Biotransformation of two-line silica-ferrihydrite by a dissimilatory Fe(III)-reducing bacterium: formation of carbonate green rust in the presence of phosphate     

Ravi K Kukkadapu  John M Zachara  David W Kennedy 《Geochimica et cosmochimica acta》2004,68(13):2799-2814

The reductive biotransformation of two Si-ferrihydrite coprecipitates (1 and 5 mole % Si) by Shewanella putrefaciens, strain CN32, was investigated in 1,4-piperazinediethanesulfonic acid-buffered media (pH ∼7) with lactate as the electron donor. Anthraquinone-2,6-disulfonate, an electron shuttle, was present in the media. Experiments were performed without and with PO₄³⁻ (P) (1 to 20 mmol/L) in media containing 50 mmol/L Fe. Our objectives were to define the combined effects of SiO₄⁴⁻ (Si) and P on the bioreducibility and biomineralization of ferrihydrites under anoxic conditions. Iron reduction was measured as a function of time, solids were characterized by powder X-ray diffraction and Mössbauer spectroscopy, and aqueous solutions were analyzed for Si, P, Cl⁻ and inorganic carbon. Both of the ferrihydrites were rapidly reduced regardless of the Si and P content. Si concentration had no effect on the reduction rate or mineralization products. Magnetite was formed in the absence of P whereas carbonate green rust GR(CO₃²⁻) ([Fe_(6−x)^IIFe^III_x(OH)₁₂]^x+(CO₃²⁻)_0.5x · yH₂O) and vivianite [Fe₃(PO₄)₂ · 8H₂O], were formed when P was present. GR(CO₃²⁻) dominated as a mineral product in samples with <4 mmol/L P. The Fe(II)/Fe(III) ratio of GR(CO₃²⁻) varied with P concentration; the ratio was 2 in 1 mmol/L P and approached 1 with 4- and 10 mmol/L P. Green rust appeared to form by solid-state transformation of ferrihydrite. Media P and Si concentration dictated the mechanism of transformation. In the 1 mole % Si coprecipitate with 1 mmol/L P, an intermediate Fe(II)/Fe(III) phase with structural Fe(II) slowly transformed to GR with time. In contrast, when ferrihydrite contained more Si (5 mole %) and/or contained higher P (4 mmol/L), sorbed Fe(II) and residual ferrihydrite together transformed to GR. Despite similar chemistries, P was shown to have a profound effect on extent of ferrihydrite reduction and biotransformations while that of Si was minimal.  相似文献   

A visualization system for mineral elasticity     

Bijaya B. Karki  Ravi Chennamsetty 《Visual Geosciences》2004,9(1):49-57

The authors have developed an efficient visualization system to gain insight into large collections of mineral elasticity data produced by an increasing number of both theoretical calculations and experiments. The system allows us to visualize multivariate elastic moduli (i.e., elastic constant tensors) and their variation with composition, pressure and temperature. Moreover, it supports visualization of elastic wave propagation in an anisotropic medium by rendering the wave velocity data, which are calculated as a function of propagation direction in a three-dimensional space. This paper describes the design, implementation and application of the visualization scheme we have developed for mineral elasticity. In particular, our scheme exploits a combination of parallel coordinates, star plot, scatter plot and polygon-surface rendering techniques, which are implemented using OpenGL, GLUI and C++. The result is a highly portable and flexible interactive visualization system. For illustration, the elastic properties of several important oxide and silicate minerals are successfully visualized as a function of pressure and temperature.Reviewed by: D. Yuen, G. Erlebacher  相似文献   

LNAPL in fine-grained soils: Conceptualization of saturation, distribution, recovery, and their modeling     

Mark Adamski  Victor Kremesec  Ravi Kolhatkar  Chris Pearson  Beth Rowan 《Ground Water Monitoring & Remediation》2005,25(1):100-112

  相似文献   

Chhotanagpur granite gneiss in relation to the schistose rocks around Murhu,Ranchi district,Bihar: a structural approach     

D. S. Bhattacharyya  Anjan Ghosal  V. Ravi Kant 《Journal of Earth System Science》1990,99(2):269-277

Structural analysis of the Chhotanagpur gneiss and the adjoining schistose rocks of the Singhbhum Group indicates perfect conformity in their structures on macroscopic, mesoscopic and microscopic scales. This precludes the possibility of the gneissic rocks having intruded into the deformed and metamorphozed schistose rocks. The observed features can be best explained by considering the gneissic rocks as the basement and the schistose rocks as the cover, both deformed and metamorphozed together. However, this does not exclude the possibility of the gneissic rocks being reactivated and intruding elsewhere.  相似文献   

Optimal Design of a Gravity Survey Network and its Application to Delineate the Jabera-Damoh Structure in the Vindhyan Basin,Central India     

Ravi Prakash Srivastava  Nimisha Vedanti  V. P. Dimri 《Pure and Applied Geophysics》2007,164(10):2009-2022

