 keV and at a pitch angle of 90°. Such a ring-like distribution is shown to excite instability in the magnetosonic mode near harmonics of the proton gyrofrequency. Magnetosonic waves are associated in other cases with sharp spatial gradients in energetic ion intensity. Such gradients are encountered in the early afternoon sector (as a consequence of the drift shell distortion caused by the convection electric field) and could likewise constitute a source of free energy for plasma instabilities.  相似文献   
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