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1.
High-Mg# peridotite xenoliths in the Cenozoic Hebi basalts from the North China Craton have refractory mineral compositions (Fo > 91.5) and highly heterogeneous Sr–Nd isotopic compositions (87Sr/86Sr = 0.7031–0.7048, 143Nd/144Nd = 0.5130–0.5118) ranging from MORB-like to EM1-type mantle, which are similar to those of peridotites from Archean cratons. Thus, the high-Mg# peridotites may represent relics of the ancient lithospheric mantle. Published Re–Os isotopic data for Cenozoic basalt-borne xenoliths show TRD ages of 3.0–1.5 Ga for the peridotites from Hebi (the center of the craton), 2.2–0 Ga for those from Hannuoba and Jining (north margin of the craton), and 2.6–0 Ga for those from Fanshi and Yangyuan (midway between the center and north margin of the craton). In situ Re–Os data of sulfides in Hannuoba peridotites suggest that whole-rock Re–Os model ages represent mixtures of multiple generations of sulfides with varying Os isotopic compositions. These observations indicate that initial lithospheric mantle beneath the Central Zone of the North China Craton formed during the Archean and was refertilized by multiple melt additions after its formation. The refertilization became more intensive from the interior to the margin of the craton, leading to the high heterogeneity of the lithospheric mantle: more ancient and refractory peridotites with highly variable Sr–Nd isotopic compositions in the interior, and more young and fertile peridotites with depleted Sr–Nd isotopic composition in the margin. Our data, coupled with published petrological and geochemical data of peridotites from the Central Zone of the North China Craton, suggest that the lithospheric mantle beneath this region is highly heterogeneous, likely produced by refertilization of Archean mantle via multiple additions of melts/fluids, which were closely related to the Paleoproterozoic collision between the Eastern and the Western Blocks and subsequent circum-craton subduction events.  相似文献   

2.
Tectonically emplaced peridotites from North Hebei Province, North China Craton, have retained an original harzburgite mineral assemblage of olivine(54%–58%) + orthopyroxene(40%–46%)+minor clinopyroxene(1%)+spinel. Samples with boninite-like chemical compositions also coexist with these peridotites. The spinels within the peridotites have high-Al end-members with Al_2O_3 content of 30 wt % –50 wt %, typical of mantle spinels. When compared with experimentally determined melt extraction trajectories, the harzburgites display a high degree of melting and enrichment of SiO_2, which is typical of cratonic mantle peridotites. The peridotites display variably enriched light rare earth elements(REEs), relatively depleted middle REEs and weakly fractionated heavy REEs, which suggest a melt extraction of over 25% in the spinel stability field. The occurrence of arc-and SSZ-type chromian spinels in the peridotites suggests that melt extraction and metasomatism occurred mostly in a subduction-related setting. This is also supported by the geochemical data of the coexisting boninite-like samples. The peridotites have ~(187)Os/~(188)Os ratios ranging from 0.113–0.122, which is typical of cratonic lithospheric mantle. These ~(187)Os/~(188)Os ratios yield model melt extraction ages(TRD) ranging from 981 Ma to 2054 Ma, which may represent the minimum estimation of the melt extraction age. The Al_2O_3-~(187)Os/~(188)Os-proxy isochron ages of 2.4 Ga–2.7 Ga suggest a mantle melt depletion age between the Late Achaean and Early Paleoproterozoic. Both the peridotites and boninite-like rocks are therefore interpreted as tectonically exhumed continental lithospheric mantle of the North China Craton, which has experienced mantle melt depletion and subduction-related mantle metasomatism during the Neoarchean-Paleoproterozoic.  相似文献   

3.
Lithospheric thinning beneath the eastern North China Craton is widely recognized, but the mechanism and timing of the thinning are contentious. New data on peridotitic xenoliths from the Cretaceous (∼100 Ma) Fuxin basalts at the northern edge of the craton have been integrated with data from other localities across the craton, to provide an overview of the processes involved. The Fuxin peridotite xenoliths can be subdivided into three types, which can also be recognized in other xenolith suites across the craton. The dominant Type 1, lherzolites with olivine Mg# ∼90, represents fertile mantle (5-12% partial-melt extraction) that makes up much of the Late Mesozoic-Cenozoic lithosphere beneath the craton. Type 2 consists of magnesian (olivine Mg# >92) harzburgites, interpreted as shallow relics of the Archean cratonic mantle. Type 3, minor lherzolite xenoliths with olivine Mg# ∼86 reflect the interaction of the lithosphere with magmas similar to the host basalts. In-situ Re-Os data on sulfides in xenoliths from Hebi (4 Ma, interior of the craton) and Hannuoba (22 Ma, northern edge of the Trans-North China Orogen within the craton) basalts give model ages of 3.1-3.0, 2.5, 2.2-2.1, 1.4 and 0.8 Ga, These correspond to the U-Pb ages of zircons from early Mesozoic (178 Ma) peridotitic xenoliths at the southern margin of the craton, and record events during which the Archean lithospheric mantle was modified. The dominance of fertile peridotite xenoliths in the 100 Ma Fuxin basalts indicates that the mantle replacement beneath the eastern North China Craton at least partly took place before that time. The regional synthesis suggests that Mesozoic-Cenozoic lithospheric thinning and mantle replacement was heterogeneously distributed across the North China Craton in space and time. Lateral spreading of the lithosphere, accompanied by asthenospheric upwelling and melt-peridotite interaction, is the most probable mechanism for the lithospheric thinning beneath the eastern part of the craton. Subsequent cooling of the upwelled asthenosphere caused some re-thickening of the lithosphere; this overall more fertile and hence denser lithosphere resulted in widespread basin formation.  相似文献   

