Combining advanced NMR techniques with ultrahigh resolution mass spectrometry: A new strategy for molecular scale characterization of macromolecular components of soil and sedimentary organic matter     

Junyan Zhong  Rachel L. SleighterElodie Salmon  Georgina A. McKeePatrick G. Hatcher 《Organic Geochemistry》2011,42(8):903-916

Molecular level characterization of complex biopolymers in nature is a key element to understanding the composition of natural organic matter (NOM) and fossil organic matter formation, such as kerogen and coal. Characterization of such geopolymers is difficult due to their heterogeneity and insolubility in common aqueous or organic solvents. Here, a strategy for extracting a representative sample is presented using the combined techniques of nuclear magnetic resonance (NMR) and Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) for chemical analysis and characterization of NOM. A variety of NOM samples (wood, kerogen, bitumen, whole sediments) are shown as examples for implementing the strategy, which include solvent extractions using pyridine. For most samples, the extracts are confirmed to be chemically representative of the insoluble solid, by comparing the liquids NMR spectrum of the extract to that of the whole, unfractionated NOM utilizing high resolution magic angle spinning (HRMAS) NMR. To assist in unambiguous peak assignment, a technique for post acquisition spectral denoising, using wavelet transformation (WT), is also employed on the 1D and 2D NMR spectra. The findings from the NMR data lay a foundation for the subsequent electrospray ionization FTICR-MS analysis of the pyridine extracts, since this instrument has the limitation of only analyzing liquid samples. The FTICR-MS analyses can, therefore, be used to molecularly represent the structural components of the NOM. Various compositional insights have been obtained on these samples, indicating the efficacy of the analytical techniques used.  相似文献   

Modelling tidal current turbine wakes using a coupled RANS-BEMT approach as a tool for analysing power capture of arrays of turbines     

Stephen R. Turnock  Alexander B. Phillips  Joe Banks  Rachel Nicholls-Lee 《Ocean Engineering》2011,38(11-12):1300-1307

An improved method is developed to couple an inner domain solution of the blade element momentum theory with an outer domain solution of the Reynolds averaged Navier Stokes equations for evaluating performance of tidal current turbines. A mesh sensitivity study shows that a mesh of at least 6 M cells with at least 40% of these within the turbine wake is required to ensure satisfactory convergence of the velocity deficit. In addition to the usually applied axial momentum source terms, angular momentum and turbulence intensity source terms are shown to be required to model the near wake evolution. Three different lateral turbine spacing of 2, 4 and 6 turbine diameters are used to demonstrate the influence of the effective channel blockage on the velocity distribution in the turbine bypass region, the rate of spread of the wake and the recovery of velocity distribution. A final study shows that for a fixed number of turbines minimising the lateral spacing within each row, with a small number of staggered rows spaced as longitudinally as far apart as practical, is the most effective strategy for energy capture.  相似文献   

Late Devonian OIB alkaline gabbro in the Yarlung Zangbo Suture Zone: Remnants of the Paleo-Tethys?     

Jingen Dai  Chengshan Wang  Réjean Hébert  Yalin Li  Hanting Zhong  Raoult Guillaume  Rachel Bezard  Yushuai Wei 《Gondwana Research》2011,19(1):232-243

The Yarlung Zangbo Suture Zone (YZSZ) is believed to be composed of material largely derived from the destruction of the Neo-Tethys that occurred from early Mesozoic to early Cenozoic. We report here geochronological and petrological data obtained for newly discovered alkaline gabbro blocks embedded in a mélange zone of the western YZSZ. Single zircon U–Pb analyses from one representative gabbro sample by SIMS (Secondary Ion Mass Spectrometry) yielded a combined crystallization age of about 363.7 ± 1.7 Ma (1σ). In situ Hf isotopic analyses yielded ε_Hf(t) values of + 2.6 to + 5.5, suggesting an enriched mantle source. All of the gabbro samples show typical Ocean Island Basalt (OIB) affinity with little or no continental crust contamination. They also display strong geochemical similarities with the Hawaii basalts and the Xigaze seamount basalts suggestive of their intra-oceanic setting. These observations, in combination with the Early Carboniferous layered gabbros reported at Luobusa, indicate that these rocks could represent remnants of the Paleo-Tethys. We propose that a branch ocean separating the Western Qiangtang terrane and the Lhasa terrane from the Gondwana continent might have been present during the Late Devonian and the Early Carboniferous, providing new constrains on the configuration of Paleo-Tethys in Tibetan Plateau during early Late Paleozoic.  相似文献   

