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Empirical evidence has shown that particle breakage affects the mechanical behaviour of granular materials. The source of this mechanism takes place at the particle scale, and the main consequence on the macromechanical behaviour is increasing compressibility. Due to the inverse correlation between particle size and particle crushing strength, coarse rockfill materials are particularly vulnerable to mechanical degradation due to particle breakage. However, such coarse materials do not fit in standard laboratory devices, and the alternative of large sample testing is usually unavailable or too expensive. Alternatively, recent works have proposed multi-scale approaches using the discrete element method (DEM) to carry out numerical testing of coarse crushable materials, although few studies have focused on size effects. This article presents the application of a DEM bonded-cell model to study particle size-strength correlation on angular rock aggregates. Each particle is modelled by a cluster of perfectly rigid polyhedral cells with Mohr–Coulomb contact law. Constant cell density within particles implies that the presence of potential fragmentation planes increases with size. Therefore, particle strength decreases with size. A comprehensive sensitivity analysis was carried out through 1477 particle crushing simulations in a given particle size. Based on published experimental data on calcareous rock aggregates, part of the simulations were used for calibration, and 97 additional simulations of a coarser size fraction were performed for validation. The results show a good agreement with the empirical data in terms of size effect and data scatter through Weibull statistics.

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We present and analyse the sunspot observations performed by Franz I.C. Hallaschka in 1814 and 1816. These solar observations were carried out during the so-called Dalton minimum, around the maximum phase of Solar Cycle 6. These records are very valuable because they allow us to complete observational gaps in the collection of sunspot group numbers, improving the coverage for this epoch. We have analysed and compared the observations made by Hallaschka with the records made by other contemporary observers. Unfortunately, the analysis of the sunspot areas and positions showed that they are too inaccurate for scientific use. We conclude, however, that the sunspot counts made by Hallaschka are similar to those made by other astronomers of that time. The observations by Hallaschka confirm a low level of solar activity during the Dalton minimum.  相似文献   
4.
A sunspot catalogue was maintained by the Astronomical Observatory of Valencia University (Spain) from 1920 to 1928. Here we present a machine-readable version of this catalogue (OV catalogue or OVc), including a quality-control analysis. Sunspot number (total and hemispheric) and sunspot area series are constructed using this catalogue. The OV catalogue data are compared with other available solar data, demonstrating that the present contribution provides the scientific community with a reliable catalogue of sunspot data.  相似文献   
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Snakebite envenoming is an important public health problem worldwide and addressing this issue has turned into a challenge for applied science. In this sense, the study of the distributional patterns of problematic snakes is central in terms of public health. Global Climate Change is affecting the distributional ranges of snakes, so that decisions regarding treatment of ophidism (poisoning by snake venom) may also change spatially and/or temporally. Here, we assessed suitable climate spaces at present conditions and estimated potential future changes in the distributions of the five southernmost venomous snakes, responsible for almost 99 % of accidents in Argentina, by implementing an ensemble of forecasts between different algorithms and scenarios for 2030 and 2080. Present suitable climate spaces showed high concordance with known distribution of the species. Future projections show moderate “north to south” displacements of the snakes’ suitable climate spaces, implying potential increments of suitable spaces in human populated areas in Argentina. Our results suggest the necessity of considering ophidism as a dynamic problem. In this regard, the analyses implemented here are useful tools in improving the assessment of snakebite envenoming in light of global climate change.  相似文献   
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Theoretical and Applied Climatology - Heat wave (HW) events are becoming more frequent, and they have important consequences because of the negative effects they can have not only on the human...  相似文献   
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This article presents a complete study of the diurnal chemical reactivity of the biogenic volatile organic compound (BVOC), 2-methyl-3-buten-2-ol (MBO) in the troposphere. Reactions of MBO with OH and with ozone were studied to analyse the respective parts of both processes in the global budget of MBO atmospheric reactivity. They were investigated under controlled conditions for pressure (atmospheric pressure) and temperature (298 ± 2 K) using three complementary European simulation chambers. Reaction with OH radicals was studied in the presence of and in the absence of NO x . The kinetic study was carried out by relative rate study using isoprene as a reference. The rate constant found for this reaction was molecule−1 cm3 s−1. FTIR spectroscopy, DNPH- and PFBHA-derivatisation analyses were performed for reactions with both OH radicals and ozone. In both reactions, the hydroxycarbonyl compound, 2-hydroxy-2-methylpropanal (HMPr) was positively identified and quantified, with a yield of in the reaction with OH, and a yield of and 0.84 ± 0.08 in the reaction with ozone under dry (HR < 1%) and humid conditions (HR = 20%–30%). A primary production of two other carbonyl compounds, acetone , and formaldehyde was found in the case of the dry ozonolysis experiments. Under humid conditions, only formaldehyde was co-produced with HMPr as a primary carbonyl compound, with a yield of . For the reaction with OH, three other carbonyl compounds were detected, acetone , formaldehyde and glycolaldehyde . In addition some realistic photo-oxidation experiments were performed to understand in an overall way the transformations of MBO in the atmosphere. The realistic photo-oxidation experiments were conducted in the EUPHORE outdoor simulation chamber. It was found that this compound is a weak secondary aerosol producer (less than 1% of the carbon balance). But it was confirmed that it is a potentially significant source of acetone, Δ[Acetone]/Δ[MBO] = 0.45. With our experimental conditions ([MBO]0 = 200 ppb, [NO]o = 50 ppb), an ozone yield of Δ[O3]/Δ[MBO] = 1.05 was found.  相似文献   
9.
Benthic biofilters were deployed under a cage fish farm and in two reference locations to assess the influence of the farm on the biofilters and the surroundings, as well as to verify the usefulness of this technology as a mitigation tool. The biofilters underneath the farm recruited a fouling community practically identical to that of the control biofilters, which included a variety of trophic strategies. The former showed a higher 15N enrichment, indicating that fouling beneath the farm was benefiting from the farm waste. The waste retention efficiency was low (0.02 g N m−2 month−1) beneath the farm. Benthic biofilters aggregated demersal wild fish around and within them. Pelagic wild fish also frequently used the biofilters beneath the farm, forming compact shoals around them. The increased complexity of the habitat below the fish farm enhanced biodiversity, but this improvement did not lead to the recovery of the sediments around the biofilters.  相似文献   
10.
Carrasco  R.M.  Pedraza  J.  Martin-Duque  J.F.  Mattera  M.  Sanz  M.A.  Bodoque  J.M. 《Natural Hazards》2003,30(3):361-381
The Jerte Valley is anortheast-southwest tending graben located in the mountainous region of west central Spain (Spanish Central System). Mass movements have been a predominant shaping process on the Valley slopes during the Quaternary. Present day activity is characterized as either `first-time failure' (shallow debris slides and debris flows) or `reactivations' of pre-existing landslides deposits.A delineation of landslide hazard zoningwithin the Valley has been carried out by using the detailed documentation of a particular event (a debris slide and a sequel torrential flood, which occurred on the Jubaguerra stream gorge), and GIS techniques. The procedure has had four stages, which are: (1) the elaboration of a susceptibility map (spatial prediction) of landslides; (2) the elaboration of a map of `restricted susceptibility' in the particular case of slopes that are connected to streams and torrents (gorges); (3) the elaboration of a digital model which relates the altitude to the occurrence probability of those particular precipitation conditions which characterized the Jubaguerra event and (4) the combination of the probability model with the `restricted susceptibility map', to establish `critical zones' or areas which are more prone to the occurrence of phenomena that have same typology as this one.  相似文献   
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