4.
The Os‐isotope compositions of sulphides in mantle xenoliths hosted by Late Miocene alkali basalts from the Sviyaginsky volcano, Russian Far East, reveal the presence of Archaean–Proterozoic subcontinental lithospheric mantle beneath the Khanka massif. Their TMA and TRD model ages reveal similar peaks at 1.1 and 0.8 Ga suggesting later thermotectonic events in the subcontinental lithospheric mantle, whereas TRD model ages range back to 2.8 ± 0.5 (2σ) Ga. The events recognized in the subcontinental lithospheric mantle are consistent with those recorded in the crust of the Khanka massif. The sulphide Os‐isotope data show that the subcontinental lithospheric mantle beneath the Khanka massif had formed at least by the Mesoproterozoic, and was subsequently metasomatized by juvenile crustal‐growth events related to the evolution of the Altaids. The Khanka massif is further proposed to have tectonic affinity to the Siberia Craton and should originate from it accordingly.  相似文献   

5.
Li concentrations and isotopic compositions of coexisting minerals (ol, opx, and cpx) from peridotite xenoliths entrained in the Hannuoba Tertiary basalts, North China Craton, provide insight into Li isotopic fractionation between mantle minerals during melt-rock interaction in the considerably thinned lithospheric mantle. Bulk analyses of mineral separates show significant enrichment of Li in cpx (2.4-3.6 ppm) relative to olivine (1.2-1.8 ppm), indicating that these peridotites have been affected by mantle metasomatism with mafic silicate melts. Bulk olivine separates (δ7Li ∼ +3.3‰ to +6.4‰) are isotopically heavier than coexisting pyroxenes (δ7Li ∼ −3.3‰ to −8.2‰ in cpx, and −4.0‰ to −6.7‰ in opx). Such large variation suggests Li elemental and isotopic disequilibrium. This conclusion is supported by results from in situ SIMS analyses of mineral grains where significant Li elemental and isotopic zonations exist. The olivine and opx have lower Li concentrations and heavier Li isotopes in the rims than in the cores. This reverse correlation of δ7Li with Li concentrations indicates diffusive fractionation of Li isotopes. However, the zoning patterns in coexisting cpx show isotopically heavier rims with higher Li abundances. This positive correlation between δ7Li and Li concentrations suggests a melt mixing trend. We attribute Li concentration and isotope zonation in minerals to the effects of two-stage diffusive fractionation coupled with melt-rock interaction. The earliest melts may have been derived from the subducted oceanic slab with low δ7Li values produced by isotopic fractionation during the dehydration of the seawater-altered slab. Melts at later stages were derived from the asthenosphere and interacted with the peridotites, producing the Li elemental and isotopic zoning in mineral grains. These data thus provide evidence for multiple-stage peridotite-melt interaction in the lithospheric mantle beneath the northern North China Craton.  相似文献   

6.
Lithospheric thinning beneath the North China Craton is widely recognized, but whether the Yangtze block has undergone the same process is a controversial issue. Based on a detailed petrographic study, a suite of xenoliths from the Lianshan Cenozoic basalts have been analyzed for the compositions of minerals and whole rocks, and their Sr–Nd isotopes to probe the nature and evolution of the subcontinental lithospheric mantle beneath the lower Yangtze block. The Lianshan xenoliths can be subdivided into two Types: the main Type 1 xenoliths (9–15% clinopyroxene and olivine-Mg# < 90) and minor Type 2 peridotites (1.8–6.2% clinopyroxene and olivine-Mg# > 90). Type 1 peridotites are characterized by low MgO, high levels of basaltic components (i.e., Al2O3, CaO and TiO2), LREE-depleted patterns in clinopyroxenes and whole rocks, and relatively high 143Nd/144Nd (0.513219–0.513331) and low 86Sr/87Sr (0.702279–0.702789). These features suggest that Type 1 peridotites represent fragments of the newly accreted fertile lithospheric mantle that have undergone ~ 1% of fractional partial melting and later weak silicate–melt metasomatism, similar to Phanerozoic lithospheric mantle beneath the eastern North China Craton. Type 2 peridotites may be shallow relics of the older lithospheric mantle depleted in basaltic components, with LREE-enriched and HREE-depleted patterns, relatively low 143Nd/144Nd (0.512499–0.512956) and high 86Sr/87Sr (0.703275–0.703997), which can be produced by 9–14% partial melting and subsequent carbonatite–melt metasomatism. Neither type shows a correlation between equilibration temperatures and Mg# in olivine, indicating that the lithospheric mantle is not compositionally stratified, but both types coexist at similar depths. This coexistence suggests that the residual refractory lithospheric mantle (i.e., Type 2 peridotites) may be irregularly eroded by upwelling asthenosphere materials along weak zones and eventually replaced to create a new and fertile lithosphere mantle (i.e., Type 1 xenoliths) as the asthenosphere cooled. Therefore, the subcontinental lithospheric mantle beneath the lower Yangtze block shared a common evolutional dynamic environment with that beneath the eastern North China Craton during late Mesozoic–Cenozoic time.  相似文献   

