Synthesis of monticellite–forsterite and merwinite–forsterite symplectites in the CaO–MgO–SiO<Subscript>2</Subscript> model system: influence of temperature and water content on microstructure evolution     

P.?Remmert  W.?Heinrich  B.?Wunder  L.?Morales  R.?Wirth  D.?Rhede  R.?AbartEmail authorView author&#;s OrcID profile 《Contributions to Mineralogy and Petrology》2018,173(1):5

Homogeneous single crystals of synthetic monticellite with the composition \({\text{Ca}}_{0.88}{\text{Mg}}_{1.12}{\text{SiO}}_4\) (Mtc I) were annealed in a piston-cylinder apparatus at temperatures between 1000 and \(1200\,^{\circ }\hbox {C}\), pressures of 1.0–1.4 GPa, for run durations from 10 min to 24 h and applying bulk water contents ranging from 0.0 to 0.5 wt% of the total charge. At these conditions, Mtc I breaks down to a fine-grained, symplectic intergrowth. Thereby, two types of symplectites are produced: a first symplectite type (Sy I) is represented by an aggregate of rod-shaped forsterite immersed in a matrix of monticellite with end-member composition (Mtc II), and a second symplectite type (Sy II) takes the form of a lamellar merwinite–forsterite intergrowth. Both symplectites may form simultaneously, where the formation of Sy I is favoured by the presence of water. Sy I is metastable with respect to Sy II and is successively replaced by the latter. For both symplectite types, the characteristic spacing of the symplectite phases is independent of run duration and is only weeakly influenced by the water content, but it is strongly temperature dependent. It varies from about 400 nm at \(1000\,^{\circ }\hbox {C}\) to 1200 nm at \(1100\,^{\circ }\hbox {C}\) in Sy I, and from 300 nm at \(1000\,^{\circ }\hbox {C}\) to 700 nm at \(1200\,^{\circ }\hbox {C}\) in Sy II. A thermodynamic analysis reveals that the temperature dependence of the characteristic spacing of the symplectite phases is due to a relatively high activation energy for chemical segregation by diffusion within the reaction front as compared to the activation energy for interface reactions at the reaction front. The temperature dependence of the characteristic lamellar spacing and the temperature-time dependence of overall reaction progress have potential for applications in geo-thermometry and geo-speedometry.  相似文献   

Erratum to: Polymorphic phase transition in Superhydrous Phase B     

M. Koch-Müller  P. Dera  Y. Fei  H. Hellwig  Z. Liu  J. Van Orman  R. Wirth 《Physics and Chemistry of Minerals》2014,41(9):725-725

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Mullite in Libyan Desert Glass: Evidence for high-temperature/low-pressure formation          下载免费PDF全文

Ansgar Greshake  Richard Wirth  Jörg Fritz  Tomasz Jakubowski  Ute Böttger 《Meteoritics & planetary science》2018,53(3):467-481

Libyan Desert Glass (LDG) is a SiO₂-rich natural glass whose origin, formation mechanism, and target material are highly debated. We here report on the finding of a lens-shaped whitish inclusion within LDG. The object is dominantly composed of siliceous glass and separated from the surrounding LDG by numerous cristobalite grains. Within cristobalite, several regions rich in mullite often associated with ilmenite were detected. Mineral assemblage, chemical composition, and grain morphologies suggest that mullite was formed by thermal decomposition of kaolinitic clay at atmospheric pressure and T ≥ 1600 °C and also attested to high cooling rates under nonequilibrium conditions. Cristobalite contains concentric and irregular internal cracks and is intensely twinned, indicating that first crystallized β-cristobalite inverted to α-cristobalite during cooling of the SiO₂-rich melt. The accompanied volume reduction of 4% induced the high density of defects. The whitish inclusion also contains several partly molten rutile grains evidencing that at least locally the LDG melt was at T ≥ 1800 °C. Based on these observations, it is concluded that LDG was formed by high-temperature melting of kaolinitic clay-, rutile-, and ilmenite-bearing Cenozoic sandstone or sand very likely during an asteroid or comet impact onto Earth. While melting and ejection occurred at high pressures, the melt solidified quickly at atmospheric pressure.  相似文献   

