Petrologic and geochemical investigation of carbonates in peridotite xenoliths from northeastern Tanzania   总被引：5，自引：1，他引：4  

Cin-Ty Lee  Roberta L. Rudnick  William F. McDonough  Ingo Horn 《Contributions to Mineralogy and Petrology》2000,139(4):470-484

Primary carbonates in peridotite xenoliths from the East African Rift in northeastern Tanzania occur as intergranular patches with accessory minerals (olivine and spinel), as patches with accessory magmatic minerals (nepheline), and as round monomineralic inclusions in primary olivine grains. All are characterized by calcitic compositions (Ca/Ca + Mg + Fe from 0.83 to 0.99), extremely low SiO₂ + Al₂O₃ + Na₂O + K₂O, low trace element abundance [total rare-earth element (REE) abundance <25 ppm], uniform extinction, and lack of reaction textures with the host xenolith. Calculated Fe–Mg exchange coefficients between carbonate and primary olivine indicate disequilibrium in most samples. Combined with the lack of significant reaction textures, this suggests that the carbonates were introduced shortly before or during eruption of the host magma. A global compilation of electron microprobe analyses of mantle-derived carbonates (in xenoliths, xenocrysts, and megacrysts) reveals compositional clusters near end member calcite, end member magnesite, and stoichiometric dolomite. Eutectic liquid compositions are less common, suggesting that many carbonate inclusions reported worldwide may be crystalline precipitates. Likewise, the calcites in this study are not interpreted to represent quenched carbonatitic melts, but are interpreted instead to be crystalline cumulates from such melts. These inferences are consistent with recent experiments, which show that carbonatitic melts cannot become more calcitic than CaCO₃∼80 wt%. Low trace element abundance may be a diagnostic feature of cumulate carbonate, and in combination with petrography and major element composition, serve to distinguish it from quenched carbonated liquid. Received: 30 July 1999 / Accepted: 5 February 2000  相似文献   

Revisiting the Gow Lake impact structure,Saskatchewan, Canada     

Gordon R. Osinski  Adam B. Coulter  Roberta L. Flemming  Alexandra Ozaruk  Annemarie E. Pickersgill  Alaura C. Singleton 《Meteoritics & planetary science》2023,58(6):775-788

The ~5 km diameter Gow Lake impact structure formed in the Canadian Shield of northern Saskatchewan approximately 197 Myr ago. This structure has not been studied in detail since its discovery during a regional gravity survey in the early 1970s. We report here on field observations from a 2011 expedition that, when combined with subsequent laboratory studies, have revealed a wealth of new information about this poorly studied Canadian impact structure. Initially considered to be a prototypical central peak (i.e., a complex) impact structure, our observations demonstrate that Gow Lake is actually a transitional impact structure, making it one of only two identified on Earth. Despite its age, a well-preserved sequence of crater-fill impactites is preserved on Calder Island in the middle of Gow Lake. From the base upward, this stratigraphy is parautochthonous target rock, lithic impact breccia, clast-rich impact melt rock, red clast-poor impact melt rock, and green clast-poor impact melt rocks. Discontinuous lenses of impact melt-bearing breccia also occur near the top of the red impact melt rocks and in the uppermost green impact melt rocks. The vitric particles in these breccias display irregular and contorted outlines. This, together with their setting within crater-fill melt rocks, is indicative of an origin as flows within the transient cavity and not an airborne mode of origin. Following impact, a hydrothermal system was initiated, which resulted in alteration of the crater-fill impactites. Major alteration phases are nontronite clay, K-feldspar, and quartz.  相似文献   

Mapping lithospheric boundaries using Os isotopes of mantle xenoliths: An example from the North China Craton   总被引：5，自引：0，他引：5  

Jingao Liu  Roberta L. Rudnick  Shan Gao  Philip M. Piccoli  Wen-liang Xu 《Geochimica et cosmochimica acta》2011,75(13):3881-6182