7.
华北东部大陆地幔橄榄岩组成、年龄与岩石圈减薄   总被引：16，自引：1，他引：15  
对比分析了华北东部地块陆下岩石圈地幔橄榄石Mg#值和单斜辉石的REE配分形式。报道了汉诺坝和鹤壁橄榄岩中不同产状硫化物的激光MC-ICPMS原位Re-Os年龄和信阳橄榄岩中锆石的U-Pb年龄和信阳橄榄岩锆石的U-Pb年龄。在这些资料基础上,进一步讨论了华北东部岩石圈中、新生代时的减薄机制。原位分析在揭示岩石圈深部过程的细节上,有比全岩分析更大的优越性,并揭示出了在华北深部有中元古代(14亿年)和新元古代(7～8亿年)热活动的记录。岩石圈拆沉作用不能很好地解释古老难熔地幔、过渡型地幔和新生饱满地幔并存的事实;同时,单纯的熔体-橄榄岩相互作用也难以解释中、新生代岩石圈的减薄过程和新生地幔单斜辉石中出现强烈LREE亏损现象,即历史复杂的克拉通岩石圈向历史明显简单的“大洋型”地幔的转换。因此,华北东部岩石圈减薄包括地幔伸展、熔-岩作用、侵蚀置换等复杂过程。这些过程可能包括:(1)早中生代时,扬子地块向北俯冲碰撞所引起华北岩石圈的熔/流体交代富集作用、地幔伸展和受扰动软流圈物质上涌并侵蚀被改造了的岩石圈;(2)晚中生代—古近纪,因太平洋俯冲的热扰动致使软流圈物质进一步的强烈侵蚀作用引起岩石圈的巨大减薄;(3)晚第三纪以来的软流圈热沉降作用所带来的小幅度岩石圈增厚过程。岩石圈先大幅减薄、后小幅增厚实现了最终的地幔置换和岩石圈整体的减薄过程。喷发时代为100Ma的阜新玄武岩所捕获的橄榄岩主体是饱满的,说明华北东部部分地区在此之前曾有过地幔置换作用。  相似文献   

8.
Whole-rock major, trace, and platinum-group elemental (PGE) data, and major and trace element compositions of diopsides are reported for peridotite xenoliths from (1) early Mesozoic volcanic breccias in Xinyang, located at the southern margin of the North China Craton, and (2) Cenozoic basalts in Hebi and Shanwang, both of which are situated within the craton and lie on the North-South Gravity Line and the Tanlu fault zone, respectively. The early Mesozoic Xinyang xenoliths are harzburgites containing <2% Cpx with high Cr# and enriched in LREE but depleted in HFSE. These xenoliths have chondritic Pd/Ir (1.9-6.6) and Ru/Ir (3.5-4.0) ratios and high Ni and low CaO, Al2O3, and S contents, indicating derivation from a highly refractory mantle that experienced carbonatitic metasomatism. Negative Ce (mean δCe = 0.50) and low Mg/Si ratios of the Xinyang peridotites record the addition of crustal components likely produced from subducted continental material of the Yangtze Craton in the early Mesozoic. The subduction-related modification of the lithospheric mantle was limited to the area close to the collision zone rather than being pervasive throughout the craton. The Cenozoic Hebi peridotite xenoliths are harzburgites with ≤4.5% Cpx and have low CaO and Al2O3 but high Ni contents, chondritic Ru/Ir ratios (2.5-5.4), and a wide range of CaO/Al2O3, Na2O/TiO2, Pt/Ir (0.4-2.3), and Pd/Pt (1.1-8.5) ratios. These peridotites are interpreted as the shallow relics of the cratonic mantle. In contrast, the Cenozoic Shanwang xenoliths are lherzolites (5.6%-19.5% Cpx), which have low Ni contents and low Ni/Cu and Mg/Si ratios, but high CaO, Al2O3, S, and HREE contents, and relatively high Ru/Ir and Pd/Ir ratios. The Shanwang peridotites show pronounced positive Ti and Sr, negative Th, and slightly negative Y, Zr, and Hf anomalies. They are believed to represent newly accreted fertile lithospheric mantle derived from cooling of upwelling asthenosphere. The documented temporal and spatial variations in the Mesozoic-Cenozoic mantle support the previous suggestion that the buoyant refractory continental keel in the eastern part of the North China Craton was heterogeneously replaced by younger fertile lithospheric mantle in the late Cretaceous-early Tertiary.  相似文献   

