Flotation of fluorite with n-alkylammonium chlorides     

J.M. Bruque  F. Gonzalez-Caballero  G. Pardo  R. Perea 《International Journal of Mineral Processing》1982,9(1):75-86

Experimental study on the electrokinetic and flotation behaviour of fluorite in solutions of n-alkylammonium chlorides (with 10, 12 and 14 carbon atoms) is given. The zero point of charge (ZPC) of luorite was determined by measuring zeta potential (streaming potential method) as a function of pH. Two conditioning times of the mineral with the solution were used (10 minutes and 48 hours) and the respective ZPC were located at pH 2.2 and 8.4. Decyl-, dodecyl- and tetradecylammonium ions seem to be strongly adsorbed on the interface because they made the zeta potential more positive as the concentration increases. Hallimond tube flotation of fluorite was studied and shown to be influenced by the chain length of the collector and both collector and hydrogen ion concentrations. Flotation recovery for a given concentration of collector increases with the number of carbon atoms of the chain. The results have been discussed in the light of the electrical double-layer theory.  相似文献   

A quantitative evaluation of Playfair's law and its use in testing long‐term stream erosion models     

Jeffrey D. Niemann  Nicole M. Gasparini  Gregory E. Tucker  Rafael L. Bras 《地球表面变化过程与地形》2001,26(12):1317-1332

Playfair's law (J. Playfair, illustrations of the Huttonian Theory of the Earth, 1802) requires any two tributaries in a river network to lower at the same rate near their junction. Although this law holds exactly at the junction, it is unclear how well it holds in the vicinity of the junction. This issue has practical importance because Playfair's law has been used to estimate parameters for detachment‐limited models of erosion. If the incision rate of a stream is modelled as βA^mSⁿ, where β is an erodibility parameter, A is the area drained by the stream, and S is the local gradient of the channel, then the ratio of the parameters m/n can be estimated from junctions by assuming that Playfair's law holds over the distance used to determine S for each tributary. In this paper, Playfair's law and associated m/n estimates are evaluated for simulated basins with constant and temporally varying uplift rates (or baselevel lowering rates). The results demonstrate that estimates of m/n may be biased for basins with upward‐concave stream profiles because the local slope must be approximated with an average upstream slope. In addition, when uplift rate varies temporally, knickpoints are shown to travel through the basins with constant vertical velocity. Because incision rates vary within the basin, Playfair's law only holds exactly at the junctions. These effects are more important when slopes are measured over longer distances. Finally, measurement techniques are presented which address these potential biases. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

CodaQ as a combination of scattering and intrinsic attenuation: Numerical simulations with the boundary integral method     

Kiyoshi Yomogida  Rafael Benites 《Pure and Applied Geophysics》1996,148(1-2):255-268

Numerical modelling ofSH wave seismograms in media whose material properties are prescribed by a random distribution of many perfectly elastic cavities and by intrinsic absorption of seismic energy (anelasticity) demonstrates that the main characteristics of the coda waves, namely amplitude decay and duration, are well described by singly scattered waves in anelastic media rather than by multiply scattered waves in either elastic or anelastic media. We use the Boundary Integral scheme developed byBenites et al. (1992) to compute the complete wave field and measure the values of the direct waveQ and coda wavesQ in a wide range of frequencies, determining the spatial decay of the direct wave log-amplitude relation and the temporal decay of the coda envelope, respectively. The effects of both intrinsic absorption and pure scattering on the overall attenuation can be quantified separately by computing theQ values for corresponding models with (anelastic) and without (elastic) absorption. For the models considered in this study, the values of codaQ ^–1 in anelastic media are in good agreement with the sum of the corresponding scatteringQ ^–1 and intrinsicQ ^–1 values, as established by the single-scattering model ofAki andChouet (1975). Also, for the same random model with intrinsic absorption it appears that the singly scattered waves propagate without significant loss of energy as compared with the multiply scattered waves, which are strongly affected by absorption, suggesting its dominant role in the attenuation of coda waves.  相似文献   

An audio-magnetotelluric investigation in Terceira Island (Azores)   总被引：2，自引：0，他引：2  

Fernando A. Monteiro Santos  Antnio Trota  Antnio Soares  Rafael Luzio  Nuno Loureno  Liliana Matos  Eugnio Almeida  Joo L. Gaspar  Jorge M. Miranda 《Journal of Applied Geophysics》2006,59(4):314-323

