Test of the vibrational modelling for the λ-type transitions: Application to the α-β quartz transition     

Joëlle Castex  Michel Madon 《Physics and Chemistry of Minerals》1995,22(1):1-10

Vibrational modelling is at the present time the only known way to predict the heat capacities of the Earth's mantle minerals at high-pressure and high-temperature. To test the validity of this method for λ-type transitions, we have applied it to the α-β quartz transition (T ₀=846±1 K). Raman spectra of quartz were recorded up to 900 K. Measured frequency shifts of the α-quartz Raman modes were then used in conjunction with available high-pressure Raman data to calculate intrinsic mode anharmonicity, through the parameter a _i=(?Lnv_i/?T)_v. Vibrational modelling of the heat capacity at constant volume, Cv, and at constant pressure, Cp, including anharmonic corrections deduced from the a _i parameters, are compared to experimental data. Taking into account the soft-mode associated to the α-β quartz transition, the model reproduces the excess of Cp related to the transition. Then, this study confirms that detecting a soft-mode from vibrational data allows one to predict λ-type transitions. However, when modelling the thermodynamic properties, the contribution of a soft-mode cannot be established from spectroscopic data. Therefore, one needs first to determine this contribution in order to predict the heat capacities of Earth's mantle minerals displaying λ-type transitions. In α-quartz, this contribution has been determined as 0.007% of the total number of the optic modes in the model of the density of states.  相似文献   

Chronostratigraphy and paleoclimatic meaning of cryogenic deformations in the Central European loess     

Brigitte van Vliet-Lanoë Dr. 《GeoJournal》1991,24(2):157-163

Cryoturbations in loess reflect cold and wet environments but not necessarily permafrost. Only flat bottomed cryoturbations are indicative of it. Outside the permafrost zone they occur during the wet period of the last glaciation: during the early Weichselian, the lower pleniglacial, the end of the middle pleniglacial and the late glacial. Their morphology ist related to the frost susceptibility of the superimposed layers, expressed in form of differential frost heaving, ruled by the drainage quality and the frost susceptibility gradient. Their diagenesis is discussed.  相似文献   

Annual variation of relationship between global radiation and cloud coverage using METEOSAT images     

Dr. A. Rimóczi-Paál 《Theoretical and Applied Climatology》1985,36(1):67-72

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Flocculation of smithsonite and dolomite using polymers containing nitrogen atoms     

A.S. Śláczka  J. Paprotny 《International Journal of Mineral Processing》1985,14(4):319-325

The possibility was investigated of carrying out selective flocculation in the model set smithsonite-dolomite using polymers containing nitrogen atoms, which should interact selectively with zinc minerals.A high activity of flocculants in relation to smithsonite and a low activity towards dolomite was observed. However, the activation of the dolomite surface by Zn²⁺ ions was determined whereby the selective flocculation was not observed in the mixture of smithsonite and dolomite.  相似文献   

Sites occupancy of Fe3+ in Garfield Nontronite: A spectroscopic study     

Dominique Bonnin  Georges Calas  Hélène Suquet  Henri Pezerat 《Physics and Chemistry of Minerals》1985,12(1):55-64

New data on the structure of Garfield nontronite have been produced by the use of different spectroscopic techniques: Mössbauer spectroscopy, optical spectroscopy, X-ray absorption edges and EXAFS and NMR. The tetrahedral iron content is found to be no higher than 1 percent. All iron atoms belong to the octahedral sheet excluding the possibility of the presence of non crystallized phases. Some ambiguities remain about the coherence of the octahedral sheet because of the presence of two doublets in the Mössbauer spectrum and at least two lineshapes in NMR spectra of OH which correspond to different environments.  相似文献   

Turbulent heat fluxes by profile and inertial dissipation methods: analysis of the atmospheric surface layer from shipboard measurements during the SOFIA/ASTEX and SEMAPHORE experiments     

Hélène Dupuis  Alain Weill  Kristina Katsaros  Peter K. Taylor 《Annales Geophysicae》1995,13(10):1065-1074

Heat flux estimates obtained using the inertial dissipation method, and the profile method applied to radiosonde soundings, are assessed with emphasis on the parameterization of the roughness lengths for temperature and specific humidity. Results from the inertial dissipation method show a decrease of the temperature and humidity roughness lengths for increasing neutral wind speed, in agreement with previous studies. The sensible heat flux estimates were obtained using the temperature estimated from the speed of sound determined by a sonic anemometer. This method seems very attractive for estimating heat fluxes over the ocean. However allowance must be made in the inertial dissipation method for non-neutral stratification. The SOFIA/ASTEX and SEMAPHORE results show that, in unstable stratification, a term due to the transport terms in the turbulent kinetic energy budget, has to be included in order to determine the friction velocity with better accuracy. Using the profile method with radiosonde data, the roughness length values showed large scatter. A reliable estimate of the temperature roughness length could not be obtained. The humidity roughness length values were compatible with those found using the inertial dissipation method.  相似文献   

Investigation of relationship between cloudiness and global radiation using METEOSAT images     