The chemical changes of DOM from black waters to coastal marine waters by HPLC combined with ultrahigh resolution mass spectrometry     

Zhanfei Liu  Rachel L. Sleighter  Junyan Zhong  Patrick G. Hatcher 《Estuarine, Coastal and Shelf Science》2011

How dissolved organic matter (DOM) undergoes chemical changes during its transit from river to ocean remains a challenge due to its complex structure. In this study, DOM along a river transect from black waters to marine waters is characterized using an offline combination of reversed-phase high performance liquid chromatography (RP-HPLC) coupled to electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR-MS), as well as tandem ESI-FTICR-MS. In addition, a water extract from degraded wood that mainly consists of lignins is used for comparison to the DOM from this transect. The HPLC chromatograms of all DOM samples and the wood extract show two major well-separated components; one is hydrophilic and the other is hydrophobic, based on their elution order from the C₁₈ column. From the FTICR-MS analysis of the HPLC fractions, the hydrophilic components mainly contain low molecular weight compounds (less than 400 Da), while the hydrophobic fractions contain the vast majority of compounds of the bulk C₁₈ extracted DOM. The wood extract and the DOM samples from the transect of black waters to coastal marine waters show strikingly similar HPLC chromatograms, and the FTICR-MS analysis further indicates that a large fraction of molecular formulas from these samples are the same, existing as lignin-like compounds. Tandem mass spectrometry experiments show that several representative molecules from the lignin-like compounds have similar functional group losses and fragmentation patterns, consistent with modified lignin structural entities in the wood extract and these DOM samples. Taken together, these data suggest that lignin-derived compounds may survive the transit from the river to the coastal ocean and can accumulate there because of their refractory nature.  相似文献   

Influence of seepage undercutting on the stability of root‐reinforced streambanks     

Rachel M. Cancienne  Garey A. Fox  Andrew Simon 《地球表面变化过程与地形》2008,33(11):1769-1786

Several mechanisms contribute to streambank failure including fluvial toe undercutting, reduced soil shear strength by increased soil pore‐water pressure, and seepage erosion. Recent research has suggested that seepage erosion of noncohesive soil layers undercutting the banks may play an equivalent role in streambank failure to increased soil pore‐water pressure. However, this past research has primarily been limited to laboratory studies of non‐vegetated banks. The objective of this research was to utilize the Bank Stability and Toe Erosion Model (BSTEM) in order to determine the importance of seepage undercutting relative to bank shear strength, bank angle, soil pore‐water pressure, and root reinforcement. The BSTEM simulated two streambanks: Little Topashaw Creek and Goodwin Creek in northern Mississippi. Simulations included three bank angles (70° to 90°), four pore‐water pressure distributions (unsaturated, two partially saturated cases, and fully saturated), six distances of undercutting (0 to 40 cm), and 13 different vegetation conditions (root cohesions from 0·0 to 15·0 kPa). A relative sensitivity analysis suggested that BSTEM was approximately three to four times more sensitive to water table position than root cohesion or depth of seepage undercutting. Seepage undercutting becomes a prominent bank failure mechanism on unsaturated to partially saturated streambanks with root reinforcement, even with undercutting distances as small as 20 cm. Consideration of seepage undercutting is less important under conditions of partially to fully saturated soil pore‐water conditions. The distance at which instability by undercutting became equivalent to instability by increased soil pore‐water pressure decreased as root reinforcement increased, with values typically ranging between 20 and 40 cm at Little Topashaw Creek and between 20 and 55 cm at Goodwin Creek. This research depicts the baseline conditions at which seepage undercutting of vegetated streambanks needs to be considered for bank stability analyses. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Phosphorus sources and demand during summer in a eutrophic lake     

Amy M. Kamarainen  Rachel M. Penczykowski  Matthew C. Van de Bogert  Paul C. Hanson  Stephen R. Carpenter 《Aquatic Sciences - Research Across Boundaries》2009,71(2):214-227