Ten audio-magnetotelluric soundings have been carried out along a profile crossing the Serra do Cume caldera in the eastern part of the Terceira Island (Azores). The main objectives of this investigation were to detect geoelectrical features related with tectonic structures and to characterize regional hydrological and hydrothermal aspects mainly those related to geothermal fluid dynamics.Three-dimensional numerical investigation showed that the data acquired at periods shorter than 1 s are not significantly affected by ocean effect. The data was analysed using the Smith's decomposition method in order to investigate possible distortions caused by superficial structures and to estimate a global regional strike. The results suggest that in general the soundings were not distorted. A regional N55°W strike was chosen for the two-dimensional data inversion.The low-resistivity zones (10–30 ohm-m) displayed in the central part of the 2-D geoelectrical model have been interpreted as caused by hydrothermal circulation. The low-resistivity anomalies at the ends of the profile might be attributed to alteration zones with interaction of seawater intrusion. High-resistivity (> 300 ohm-m) values have been related with less permeable zones in the SW of Cinco Picos and Guilherme Moniz caldera walls.  相似文献   

Structural framework and Mesozoic–Cenozoic evolution of Ponta Grossa Arch, Paraná Basin, southern Brazil     

Michael Strugale  Sidnei Pires Rostirolla  Fernando Mancini  Carlos Vieira Portela Filho  Francisco Jos Fonseca Ferreira  Rafael Corrêa de Freitas 《Journal of South American Earth Sciences》2007,24(2-4):203-227

  相似文献   

The development of folds in bedded chert and related rocks in the Malaguide Complex, southern Spain     

Miguel Orozco  Rafael Galvez 《Tectonophysics》1979,56(3-4)

Folds and folding mechanism in a chert sequence and related rocks of the Maláguide Complex (the uppermost tectonic unit of the Betic Zone) have been investigated. The geometric study shows that folds that developed in the chert sequence are usually angular in shape and asymmetric. Chevron and conjugate folds are common.Folding in bedded chert is explained in terms of a suggested model:

1. (1) Development of folds by kink and conjugate kinking.

2. (2) As the shortening increases, the interlimb angles decrease; in the kink folds this is caused by a reduction of the angle between the layers within the kink and the kink boundaries. There seems to be a relationship between this angle and the asymmetrical thinning-out in the limbs of many folds: the smaller is the angle between the kink boundary and the layers within the kink band, the larger is the reduction of the thickness in these layers.

Single limestone layers embedded in slate deform very probably by a buckling mechanism, implying tangential longitudinal strain and an additional flattening.  相似文献   

Low calcification rates and calcium carbonate production in Porites panamensis at its northernmost geographic distribution          下载免费PDF全文

Carlos Orión Norzagaray‐López  Luis Eduardo Calderon‐Aguilera  José Martín Hernández‐Ayón  Héctor Reyes‐Bonilla  Juan P. Carricart‐Ganivet  Rafael Andrés Cabral‐Tena  Eduardo Francisco Balart 《Marine Ecology》2015,36(4):1244-1255

Porites panamensis is a hermatypic coral present in the eastern Pacific Ocean. Skeletal growth parameters have been reported, but studies of the relationship between annual calcification rates and environmental controls are scarce. In this study, we investigated three aspects of the annual calcification rates of P. panamensis: growth parameters among three P. panamensis populations; the sea surface temperature as a calcification rate control spanning a latitudinal gradient; and calcium carbonate production among three sites. Growth parameters varied among the sites due to the colony growth form. Massive colonies in the north showed a higher calcification rate than encrusting colonies in the south (mean: 1.22–0.49 g CaCO₃ · cm^?2 · yr^?1), where variations in calcification rates were related to growth rate (0.91–0.38 cm · yr^?1) rather than to skeletal density differences (overall mean ± SD, 1.31 ± 0.04 g CaCO₃ · cm^?3). Our results showed a positive linear relationship between annual calcification rates and sea surface temperatures within these P. panamensis populations. Differences were related to distinct oceanographic environments (within and at the entrance of the Gulf of California) with different sea surface temperature regimes and other chemical properties. Different populations calcified under different environmental conditions. Calcium carbonate production was dependent upon the calcification rate and coral cover and so carbonate production was higher in the north (coral cover 12%) than in the south (coral cover 3.5). Thus, the studied sites showed low calcium carbonate production (0.25–0.43 kg CaCO₃ · m^?2 · yr^?1). Our results showed reduced calcification rates, regional temperature regime control over calcification rates, different growth forms, low coral cover and low calcium carbonate production rates in P. panamensis.  相似文献   

Early-Morning Flow Transition in a Valley in Low-Mountain Terrain Under Clear-Sky Conditions     

Björn Brötz  Rafael Eigenmann  Andreas Dörnbrack  Thomas Foken  Volkmar Wirth 《Boundary-Layer Meteorology》2014,152(1):45-63