9.
The ages of subcontinental lithospheric mantle beneath the North China and South China cratons are less well-constrained than the overlying crust. We report Re–Os isotope systematics of mantle xenoliths entrained in Paleozoic kimberlites and Mesozoic basalts from eastern China. Peridotite xenoliths from the Fuxian and Mengyin Paleozoic diamondiferous kimberlites in the North China Craton give Archean Re depletion ages of 2.6–3.2 Ga and melt depletion ages of 2.9–3.4 Ga. No obvious differences in Re and Os abundances, Os isotopic ratios and model ages are observed between spinel-facies and garnet-facies peridotites from both kimberlite localities. The Re–Os isotopic data, together with the PGE concentrations, demonstrate that beneath the Archean continental crust of the eastern North China Craton, Archean lithospheric mantle of spinel- to diamond-facies existed without apparent compositional stratification during the Paleozoic. The Mesozoic and Cenozoic basalt-borne peridotite and pyroxenite xenoliths, on the other hand, show geochemical features indicating metasomatic enrichment, along with a large range of the Re–Os isotopic model ages from Proterozoic to Phanerozoic. These features indicate that lithospheric transformation or refertilization through melt-peridotite interaction could be the primary mechanism for compositional changes during the Phanerozoic, rather than delamination or thermal-mechanical erosion, despite the potential of these latter processes to play an important role for the loss of garnet-facies mantle. A fresh garnet lherzolite xenolith from the Yangtze Block has a Re depletion age of ∼1.04 Ga, much younger than overlying Archean crustal rocks but the same Re depletion ages as spinel lherzolite xenoliths from adjacent Mesozoic basalts, indicating Neoproterozoic resetting of the Re–Os system in the South China Craton.  相似文献   

10.
The Mg- and Si-rich nature of the sub-cratonic lithospheric mantle (SCLM) beneath the Kaapvaal Craton indicates extensive melt depletion, followed by a Si-enrichment process. Six highly silica enriched peridotites from Kimberley containing high amounts of orthopyroxene (Opx) or garnet (Grt) that are locally concentrated in clots, were investigated to constrain the timing and nature of the Si-enrichment process. A clinopyroxene-bearing lherzolite containing an Opx-clot was studied to quantify the effects of recent metasomatism on the Si-enriched samples. Minerals from the lherzolite, together with Opx from harzburgites and Opx- and Grt-clots have Hf-Nd isotope ratios at the time of kimberlite eruption, 90 Ma, comparable to group I kimberlites and are close to trace element equilibrium with kimberlitic melts. This implies the xenoliths underwent major interaction with kimberlitic melts close to the time of kimberlite eruption.Harzburgites and mineral clots record equilibration pressures and temperatures of, respectively, between 3.5-4.3 GPa and 930-1060 °C. The garnets in Opx-clots have low Lu/Hf and εHf(t) −15, whereas garnets from Grt-clots have high Lu/Hf and εHf(t) +10. In contrast, Grt from both Grt- and Opx-clots have low Sm/Nd and εNd −10. The whole rock platinum group element (PGE) concentrations are an order of magnitude higher in the Grt-clot than the Opx-clot. Measured 187Os/188Os range from 0.1085 to 0.1222. The Grt-clot bearing sample yields Nd-Hf-Os isotope model ages that suggest formation in the Neoproterozoic (∼650 Ma). In contrast, an Opx-clot yields TRD ages of 2.8 Ga, which is interpreted as the time of formation of the host harzburgite. The Opx-clots and host harzburgites have comparable Lu-Hf isotope systematics that imply Opx growth at ∼1.3 Ga and hence their formation is not related to the Grt-clots.Garnets from Opx- and Grt-clots have elevated high-field strength element (HFSE) concentrations, and lack HFSE depletion relative to other trace elements with comparable degrees of incompatibility in the mantle (La/Nb < 0.5). In addition, calculated melts in equilibrium with Grt have strongly fractionated REE (Nd/Yb > 300) and HREE depletion (YbN < 0.1) suggesting equilibration with a hydrous melt that is more HREE depleted than a kimberlitic melt. Previous models that related Si-enrichment to subduction are inconsistent with the lack of HFSE depletion (La/Nb < 0.5). Therefore the favoured model for Opx- and Grt-clot formation is infiltration of a hydrous melt in a within plate geodynamical environment associated with volcanism in the Mid-proterozoic and Neoproterozoic, respectively. This implies that Si-enrichment of the Kaapvaal SCLM may be a consequence of numerous localised magmatic events rather than a single craton-wide process.  相似文献   

