The Messinian salinity crisis in Cyprus: a further step towards a new stratigraphic framework for Eastern Mediterranean   总被引：1，自引：1，他引：0       下载免费PDF全文

Vinicio Manzi  Stefano Lugli  Marco Roveri  Francesco Dela Pierre  Rocco Gennari  Francesca Lozar  Marcello Natalicchio  B. Charlotte Schreiber  Marco Taviani  Elena Turco 《Basin Research》2016,28(2):207-236

A revised stratigraphic framework for the Messinian succession of Cyprus is proposed demonstrating that the three‐stage model for the Messinian salinity crisis recently established for the Western Mediterranean also applies to the Eastern Mediterranean, at least for its marginal basins. This analysis is based on a multidisciplinary study of the Messinian evaporites and associated deposits exposed in the Polemi, Pissouri, Maroni/Psematismenos and Mesaoria basins. Here, we document for the first time that the base of the unit usually referred to the ‘Lower Evaporites’ in Cyprus does not actually correspond to the onset of the Messinian salinity crisis. The basal surface of this unit rather corresponds to a regional‐scale unconformity, locally associated with an angular discordance, and is related to the erosion and resedimentation of primary evaporites deposited during the first stage of the Messinian salinity crisis. This evidence suggests that the ‘Lower Evaporites’ of the southern basins of Cyprus actually belong to the second stage of the Messinian salinity crisis; they can be thus ascribed to the Resedimented Lower Gypsum unit that was deposited between 5.6 and 5.5 Ma and is possibly coeval to the halite deposited in the northern Mesaoria basin. Primary, in situ evaporites of the first stage of the Messinian salinity crisis were not preserved in Cyprus basins. Conversely, shallow‐water primary evaporites deposited during the third stage of the Messinian salinity crisis are well preserved; these deposits can be regarded as the equivalent of the Upper Gypsum of Sicily. Our study documents that the Messinian stratigraphy shows many similarities between the Western and Eastern Mediterranean marginal basins, implying a common and likely coeval development of the Messinian salinity crisis. This could be reflected also in intermediate and deep‐water basins; we infer that the Lower Evaporites seismic unit in the deep Eastern Mediterranean basins could well be mainly composed of clastic evaporites and that its base could correspond to the Messinian erosional surface.  相似文献   

Petrological, geochemical and isotopic characteristics of the lithospheric mantle beneath Sardinia (Italy) as indicated by ultramafic xenoliths enclosed in alkaline lavas     

Ivana Rocco  Michele Lustrino  Vincenzo Morra  Leone Melluso 《International Journal of Earth Sciences》2012,101(5):1111-1125

Mantle xenoliths hosted in Miocene-Quaternary mafic alkaline volcanic rocks from Sardinia have been investigated with electron microprobe, laser ablation microprobe-inductively coupled plasma-mass spectrometry and thermal ionization mass spectrometry techniques. The xenoliths are anhydrous clinopyroxene-poor lherzolites and harzburgites, plus very rare websterites and olivine-websterites. Glassy pods having thin subhedral to euhedral microlites of olivine, clinopyroxene and spinel have been found in harzburgites and websterites. Clinopyroxene shows trace element variability, with values of (La/Yb)_N ranging from sub-chondritic (0.01) to supra-chondritic (8.6). The Sr–Nd isotopic ratios of the clinopyroxenes fall mostly in the field of the European lithospheric mantle xenoliths (⁸⁷Sr/⁸⁶Sr from 0.70385 to 0.70568 and ¹⁴³Nd/¹⁴⁴Nd ranging from 0.512557 to 0.512953). The geochemical characteristics of the Sardinian xenoliths testify to the variable degrees of earlier partial melt extraction, followed by metasomatic modification by alkaline melts or fluids. Websterites are considered to represent small lenses or veins of cumulitic (i.e. magmatic) origin within the mantle peridotite.  相似文献   

A fully convex reformulation of the original Matsuoka–Nakai failure criterion and its implicit numerically efficient integration algorithm     

Andrea Panteghini  Rocco Lagioia 《国际地质力学数值与分析法杂志》2014,38(6):593-614

This paper presents a reformulation of the original Matsuoka–Nakai criterion for overcoming the limitations which make its use in a stress point algorithm problematic. In fact, its graphical representation in the principal stress space is not convex as it comprises more branches, plotting also in negative octants, and it does not increase monotonically as the distance of the stress point from the failure surface rises. The proposed mathematical reformulation plots as a single, convex surface, which entirely lies in the positive octant of the stress space and evaluates to a quantity which monotonically increases as the stress point moves away from the failure surface. It is an exact reproduction, and not an approximated one, of the only significant branch of the original criterion. It is also suitable for shaping in the deviatoric plane the yield and plastic potential surfaces of complex constitutive models. A very efficient numerical algorithm for the implicit integration of the proposed formulation is presented, which enables the evaluation of the stress at the end of each increment by solving a single scalar equation, both for associated and non‐associated plasticity. The algorithm can be easily adapted for other smooth surfaces with linear meridian section. Finally, a close expression of the consistent Jacobian matrix is given for achieving quadratic convergence in the external structural newton loop. It is shown that all this results in extremely fast solutions of boundary value problems. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

