Metal and metalloid leaching from tailings into streamwater and sediments in the old Ag–Pb–Zn Terramonte mine,northern Portugal     

P. C. S. Carvalho  A. M. R. Neiva  M. M. V. G. Silva  I. M. H. R. Antunes 《Environmental Earth Sciences》2014,71(5):2029-2041

Tailings deposited over the Castanheira, a stream which flows through the old Ag–Pb–Zn Terramonte mine area, showed a great potential environmental risk due to sulphide weathering, facilitated by the tailings–water interaction. The high concentrations of Al, Fe, Pb and Zn in the tailings are associated with the exchangeable, reducible and sulphide fractions and suggest sphalerite and pyrite occurrences. Oxidation of pyrite is responsible for the low pH values (3.38–4.89) of the tailings. The water from the Castanheira stream is not suitable for human consumption due to high concentrations of SO₄ ^2?, Mn, Al, Cd, Ni, and Pb. The lowest concentrations of metals and metalloids were detected in downstream stretches of the Castanheira. However, As, Fe and Zn in deeper sediments tend to increase downstream. Significant concentrations of trivalent forms of arsenic were detected in water samples. In downstream stretches of the Castanheira, some free ions (Fe²⁺, Mn²⁺ and Zn²⁺) also predominate and the water is saturated with ferrihydrite, goethite, hematite, lepidocrosite and magnetite.  相似文献   

Fate and transport of pollutants through a municipal solid waste landfill leachate in Sri Lanka     

S. S. R. M. D. H. R. Wijesekara  Sonia S. Mayakaduwa  A. R. Siriwardana  Nalin de Silva  B. F. A. Basnayake  Ken Kawamoto  Meththika Vithanage 《Environmental Earth Sciences》2014,72(5):1707-1719

This study focuses on the characterization of leachate generated from Gohagoda dumpsite in Kandy, Sri Lanka, assessment of its spatial and temporal variations, and identification of subsurface canals and perched water bodies in the wetland system affected by the leachate flow. Leachate samples were collected monthly throughout dry and rainy seasons from different points of the leachate drainage channel over a period of 1 year and they were tested for quality parameters: pH, temperature, electrical conductivity, total dissolved soils, alkalinity, hardness, total solids, volatile solids, total suspended solids, volatile suspended solids, biochemical oxygen demand (BOD₅), chemical oxygen demand, nitrate-nitrogen, nitrite-nitrogen, phosphates, ammonium-nitrogen, chloride, dissolved organic carbon, total organic carbon and heavy metals. Sequential soil extraction procedures were performed for the characterization of leachate-affected local soil. A geophysical survey using direct current resistivity technique was conducted at locations downstream of the dumpsite. Leachate characteristics indicated that the leachate is in the methanogenic phase and the results strongly suggest that the leachate may be polluting the river where the leachate is discharged directly. Leachate exceeds the allowable limits of Sri Lankan wastewater discharge standards for many of the parameters. Significant difference (P < 0.05) was observed for most of organic and inorganic parameters among all sampling locations. Many parameters showed a negative correlation with pH. The affected soils showed high heavy metal concentrations. Resistivity study confirmed a confined leachate flow at the near surface with few subsurface canals. However, no separate subsurface plume movement was observed. The results of this research can effectively be used for the establishment of an efficient and effective treatment method for the Gohagoda landfill leachate.  相似文献   

A Multiple Training Image Approach for Spatial Modeling of Geologic Domains     

Daniel A. Silva  Clayton V. Deutsch 《Mathematical Geosciences》2014,46(7):815-840

Characterization of complex geological features and patterns remains one of the most challenging tasks in geostatistics. Multiple point statistics (MPS) simulation offers an alternative to accomplish this aim by going beyond classical two-point statistics. Reproduction of features in the final realizations is achieved by borrowing high-order spatial statistics from a training image. Most MPS algorithms use one training image at a time chosen by the geomodeler. This paper proposes the use of multiple training images simultaneously for spatial modeling through a scheme of data integration for conditional probabilities known as a linear opinion pool. The training images (TIs) are based on the available information and not on conceptual geological models; one image comes from modeling the categories by a deterministic approach and another comes from the application of conventional sequential indicator simulation. The first is too continuous and the second too random. The mixing of TIs requires weights for each of them. A methodology for calibrating the weights based on the available drillholes is proposed. A measure of multipoint entropy along the drillholes is matched by the combination of the two TIs. The proposed methodology reproduces geologic features from both TIs with the correct amount of continuity and variability. There is no need for a conceptual training image from another modeling technique; the data-driven TIs permit a robust inference of spatial structure from reasonably spaced drillhole data.  相似文献   

Scales and causes of heterogeneity in bars in a large multi‐channel river: Río Paraná, Argentina     

Arnold J. H. Reesink  Philip J. Ashworth  Gregory H. Sambrook Smith  James L. Best  Daniel R. Parsons  Mario L. Amsler  Richard J. Hardy  Stuart N. Lane  Andrew P. Nicholas  Oscar Orfeo  Steven D. Sandbach  Christopher J. Simpson  Ricardo N. Szupiany 《Sedimentology》2014,61(4):1055-1085

