胶州湾沉积物重金属形态不同浸取方法的比较与污染讯息指示作用初探   总被引：1，自引：0，他引：1  

梁宪萌  宋金明  段丽琴  袁华茂  李宁  李学刚 《海洋学报》2016,38(10):12-21

海洋沉积物中重金属的活性形态对于指示沉积物污染状况具有重要作用;为探寻简洁且能够有效提取重金属活性形态的浸提方法;实验研究了0.1 mol/L和1 mol/L盐酸的单级提取和欧共体标准局（European Community Bureau of Reference）提出的BCR分级提取法对胶州湾表层沉积物中重金属（Cr、Cu、Ni、Pb、Zn）和Al、Fe、Mn的浸取效果。结果显示;3种提取方法提取的金属含量呈显著正相关关系;两种浓度的稀盐酸对BCR方法中的酸可提取态和可还原态金属均具有较好浸提效果;但对可氧化态金属浸提能力相对较弱。不同提取方法的人为信号指数（ASI）计算结果表明;BCR浸取法提取结果的金属ASI值最大;表明其对沉积物中金属活性形态提取效率较高;1 mol/L HCl提取结果的金属ASI值最低;可能是较高浓度强酸使沉积物较大颗粒内层中“惰性”金属被浸取出来;“增加”了金属活性组分的污染讯息信号;对沉积物中Cu、Pb和Zn而言;0.1 mol/L HCl提取结果的ASI值与BCR方法接近。经过Al归一化后;0.1 mol/L HCl浸提的重金属含量的空间分布与胶州湾的实际污染状况相吻合;表明0.1 mol/L的HCl在一定程度上能够代替复杂的BCR浸取法;此方法可简化重金属活性形态的提取步骤;适合大范围沉积物重金属污染评价。  相似文献   

利用被动示踪物模拟对黑潮入侵南海的数值研究   总被引：1，自引：1，他引：0  

刘统亚  许洁馨  何映晖  吕海滨  姚远  蔡树群 《海洋学报(英文版)》2016,35(9):1-12

由于缺少观测数据和对黑潮水准确定义,很难识别出从太平洋入侵到南海的黑潮水团。本文基于一个经过观测验证的三维模式MITgcm,利用被动示踪物标记黑潮水,研究了入侵南海的黑潮水的时空变化。研究表明,在冬季,黑潮水入侵的范围最广,几乎占据了18°N-23°N和114°E-121°E的区域;并有一个分支进入台湾海峡;黑潮入侵的范围随深度增加逐渐减小。在夏季,黑潮水被限制在118°E以东,且没有分支进入台湾海峡;入侵的范围从海面到约205米是增大的,之后随深度增加逐渐减小。通过分析从2003年到2012年黑潮入侵的年际变化,与厄尔尼诺年和正常年相比,冬季黑潮入侵后向台湾海峡的分支在拉尼娜年是最弱的,这可能与中国大陆东南方向的风应力旋度有关。通过吕宋海峡的黑潮入侵通量（KIT）是西向的,其年平均值约为-3.86×10⁶ m³/s,大于吕宋海峡通量（LST,约-3.15×10⁶ m³/s）。250米以上的KIT约占了全深度通量的60-80%。此外,从2003年到2012年KIT与Niño 3.4指数的相关系数到达0.41,小于LST与Niño 3.4指数的相关系数0.78。  相似文献   

The Air-Coastal Sea Chemical Exchange: A Case Study on the New Jersey Coast     

Yuan Gao  Pami Mukherjee  Rafael Jusino-Atresino 《Aquatic Geochemistry》2016,22(4):275-289

The coastal marine atmosphere adjacent to large urban and industrial centers is in general strongly impacted by pollution emissions, resulting in high loading of pollutants in the ambient air. Among the airborne substances are certain trace elements from a variety of emission sources that can serve as micronutrients to marine organisms in coastal waters. High concentrations of such elements in coastal air can result in enhanced air-to-sea deposition fluxes to coastal waters. They could also be transported over the open ocean, affecting the composition of the remote marine atmosphere and then ocean ecosystems. To provide better understanding of the extent of air-to-sea deposition processes on the New Jersey coast, a heavily polluted coastal region on the US East Coast, a synthesis of observation data was carried out for selected trace elements, including Fe, Cd, Cr and Cu, derived from measurements of both size-segregated and bulk aerosol particles, as well as precipitation around the New Jersey coast. The atmospheric input of Hg was also estimated based on measurement data. Results indicated that the total deposition fluxes of most trace elements were higher in Northern coastal NJ compared to Southern coastal NJ, reflecting the differences in the source strengths of these element emissions between the two coastal regions. Dry deposition processes were more significant for common dust-derived elements, particularly Fe and Al, compared with their wet deposition fluxes. However, the processes of precipitation scavenging appeared to be more important for the elements that were often enriched in fine particles including Zn, Cu, Pb and Ni. The removal of Hg from the ambient air was overwhelmingly dominated by atmospheric wet deposition. In the future, atmospheric measurements at more sites on the NJ coast should be performed simultaneously to reduce the spatial and temporal uncertainties associated with atmospheric deposition fluxes estimated in this study.  相似文献   

The removal kinetics of dissolved organic matter and the optical clarity of groundwater     

Francis H. Chapelle  Yuan Shen  Eric W. Strom  Ronald Benner 《Hydrogeology Journal》2016,24(6):1413-1422

