The wide boron isotopic variations occurring in natural waters mainly are derived from the 20‰ fractionation between dissolved boric acid and borate anions, associated with the preferential removal from the system of 11B depleted borate ions by adsorption and/or minerals formation. Typical adsorbants of boron dissolved in groundwater are clay minerals of the aquifer matrix. Boron (and strontium) isotopes were used in investigating two alluvial aquifers in Tuscany, where boron concentration is often above 1 mg L− 1 and may attain 8 mg L− 1. The isotopic results indicate that, in the first case (Cecina River basin), the boron contamination is anthropogenic and derives from past discharge into streams of boron-rich industrial wastes. In the second case (Cornia Plain), the dissolved boron is released by boron-rich clayey sediments of the aquifer matrix and has, therefore, a natural origin. 相似文献
A methodology is proposed for the inference, at the regional and local scales, of flood magnitude and associated probability. Once properly set-up, this methodology is able to provide flood frequencies distributions at gauged and un-gauged river sections pertaining to the same homogeneous region, using information extracted from rainfall observations. A proper flood frequency distribution can be therefore predicted even in un-gauged watersheds, for which no discharge time series is available. 相似文献
The most conspicuous waterbodies in the Pampa region of Argentina are the so-called “lagunas”. A typical Pampean laguna may be described as a relatively large (100+ha), permanent, shallow lake. Here, we report the dynamics of laguna Chascomús, sampled weekly, from April 2001 to June 2003. During the period, the lakes experienced three consecutive floods waves that affected the concentration of major ions and the optical signature of the dissolved organic matter. Despite these hydrological alterations, laguna Chascomús was permanently limited by light. Transparency was to a great extent controlled by the incident photosynthetic available radiation irradiance. We hypothesize that wind contributes to the permanent mixing of the lake, as well as to lessen the sedimentation losses of photoautotrophs. 相似文献
The interaction between surface and subsurface water has a crucial influence on the biochemistry of stream environments. Even though the river discharge and the flow conditions can seldom be considered to be steady, the influence of this unsteadiness on the hyporheic exchange has often been neglected. In this work, a model for the study of hyporheic exchange during unsteady conditions has been developed. The model provides a sound analytical framework for the analysis of the effects of a varying stream discharge on the exchange between a stream and the hyporheic zone. The effects of the unsteadiness on the water exchange flux, the residence time of the solutes in the bed, and the stored mass are quantified. A synthetic example shows the substantial influence of a flood on the hyporheic exchange, and that the application of a steady model can lead to an underestimation of the exchanged mass, even after the flood has ended. 相似文献
We present the basic concepts of the two-mirror, three-reflection optical system (2MTRT), and discuss the important benefits of such a system for space projects: wide ( 2°) correctedand unvignetted FOV, without the use of refractive optics for thefield correction, planarity of the focal surface for an optimizedinstallation of wide area detectors, easy telescope adjustement, small volume and little mass.We also report the results of optical tests made with a 30 cm prototype,equipped with a 2k × 2k CCD camera, and give examples of scientific programmes which can be performed from space and in hostile terrestrial sites such as the Antarctic Plateau. 相似文献
The sorption of226Ra from oil-production brine by soils and sediments was investigated. Sorption was rapid, and the percentage sorbed increased
with brine dilution. Greatest removals of226Ra from sediments in the laboratory occurred with alkaline DTPA, HCl, and BaCl2, with lesser removals using CaCl2 and NaCl solutions. Digestion of sediments with NaOCl indicates that most of the native and sorbed226Ra is associated with the mineral rather than organic fraction of the sediments. Correlation analysis based on 14 soils indicates
that the retention of226Ra may involve precipitation reactions associated with sulfate-bearing minerals, as well as ion-exchange reactions with the
clay mineral fractions of surficial earth materials.
Oceanographer, Naval Ocean Research and Development Activity, Code 334; NSTL Station, Mississippi 39529 NORDA Contribution
#83:334:01. 相似文献
This study presents near future (2020–2044) temperature and precipitation changes over the Antarctic Peninsula under the high-emission scenario (RCP8.5). We make use of historical and projected simulations from 19 global climate models (GCMs) participating in Coupled Model Intercomparison Project phase 5 (CMIP5). We compare and contrast GCMs projections with two groups of regional climate model simulations (RCMs): (1) high resolution (15-km) simulations performed with Polar-WRF model forced with bias-corrected NCAR-CESM1 (NC-CORR) over the Antarctic Peninsula, (2) medium resolution (50-km) simulations of KNMI-RACMO21P forced with EC-EARTH (EC) obtained from the CORDEX-Antarctica. A further comparison of historical simulations (1981–2005) with respect to ERA5 reanalysis is also included for circulation patterns and near-surface temperature climatology. In general, both RCM boundary conditions represent well the main circulation patterns of the historical period. Nonetheless, there are important differences in projections such as a notable deepening and weakening of the Amundsen Sea Low in EC and NC-CORR, respectively. Mean annual near-surface temperatures are projected to increase by about 0.5–1.5 \(^{\circ }\)C across the entire peninsula. Temperature increase is more substantial in autumn and winter (\(\sim \) 2 \(^{\circ }\)C). Following opposite circulation pattern changes, both EC and NC-CORR exhibit different warming rates, indicating a possible continuation of natural decadal variability. Although generally showing similar temperature changes, RCM projections show less warming and a smaller increase in melt days in the Larsen Ice Shelf compared to their respective driving fields. Regarding precipitation, there is a broad agreement among the simulations, indicating an increase in mean annual precipitation (\(\sim \) 5 to 10%). However, RCMs show some notable differences over the Larsen Ice Shelf where total precipitation decreases (for RACMO) and shows a small increase in rain frequency. We conclude that it seems still difficult to get consistent projections from GCMs for the Antarctic Peninsula as depicted in both RCM boundary conditions. In addition, dominant and common changes from the boundary conditions are largely evident in the RCM simulations. We argue that added value of RCM projections is driven by processes shaped by finer local details and different physics schemes that are introduced by RCMs, particularly over the Larsen Ice Shelf.
Population abundance, distribution and habitat preference of the Mediterranean sympatric seahorses Hippocampus guttulatus and Hippocampus hippocampus were investigated in a semi‐enclosed sea system (Apulian coast, Ionian Sea). A total of 242 individuals of seahorses were sighted in the 11 transects surveyed in summer 2011. Hippocampus guttulatus (n = 225) were 14 times more abundant than H. hippocampus (17). The mean abundance of H. guttulatus for all the pooled sites was 0.018 m?2 (SE ± 0.003) ranging from a maximum of 0.035 (SE ± 0.007) to a minimum of 0.008 (SE ± 0.002). The size structure of long‐snouted seahorse shows a population ranging from 7 to 14 cm (SL) with a peak at 10 cm (TL). Juveniles (96.0 ± 8.0 mm) represent a significant fraction of the population, accounting more than 21% of the sighted individuals. In Mar Piccolo, H. guttulatus is able to shelter both in monotonous habitats, including the algal beds, and diversified ones, such as the rich filter‐feeder communities that colonize hard substrates. By contrast, H. hippocampus is mainly associated with habitats of low complexity. Today, the Mar Piccolo di Taranto is among the most heavily polluted water bodies in South Italy, with trace metals, hydrocarbons, pesticides and organic wastes affecting both biotic and abiotic matrices. However, despite the high level of degradation, the presence of a large mussel farm has avoided the impact of towed fishing gears, and eutrophication of water bodies has ensured a high trophic level that supports large crustacean populations, potential prey for seahorses. 相似文献