The influence of the plastic potential on plane strain failure   总被引：1，自引：0，他引：1  

Rocco Lagioia  Andrea Panteghini 《国际地质力学数值与分析法杂志》2014,38(8):844-862

The influence of the shape of the plastic potential in the deviatoric plane on plane strain collapse is investigated. The most commonly employed elastic‐perfect plastic models are considered, which adopt well‐known failure criteria for defining the yield and plastic potential surfaces, namely the von Mises, the Drucker–Prager, the Tresca, the Mohr–Coulomb and the Matsuoka–Nakai criteria. Finally, the conclusions are also extended to strain hardening/softening models. For simple constitutive models based on perfect plasticity, it is shown that the value of the Lode's angle at plastic collapse in plane strain conditions strongly depends on the specific failure surface adopted for reproducing the plastic potential surface. If the value of the Lode's angle at yield coincides with the failure value prescribed by the plastic potential, the stress–strain curves exhibit the typical perfect plastic behaviour with yield coinciding with failure, otherwise the stress changes after yield and the stress‐strain curves resemble those of strain hardening/softening models. The infinite strength which is in some situations exhibited by the Drucker–Prager model in plane strain condition is investigated and explained, and it is shown that this can also affect strain hardening/softening models. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Gas hazard assessment at the Monticchio crater lakes of Mt. Vulture, a volcano in Southern Italy     

Antonio Caracausi  P. Mario Nuccio  Rocco Favara  Marco Nicolosi  Michele Paternoster 《地学学报》2009,21(2):83-87

Geochemical investigations have shown that there is a considerable inflow of gas into both crater lakes of Monticchio, Southern Italy. These lakes are located in two maars that formed 140 000 years ago during Mt. Vulture volcano's last eruptive activity. Isotopic analyses suggest that CO₂ and helium are of magmatic origin; the latter displays ³He/⁴He isotope ratios similar to those measured in olivines of the maar ejecta. In spite of the fact that the amount of dissolved gases in the water is less than that found in Lake Nyos (Cameroon), both the results obtained and the historical reports studied indicate that these crater lakes could be highly hazardous sites, even though they are located in a region currently considered inactive. This could be of special significance in very popular tourist areas such as the Monticchio lakes, which are visited by about 30 000 people throughout the summer, for the most part on Sundays.  相似文献   

Parentage Identification of Differentiated Achondritic Meteorites by Hand‐held Energy Dispersive X‐Ray Fluorescence Spectrometry          下载免费PDF全文

Maurizio Gemelli  Tommaso Di Rocco  Luigi Folco  Massimo D'Orazio 《Geostandards and Geoanalytical Research》2017,41(4):613-632

We evaluate the potential of a hand‐held energy dispersive XRF spectrometer for the preliminary classification of non‐chondritic differentiated meteorites. The studied achondrites include nine lunar meteorites, seventeen Martian meteorites, five angrites and eighteen meteorites from asteroid 4 Vesta. Analytical precision and accuracy was tested on thirty‐nine terrestrial igneous rock slabs with a wide range of composition. Replicate analyses, performed on the studied meteorites, show that Fe/Mn values together with Si and Ca/K ratio can be used in the discrimination of different achondrite groups. Fusion crust's Fe/Mn values of meteorites from Vesta and Mars are indistinguishable from those of the interior implying that even measurements on the fusion‐crusted external surface could be sufficient to pigeonhole non‐chondritic meteorites. Hand‐held energy dispersive XRF spectrometer is a non‐destructive but very effective technique for preliminary classification of achondrites in the field and in laboratory and for the identification of mislabelled meteorites in museum collections.  相似文献   

Carbonate assimilation in magmas: A reappraisal based on experimental petrology     

Silvio Mollo  Mario Gaeta  Carmela Freda  Tommaso Di Rocco  Valeria Misiti  Piergiorgio Scarlato 《Lithos》2010,114(3-4):503-514

The main effect of magma–carbonate interaction on magma differentiation is the formation of a silica-undersaturated, alkali-rich residual melt. Such a desilication process was explained as the progressive dissolution of CaCO₃ in melt by consumption of SiO₂ and MgO to form diopside sensu stricto. Magma chambers emplaced in carbonate substrata, however, are generally associated with magmatic skarns containing clinopyroxene with a high Ca-Tschermak activity in their paragenesis. Data are presented from magma–carbonate interaction experiments, demonstrating that carbonate assimilation is a complex process involving more components than so far assumed. Experimental results show that, during carbonate assimilation, a diopside–hedenbergite–Ca-Tschermak clinopyroxene solid solution is formed and that Ca-Tschermak/diopside and hedenbergite/diopside ratios increase as a function of the progressive carbonate assimilation. Accordingly, carbonate assimilation reaction should be written as follows, taking into account all the involved magmatic components:CaCO₃^solid + SiO₂^melt + MgO^melt + FeO^melt + Al₂O₃^melt → (Di–Hd–CaTs)_ss^solid + CO₂^fluidThe texture of experimental products demonstrates that carbonate assimilation produces three-phases (solid, melt, and fluid) whose main products are: i) diopside–hedenbergite–Ca-Tschermak clinopyroxene solid solution; ii) silica-undersaturated CaO-rich melt; and iii) C–O–H fluid phase. The silica undersaturation of the melt and, more importantly, the occurrence of a CO₂-rich fluid phase, must be taken into account as they significantly affect partition coefficients and the redox state of carbonated systems, respectively.  相似文献   