Grain boundary and volume diffusion experiments in yttrium aluminium garnet bicrystals at 1,723 K: a miniaturized study     

Katharina?Marquardt  Elena?Petrishcheva  Emmanuel?Gardés  Richard?Wirth  Rainer?Abart  Wilhelm?Heinrich 《Contributions to Mineralogy and Petrology》2011,162(4):739-749

Yb-Y inter-diffusion along a single grain boundary of a synthetic yttrium aluminium garnet (YAG) bicrystal has been studied using analytical transmission electron microscopy (ATEM). To investigate the diffusion, a thin-film containing Yb as the diffusant was deposited perpendicular to the bicrystal grain boundary by pulsed laser deposition (PLD). Structural properties and their change with time in both the diffusant source and the grain boundary are reported. The diffusion profiles are incorporated in a numerical diffusion model, which is applied to determine the grain boundary diffusion coefficient, D _gb , at 1.723 K it is equal to 3 × 10⁻¹⁵ m²/s. We find that grain boundary diffusion is 4.85 orders of magnitude faster than volume diffusion, which was determined from the same diffusion experiment. This result is discussed in the context of special versus general grain boundaries. Finally, we successfully tested the capability of synchrotron-based nano-X-ray fluorescence analysis to map micro-chemical patterns in two dimensions with sub-micrometre resolution.  相似文献   

Mineralogical siting of platinum-group elements in pentlandite from the Bushveld Complex,South Africa     

Malte Junge  Richard Wirth  Thomas Oberthür  Frank Melcher  Anja Schreiber 《Mineralium Deposita》2015,50(1):41-54

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Carbon-bearing phases in shock-induced melt zones of the Elga meteorite     

N. R. Khisina  S. N. Teplyakova  R. Wirth  V. G. Senin  A. A. Averin  A. A. Shiryaev 《Geochemistry International》2017,55(4):317-329

The mineralogy and texture of shock-induced melt veinlets and melt pockets in silicate inclusions in the Elga IIE iron meteorite have been studied by reflected-light optical microscopy, EMPA, SEM, Raman spectroscopy and TEM. The results suggest that Elga experienced two discrete impact events. The earlier event involved the collision of a metallic projectile with a silicate target and resulted in partial melting and recrystallization of the silicate material, forming schreibersite and oxide rims between the metal and silicate. The later impact event resulted in melt pockets in the silicate inclusions and was associated with fragmentation, melting, and brecciation of the rims and displacement of some fragments into the melt pockets. These fragments are shown to contain carbon-bearing phases: siderite and amorphous sp ² carbon, which form carbon–oxide, siderite–oxide, and siderite–schreibersite associations. The fact that the carbon-bearing fragments are spatially constrained to shock breccia and melt zones indicates that these fragments are genetically related to the impact process and that their carbon-bearing phases are of cosmic origin.  相似文献   

A re-examination of petrogenesis and 40Ar/39Ar systematics in the Chain of Ponds K-feldspar: “diffusion domain” archetype versus polyphase hygrochronology     

Alex N. Chafe  Igor M. Villa  John M. Hanchar  Richard Wirth 《Contributions to Mineralogy and Petrology》2014,167(5):1-17

