Modifications in the solubility and precipitation behavior of various metals as a result of their interaction with sedimentary humic acid     

M.A. Rashid  J.D. Leonard 《Chemical Geology》1973,11(2):89-97

The sedimentary humic acid or its acid-hydrolysate, consisting of various amino acids, was found effective in dissolving unusually large quantities of metals (up to 682 mg/g of organic matter) from their insoluble salts. The presence of humic acid in the reaction media which had favorable conditions for the precipitation of metals as carbonates, hydroxides or sulfides, prevented the formation of insoluble metal salts. Infrared analysis suggests that the metals added to various anionic systems and humic acid do not react with the anion. The most likely mechanism of reaction appears to be a complex formation between metals and organic matter which keeps the metal in solution.The enhanced solubility and consequent decrease in precipitation of metals under the influence of humic compounds, as evidenced in these studies should play a leading role in the accumulation of metals in sedimentary deposits.  相似文献   

Environmental controls of methane production in Holocene basins in eastern Canada     

M.A. Rashid  G. Vilks 《Organic Geochemistry》1977,1(1):53-59

Rapid rates of sedimentation from 54 to 134 cm/1000 yr are typical of the Holocene basins in St. Margaret's Bay and the Grand Manan Basin, Nova Scotia. The water column is well oxygenated but, because of the rapid rate of sedimentation, anoxic conditions developed and enhanced the preservation of organic matter and its fermentative degradation; also the concentrations of sulfide increased and soluble sulfates were rapidly depleted. A direct result of this has been the production of methane in amounts exceeding 22,000 ppm. In contrast, nearby cores with rates of sedimentation of less than 20 cm/1000 yr have only 30–40 ppm methane. High rates of sedimentation and the ensuing anaerobic conditions appear to be the principal factors for the genesis and preservation of methane.The δ ¹³C values and the n-alkane distribution show that there is more terrestrial organic matter in the Grand Manan Basin than in St. Margaret's Bay. This could account for the high concentrations of methane in the Grand Manan cores despite the low concentrations of organic carbon.  相似文献   

High Ni Levels in Soil Can Modify Growth Performance and Mineral Status of Wheat Cultivars          下载免费PDF全文

Muhammad Sabir  Khalid Rehman Hakeem  Tariq Aziz  Muhammad Zia‐ur‐Rehman  Irfan Rashid  Munir Ozturk 《洁净——土壤、空气、水》2014,42(9):1263-1271

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Erosion potential assessment of watersheds through GIS<Emphasis Type="Bold">-</Emphasis>based hypsometric analysis: a case study of Kurram Tangi Dam     

Wasif Yousaf  Syed Ghulam Mohayud-Din-Hashmi  Usman Akram  Urooj Saeed  Sajid Rashid Ahmad  Muhammad Umar  Ambreena Mubashir 《Arabian Journal of Geosciences》2018,11(22):711

Sediment discharge due to soil and rock erosion within the watersheds is the major cause of siltation in water reservoirs. Siltation in reservoirs reduces the capacity for power production, irrigation water supply, and other domestic purposes. Hypsometric analysis has widely been used to identifying the geomorphic development stages (stabilized, equilibrium, and un-stable) to assess the erosion proneness of watersheds. In this study, watershed of Kurram Tangi Dam and its four sub-watersheds (SWs) were considered to determine their sediment discharge capacity through hypsometric analysis. The boundaries of watershed and sub-watersheds were delineated from Digital Elevation Model (DEM). The hypsometric parameters i.e., hypsometric integral (HI) and curves were generated using Geographic Information System (GIS) techniques. The HI values of SW-1 (0.41) and SW-2 (0.36) indicated that these two SWs were relatively more prone to erosion and contributed higher sediment discharge in Dam siltation. The results were validated through sampling the main drainage channel (Kurram River) to determine the sediment concentration at 12 sites during summer, winter, and spring seasons. Comparison of HI and sediment concentration of SWs presented high correlation (R²?=?0.87). The results emphasized the effective watershed management, extensive afforestation, and construction of silt-control structures at appropriate locations in sub-watersheds. This will ultimately maintain the water and power generation capacity as well as extending the life span of the Dam.  相似文献   

The probability distributions and fractal dimension of sunspot cycles associated with ENSO phenomena     

Asma Zaffar  Shaheen Abbas  Muhammad Rashid Kamal Ansari 《Arabian Journal of Geosciences》2018,11(3):63