11.
Major- and trace-element data on the constituent minerals ofgarnet peridotite xenoliths hosted in early Paleozoic (457–500Ma) kimberlites and Neogene (16–18 Ma) volcanic rockswithin the North China Craton are compared with those from thepre-pilot hole of the Chinese Continental Scientific DrillingProject (CCSD-PP1) in the tectonically exhumed Triassic (220Ma) Sulu ultrahigh-pressure (UHP) terrane along its southernmargin. P–T estimates for the Paleozoic and Neogene peridotitexenoliths reflect different model geotherms corresponding tosurface heat flows of 40 mW/m2 (Paleozoic) and 80 mW/m2 (Neogene).Garnet peridotite xenoliths or xenocrysts from the Paleozoickimberlites are strongly depleted, similar to peridotites fromother areas of cratonic mantle, with magnesium olivine (meanFo92.7), Cr-rich garnet and clinopyroxene with high La/Yb. Garnet(and spinel) peridotite xenoliths hosted in Neogene basaltsare derived from fertile mantle; they have high Al2O3 and TiO2contents, low-Mg-number olivine (mean Fo89.5), low-Cr garnetand diopside with flat rare earth element (REE) patterns. Thedifferences between the Paleozoic and Neogene xenoliths suggestthat a buoyant refractory lithospheric keel present beneaththe eastern North China Craton in Paleozoic times was at leastpartly replaced by younger, hotter and more fertile lithosphericmantle during Mesozoic–Cenozoic times. Garnet peridotitesfrom the Sulu UHP terrane have less magnesian olivine (Fo91.5),and lower-Cr garnet than the Paleozoic xenoliths. The diopsideshave low heavy REE (HREE) contents and sinusoidal to light REE(LREE)-enriched REE patterns. These features, and their highMg/Si and low CaO and Al2O3 contents, indicate that the CCSD-PP1peridotites represent a moderately refractory mantle protolith.Details of mineral chemistry indicate that this protolith experiencedcomplex metasomatism by asthenosphere-derived melts or fluidsin Mesoproterozoic, and subsolidus re-equilibration involvingfluids/melts derived from the subducted Yangtze continentalcrust during UHP metamorphism in the early Mesozoic. Tectonicextension of the subcontinental lithospheric mantle of the NorthChina Craton and exhumation of the Sulu UHP rocks in the earlyMesozoic induced upwelling of the asthenosphere. Peridotitessampled by the Neogene basalts represent newly formed lithospherederived by cooling of the upwelling asthenospheric mantle inJurassic–Cretaceous and Paleogene time. KEY WORDS: garnet peridotite xenoliths; North China Craton; lithospheric thinning; Sulu UHP terrane; UHP lithosphere evolution; mantle replacement  相似文献   

12.
We have carried out a Pb double-spike and Lu-Hf isotope study of clinopyroxenes from spinel-facies mantle xenoliths entrained in Cenozoic intraplate continental volcanism of the French Massif Central (FMC). U-Th-Pb and Lu-Hf isotope systematics verify the existence of different lithospheric domains beneath the northern and southern FMC. Northern FMC clinopyroxenes have extreme Lu/Hf ratios and ultra-radiogenic Hf (εHf = +39.6 to +2586) that reflect ∼15-25% partial melting in Variscan times (depleted mantle model ages ∼360 Ma). Zr, Hf and Th abundances in these clinopyroxenes are low and unaffected by hydrous/carbonatitic metasomatism that overprinted LILE and light REE abundances and caused decoupling of Lu/Hf-Sm/Nd ratios and Nd-Hf isotopes (εNd = +2.1 to +91.2). Pb isotopes of northern FMC clinopyroxenes are radiogenic (206Pb/204Pb > 19), and typically more so than the host intraplate volcanic rocks. 238U/204Pb ratios range from 17 to 68, and most samples have distinctively low 232Th/238U (<1) and 232Th/204Pb (3-22). Clinopyroxenes from southern FMC lherzolites are generally marked by overall incompatible trace element enrichment including Zr, Hf and Th abundances, and have Pb isotopes that are similar to or less radiogenic than the host volcanic rocks. Hf isotope ratios are less radiogenic (εHf = +5.4 to +41.5) than northern FMC mantle and have been overprinted by silicate-melt-dominated metasomatism that affected this part of FMC mantle. Major element and Lu concentrations of clinopyroxenes from southern FMC harzburgites are broadly similar to northern FMC clinopyroxenes and suggest they experienced similar degrees of melt extraction as northern FMC mantle. 238U/204Pb (53-111) and 232Th/204Pb ratios (157-355) of enriched clinopyroxenes from the southern FMC are extreme and significantly higher than the intraplate volcanic rocks. In summary, mantle peridotites from different parts of the FMC record depletion at ∼360 Ma during Variscan subduction, followed by differing styles of enrichment. Northern FMC mantle was overprinted by a fluid/carbonatitic metasomatic agent that carried elements like U, Pb, Sr and light REE. In contrast, much of the southern FMC mantle was metasomatised by a small-degree partial silicate melt resulting in enrichment of all incompatible trace elements. The extreme mantle 238U/204Pb (northern and southern FMC), 232Th/238U (northern FMC) and 232Th/204Pb ratios (southern FMC), coupled with unremarkable present-day Pb isotope ratios, constrain the timing of enrichment. Mantle metasomatism is a young feature related to melting of the upwelling mantle responsible for Cenozoic FMC volcanism, rather than subduction-related metasomatism intimately associated with mantle depletion during the Variscan orogeny. The varying metasomatic styles relate to pre-existing variations in the thickness of the continental lithospheric lid, which controlled the extent to which upwelling mantle could ascend and melt. In the northern FMC, a thicker and more refractory lithospheric lid (?80 km) only allowed incipient degrees of melting resulting in fluid/carbonatitic metasomatism of the overlying sub-continental lithospheric mantle. The thinner lithospheric lid of the southern FMC (?70 km) allowed larger degrees of melting and resulted in silicate-melt-dominated metasomatism, and also focused the location of the volcanic fields of the FMC above this region.  相似文献   

