This study assessed the role of picocyanobacterial photosynthesis in the induction of calcite precipitation. It aimed at establishing whether photosynthetic uptake of bicarbonate by Synechoccoccus cells leads to calcite nucleation. The precipitation of calcite was initiated by addition of previously washed cyanobacterial cells of Synechococcus strain PCC 7942 to solutions of calcium carbonate at different saturation levels with respect to calcite. Precipitation experiments were performed under controlled laboratory conditions in two set-ups: one in which photosynthesis was inhibited using a herbicide called Diuron and the other one in which photosynthesis was taking place. During the experiments, a pH meter monitored the pH and ion selective electrodes monitored concentrations of carbonate and calcium ions. The morphology of the precipitated crystals was analysed using Scanning Electron Microscopy. When the kinetics of calcium carbonate nucleation by the Synechococcus cells were compared for the two sets of experiments, there were very little differences. In fact, the induction times for precipitation reactions with photosynthesis were shorter due to the uptake of carbon dioxide. It is therefore, concluded that photosynthesis does not directly influence the nucleation of calcite at the surface of Synechococcus cells with sufficient supply of carbon dioxide, i.e. cells took up carbon dioxide and not bicarbonate. The microscopic observations, however, provided some evidence that picocyanobacterial cell walls act as a template for calcite nucleation. 相似文献
This paper examines the coastal regional trends in urbanization processes using remotely sensed images around the Kucukcekmece Lagoon as a case study, located in the western part of Istanbul, Turkey. Throughout the examination process, the coastline changes are determined for a long-term period. To achieve this goal, post-classification comparison method is applied to the CORONA and LANDSAT TM satellite images of 1963, 1987 and 2005. In order to identify the land use changes, common landscape structures in the region were distinguished as water, green and open land, urban and industrial areas. Due to the mix up of land-cover types between urban and industrial areas, the classified images are integrated with geographic information system data obtained from visual interpretation of the enhanced images and auxiliary data sets. The results of the change analyses in coastal region showed that important alterations are taking place in the area due to the unplanned urban and industrial expansions that has irreversibly changed the physical features of the Kucukcekmece Lagoon. According to image classification results, the urban land use area increased from 2 % oftotal area in 1963 to 38 % in 1987 and 46 % in 2005, most of which converted from agricultural and greenlands. At the same time, the ecological impact of the loss of specific land covers is highlighted based on the results of the land use changes and the previous scientific applications. Furthermore, some recommendations are given to planners, decision makers and politicians to maintain the sustainable coastal ecosystem management. 相似文献
Use of native soil in adsorption of phenol from industrial wastewater has been one of the attractive option for dephenolation, especially in view of low cost and ease in accessibility, as well as scope for regeneration (or, at least reuse). However, an effective usage of the adsorbent necessitates a deeper understanding of the adsorption characteristics. Most of the study of adsorption characteristics are confined to analysis of mono- and bi- parametric isotherm models (and rarely, linearized multi-parametric isotherm models), due to the difficulties in solving higher parametric models, as well as fairly satisfying results by lower-parametric models. In the present study, adsorption batch studies were carried out using a naturally and widely available common soil of south India (namely, Adhanur soil), for removal of phenol from the aqueous solution, with an explicit objective of comparison of linear and non-linear regression methods for finding variation in isotherm coefficients and fitness of the models. Six linearized isotherm models (including four linearized Langmuir models) and three non-linear isotherm model were discussed in this paper, and their coefficients were estimated. Although all the studied isotherm models showed fairly good fit to the experimental data, but Redlich—Peterson isotherm was found to be the best representative for phenol-sorption on the used soil adsorbent. Besides, it was observed that to determine the isotherm parameters non-linear isotherm models were found to be the best representative of adsorption characteristics, than their linearized counter-parts. 相似文献
Street dust is a potential source of lead exposure to humans, however scarce information about the pollution levels with lead and polyromatic hydrocarbons exists in Venezuela, limiting the appropriate evaluation of the levels of risk of the people. This work was aimed in the determination of the concentrations of lead, naphtalene, anthracene, phenanthrene and pyrene in the street dust of the most transited avenues and streets of Maracay city. Thirty street dust samples were collected at the streets and avenues, troll and bus main station. Lead was determined by atomic absorption spectrometry after acid digestion (Pb-total), also the fractions of lead soluble in 1 M MgCl2 and 0.5 M ammonium acetate (pH = 7) were quantified. The polyaromatic hydrocarbons concentrations were determined by capillary gas chromatography equipped with a flame ionization detector. The Pb-total ranged between 734 and 11.439 μg/g with the higher values at the most transited streets and avenues. About 60 % of samples exhibited concentrations between 1.000 and 2.500 μg/g, similar to the values reported in the literature for soils of urban areas. The fraction of lead soluble in magnesium accounted for less than 3 % of Pb-Total, while the 0.5 M ammonium acetate solution represented more than the 75 % of the total loads of the pollutant. The most contaminated samples were those taken at the toll with concentrations of 695.5 and 252.1 μg/g phenanthrene and anthracene were the most abundant, while at the bus station all compounds were detected. 相似文献