Fractal dimension analysis was carried out for optimal designing of 2-D gravity survey network and to determine an optimum range of gridding interval to generate least aliased Bouguer anomaly maps. As a test case, this method has been successfully applied to the Jabera-Damoh region of the Vindhyan Basin, which is considered as a potential hydrocarbon bearing area. In particular, we aim to delineate accurately the lateral extent of a possible hydrocarbon bearing structure. To achieve this aim, fractal dimension of survey network was computed using 2-D distributions of observation points in the planning phase of the survey so that the optimum station spacing for gravity survey can be obtained. A range of optimum gridding interval for the gravity data set was suggested using the box-counting method of fractal dimension determination. Bouguer anomaly maps of the region are prepared utilizing the optimum gridding interval. For the first time, these anomaly maps clearly outline the gravity evidence of an anomalous rifted structure, which is bounded by parallel faults on either side. This structure is interpreted as a favorable basin for the occurrence of hydrocarbons. Another finding of this study has been the delineation of an apparently small ridge-like structure running east-west, dividing this basin in two parts. A subsurface geological model along a profile across the Jabera structure has also been presented.  相似文献   

Impact of the moisture and land surface processes on the sustenance of the cyclonic storm Yemyin over land using the WRF-ARW model     

Nellipudi  Nanaji Rao  Ramakrishna  S. S. V. S.  Podeti  Srinivasa Rao  Rao  B. Ravi Srinivasa  Yesubabu  V.  Rao  V. Brahmananda 《Natural Hazards》2022,114(1):495-519

Natural Hazards - In this study, an attempt is made to analyze the sensitivity of land surface process and the associated moisture budget characteristics of the cyclonic storm Yemyin (2007), which...  相似文献   

Comparison of earthquake source characteristics in the Kachchh Rift Basin and Saurashtra horst,Deccan Volcanic Province,western India     

B Sairam  A P Singh  M Ravi Kumar 《Journal of Earth System Science》2018,127(4):55

Seismic source parameters of small to moderate sized intraplate earthquakes that occurred during 2002–2009 in the tectonic blocks of Kachchh Rift Basin (KRB) and the Saurashtra Horst (SH), in the stable continental region of western peninsular India, are studied through spectral analysis of shear waves. The data of aftershock sequence of the 2001 Bhuj earthquake (\(M_{w}\) 7.7) in the KRB and the 2007 Talala earthquake (\(M_{w}\) 5.0) in the SH are used for this study. In the SH, the seismic moment (\(M_{o})\), corner frequency \((f_{c})\), stress drop (\(\varDelta \sigma \)) and source radius (r) vary from \(7.8\times 10^{11}\) to \(4.0\times \)10\(^{16}\) N-m, 1.0–8.9 Hz, 4.8–10.2 MPa and 195–1480 m, respectively. While in the KRB, these parameters vary from \(M_{o} \sim 1.24 \,\times \, 10^{11}\) to \(4.1 \times 10^{16}\) N-m, \(f_{c }\sim \) 1.6 to 13.1 Hz, \(\varDelta \sigma \sim 0.06\) to 16.62 MPa and \(r \sim 100\) to 840 m. The kappa (K) value in the KRB (0.025–0.03) is slightly larger than that in the SH region (0.02), probably due to thick sedimentary layers. The estimated stress drops of earthquakes in the KRB are relatively higher than those in SH, due to large crustal stress concentration associated with mafic/ultramafic rocks at the hypocentral depths. The results also suggest that the stress drop value of intraplate earthquakes is larger than the interplate earthquakes. In addition, it is observed that the strike-slip events in the SH have lower stress drops, compared to the thrust and strike-slip events.  相似文献   

Effect of uncertainty in $$V_{\mathrm{S}}{-}N$$ correlations on seismic site response analysis     

Narayan Roy  Amit Shiuly  R B Sahu  Ravi S Jakka 《Journal of Earth System Science》2018,127(7):103

This paper studies the reliability of the calculated shear-wave velocity (\(V_{\mathrm{S}}\)) from different available \(V_{\mathrm{S}}\) and SPT-N correlations in terms of seismic site response analysis. In the present study, various \(V_{\mathrm{S}}\)–N correlations developed for different regions around the globe have been used to calculate the bound of \(V_{\mathrm{S}}\) variations with depth at three different sites in Kolkata city. This bound has later been used to generate the random \(V_{\mathrm{S}}\) profiles using the Monte Carlo simulation. Equivalent linear site response analysis has been performed to study the response of those generated profiles under different input motion excitations. Strong-to-weak ground motion records have been used for this purpose. The amplification spectra of the generated \(V_{\mathrm{S}}\) profiles using all soil types and specific soil-type \(V_{\mathrm{S}}\)–N correlations show significant variations. The study also shows that the \(V_{\mathrm{S}}\)–N correlation may result in quite different \(V_{\mathrm{S},30}\) values and subsequently it may lead to the different site classes according to the NEHRP 2003 classification. So, the random choice of the \(V_{\mathrm{S}}\)–N correlation, where the direct measurement of \(V_{\mathrm{S}}\) is not available, may affect the outcome of seismic hazard analysis significantly. The study points out the need for accurate estimation of the \(V_{\mathrm{S}}\) profile either from in-situ determination or using site-specific correlation.  相似文献   