13.
The effects of melt percolation on highly siderophile element (HSE) concentrations and Re-Os isotopic systematics of subcontinental lithospheric mantle are examined for a suite of spinel peridotite xenoliths from the 4 Ma Kozákov volcano, Bohemian Massif, Czech Republic. The xenoliths have previously been estimated to originate from depths ranging from ∼32 to 70 km and represent a layered upper mantle profile. Prior petrographic and lithophile trace element data for the xenoliths indicate that they were variably modified via metasomatism resulting from the percolation of basaltic melt derived from the asthenosphere. Chemical and isotopic data suggest that lower sections of the upper mantle profile interacted with melt characterized by a primitive, S-undersaturated composition at high melt/rock ratios. The middle and upper layers of the profile were modified by more evolved melt at moderate to low melt/rock ratios. This profile permits an unusual opportunity to examine the effects of variable melt percolation on HSE abundances and Os isotopes.Most HSE concentrations in the studied rocks are significantly depleted compared to estimates for the primitive upper mantle. The depletions, which are most pronounced for Os, Ir and Ru in the lower sections of the mantle profile, are coupled with strong HSE fractionations (e.g., OsN/IrN ratios ranging from 0.3 to 2.4). Platinum appears to have been removed from some rocks, and enriched in others. This enrichment is coupled with lithophile element evidence for the degree of percolating melt fractionation (i.e., Ce/Tb ratio).Osmium isotopic compositions vary considerably from subchondritic to approximately chondritic (γOs at 5 Ma from -6.9 to +2.1). The absence of correlations between 187Os/188Os and indicators of fertility, as is common in many lithospheric mantle suites, may suggest significant perturbation of the Os isotopic compositions of some of these rocks, but more likely reflect the normal range of isotopic compositions found in the modern convecting mantle. Osmium isotopic compositions correspondingly yield model Re-depletion (TRD) ages that range from essentially modern to ∼1.3 Ga.Our data provide evidence for large-scale incompatible behavior of HSE during melt percolation as a result of sulfide dissolution, consistent with observations of prior studies. The degree of incompatibility evidently depended on melt/rock ratios and the degree of S-saturation of the percolating melt. The high Pt contents of some of these rocks suggest that the Pt present in this pervasively metasomatized mantle was controlled by a phase unique to the other HSE. Further, high Os concentrations in several samples suggest deposition of Os in a minority of the samples by melt percolation. In these rocks, the mobilized Os was characterized by similar to the 187Os/188Os ratios in the ambient rocks. There is no evidence for either the addition of Os with a strongly depleted isotopic composition, or Os with suprachondritic isotopic composition, as is commonly observed under such circumstances.  相似文献   

14.
高山  刘勇胜 《地学前缘》2003,10(3):61-67
测定了辽宁复县奥陶纪金伯利岩和河北汉诺坝与山东栖霞第三纪碱性玄武岩中产出的地幔包体的Re Os同位素组成。金伯利岩中地幔包体的Re贫化Os同位素模式年龄 (TRD)为 2 .5～ 2 .8Ga ,从Re Os同位素定年角度证明了华北克拉通确实存在太古宙岩石圈地幔。对汉诺坝二辉橄榄岩包体获得了 (1.9± 0 .18)Ga的Re Os同位素等时线年龄 ,表明现今保存在那里的地幔主要是古元古代时形成的。汉诺坝地区出露有大量新太古代岩石 ,表明曾存在太古宙地幔。由于缺乏太古宙年龄 ,说明由汉诺坝所代表的克拉通中部曾存在的太古宙地幔在古元古代时已被减薄 ,并被 1.9Ga的新生岩石圈地幔置换。该事件与华北克拉通中部广泛的古元古代碰撞造山过程导致的麻粒岩相变质作用的时代相同 ,说明有关的岩石圈置换作用可能主要与拆沉作用有关。栖霞地幔包体具有与现代对流地幔相同的Os同位素组成 ,且Os同位素组成与Re/Os比值没有明显相关性 ,表明年龄很新。结合其它地质地球化学证据 ,说明克拉通东部的太古宙岩石圈地幔的置换作用主要发生在中生代 ,且可能与三叠纪华北和扬子陆块的陆陆碰撞造山导致的岩石圈地幔和下地壳的拆沉作用有关。本研究表明华北克拉通岩石圈地幔置换作用在时空上的分布是十分不均一的。 2 .5～ 2 .8Ga与 1.9Ga不仅?  相似文献   

