Identification of a sulfide derivative with a bicyclic hydrocarbon skeleton related to squalene. Part II: synthesis of a S-spiro-like dithiolane triterpenoid     

Pierre Adam  Philippe Schaeffer  Sylvestre Gug  Estelle Motsch  Pierre Albrecht 《Organic Geochemistry》2009,40(8):885-894

A sulfide with a bicyclic squalene hydrocarbon skeleton present in sediments from various depositional settings and of different geological age has been identified by synthesis of a reference compound. In contrast to previous expectations [cf. Schouten, S., Sinninghe Damsté, J.S., de Leeuw, J.W., 1995. A novel triterpenoid carbon skeleton in immature sulphur-rich sediments. Geochimica et Cosmochimica Acta 59, 953–958; Gug, S., Schaeffer, P., Adam, P., Klein, S., Motsch, E., Albrecht, P., 2009. Identification of a sulfide derivative with a bicyclic hydrocarbon skeleton related to squalene. Part I: Synthesis of a dithiane triterpenoid. Organic Geochemistry 40, 876–884.], this sulfide bears two “S-spiro type“ thiolane moities, but not the two thiochromane moieties originally envisaged. The synthesis resulted in the formation of a complex isomeric mixture of compounds, all co-eluting in gas chromatography (GC) in the form of one broad peak, as is the case with the geochemical compound. The spiro-type sulfide was formed by intramolecular sulfurization of a polyunsaturated bicyclic squalene derivative of unknown biological origin. The presence of this sulfide in a number of Triassic to Miocene marine sediments from various and contrasting depositional settings (upwelling environments, shallow continental platforms, lagoonal sub-basins, hypersaline environments), all characterized by strongly anoxic conditions, but with or without photic zone anoxia, indicates that the microorganisms biosynthesizing the precursor bicyclic squalene occupy diverse ecological niches.  相似文献   

Peierls dislocation modelling in perovskite (CaTiO<Subscript>3</Subscript>): comparison with tausonite (SrTiO<Subscript>3</Subscript>) and MgSiO<Subscript>3</Subscript> perovskite     

Denise Ferré  Philippe Carrez  Patrick Cordier 《Physics and Chemistry of Minerals》2009,36(4):233-239

We present here a numerical modelling study of dislocations in perovskite CaTiO₃. The dislocation core structures and properties are calculated through the Peierls–Nabarro model using the generalized stacking fault (GSF) results as a starting model. The GSF are determined from first-principles calculations using the VASP code. The dislocation properties such as collinear, planar core spreading and Peierls stresses are determined for the following slip systems: [100](010), [100](001), [010](100), [010](001), [001](100), [001](010), and All dislocations exhibit lattice friction, but glide appears to be easier for [100](010) and [010](100). [001](010) and [001](100) exhibit collinear dissociation. Comparing Peierls stresses among tausonite (SrTiO₃), perovskite (CaTiO₃) and MgSiO₃ perovskite demonstrates the strong influence of orthorhombic distortions on lattice friction. However, and despite some quantitative differences, CaTiO₃ appears to be a satisfactory analogue material for MgSiO₃ perovskite as far as dislocation glide is concerned.  相似文献   

GETEMME—a mission to explore the Martian satellites and the fundamentals of solar system physics     

Jürgen Oberst  Valéry Lainey  Christophe Le Poncin-Lafitte  Veronique Dehant  Pascal Rosenblatt  Stephan Ulamec  Jens Biele  J?rn Spurmann  Ralph Kahle  Volker Klein  Ulrich Schreiber  Anja Schlicht  Nicolas Rambaux  Philippe Laurent  Beno?t Noyelles  Bernard Foulon  Alexander Zakharov  Leonid Gurvits  Denis Uchaev  Scott Murchie  Cheryl Reed  Slava G. Turyshev  Jesus Gil  Mariella Graziano  Konrad Willner  Kai Wickhusen  Andreas Pasewaldt  Marita W?hlisch  Harald Hoffmann 《Experimental Astronomy》2012,34(2):243-271

GETEMME (Gravity, Einstein??s Theory, and Exploration of the Martian Moons?? Environment), a mission which is being proposed in ESA??s Cosmic Vision program, shall be launched for Mars on a Soyuz Fregat in 2020. The spacecraft will initially rendezvous with Phobos and Deimos in order to carry out a comprehensive mapping and characterization of the two satellites and to deploy passive Laser retro-reflectors on their surfaces. In the second stage of the mission, the spacecraft will be transferred into a lower 1500-km Mars orbit, to carry out routine Laser range measurements to the reflectors on Phobos and Deimos. Also, asynchronous two-way Laser ranging measurements between the spacecraft and stations of the ILRS (International Laser Ranging Service) on Earth are foreseen. An onboard accelerometer will ensure a high accuracy for the spacecraft orbit determination. The inversion of all range and accelerometer data will allow us to determine or improve dramatically on a host of dynamic parameters of the Martian satellite system. From the complex motion and rotation of Phobos and Deimos we will obtain clues on internal structures and the origins of the satellites. Also, crucial data on the time-varying gravity field of Mars related to climate variation and internal structure will be obtained. Ranging measurements will also be essential to improve on several parameters in fundamental physics, such as the Post-Newtonian parameter ?? as well as time-rate changes of the gravitational constant and the Lense-Thirring effect. Measurements by GETEMME will firmly embed Mars and its satellites into the Solar System reference frame.  相似文献   