Various methods have been used to secure the certainty of significant relations among the sunspot cycles and some of the terrestrial climate parameters such as temperature, rainfall, and ENSO. This study investigates the behavior of ENSO cycles and mean monthly sunspot cycles. Sunspot cycles range from 1755 to 2016 whereas, ENSO cycles range from 1866 to 2012. In this regard, the appropriateness of distributions is investigated with the help of Kolmogorov-Smirnov D, Anderson-Darling, and chi-square tests. It is found that most of the sunspot cycle follows generalized Pareto distribution whereas, generalized extreme value distribution was found appropriate for ENSO cycles. Probability distribution is used to analyze the behavior of each sunspot cycle and ENSO cycle separately. Probability distribution indicates the tail behavior of each cycle; tail explored correlation cycles. Furthermore, self-similar and self-affine fractal dimension methods are used to compute Hurst exponents to determine the persistency of the available data. Fractal dimension has an ability to study the complexity involved in sunspot and ENSO cycles. The fractal dimension and Hurst exponent describe persistency (smoothness) and complexity of data. Hurst exponent measures long-term behavior of time series, making it more helpful for forecasting. This is the measure of regularity or irregularity (chaos) of the time function in the form of their persistency or anti-persistency, respectively. Hurst exponents are computed using rescaled range analysis method and box counting methods. Both these methods are suitable for long-term forecasting. The results of this study confirm that during the period 1980–2000, ENSO cycles were very active. Simultaneously, ENSO was active for the periods 1982–1983, 1986–1987, 1991–1993, 1994–1995, and 1997–1998; these periods include two strongest periods of the century viz., 1982–1983 and 1997–1998. Sunspot cycles and ENSO cycles both were found to be persistent. Self-similar fractal dimensions exhibited a better persistency and a better correlation as compared to self-affine fractal dimension. This research is a part of a larger research project investigating the correlation of sunspot cycles and ENSO cycles, and the influence of ENSO cycles on variations of the local climatic parameters which in turn depends on solar activity changes.  相似文献   

Groundwater recharge to ophiolite aquifer in North Oman: constrained by stable isotopes and geochemistry     

Osman Abdalla  Rashid Al Abri  Khadija Semhi  Talal Al Hosni  Mansour Amerjeed  Ian Clark 《Environmental Earth Sciences》2016,75(15):1117

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Xanthan gum biopolymer: an eco-friendly additive for stabilization of tropical organic peat     

Nima Latifi  Suksun Horpibulsuk  Christopher L. Meehan  Muhd.Zaimi Abd Majid  Ahmad Safuan A. Rashid 《Environmental Earth Sciences》2016,75(9):825

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Changes of backfill soil of tower foundation in the permafrost regions with warm ice-rich frozen soil on the Qinghai–Tibet Plateau     

Junfeng Wang  Kun Jia  Rashid Rafique  Lei Guo  Qihao Yu  Yongyu Yue  Chang Yuan 《Environmental Earth Sciences》2016,75(21):1416

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An integrated approach for aquifer vulnerability mapping using GIS and rough sets: study from an alluvial aquifer in North India     

Arina Khan  Haris Hasan Khan  Rashid Umar  Muneeb Hasan Khan 《Hydrogeology Journal》2014,22(7):1561-1572

A modified DRASTIC model in a geographic information system (GIS) environment coupled with an information-analytic technique called ‘rough sets’ is used to understand the aquifer vulnerability characteristics of a segment of the lower Kali watershed in western Uttar Pradesh, India. Since the region is a flat plain, topography (T) is removed as a potential control. Other parameters are the same as in DRASTIC, hence the new model is termed as DRASIC. The rough set technique is employed to provide insight into the relative vulnerabilities of different administrative units (blocks) within the study area. Using rough sets, three important factors are computed: strength, certainty and coverage. Strength indicates how the vulnerability characteristics vary in the entire area, certainty gives the relative fractions of low, medium and high vulnerability regions within a particular block, and coverage computes the percentage of a particular vulnerability state in each block. The purpose of the work is to demonstrate the utility of this integrated approach in classifying different administrative blocks in the study area according to their aquifer vulnerability characteristics. This approach is particularly useful for block-level planning and decision making for sustainable management of groundwater resources.  相似文献   

A geospatial model for the optimization grazing management in semi-arid rangeland of Iran     

Fazel Amiri  Abdul Rashid bin Mohamed Shariff  Taybeh Tabatabaie  Biswajeet Pradhan 《Arabian Journal of Geosciences》2014,7(3):1101-1114

Extensive livestock grazing even in unsuitable land has increasingly grown in most parts of semi-arid rangeland. Therefore, it is of paramount importance to identify suitable land for livestock grazing for optimum utilization while causing minimum impact to the environment. This paper adapted the schematic model based on the concepts presented by the Food and Agriculture Organization of suitability analysis for optimal grazing management in semi-arid rangeland in Iran. Factors affecting extensive grazing were determined and incorporated into the model. Semi-arid rangeland with variable such as climate and other agents were examined for common types of animal grazing and the advantages and limitations were elicited. Many ecosystem components affect land suitability for livestock grazing but due to time and funding restrictions, the most important and feasible elements were investigated. Within the model parameters, three submodels including water accessibility source, forage production, and erosion sensitivity were considered. Suitable areas at four levels of suitability were determined using geographic information systems. This suitability modeling approach was adopted due to its simplicity and the minimal time required for transforming and analyzing datasets. The most important reducing factors in model suitability were found to be: (a) land use and vegetation cover (in relation to soil erosion sensitivity), (b) the amount of the available forage in comparison with the total production, and (c) the existence of less palatability plants among the pasture plant species (forage production suitability). The results of the study would be beneficial to rangeland managers in devising measures more wisely to cope with the limitations and enhance the health and productivity of the rangelands.  相似文献