K-feldspar (Kfs) from the Chain of Ponds Pluton (CPP) is the archetypal reference material, upon which thermochronological modeling of Ar diffusion in discrete “domains” was founded. We re-examine the CPP Kfs using cathodoluminescence and back-scattered electron imaging, transmission electron microscopy, and electron probe microanalysis. ⁴⁰Ar/³⁹Ar stepwise heating experiments on different sieve fractions, and on handpicked and unpicked aliquots, are compared. Our results reproduce the staircase-shaped age spectrum and the Arrhenius trajectory of the literature sample, confirming that samples collected from the same locality have an identical Ar isotope record. Even the most pristine-looking Kfs from the CPP contains successive generations of secondary, metasomatic/retrograde mineral replacements that post-date magmatic crystallization. These chemically and chronologically distinct phases are responsible for its staircase-shaped age spectra, which are modified by handpicking. While genuine within-grain diffusion gradients are not ruled out by these data, this study demonstrates that the most important control on staircase-shaped age spectra is the simultaneous presence of heterochemical, diachronous post-magmatic mineral growth. At least five distinct mineral species were identified in the Kfs separate, three of which can be traced to external fluids interacting with the CPP in a chemically open system. Sieve fractions have size-shifted Arrhenius trajectories, negating the existence of the smallest “diffusion domains.” Heterochemical phases also play an important role in producing nonlinear trajectories. In vacuo degassing rates recovered from Arrhenius plots are neither related to true Fick’s Law diffusion nor to the staircase shape of the age spectra. The CPP Kfs used to define the “diffusion domain” model demonstrates the predominance of metasomatic alteration by hydrothermal fluids and recrystallization in establishing the natural Ar distribution among different coexisting phases that gives rise to the staircase-shaped age spectrum. Microbeam imaging of textures is as essential for ⁴⁰Ar/³⁹Ar hygrochronology as it is for U–Pb geochronology.  相似文献   

Sedimentological investigations of metamorphic clastics: the basal clastic rocks of the Brenner Mesozoic (Stubai Alps, Austria/Italy)     

Volkmar Stingl  Peter Krois 《地学学报》1990,2(3):273-281

Sedimentological investigations were carried out in the basal clastic rocks of the Brenner Mesozoic in the Stubai Alps. These are Scythian in age and metamorphosed to a greenschist grade. The increase of temperature and pressure from north to south allows the metamorphic effects on Sedimentological features to be gradually traced into higher grade metamorphic areas. The use of various laboratory methods as well as profiling with lithofacies types shows the limitation of using only single methods in sediments suffering thermal and deformational overprint. Only a combined application of different methods allows the extraction of useful sedimentological information. Based on the results of these investigations, a fan delta to shelf succession is proposed for the basal clastic rocks. Petrographic analyses show the relation of the sediments to an underlying weathering horizon.  相似文献   

Koordinatentransformation,Mittelbare Orientierung,Nachbarwinkelstatistik     

Dr. Hans-Rudolf Wenk  Dr. Volkmar Trommsdorff 《Contributions to Mineralogy and Petrology》1965,11(6):559-585

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Microtexture,nanomineralogy, and local chemistry of cryptocrystalline cosmic spherules     

N. R. Khisina  D. D. Badyukov  R. Wirth 《Geochemistry International》2016,54(1):68-77

The paper reports scanning electron microscopy (FEG-SEM) and transmission electron microscopy (TEM) data on three cryptocrystalline (CC) cosmic spherules of chondritic composition (Mg/Si ≈ 1) from two collections taken up at glaciers at the Novaya Zemlya and in the area of the Tunguska event. The spherules show “brickwork” microtextures formed by minute parallel olivine crystals set in glass of pyroxene–plagioclase composition. The bulk-rock silicate chemistry, microtexture, mineralogy, and the chemical composition of the olivine and the local chemistry of the glass in these spherules testify to a chondritic source of the spherules. The solidification of the spherules in the Earth’s atmosphere was proved to be a highly unequilibrated process. A metastable state of the material follows, for example, from the occurrence of numerous nanometer-sized SiO₂ globules in the interstitial glass. These globules were formed by liquid immiscibility in the pyroxene–SiO₂ system. Troilite FeS and schreibersite (Fe,Ni)₃P globules were found in the FeNi metal in one of the spherules, which suggests that the precursor was not chemically modified when melted in the Earth’s atmosphere. Our results allowed us to estimate the mineralogy of the precursor material and correlate the CC spherules with the chondrule material of chondrites. The bulk compositions of the spherules are closely similar to those of type-IIA chondrules.  相似文献