Concentrations of dissolved organic matter (DOM) and ultraviolet/visible light absorbance decrease systematically as groundwater moves through the unsaturated zones overlying aquifers and along flowpaths within aquifers. These changes occur over distances of tens of meters (m) implying rapid removal kinetics of the chromophoric DOM that imparts color to groundwater. A one-compartment input-output model was used to derive a differential equation describing the removal of DOM from the dissolved phase due to the combined effects of biodegradation and sorption. The general solution to the equation was parameterized using a 2-year record of dissolved organic carbon (DOC) concentration changes in groundwater at a long-term observation well. Estimated rates of DOC loss were rapid and ranged from 0.093 to 0.21 micromoles per liter per day (μM d^?1), and rate constants for DOC removal ranged from 0.0021 to 0.011 per day (d^?1). Applying these removal rate constants to an advective-dispersion model illustrates substantial depletion of DOC over flow-path distances of 200 m or less and in timeframes of 2 years or less. These results explain the low to moderate DOC concentrations (20–75 μM; 0.26–1 mg L^?1) and ultraviolet absorption coefficient values (a ₂₅₄?<?5 m^?1) observed in groundwater produced from 59 wells tapping eight different aquifer systems of the United States. The nearly uniform optical clarity of groundwater, therefore, results from similarly rapid DOM-removal kinetics exhibited by geologically and hydrologically dissimilar aquifers.  相似文献   

格尔木河流域河水钾硼锂元素分布特征及富集规律          下载免费PDF全文

唐启亮  张西营  苗卫良  李永寿  李雯霞   王波  薛园  朱广琴 《盐湖研究》2016,24(2):26-31

在柴达木格尔木河流域,随着内陆流域水系的产生与地表径流的消亡,从山区至盐湖区钾(K)硼(B)锂(Li)等有益元素的分布可以划分为淋溶-径流区、径流-蒸发区与溶滤-蒸发浓缩富集区3个具有显著特点的水文化学分带。河水中,K、B、Li含量随矿化度升高而升高,且呈正相关关系。在盐湖区,K、B、Li等资源性元素明显富集。研究发现,格尔木河东部主流(秀水河)是格尔木河水中B和Li的主要贡献者。  相似文献   

矿业权边界在资源储量估算垂直纵投影图上的确定   总被引：1，自引：0，他引：1       下载免费PDF全文

贾绍松  栾元滇  岳伟佳  杨元 《山东国土资源》2016,32(1)

利用垂直纵投影图进行资源储量估算时,当矿体走向与矿业权边界斜交时,矿业权边界在资源储量垂直纵投影图上投影的准确位置较难确定。该文介绍了利用不同中段平面图和利用计算公式确定矿业权边界在资源储量垂直纵投影图上的投影位置,对解决此类问题具有一定的参考价值。  相似文献   

Zircon M127 – A Homogeneous Reference Material for SIMS U–Pb Geochronology Combined with Hafnium,Oxygen and,Potentially, Lithium Isotope Analysis          下载免费PDF全文

Lutz Nasdala  Fernando Corfu  John W. Valley  Michael J. Spicuzza  Fu‐Yuan Wu  Qiu‐Li Li  Yue‐Heng Yang  Chris Fisher  Carsten Münker  Allen K. Kennedy  Peter W. Reiners  Andreas Kronz  Michael Wiedenbeck  Richard Wirth  Chutimun Chanmuang  Manuela Zeug  Tamás Váczi  Nicholas Norberg  Tobias Häger  Alfred Kröner  Wolfgang Hofmeister 《Geostandards and Geoanalytical Research》2016,40(4):457-475

In this article, we document a detailed analytical characterisation of zircon M127, a homogeneous 12.7 carat gemstone from Ratnapura, Sri Lanka. Zircon M127 has TIMS‐determined mean U–Pb radiogenic isotopic ratios of 0.084743 ± 0.000027 for ²⁰⁶Pb/²³⁸U and 0.67676 ± 0.00023 for ²⁰⁷Pb/²³⁵U (weighted means, 2s uncertainties). Its ²⁰⁶Pb/²³⁸U age of 524.36 ± 0.16 Ma (95% confidence uncertainty) is concordant within the uncertainties of decay constants. The δ¹⁸O value (determined by laser fluorination) is 8.26 ± 0.06‰ VSMOW (2s), and the mean ¹⁷⁶Hf/¹⁷⁷Hf ratio (determined by solution ICP‐MS) is 0.282396 ± 0.000004 (2s). The SIMS‐determined δ⁷Li value is ?0.6 ± 0.9‰ (2s), with a mean mass fraction of 1.0 ± 0.1 μg g^?1 Li (2s). Zircon M127 contains ~ 923 μg g^?1 U. The moderate degree of radiation damage corresponds well with the time‐integrated self‐irradiation dose of 1.82 × 10¹⁸ alpha events per gram. This observation, and the (U–Th)/He age of 426 ± 7 Ma (2s), which is typical of unheated Sri Lankan zircon, enable us to exclude any thermal treatment. Zircon M127 is proposed as a reference material for the determination of zircon U–Pb ages by means of SIMS in combination with hafnium and stable isotope (oxygen and potentially also lithium) determination.  相似文献   

Ground deformation induced by vacuum loading–unloading     

Yajun Wu  Fang Xu  Mei Yuan  Dean Sun 《Environmental Earth Sciences》2016,75(3):218

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Application of a distributed degree-day model of glaciers in the upper reaches of the Beida River Basin     

Sheng Wang  Jinfeng Wang  Jianchen Pu 《Environmental Earth Sciences》2016,75(6):493

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Impacts of anthropogenic activities on weathering and carbon fluxes: a case study in the Xijiang River basin,southwest China   总被引：1，自引：0，他引：1  

Shi Yu  Shiyi He  Ping’an Sun  Junbing Pu  Jie Huang  Huixian Luo  Yongshan Li  Rui Li  Yaqiong Yuan 《Environmental Earth Sciences》2016,75(7):589

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