Intercomparison of the LASCO-C2, SECCHI-COR1, SECCHI-COR2, and Mk4 Coronagraphs     

Richard A. Frazin  Alberto M. Vásquez  William T. Thompson  Russell J. Hewett  Philippe Lamy  Antoine Llebaria  Angelos Vourlidas  Joan Burkepile 《Solar physics》2012,280(1):273-293

In order to assess the reliability and consistency of white-light coronagraph measurements, we report on quantitative comparisons between polarized brightness [pB] and total brightness [B] images taken by the following white-light coronagraphs: LASCO-C2 on SOHO, SECCHI-COR1 and -COR2 on STEREO, and the ground-based MLSO-Mk4. The data for this comparison were taken on 16?April 2007, when both STEREO spacecraft were within 3.1^° of Earth??s heliographic longitude, affording essentially the same view of the Sun for all of the instruments. Due to the difficulties of estimating stray-light backgrounds in COR1 and COR2, only Mk4 and C2 produce reliable coronal-hole values (but not at overlapping heights), and these cannot be validated without rocket flights or ground-based eclipse measurements. Generally, the agreement between all of the instruments?? pB values is within the uncertainties in bright streamer structures, implying that measurements of bright CMEs also should be trustworthy. Dominant sources of uncertainty and stray light are discussed, as is the design of future coronagraphs from the perspective of the experiences with these instruments.  相似文献   

The information system of the French Peatland Observation Service: Service National d'Observation Tourbières – A valuable tool to assess the impact of global changes on the hydrology and biogeochemistry of temperate peatlands through long term monitoring     

Sébastien Gogo  Jean-Baptiste Paroissien  Fatima Laggoun-Défarge  Jean-Marc Antoine  Léonard Bernard-Jannin  Guillaume Bertrand  Philippe Binet  Stéphane Binet  Guillaume Bouger  Yohann Brossard  Thierry Camboulive  Jean-Pierre Caudal  Stéphane Chevrier  Geneviève Chiapiuso  Benoît D'Angelo  Pilar Durantez  Chris Flechard  André-Jean Francez  Didier Galop  Laure Gandois  Daniel Gilbert  Christophe Guimbaud  Louis Hinault  Adrien Jacotot  Franck Le Moing  Emilie Lerigoleur  Gaël Le Roux  Fabien Leroy  Alexandre Lhosmot  Qian Li  Elodie Machado Da Silva  Jean-Sébastien Moquet  Juanita Mora-Gomez  Laurent Perdereau  Thomas Rosset  Marie-Laure Toussaint 《水文研究》2021,35(6):e14244

Mitigating and adapting to global changes requires a better understanding of the response of the Biosphere to these environmental variations. Human disturbances and their effects act in the long term (decades to centuries) and consequently, a similar time frame is needed to fully understand the hydrological and biogeochemical functioning of a natural system. To this end, the ‘Centre National de la Recherche Scientifique’ (CNRS) promotes and certifies long-term monitoring tools called national observation services or ‘Service National d'Observation’ (SNO) in a large range of hydrological and biogeochemical systems (e.g., cryosphere, catchments, aquifers). The SNO investigating peatlands, the SNO ‘Tourbières’, was certified in 2011 ( https://www.sno-tourbieres.cnrs.fr/ ). Peatlands are mostly found in the high latitudes of the northern hemisphere and French peatlands are located in the southern part of this area. Thus, they are located in environmental conditions that will occur in northern peatlands in coming decades or centuries and can be considered as sentinels. The SNO Tourbières is composed of four peatlands: La Guette (lowland central France), Landemarais (lowland oceanic western France), Frasne (upland continental eastern France) and Bernadouze (upland southern France). Thirty target variables are monitored to study the hydrological and biogeochemical functioning of the sites. They are grouped into four datasets: hydrology, fluvial export of organic matter, greenhouse gas fluxes and meteorology/soil physics. The data from all sites follow a common processing chain from the sensors to the public repository. The raw data are stored on an FTP server. After operator or automatic processing, data are stored in a database, from which a web application extracts the data to make them available ( https://data-snot.cnrs.fr/data-access/ ). Each year at least, an archive of each dataset is stored in Zenodo, with a digital object identifier (DOI) attribution ( https://zenodo.org/communities/sno_tourbieres_data/ ).  相似文献   