15.
Spinel peridotite xenoliths in alkali basalts at Tok, SE Siberian craton range from fertile lherzolites to harzburgites and wehrlites; olivine-rich (70-84%) rocks are dominant. REE patterns in the lherzolites range from nearly flat for fertile rocks (14-17% cpx) to LREE-enriched; the enrichments are positively correlated with modal olivine, consistent with high-permeability of olivine-rich rocks during melt percolation. Clinopyroxene in olivine-rich Tok peridotites typically has convex-upward trace element patterns (La/NdPM < 1 and Nd/YbPM ? 1), which we consider as evidence for equilibration with evolved silicate liquids (with higher REE and lower Ti contents than in host basalts). Whole-rock patterns of the olivine-rich xenoliths range from convex-upward to LREE-enriched (La/NdPM > 1); the LREE-enrichments are positively correlated with phosphorus abundances and are mainly hosted by accessory phosphates and P-rich cryptocrystalline materials. In addition to apatite, some Tok xenoliths contain whitlockite (an anhydrous, halogen-poor and Na-Mg-rich phosphate), which is common in meteorites and lunar rocks, but has not been reported from any terrestrial mantle samples. Some olivine-rich peridotites have generations of clinopyroxene with distinct abundances of Na, LREE, Sr and Zr. The mineralogical and trace element data indicate that the lithospheric mantle section represented by the xenoliths experienced a large-scale metasomatic event produced by upward migration of mafic silicate melts followed by percolation of low-T, alkali-rich melts and fluids. Chromatographic fractionation and fractional crystallisation of the melts close to the percolation front produced strong LREE-enrichments, which are most common in the uppermost mantle and are related to carbonate- and P2O5-rich derivatives of the initial melt. Reversal and gradual retreat of the percolation front during thermal relaxation to ambient geotherm (“retrograde” metasomatism) caused local migration and entrapment of small-volume residual fluids and precipitation of volatile-rich accessory minerals. A distinct metasomatic episode, which mainly produced “anhydrous” late-stage interstitial materials was concomitant with the alkali basaltic magmatism, which brought the xenoliths to the surface.  相似文献   

16.
Recent tectonic analysis suggests that the North China Craton consists of two Archean continental blocks, called the Eastern and Western Blocks, separated by the Paleoproterozoic Trans-North China Orogen. Although the published geochronological data are not sufficient to constrain the detailed tectonothermal evolution of the craton, the available Nd isotopic data show some important differences in Nd model ages between the tectonic units. The Eastern Block shows two main Nd model age peaks, one between 3.6 and 3.2 Ga and the other between 3.0 and 2.6 Ga. Limited Nd isotopic data from the Western Block show a large range of model ages between 3.2 and 2.4 Ga. These differences are consistent with the recently-proposed model.The Nd isotopic data from mantle-derived mafic rocks indicate that the mantle beneath the North China Craton was depleted in the Archean, consistent with major crustal growth during this period. In the Paleoproterozoic, however, the mantle-derived mafic rocks show negative εNd(t) values, implying crustal contamination. This may have resulted from subduction and collision between the Eastern and Western Block, implying that the mechanisms of crustal formation and evolution may have been different between the Archean and Paleoproterozoic.The North China Craton was re-activated by addition of mantle-derived magma into the lower crust in the late Mesozoic, resulting in rejuvenation of the lower crust. This indicates that underplating is also an important mechanism for continental addition, although in this case it may not equate to crustal growth, since it was preceded by removal of lithospheric mantle and possible some lower crust.  相似文献   

17.
橄榄石是地幔橄榄岩和辉石岩的主要组成矿物,但也经常以斑晶和捕虏晶的形式出现在玄武质岩石中。结合近年来在地幔橄榄岩的主要元素（如Mg和Fe）组成特征以及Li、Mg和Fe稳定同位素地球化学方面的研究成果,重点对橄榄石的地球化学特征与华北克拉通岩石圈地幔演化过程之间的联系进行了讨论,旨在加深对华北克拉通岩石圈地幔演化过程的理解。现有研究表明：地幔橄榄岩中橄榄石的矿物学特征、元素和同位素地球化学组成能够很好地指示岩石圈地幔的特征及其演化过程,因而具有重要的意义。对于克拉通地区的地幔橄榄岩来说,橄榄石的Mg#通常可以指示岩石圈地幔的属性,古老、难熔的地幔橄榄岩中的橄榄石一般具有较高的Mg#（〉92）,而新生的岩石圈地幔橄榄岩中的橄榄石则具有较低的Mg#（〈91）。因此,地幔橄榄岩中橄榄石的Mg#在一定程度上具有年龄意义。橄榄岩中橄榄石的Li、Mg和Fe同位素组成也可以明确指示岩石圈地幔的属性及其所经历的演化过程,正常地幔的δ7Li、δ26Mg和δ57Fe组成相对均一,如果上述同位素组成偏离正常地幔值,则说明岩石圈地幔经历了熔体/流体的交代作用。华北克拉通地区地幔橄榄岩捕虏体中橄榄石的Li、Mg和Fe同位素组成研究表明：该区的岩石圈地幔经历了多个阶段、不同来源的熔体/流体的改造过程。  相似文献   

18.
Dunite, wehrlite and websterite are rare members of the mantle xenolith suite in the Kimberley kimberlites of the Kaapvaal Craton in southern Africa. All three types were originally residues of extensive melt extraction and experienced varying amounts and types of melt re-enrichment. The melt depletion event, dated by Re-Os isotope systematics at 2.9 Ga or older, is evidenced by the high Mg# (Mg/(Mg + Fe)) of silicate minerals (olivine (0.89-0.93); pyroxene (0.88-0.93); garnet (0.72-0.85)), high Cr# (Cr/(Cr + Al)) of spinel (0.53-0.84) and mostly low whole-rock SiO2, CaO and Al2O3 contents. Shortly after melt depletion, websterites were formed by reaction between depleted peridotites and silica-rich melt (>60 wt% SiO2) derived by partial melting of eclogite before or during cratonization. The melt-peridotite interaction converted olivine into orthopyroxene.All three xenolith types have secondary metasomatic clinopyroxene and garnet, which occur along olivine grain boundaries and have an amoeboid texture. As indicated by the preservation of oxygen isotope disequilibrium in the minerals and trace-element concentrations in clinopyroxene and garnet, this metasomatic event is probably of Mesozoic age and was caused by percolating alkaline basaltic melts. This melt metasomatism enriched the xenoliths in CaO, Al2O3, FeO and high-field-strength-elements, and might correspond to the Karoo magmatism at 200 Ma. The websterite xenoliths experienced both the orthoyproxene-enrichment and clinopyroxene-garnet metasomatic events, whereas dunite and wehrlite xenoliths only saw the later basaltic melt event, and may have been situated further away from the source of melt migration channels.  相似文献   