The petrology, mineral compositions, whole rock major/trace element concentrations, including highly siderophile elements, and Re-Os isotopes of 99 peridotite xenoliths from the central North China Craton were determined in order to constrain the structure and evolution of the deep lithosphere. Samples from seven Early Cretaceous-Tertiary volcanic centers display distinct geochemical characteristics from north to south. Peridotites from the northern section are generally more fertile (e.g., Al₂O₃ = 0.9-4.0%) than those from the south (e.g., Al₂O₃ = 0.2-2.2%), and have maximum whole-rock Re-depletion Os model ages (T_RD) of ∼1.8 Ga suggesting their coeval formation in the latest Paleoproterozoic. By contrast, peridotites from the south have maximum T_RD model ages that span the Archean-Proterozoic boundary (2.1-2.5 Ga). Peridotites with model ages from both groups are found at Fansi, the southernmost locality in the northern group, which likely marks a lithospheric boundary. The Neoarchean age of the lithospheric mantle in the southern section matches that of the overlying crust and likely reflects the time of amalgamation of the North China Craton via collision between the Eastern and Western blocks. The Late Paleoproterozoic (∼1.8 Ga) lithospheric mantle beneath the northern section is significantly younger than the overlying Archean crust, indicating that the original lithospheric mantle was replaced in this region, either during a major north-south continent-continent collision that occurred during assembly of the Columbia supercontinent at ∼1.8-1.9 Ga, or from extrusion of ∼1.9 Ga lithosphere from the Khondalite Belt beneath the northern Trans-North China Orogen, during the ∼1.85 Ga continental collision between Eastern and Western blocks. Post-Cretaceous heating of the southern section is indicated by high temperatures (>1000 °C) recorded in peridotites from the 4 Ma Hebi suite, which are significantly higher than the temperatures recorded in peridotites from the nearby Early Cretaceous Fushan suite (<720 °C), and likely reflects significant lithospheric thinning after the Early Cretaceous. Combining previous Os isotope results on mantle xenoliths from the eastern North China Craton with our new data, it appears that lithospheric thinning and replacement may have evolved from east to west with time, commencing before the Triassic on the eastern edge of the craton, occurring during the Jurassic-Cretaceous within the interior, and post-dating 125 Ma on the westernmost boundary.  相似文献   

GSD‐1G and MPI‐DING Reference Glasses for In Situ and Bulk Isotopic Determination     

Klaus Peter Jochum  Steven A. Wilson  Wafa Abouchami  Marghaleray Amini  Jérome Chmeleff  Anton Eisenhauer  Ernst Hegner  Linda M. Iaccheri  Bruno Kieffer  Joachim Krause  William F. McDonough  Regina Mertz‐Kraus  Ingrid Raczek  Roberta L. Rudnick  Denis Scholz  Grit Steinhoefel  Brigitte Stoll  Andreas Stracke  Sonia Tonarini  Dominique Weis  Ulrike Weis  Jon D. Woodhead 《Geostandards and Geoanalytical Research》2011,35(2):193-226

This paper contains the results of an extensive isotopic study of United States Geological Survey GSD‐1G and MPI‐DING reference glasses. Thirteen different laboratories were involved using high‐precision bulk (TIMS, MC‐ICP‐MS) and microanalytical (LA‐MC‐ICP‐MS, LA‐ICP‐MS) techniques. Detailed studies were performed to demonstrate the large‐scale and small‐scale homogeneity of the reference glasses. Together with previously published isotopic data from ten other laboratories, preliminary reference and information values as well as their uncertainties at the 95% confidence level were determined for H, O, Li, B, Si, Ca, Sr, Nd, Hf, Pb, Th and U isotopes using the recommendations of the International Association of Geoanalysts for certification of reference materials. Our results indicate that GSD‐1G and the MPI‐DING glasses are suitable reference materials for microanalytical and bulk analytical purposes.  相似文献   

Annual and spatial variations of chemical and physical properties in the Ross Sea surface waters (Antarctica)     

Serena Massolo  Roberta Messa  Paola Rivaro  Riccardo Leardi 《Continental Shelf Research》2009

Temperature, salinity, meltwater percentage, water column stability, dissolved oxygen and nutrients were measured in seawater samples collected at three fixed depths (0, 20, 100 m) in 104 stations located in three different areas of the Ross Sea (Antarctica), during four Italian Antarctic surveys carried out between 1998 and 2006. Nutrient data were used to quantify the nutrient removal, which appears particularly high in 2006, especially in polynya area. The N:P and Si:N disappearance ratios were studied to estimate the dominant phytoplanktonic community. No significant differences in the nutrient drawdown ratio were observed, in fact the N:P ratio was always below the Redfield standard ratio.  相似文献   

Tracking the lithium isotopic evolution of the mantle using carbonatites     

Ralf Halama  William F. McDonough  Roberta L. Rudnick  Keith Bell 《Earth and Planetary Science Letters》2008,265(3-4):726-742

Carbonatites are mantle-derived, intraplate magmas that provide a means of documenting isotopic variations of the Earth's mantle through time. To investigate the secular Li isotopic evolution of the mantle and to test whether Li isotopes document systematic recycling of material processed at or near the Earth's surface into the mantle, we analyzed the Li isotopic compositions of carbonatites and spatially associated mafic silicate rocks. The Li isotopic compositions of Archean (2.7 Ga) to Recent carbonatites (δ⁷Li = 4.1 ± 1.3 (n = 23, 1σ)) overlap the range typical for modern mantle-derived rocks, and do not change with time, despite ongoing crustal recycling. Thus, the average Li isotopic composition of recycled crustal components has not deviated greatly from the mantle value (~ + 4) and/or Li diffusion is sufficiently fast to attenuate significant heterogeneities over timescales of 10⁸ years. Modeling of Li diffusion at mantle temperatures suggests that limited δ⁷Li variation in the mantle through time reflects the more effective homogenization of Li in the mantle compared to radiogenic isotope systems. The real (but limited) variations in δ⁷Li that exist in modern mantle-derived magmas as well as carbonatites studied here may reflect isotopic fractionation associated with shallow-level processes, such as crustal assimilation and diffusive isotopic fractionation in magmatic systems, with some of the scatter possibly related to low-temperature alteration.  相似文献   