1 Introduction Directsolarradiation (DSR)isthe key com ponentofthe globalradiation reaching the Earth.For the influence of terrain factors,calculation of DSR quantity of rugged terrain is considerably com plex (Oliphantetal.,2003). The solarradiation quan… 相似文献
Benthic macroinvertebrates have been commonly used as indicator species for assessment of aquatic ecology. Streambed sediment, or substrate, plays an important role in habitat conditions for macroinvertebrate communities. Field investigations were done to study the benthic diversity and macroinvertebrate compositions in various stream substrata. Sampling sites with different bed sediment, latitude, and climate were selected along the Yangtze River, the Yellow River, the East River, and the Juma River, in China. The results show that benthic community structures found in different substrata clearly differ, while those found in substrata of similar composition and flow conditions but in different macroclimates are similar. The study, thus, demonstrates that the benthic macroinvertebrate community is mainly affected by substrate composition and flow conditions, but is generally unaffected by latitudinal position and macroclimate. Taxa richness of the maeroinvertebrate community was found to be the highest on hydrophyte-covered cobbles, high on moss-covered bedrock, and low on clay beds and cobble beds devoid of plant biomass. Sandy beds are compact and unstable, thus, no benthic macroinvertebrates were found colonizing such substrata. Aquatic insects account for most of the macroinvertebrates collected in these rivers. Different insects dominate in different types of substrata: mainly EPT species (Ephemeroptera, Ptecoptera, Tfichoptera) in cobble, gravel, and moss-covered bedrock; and Chironomidae larvae in clay beds. The relation between the number of species in the samples and the size of the sampling area fits a power function of the species area. One square meter (lm) is suggested as the minimum sampling area. A substrate suitability index is proposed by integrating the suitability of sediment, periphyton, and benthic organic materials for macroinvertebrates. The biodiversity of macroinvertebrates increases linearly with the substrate suitability index. Benthic taxa richness increases linearly with the suitability index. 相似文献
This paper builds on a recently published one-dimensional moving-boundary model of the coevolution of topset, foreset and bottomset in a reservoir that captures the dynamics of the internal muddy pond typical to reservoirs. This model was modified to account for different outlet locations at the reservoir's downstream end. This model considers a river carrying two sustained phases of sediments: coarse (sand) and fine (mud). The coarse phase deposits in the topset and delta foreset, while the fine phase forms a dilute suspension of wash load in the river. As the river enters the reservoir, the muddy water plunges on the foreset to form a Froude-supercritical (purely depositional) turbidity current. This turbidity current emplaces the bottomset. The modified numerical model was tested against five laboratory experiments previously reported by the author. The model successfully locates the muddy-water/clear-water interface. In addition, modeled and measured bed deposits are in good agreement. Results clearly indicate that the location of the internal hydraulic jump plays a key role in the final bed deposit. 相似文献
The Loire River, with one of the largest watersheds in France, has been monitored just outside the city of Orleans since 1994. Physico-chemical parameters and major and trace elements were measured between 2-day and 1-week intervals according to the river flow. The sampling site represents 34% of the total Loire watershed with 76% silicate rocks and 24% carbonate rocks.
Elements are transported mainly in the dissolved phase with the ratio of total dissolved salts (TDS) to suspended matter (SM) ranging between 1.6 and 17.4. Chemical weathering of rocks and soils are thus the dominant mechanisms in the Loire waters composition. The highest TDS/SM ratios are due to dissolved anthropogenic inputs. The database shows no link between NO3− content and river flow. The Na+, K+, Mg2+, SO42−, and Cl− concentrations are seen to decrease with increasing discharge, in agreement with a mixing process involving at least two components: the first component (during low flow) is concentrated and may be related with input from the groundwater and sewage station water, the second component (during high flow) is more dilute and is in agreement with bedrock weathering and rainwater inputs. A geochemical behaviour pattern is also observed for HCO3− and Ca2+ species, their concentrations increase with increasing discharge up to 300 m3/s, after which, they decrease with increasing discharge. The Sr isotopic composition of the dissolved load is controlled by at least five components — a series of natural components represented by (a) waters draining the silicate and carbonate bedrock, (b) groundwater, and (c) rainwaters, and two kinds of anthropogenic components.
The aim of this study is to describe the mixing model in order to estimate the contribution of each component. Finally, specific export rates in the upper Loire watershed were evaluated close to 12 t year−1 km−2 for the silicate rate and 47 t year−1 km−2 for the carbonate rate. 相似文献
This paper studies urban waterlog-draining decision support system based on the 4D data fusion technique.4D data includes DEM,DOQ,DLG and DRG.It supplies entire databases for waterlog forecast and analysis together with non-spatial fundamental database.Data composition and reasoning are two key steps of 4D data fusion.Finally,this paper gives a real case: Ezhou Waterlog-Draining Decision Support System (EWDSS) with two application models,i.e.,DEM application model,water generating and draining model. 相似文献