19.
Garnet-facies continental mantle is poorly understood because the vast majority of mantle xenoliths in continental basalts are spinel peridotite. Peridotite xenoliths from Vitim (southern Siberia) and Mongolia provide some of the best samples of garnet and garnet-spinel facies off-craton lithospheric mantle. Garnets in those fertile to moderately depleted lherzolites show a surprisingly broad range of HREE abundances, which poorly correlate with modal and major oxide compositions. Some garnets are zoned and have Lu-rich cores. We argue that these features indicate HREE redistribution after the partial melting, possibly related to spinel-garnet phase transition on isobaric cooling. Most peridotites from Vitim have depleted to ultra-depleted Hf isotope compositions (calculated from mineral analyses: εHf(0) = +17 to +45). HREE-rich garnets have the most radiogenic εHf values and plot above the mantle Hf-Nd isotope array while xenoliths with normal HREE abundances usually fall within or near the depleted end of the MORB field. Model Hf isotope ages for the normal peridotites indicate an origin by ancient partial melt extraction from primitive mantle, most likely in the Proterozoic. By contrast, an HREE-rich peridotite yields a Phanerozoic model age, possibly reflecting overprinting of the ancient partial melting record with that related to a recent enrichment in Lu. Clinopyroxene-garnet Lu-Hf isochron ages (31-84 Ma) are higher than the likely eruption age of the host volcanic rocks (∼16 Ma). Garnet-controlled HREE migration during spinel-garnet and garnet-spinel phase transitions may be one explanation for extremely radiogenic 176Hf/177Hf reported for some mantle peridotites; it may also contribute to Hf isotope variations in sub-lithospheric source regions of mantle-derived magmas.  相似文献   

20.
The Dabie ultrahigh-pressure (UHP) metamorphic belt, central China, contains two contrasting types of ultramafic–mafic complex. The Bixiling peridotite in the southern Dabie terrane contains abundant garnet (21–32 vol.%) and thus has high CaO +Al2O3 (9.94–15.3 wt.%). The peridotite also has high REE contents with flat REE patterns, high contents of S and other incompatible trace elements, together with low-Mg# olivine and pyroxene and low Ni and PGE contents. Zircons from this peridotite mostly have low Th/U ratios, interpreted to reflect a metamorphic origin, and give dominantly Triassic ages (ca. 210 Ma). Other zircons with high Th/U ratios give upper intercept ages of 745 Ma. Most zircons have positive ?Hf (+- 3.6 ～ +- 8.1) values with depleted-mantle model ages (TDM) of 0.6–1.0 Ga (mean 0.8 Ga) and crustal model ages (Tcrust) of 0.8–1.4 Ga (mean 1.1 Ga). We interpret that the Bixiling complex was formed as cumulates in a Neoproterozoic asthenosphere-derived magma chamber in the continental crust, and was later carried to garnet-stable depths (ca. ～ 4.4 GPa) during the subduction of the Yangtze Craton in the Triassic. In contrast, the Raobazhai peridotite in the northern Dabie terrane was metamorphosed at lower P/T conditions (i.e. 15 Kb and 1000 °C). All zircon grains from the peridotite yield Triassic ages (ca. 212 Ma) and have negative ?Hf values (? 16.6 ～ ? 3.2), Mesoproterozoic model ages (TDM = 1.0–1.5 Ga) and Paleoproterozoic crustal model ages (Tcrust = 1.5–2.3 Ga). The peridotite is enriched in LREE ((La/Yb)n ≈ 3.5), has high-Mg# olivine and pyroxene, high Ni and PGEs but low Pd/Ir (mean 3.0). It represents a highly refractory residue of partial melting (up to 18%) of primitive mantle, and is similar to the cratonic mantle xenoliths in Phanerozoic igneous rocks from the eastern North China Craton (e.g. Mengyin and Hebi areas). Negative Ce, Eu and HFSE anomalies in the peridotites suggest that their protolith was derived from the shallow part of the mantle wedge (e.g. plagioclase-stable field) of the North China Craton, and was pulled to a deeper level (e.g. spinel-stable field) during the subduction of the Yangtze Craton. The mantle wedge, like peridotitic xenoliths in the Jurassic Xinyang diatremes at the southern edge of the North China Craton, was metasomatised by fluids/melts released from the subducted continental crust. The fragments of this modified mantle wedge were incorporated into the Yangtze crust during its subduction.  相似文献   

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