A. Paál 《Pure and Applied Geophysics》1987,125(1):109-120

The relationship between the daily values of global radiation measured at the ground in the vicinity of Budapest and in the Hungarian Great Plain and two kinds of cloud parameters determined on the basis of METEOSAT analogue paper pictures was studied for the period between November 1981 and July 1983. One of the cloud parameters, the cloud coverage given in tenths, has a quadratic relationship with the surface global radiation. The other cloud parameter, the relative brightness, is in a good linear connection with the global radiation. The advantage of the first parameter is that its determination does not demand any technical equipment, but the second parameter is more objective. The comparison of the calculated global radiation values with the data measured shows that the precision of the formulae determined is good in both cases.  相似文献   

U-Pb dating of an early paleozoic bimodal magmatism in the french Massif Central and of its further metamorphic evolution     

Christian Pin  Joël Lancelot 《Contributions to Mineralogy and Petrology》1982,79(1):1-12

In the Marvejols area (Southern french Massif Central), the gneissic Marvejols supergroup is overthrust on the metasedimentary “Série du Lot”, deposited in part prior to 540 Ma. The allochtonous terranes are characterized by the occurrence of a leptyno-amphibolitic group, a complex association of mafic and felsic rocks of igneous and sedimentary derivation. A 480±10 Ma age has been obtained by U-Pb dating of zircons, for the crystallization of both mafic and felsic meta-igneous rocks. These rocks were emplaced during an important extensional tectonics. Relics of eclogites, pyrigarnites, coronite gabbros and HP-trondhjemites are clear evidence for a further HP-HT event dated at 415±6 Ma on zircons from a HP trondhjemite. Subsequently, the Marvejols supergroup underwent an amphibolite facies metamorphism with incipient mobilization dated at 345±10 Ma. Rifting and thinning of the continental crust in Cambro-Ordovician times appears to be a major geodynamic feature which could account for the thermal events often referred to the “Caledonian” orogeny. The Silurian (415 Ma) age of the HP episode is clearly older than the main Variscan tectonometamorphic event; it is in agreement with Rb-Sr dating of the Moldanubian granulites and with some radiometric data from Southern Brittany (France). These results point to a compressive phase, probably in a subduction context, in view of the high pressures reached (15–20 Kb), after the Cambro-Ordovician distensive phase. The main final tectono-metamorphic paroxysm (blocking of subduction process and continental collison ?) is not prior to the end of Devonian (340–350 Ma) and is related to the Variscan orogeny s.s  相似文献   

Neotectonics of the Pontides: implications for ‘incompatible’ structures along the North Anatolian fault     

A.M Celál Şengör  Si̇lva Büyükaşikoğlu  Nezi̇hi̇ Canitez 《Journal of Structural Geology》1983,5(2):211-216

Data for the post-Serravallian, ‘neotectonic’ evolution of the Pontides in northern Turkey indicate predominant ENE-WSW shortening with complementary NNW-SSE extension. We present a new fault plane solution for the Bartin earthquake (3 September 1968) and compare its mechanism with the movement picture of other neotectonic faults in the Pontides and northern Greece together with that of the Thessaloniki earthquake (20 May 1978). The general strain pattern exhibited by these structures agrees remarkably well with that inferred from early Tortonian-early Pleistocene structures reported from within the North Anatolian fault zone, which have been interpreted as indicating a possible reversal of the sense of movement along the North Anatolian transform fault. Here, we argue that such ‘incompatible’ structures may be related to the overall E-W shortening of Anatolia and the southern parts of the Black Sea resulting from the sideways continental escape from around the African and the Arabian promontories, rather than to hypothetical reversal of motion along the North Anatolian fault, for which there is no evidence other than the above-mentioned ‘incompatible’ structures. This new model also has important implications for seismicity and earthquake risk in regions contained within the southern part of the Black Sea plate.  相似文献   

Influence of Temporal Variations in River Discharge, pH, Alkalinity and Ca on the Speciation and Concentration of Heavy Metals in Some Mining Polluted Rivers     

Pål Gundersen  Eiliv Steinnes 《Aquatic Geochemistry》2001,7(3):173-193

Dissolved (dialysis in situ) and total concentrations ofCu, Zn, Cd and Al in eight mining polluted rivers in the Røros area, central Norway, were determinedby atomic absorption spectrometry (flame and graphite furnace) and compared to pH, Caconcentration and alkalinity through seasonal variations in river discharge. Totalconcentrations of the metals were highest during early spring flood and during summer andautumn rain episodes. Dissolved concentrations also increased as the spring floodproceeded, but small discharge peaks within this 2 month period as well as a considerableautumn flood episode appeared to lower rather than to raise the dissolved metal concentrations.Consequently the dissolved fractions of Zn, Cd and Al showed a significant negative correlationwith river discharge, and were low at the discharge peaks. Possibly high sediment concentrationsoccurring at high flood conditions more than counteracted desorption induced by pHdecrease, and led to decreased dissolved fractions through adsorption. Cu speciationon the other hand seemed to be more closely linked to pH. Alkalinity and Ca concentration,both assumed to protect aquatic life from metal pollution, were significantly lowerduring episodes with high Cu and Al total concentrations.  相似文献