  相似文献   

How ready is ready? Measuring physical preparedness for severe storms     

Ryan  Barbara  King  Rachel 《Natural Hazards》2020,104(1):171-199

This paper investigates use of inventories, or checklists of activities, as an emergency management tool to motivate preparedness action in individuals. It develops the inventory concept to provide the foundation for a more targeted approach to storm preparation communication and community engagement. It also examines the potential efficacy of alternatives to paper-based checklists, such as web or smartphone applications. Academic and grey literature was reviewed to collect activities for a storm inventory for emergency agencies to measure individual preparedness and for individuals to measure their preparation progress. The resulting master list was refined for application and tested for useability in a pilot study of semi-structured interviews in a storm-susceptible community in Queensland, Australia. Also, clustering items by type of preparedness activity reveal where strengths and weaknesses exist in individual preparedness. For instance, preparation for leaving and safety planning were shown to be the areas of weakest activity in the pilot sample, while preparation of the house for a storm was the strongest area. In addition, behaviour change literature shows potential for effective use of an inventory-based smartphone application in motivating preparation activity. Data collected by a storm preparedness smartphone application could show where a communication or engagement program for targeted communities should be focused. It is supported by health literature that identifies preferences of individuals to make progress on complex tasks in stages, the value of lists to achievement of goals and demonstrated increase in uptake of activities prompted by smartphone applications over web or paper-based diaries.

  相似文献   

Facies and sequence stratigraphic architecture of the Mural Limestone (Albian), Arizona: Carbonate response to global and local factors and implications for reservoir characterization     

Rachel Aisner-Williams  Charles Kerans 《Sedimentology》2020,67(7):3735-3768

This study documents the detailed facies and sequence stratigraphic architecture of a multi-cyclic patch-reef and its associated ramp interior facies that formed during Oceanic Anoxic Event 1b in the Mural Limestone, Arizona, USA. Ramp interior facies are comprised of bedded wackestone/packstone, rudist build-up and coral–algal patch-reef facies located north of Bisbee, Arizona, at the Grassy Hill locality. The larger multi-cyclic patch-reef that developed coevally ca 5 km to the south of Grassy Hill consists of a high-angle windward margin with a narrow ca 70 m long reef frame containing vertically zonated Microsolena, Actinastrea, diverse branching coral and rudist assemblages, and an 870 m long low-angle leeward margin comprised of reef debris rudstone and grainstone shoal facies. Similar reef geomorphology and orientation is documented across the Gulf of Mexico and reflects the shelf-wide north to north-east-trending prevailing wind and current energies. Controls affecting reef formation and growth patterns include changes in accommodation space associated with low-amplitude global sea-level rise and regional thermotectonic subsidence, local accommodation space and nutrient fluctuations associated with the inner shelf depositional setting within a humid and siliciclastic-rich environment. Four aggradational to retrogradational high-frequency sequences are documented in Arizona: High-frequency sequences 1 and 2 represent the first pulse of patch-reef development in an overall second-order marine transgression over the Sonora/Bisbee Shelf. These sequences correlate to δ¹³C signatures associated with Oceanic Anoxic Event 1b across the Gulf of Mexico and suggest that carbonate reefs persisted on the ramp interior during this time. High-frequency sequences 3 and 4 record a second brief transgression and backstepping of reef facies followed by the final regression of shallow shelf carbonates that correlates to more robust patch-reef development in Sonora, Mexico. The patch-reef at Paul Spur is an excellent outcrop analogue for productive patch-reefs in the Maverick Basin (Comanche Shelf) of Texas. Detailed facies mapping of this outcrop analogue shows that the greatest reservoir potential is contained within the backreef grainstone shoals where primary porosity of up to 15% is observed.  相似文献   

Use of terrestrial photogrammetry for monitoring and measuring bank erosion     

Rachel Barker  Lawrence Dixon  Janet Hooke 《地球表面变化过程与地形》1997,22(13):1217-1227

This paper examines the use of terrestrial photogrammetry as a technique for measuring bank erosion in a rapidly changing fluvial environment. It has been recognized that there are a number of advantages when applying photogrammetric techniques to geomorphological situations. In this study the enhancement of spatial sampling combined with the ability to capture additional information, such as soil moisture, on film, is of particular importance in enabling the identification of specific processes involved in bank erosion as well as detailed volumetric analysis of losses. Metric terrestrial photography was taken of the river bank on several dates, and data were abstracted by the use of analytical photogrammetry. This enabled the generation of digital terrain models from which morphological and volumetric changes could be assessed. © 1997 John Wiley & Sons, Ltd.  相似文献   

Geophysical and geochemical constraints on the age and paleoclimate implications of Holocene lacustrine cores from the Andes of central Chile          下载免费PDF全文

Rachel J. Tiner  Robert M. Negrini  Jose L. Antinao  Eric McDonald  Antonio Maldonado 《第四纪科学杂志》2018,33(2):150-165

  相似文献