To date, published studies of alluvial bar architecture in large rivers have been restricted mostly to case studies of individual bars and single locations. Relatively little is known about how the depositional processes and sedimentary architecture of kilometre‐scale bars vary within a multi‐kilometre reach or over several hundreds of kilometres downstream. This study presents Ground Penetrating Radar and core data from 11, kilometre‐scale bars from the Río Paraná, Argentina. The investigated bars are located between 30 km upstream and 540 km downstream of the Río Paraná – Río Paraguay confluence, where a significant volume of fine‐grained suspended sediment is introduced into the network. Bar‐scale cross‐stratified sets, with lengths and widths up to 600 m and thicknesses up to 12 m, enable the distinction of large river deposits from stacked deposits of smaller rivers, but are only present in half the surface area of the bars. Up to 90% of bar‐scale sets are found on top of finer‐grained ripple‐laminated bar‐trough deposits. Bar‐scale sets make up as much as 58% of the volume of the deposits in small, incipient mid‐channel bars, but this proportion decreases significantly with increasing age and size of the bars. Contrary to what might be expected, a significant proportion of the sedimentary structures found in the Río Paraná is similar in scale to those found in much smaller rivers. In other words, large river deposits are not always characterized by big structures that allow a simple interpretation of river scale. However, the large scale of the depositional units in big rivers causes small‐scale structures, such as ripple sets, to be grouped into thicker cosets, which indicate river scale even when no obvious large‐scale sets are present. The results also show that the composition of bars differs between the studied reaches upstream and downstream of the confluence with the Río Paraguay. Relative to other controls on downstream fining, the tributary input of fine‐grained suspended material from the Río Paraguay causes a marked change in the composition of the bar deposits. Compared to the upstream reaches, the sedimentary architecture of the downstream reaches in the top ca 5 m of mid‐channel bars shows: (i) an increase in the abundance and thickness (up to metre‐scale) of laterally extensive (hundreds of metres) fine‐grained layers; (ii) an increase in the percentage of deposits comprised of ripple sets (to >40% in the upper bar deposits); and (iii) an increase in bar‐trough deposits and a corresponding decrease in bar‐scale cross‐strata (<10%). The thalweg deposits of the Río Paraná are composed of dune sets, even directly downstream from the Río Paraguay where the upper channel deposits are dominantly fine‐grained. Thus, the change in sedimentary facies due to a tributary point‐source of fine‐grained sediment is primarily expressed in the composition of the upper bar deposits.  相似文献   

A Middle Miocene carbonate embankment on an active volcanic slope: Ilhéu de Baixo,Madeira Archipelago,Eastern Atlantic     

B. Gudveig Baarli  Mrio Cacho  Carlos M. da Silva  Markes E. Johnson  Eduardo J. Mayoral  Ana Santos 《Geological Journal》2014,49(1):90-106

Carbonate factories on insular oceanic islands in active volcanic settings are poorly explored. This case study illuminates marginal limestone deposits on a steep volcanic flank and their recurring interruption by deposits linked to volcaniclastic processes. Historically known as Ilhéu da Cal (Lime Island), Ilhéu de Baixo was separated from Porto Santo, in the Madeira Archipelago, during the course of the Quaternary. Here, extensive mines were tunnelled in the Miocene carbonate strata for the production of slaked lime. Approximately 10 000 m³ of calcarenite (−1 to 1ø) was removed by hand labour from the Blandy Brothers mine at the south end of the islet. Investigations of two stratigraphic sections at opposite ends of the mine reveal that the quarried material represents an incipient carbonate ramp developed from east to west and embanked against the flank of a volcanic island. A petrographic analysis of limestones from the mine shows that coralline red algae from crushed rhodoliths account for 51% of all identifiable bioclasts. This material was transported shoreward and deposited on the ramp between normal wave base and storm wave base at moderate depths. The mine's roof rocks are formed by Surtseyan deposits from a subsequent volcanic eruption. Volcaniclastic density flows also are a prevalent factor interrupting renewed carbonate deposition. These flows arrived downslope from the north and gradually steepened the debris apron westwards. Slope instability is further shown by a coral rudstone density flow that followed from growth of a coral reef dominated by Pocillopora madreporacea (Lamarck), partial reef collapse, and transport from a more easterly direction into a fore‐reef setting. The uppermost facies represents a soft bottom at moderate depths in a quiet, but shore‐proximal setting. Application of this study to a broader understanding of the relationship between carbonate and volcaniclastic deposition on oceanic islands emphasizes the susceptibility of carbonates to dilution and complete removal by density flows of various kinds, in contrast to the potential for preservation beneath less‐disruptive Surtseyan deposits. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Natural Variability of Shear Strength in a Granite Residual Soil from Porto     