Regional mesoscale air–sea coupling impacts and extreme meteorological events role on the Mediterranean Sea water budget     

Cindy Lebeaupin Brossier  Sophie Bastin  Karine Béranger  Philippe Drobinski 《Climate Dynamics》2015,44(3-4):1029-1051

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Defining deep decarbonization pathways for Switzerland: an economic evaluation     

Frédéric Babonneau  Philippe Thalmann 《Climate Policy》2018,18(1):1-13

This article simulates deep decarbonization pathways for a small open economy that lacks the usual avenues for large CO₂ reductions – heavy industry and power generation. A computable general equilibrium model is used to assess the energy and economic impacts of the transition to only one ton of CO₂ emissions per capita in 2050. This represents a 76% reduction with respect to 1990 levels, while the population is expected to be 46% larger and GPD to increase by 90%. The article discusses several options and scenarios that are compatible with this emissions target and compares them with a reference scenario that extrapolates already-decided climate and energy policy instruments. We show that the ambitious target is attainable at moderate welfare costs, even if it needs very high carbon prices, and that these costs are lower when either CO₂ can be captured and sequestered or electricity consumption can be taxed sufficiently to stabilize it.

Policy relevance

In the context of COP 21, all countries must propose intended contributions that involve deep decarbonization of their economy over the next decades. This article defines and analyses such pathways for Switzerland, taking into consideration the existing energy demand and supply and also already-defined climate policies. It draws several scenarios that are compatible with a target of 1 ton of CO₂ emissions per capita in 2050. This objective is very challenging, especially with the nuclear phase out decided after the disaster in Fukushima and the political decision to balance electricity trade. Nevertheless, it is possible to design several feasible pathways that are based on different options. The economic cost is significant but affordable for the Swiss economy. The insights are relevant not only for Switzerland, but also for other industrialized countries when defining their INDCs.  相似文献   

Mapping the mean monthly precipitation of a small island using kriging with external drifts     

Philippe?CantetEmail author 《Theoretical and Applied Climatology》2017,127(1-2):31-44

This study focuses on the spatial distribution of mean annual and monthly precipitation in a small island (1128 km²) named Martinique, located in the Lesser Antilles. Only 35 meteorological stations are available on the territory, which has a complex topography. With a digital elevation model (DEM), 17 covariates that are likely to explain precipitation were built. Several interpolation methods, such as regression-kriging (????????, ????????, and ????????) and external drift kriging (??????) were tested using a cross-validation procedure. For the regression methods, predictors were chosen by established techniques whereas a new approach is proposed to select external drifts in a kriging which is based on a stepwise model selection by the Akaike Information Criterion (AIC). The prediction accuracy was assessed at validation sites with three different skill scores. Results show that using methods with no predictors such as inverse distance weighting (??????) or universal kriging (????) is inappropriate in such a territory. ?????? appears to outperform regression methods for any criteria, and selecting predictors by our approach improves the prediction of mean annual precipitation compared to kriging with only elevation as drift. Finally, the predicting performance was also studied by varying the size of the training set leading to less conclusive results for ?????? and its performance. Nevertheless, the proposed method seems to be a good way to improve the mapping of climatic variables in a small island.  相似文献   

Scaling in gravitational clustering, two- and three-dimensional dynamics     

D. Munshi  F. Bernardeau  A. L. Melott  R. Schaeffer 《Monthly notices of the Royal Astronomical Society》1999,303(3):433-445

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Predicted present-day evolution patterns of ice thickness and bedrock elevation over Greenland and Antarctica   总被引：4，自引：0，他引：4  

Philippe Huybrechts  Emmanuel Le Meur 《Polar research》1999,18(2):299-306

This paper discusses predicted evolution patterns of present-day changes of ice thickness, surface elevation, and bedrock elevation over the Greenland and Antarctic continents. These were obtained from calculations with dynamic 3-D ice sheet models which were coupled to a visco-elastic solid Earth model. The experiments were initialized over the last two glacial cycles and subsequently averaged over the last 200 years to obtain the current evolution. The calculations indicate that the Antarctic Ice Sheet is still adjusting to the last glacial-interglacial transition yielding a decreasing ice volume and a rising bedrock elevation of the order of several centimetres per year. The Greenland Ice Sheet was found to be close to a stationary state with a mean thickness change of only a few millimetres per year, but the calculations revealed large spatial differences. Predicted patterns over Greenland are characterized by a small thickening over the ice sheet interior and a general thinning of the ablation area. In Antarctica, almost all of the predicted changes are concentrated in the West Antarctic Ice Sheet, which is still retreating at both the Weddell and Ross Sea margins. Over most of both ice sheets, the model indicates that the surface elevation trend is dominated by ice thickness changes rather than by bedrock elevation changes.  相似文献