We investigate the evolution of the early-morning boundary layer in a low-mountain valley in south-western Germany during COPS (convective and orographically induced precipitation study) in summer 2007. The term low-mountain refers to a mountainous region with a relief of gentle slopes and with an absolute altitude that remains under a specified height (usually 1,500 m a.s.l.). A subset of 23 fair weather days from the campaign was selected to study the transition of the boundary-layer flow in the early morning. The typical valley atmosphere in the morning hours was characterized by a stable temperature stratification and a pronounced valley wind system. During the reversal period—called the low wind period—of the valley wind system (duration of 1–2 h), the horizontal flow was very weak and the conditions for free convection were fulfilled close to the ground. Ground-based sodar observations of the vertical wind show enhanced values of upward motion, and the corresponding statistical properties differ from those observed under windless convective conditions over flat terrain. Large-eddy simulations of the boundary-layer transition in the valley were conducted, and statistical properties of the simulated flow agree with the observed quantities. Spatially coherent turbulence structures are present in the temporal as well as in the ensemble mean analysis. Thus, the complex orography induces coherent convective structures at predictable, specific locations during the early-morning low wind situations. These coherent updrafts, found in both the sodar observations and the simulation, lead to a flux counter to the gradient of the stably stratified valley atmosphere and reach up to the heights of the surrounding ridges. Furthermore, the energy balance in the surface layer during the low wind periods is closed. However, it becomes unclosed after the onset of the valley wind. The partition into the sensible and the latent heat fluxes indicates that missing flux components of sensible heat are the main reason for the unclosed energy balance in the considered situations. This result supports previously published investigations on the energy balance closure.  相似文献   

Modelling river water temperature using deterministic,empirical, and hybrid formulations in a Mediterranean stream     

Rafael Marcé  Joan Armengol 《水文研究》2008,22(17):3418-3430

River water temperature is a common target of water quality models at the watershed scale, owing to its principal role in shaping biogeochemical processes and in stream ecology. Usually, models include physically‐based, deterministic formulations to calculate water temperatures from detailed meteorological information, which usually comes from meteorological stations located far from the river reaches. However, alternative empirical approaches have been proposed, that usually depend on air temperature as master variable. This study explored the performance of a semidistributed water quality application modelling river water temperature in a Mediterranean watershed, using three different approaches. First, a deterministic approach was used accounting for the different heat exchange components usually considered in water temperature models. Second, an empirical approximation was applied using the equilibrium temperature concept, assuming a linear relationship with air temperature. And third, a hybrid approach was constructed, in which the temperature equilibrium concept and the deterministic approach were combined. Results showed that the hybrid approach gave the best results, followed by the empirical approximation. The deterministic formulation gave the worst results. The hybrid approach not only fitted daily river water temperatures, but also adequately modelled the daily temperature range (maximum–minimum daily temperature). Other river water features directly dependent on water temperature, such as river intrusion depth in lentic systems (i.e. the depth at which the river inflow plunges to equilibrate density differences with lake water), were also correctly modelled even at hourly time steps. However, results for the different heat fluxes between river and atmosphere were very unrealistic. Although direct evidence of discrepancies between meteorological drivers measured at the meteorological stations and the actual river microclimate was not found, the use of models including empirical or hybrid formulations depending mainly on air temperature is recommended if only meteorological data from locations far from the river reaches are available. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Towards a comprehensive approach to parameter estimation in land surface parameterization schemes     

Rafael Rosolem  Hoshin V. Gupta  W. James Shuttleworth  Luis Gustavo Gonçalves de Gonçalves  Xubin Zeng 《水文研究》2013,27(14):2075-2097

In climate models, the land–atmosphere interactions are described numerically by land surface parameterization (LSP) schemes. The continuing improvement in realism in these schemes comes at the expense of the need to specify a large number of parameters that are either directly measured or estimated. Also, an emerging problem is whether the relationships used in LSPs are universal and globally applicable. One plausible approach to evaluate this is to first minimize uncertainty in model parameters by calibration. In this paper, we conduct a comprehensive analysis of some model diagnostics using a slightly modified version of the Simple Biosphere 3 model for a variety of biomes located mainly in the Amazon. First, the degree of influence of each individual parameter in simulating surface fluxes is identified. Next, we estimate parameters using a multi‐operator genetic algorithm applied in a multi‐objective context and evaluate simulations of energy and carbon fluxes against observations. Compared with the default parameter sets, these parameter estimates improve the partitioning of energy fluxes in forest and cropland sites and provide better simulations of daytime increases in assimilation of net carbon during the dry season at forest sites. Finally, a detailed assessment of the parameter estimation problem was performed by accounting for the decomposition of the mean squared error to the total model uncertainty. Analysis of the total prediction uncertainty reveals that the parameter adjustments significantly improve reproduction of the mean and variability of the flux time series at all sites and generally remove seasonality of the errors but do not improve dynamical properties. Our results demonstrate that error decomposition provides a meaningful and intuitive way to understand differences in model performance. To make further advancements in the knowledge of these models, we encourage the LSP community to adopt similar approaches in the future. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献