Luís Pinheiro Branco  António Topa Gomes  António Silva Cardoso  Carla Santos Pereira 《Geotechnical and Geological Engineering》2014,32(4):911-922

The renewal imposed by the Eurocodes regarding the methodologies of safety evaluation requires a statistical analysis of the variability of ground geotechnical parameters. However, the studies published in the reviewed literature do not cover the typical materials from the northeast region of Portugal—residual soils from granite—to which a strong heterogeneity is associated. Hence, a statistical characterization of the natural variability of a granite residual soil from Porto has been made through a significant amount of experimental tests, focusing on its geomechanical properties. In order to provide a database for probabilistic analysis of problems involving this type of soils, an appropriate statistical law has been used to model its variability, which has been quantified by means of coefficients of variation and scales of fluctuation.  相似文献   

Literature review of accessibility measures and models used in land use and transportation planning in last 5 years     

Marwal  Aviral  Silva  Elisabete 《地理学报(英文版)》2022,32(3):560-584

Journal of Geographical Sciences - Since its inception accessibility has undergone various changes in the way it is defined, measured, and modeled. The paper reviews the recent advancements made in...  相似文献   

Center-to-Limb Variation of Solar Microwave Bursts     

Silva  Adriana V.R.  Valente  Marcelo M. 《Solar physics》2002,206(1):177-188

Statistical studies of hard X-ray flares position on the solar disk have shown that the more energetic hard X-rays have a tendency to be more concentrated near the limb rather than at disk center, whereas lower-energy hard X-ray emission seems isotropic. Since the high-frequency radio emission is believed to be produced by the same energetic electron population responsible for the high-energy hard X-rays, we searched the microwave/millimeter emitting bursts for center-to-limb variation in their emission. A total of 499 bursts observed by the radio telescopes in Bern at the frequencies of 3.1, 5.2, 8.4, 11.8, 19.6, 35.0, and 50.0 GHz were analyzed. Simultaneous Hα flares were used for determination of the radio burst position on the solar disk. For each of the 7 frequencies, the peak flux and duration were studied as a function of heliocentric position. For 312 bursts, spectral parameters such as spectral index, peak frequency, and flux at spectral maximum were analyzed. For a subset of 43 bursts with emission at all frequencies, the emission and spectral parameters were analyzed. Center-to-limb variations of the spectral parameters for all bursts were sought. In order to interpret the observational results, we have performed a numerical simulation of gyrosynchrotron spectra. We find that high-frequency events, which are also the more energetic ones, have larger center-to-limb variations in their parameters than do the overall flares. Moreover, this behavior agrees with theoretical predictions.  相似文献   

Pliocene and late Pleistocene (MIS 5e) decapod crustaceans from Santa Maria Island (Azores Archipelago: Central Atlantic): systematics,palaeoecology and palaeobiogeography     

Matúš Hyžný  Carlos S. Melo  Ricardo S. Ramalho  Ricardo Cordeiro  Patrícia Madeira  Lara Baptista  A. Cristina Rebelo  Cynthia Gómez  Alfred Uchman  Markes E. Johnson  Björn Berning  Sérgio P. Ávila 《第四纪科学杂志》2021,36(1):91-109

The presence of decapod crustaceans in the Pliocene and Pleistocene (MIS 5e) fossil record of Santa Maria Island (Azores Archipelago) is herein reviewed. Our study raises the number of fossil decapods from this island from one species to 10 taxa (three for the Pliocene and seven for the Last Interglacial). Four of these 10 taxa are reported for the first time in the fossil record, worldwide. A new species of a mud shrimp is also described (Upogebia azorensis n. sp.). Our study suggests that the Plio–Pleistocene decapod assemblages of the Azores did not differ significantly from modern ones, being dominated by species that are today widespread across the Webbnesia ecoregion, the Mediterranean Sea, and the eastern Atlantic shores, including the Azores. As far as can be judged from the limited fossil record, apparently no tropical crab species with a Cabo Verdean/Senegalese provenance reached the Azores during windows of opportunity associated with Glacial Termination 2 or with the initial setting of the Last Interglacial period. This contribution increases the total number of marine taxa reported for the Pliocene and Pleistocene outcrops of Santa Maria Island to 218 and 155, respectively, highlighting the scientific relevance of its palaeontological heritage.  相似文献   

Identification of Possible Intense Historical Solar Storms During the Years 1781–1788 Inferred from Aurorae and Geomagnetic Observations in Rio De Janeiro     

José M. Vaquero  Ricardo M. Trigo 《Solar physics》2006,235(1-2):419-432

The reconstruction of solar activity during the late 18th century is a puzzle for researchers due to the scarcity of sunspot observations in that epoch. In this work, we analyse some details of the solar activity during the years 1781–1788, inferred from geomagnetic measurements and visual observations of aurorae performed by the Portuguese scientist Bento Sanches Dorta from Rio de Janeiro. We describe in greater detail four large solar storms that induced large changes in daily values of geomagnetic declination and, simultaneously, correspond to visual observations of aurorae described by Sanches Dorta.  相似文献