(137)Cs baseline levels in the Mediterranean and Black Sea: a cross-basin survey of the CIESM Mediterranean Mussel Watch programme     

Thébault H  Rodriguez Y Baena AM  Andral B  Barisic D  Albaladejo JB  Bologa AS  Boudjenoun R  Delfanti R  Egorov VN  El Khoukhi T  Florou H  Kniewald G  Noureddine A  Patrascu V  Pham MK  Scarpato A  Stokozov NA  Topcuoglu S  Warnau M 《Marine pollution bulletin》2008,57(6-12):801-806

The common mussel Mytilus galloprovincialis was selected as unique biomonitor species to implement a regional monitoring programme, the CIESM Mediterranean Mussel Watch (MMW), in the Mediterranean and Black Seas. As of today, and upon standardization of the methodological approach, the MMW Network has been able to quantify (137)Cs levels in mussels from 60 coastal stations and to produce the first distribution map of this artificial radionuclide at the scale of the entire Mediterranean and Black Seas. While measured (137)Cs levels were found to be very low (usually < 1 Bq kg(-1) wet wt) (137)Cs activity concentrations in the Black Sea and North Aegean Sea were up to two orders of magnitude higher than those in the western Mediterranean Basin. Such effects, far from representing a threat to human populations or the environment, reflect a persistent signature of the Chernobyl fallout in this area.  相似文献   

Rockfall trajectory modeling combined with heuristic analysis for assessing the rockfall hazard along the Maratea SS18 coastal road (Basilicata,Southern Italy)   总被引：2，自引：1，他引：1  

Roberta Pellicani  Giuseppe Spilotro  Cees J. Van Westen 《Landslides》2016,13(5):985-1003

In this paper, a study aimed to assess the rockfall hazard along a portion of the SS18 coastal road, located in the coastal area of Maratea (Basilicata Region, Southern Italy), is presented. The relevance of this study derives from the location of the study area, because the SS18 is a strategic roads in a touristic area, and, since the hazard assessment was performed in 2004 within a project financed by the Viability Regional Department of Autonomous National Company of Roads (ANAS), from the possibility to validate the results by using real rockfall events occurred after 2004. The procedure for assessing the rockfall hazard was composed of four sequential analyses: (i) geomechanical and kinematic characterization of rock mass, (ii) implementation of Romana’s (1985) Slope Mass Rating (SMR) method for identifying the potential boulder release areas (rockfall initiation areas), (iii) determination of rockfall trajectories by using a 3D numerical model (ROTOMAP), (iv) calculation and mapping of the hazard index by combining three factors, i.e., (a) lithological features of outcropping materials on rock faces, (b) kinematic compatibility defined by simulating the rockfall trajectories, and (c) spatial distribution of occurred rockfall events. Finally, the proposed methodology was validated by combining the distribution of the hazard levels along the road with the location on the SS18 of the rockfall events occurred from 2004 to 2014.  相似文献   

A method to reveal climatic variables triggering slope failures at high elevation     

Roberta Paranunzio  Francesco Laio  Guido Nigrelli  Marta Chiarle 《Natural Hazards》2015,76(2):1039-1061

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Middle to Late Pleistocene palaeoenvironmental evolution of the southeastern Alpine Valeriano Creek succession (northeastern Italy)     

Giovanni Monegato  Sally E. Lowick  Cesare Ravazzi  Roberta Banino  Marta Donegana  Frank Preusser 《第四纪科学杂志》2010,25(5):617-632

The Middle–Late Pleistocene alluvial and lacustrine succession of Valeriano Creek (southeastern Alpine foothills, 190 m a.s.l.) documents the environmental evolution of the piedmont plain before the onset of the Last Glacial Maximum (LGM). The sedimentary record was investigated by multidisciplinary stratigraphical and sedimentological studies coupled with petrographic and palaeobotanical analysis. A chronology has been provided by luminescence, radiocarbon dating and pollen biochronology. The succession developed at the valley mouth of a small catchment and is confined in the piedmont plain by the alluvial fans of major rivers. The oldest deposits were formed during a cold phase during the late Middle Pleistocene. This part of the piedmont plain was generally stable until Termination II, when it was trenched more than 15 m deep by watercourses. The infilling succession of the trench, mostly by low‐energy alluvial sediments interbedded with mire and peat deposits, documents, for the first time on the southern side of the Alps, the relationships between fluvial activity, vegetation and climate change at the foothills piedmont plain during late Marine Isotope Stage (MIS) 5. The stadial–interstadial climate forcing implies a local reorganisation of fluvial dynamics and of forest composition, although substantial plant cover persisted even during cooler stadials. In accordance with coeval alluvial and speleothem records from the northern side of the Alps, this environmental evolution supports a very restricted Alpine glaciation of the main fluvial catchments of the southeastern Alps during MIS 5a–d. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献