The P3 kimberlite and P4 lamproite,Wajrakarur kimberlite field,India: mineralogy,and major and minor element compositions of olivines as records of their phenocrystic vs xenocrystic origin     

Shaikh  Azhar M.  Kumar  Satya P.  Patel  Suresh C.  Thakur  Satyajeet S.  Ravi  Subramanian  Behera  Duryadhan 《Mineralogy and Petrology》2018,112(2):609-624

Distinctly different groundmass mineralogy characterise the hypabyssal facies, Mesoproterozoic diamondiferous P3 and P4 intrusions from the Wajrakarur Kimberlite Field, southern India. P3 is an archetypal kimberlite with macrocrysts of olivine and phlogopite set in a groundmass dominated by phlogopite and monticellite with subordinate amounts of serpentine, spinel, perovskite, apatite, calcite and rare baddeleyite. P4 contains mega- and macrocrysts of olivine set in a groundmass dominated by clinopyroxene and phlogopite with subordinate amounts of serpentine, spinel, perovskite, apatite, and occasional gittinsite, and is mineralogically interpreted as an olivine lamproite. Three distinct populations of olivine, phlogopite and clinopyroxene are recognized based on their microtextural and compositional characteristics. The first population includes glimmerite and phlogopite–clinopyroxene nodules, and Mg-rich olivine macrocrysts (Fo 90–93) which are interpreted to be derived from disaggregated mantle xenoliths. The second population comprises macrocrysts of phlogopite and Fe-rich olivine (Fo 81–89) from P3, megacrysts and macrocrysts of Fe-rich olivine (Fo 85–87) from P4 and a rare olivine–clinopyroxene nodule from P4 which are suggested to have a genetic link with the precursor melt of the respective intrusions. The third population represents clearly magmatic minerals such as euhedral phenocrysts of Fe-rich olivine (Fo 85–90) crystallised at mantle depths, and olivine overgrowth rims formed contemporaneously with groundmass minerals at crustal levels. Close spatial association and contemporaneous emplacement of P3 kimberlite and P4 lamproite is explained by a unifying petrogenetic model which involves the interaction of a silica-poor carbonatite melt with differently metasomatised wall rocks in the lithospheric mantle. It is proposed that the metasomatised wall rock for lamproite contained abundant MARID-type and phlogopite-rich metasomatic veins, while that for kimberlite was relatively refractory in nature.

  相似文献   

Sulfate Land Application Enhances Biodegradation in a Petroleum Hydrocarbon Smear Zone     

Kanwartej S. Sra  Violaine Ponsin  Ravi Kolhatkar  Daniel Hunkeler  Neil R. Thomson  Eugene L. Madsen  Timothy Buscheck 《Ground Water Monitoring & Remediation》2023,43(1):44-59

Delivery of sulfate to petroleum hydrocarbons (PHCs) source zones and groundwater plumes is desirable to enhance biodegradation rates when treatment has become limited due to depletion of sulfate. Sulfate land application involves spreading sulfate salts on ground surface and allowing their dissolution and infiltration of sulfate into subsurface. The objectives of this pilot-scale investigation were to capture the vertical transport of sulfate beneath an application area, confirm that sulfate reduction was occurring, and explore how the added sulfate affected biodegradation of benzene and toluene. Approximately 4000 kg of gypsum was spread over a 30 m × 30 m study area above a smear zone located approximately 2 m below-ground surface. Precipitation was augmented by two irrigation events. Groundwater samples, collected over 1058 days from multilevel wells and a conventional long-screened monitoring well, were analyzed for benzene, toluene, ethylbenzene, and xylenes (BTEX), sulfate, bromide, dissolved inorganic carbon (DIC) and methane. Compound-specific isotope analyses (CSIA) for benzene and toluene, and isotope analyses of ¹³C-DIC and ³⁴S-SO₄²⁻ were performed. Following application, an increase in sulfate concentration was noted in the smear zone. ³⁴S-SO₄²⁻ enrichment and ¹³C-DIC depletion indicated that sulfate reduction and mineralization of PHCs were enhanced. CSIA results provided unequivocal evidence of anaerobic biodegradation of benzene and toluene. After 1058 days when sulfate was depleted, methane concentrations were about three times greater than baseline conditions suggesting syntrophic benefit of the delivered sulfate. Observations from this investigation support the viability of sulfate land application to enhance biodegradation rates in shallow PHC smear zones.  相似文献