Tectonic and climatic control on the Late Messinian sedimentary evolution of the Nijar Basin (Betic Cordillera,Southern Spain)     

Silvia Omodeo Salé  Rocco Gennari  Stefano Lugli  Vinicio Manzi  Marco Roveri 《Basin Research》2012,24(3):314-337

The Late Messinian fill of the Nijar Basin (Betic Cordillera, southeastern Spain) mainly consists of clastic deposits of the Feos Formation that at basin margins rest unconformably above the primary evaporites of the Yesares Formation, the local equivalent of the Mediterranean Lower Gypsum. The Feos Fm. records the upward transition towards non‐marine environments before the abrupt return to fully marine conditions at the base of the Pliocene. The Feos Fm. is clearly two‐phase, with ‘lower’ and ‘upper’ members, which exhibit substantial differences in terms of facies, thickness, depositional trends and cyclical organization. These members record two distinct sedimentary and tectonic stages of Nijar Basin infilling. A high‐resolution, physical‐stratigraphic framework is proposed based on key beds and stratigraphic cyclicity and patterns that differ largely from those of most previously published studies. The predominant influence on stratigraphic cyclicity is interpreted to be precessionally driven climate changes, allowing their correlation to the Late Messinian astronomically calibrated chronostratigraphic framework. Detailed correlations suggest a phase of enhanced tectonic activity, possibly related to the Serrata‐Carboneras strike‐slip fault zone, during the first stage (‘lower’ member), resulting in a strongly articulated topography with structural lows and highs controlling sediment thickness and facies variation. Tectonic activity decreased during the second stage (‘upper’ member), which is characterized by (1) a progressively dampened and homogenized, (2) overall relative base‐level rise and (3) gradual establishment of hypohaline environments. Facies characteristics, overall stacking patterns and depositional trends of the Feos Fm. are analogous with uppermost Messinian successions of the Northern Apennines, Piedmont Basin and Calabria. Despite minor differences related to the local geodynamic setting, these basins experienced a common Late Messinian history that supports the development of a single, large Mediterranean water body characterized by high‐frequency, climatically‐driven changes in sediment flux and base‐level.  相似文献   

Survival of endospores of Bacillus subtilis on spacecraft surfaces under simulated martian environments: implications for the forward contamination of Mars     

Schuerger AC  Mancinelli RL  Kern RG  Rothschild LJ  McKay CP 《Icarus》2003,165(2):253-276

Experiments were conducted in a Mars simulation chamber (MSC) to characterize the survival of endospores of Bacillus subtilis under high UV irradiation and simulated martian conditions. The MSC was used to create Mars surface environments in which pressure (8.5 mb), temperature (-80, -40, -10, or +23 degrees C), gas composition (Earth-normal N2/O2 mix, pure N2, pure CO2, or a Mars gas mix), and UV-VIS-NIR fluence rates (200-1200 nm) were maintained within tight limits. The Mars gas mix was composed of CO2 (95.3%), N2 (2.7%), Ar (1.7%), O2 (0.2%), and water vapor (0.03%). Experiments were conducted to measure the effects of pressure, gas composition, and temperature alone or in combination with Mars-normal UV-VIS-NIR light environments. Endospores of B. subtilis, were deposited on aluminum coupons as monolayers in which the average density applied to coupons was 2.47 x 10(6) bacteria per sample. Populations of B. subtilis placed on aluminum coupons and subjected to an Earth-normal temperature (23 degrees C), pressure (1013 mb), and gas mix (normal N2/O2 ratio) but illuminated with a Mars-normal UV-VIS-NIR spectrum were reduced by over 99.9% after 30 sec exposure to Mars-normal UV fluence rates. However, it required at least 15 min of Mars-normal UV exposure to reduce bacterial populations on aluminum coupons to non-recoverable levels. These results were duplicated when bacteria were exposed to Mars-normal environments of temperature (-10 degrees C), pressure (8.5 mb), gas composition (pure CO2), and UV fluence rates. In other experiments, results indicated that the gas composition of the atmosphere and the temperature of the bacterial monolayers at the time of Mars UV exposure had no effects on the survival of bacterial endospores. But Mars-normal pressures (8.5 mb) were found to reduce survival by approximately 20-35% compared to Earth-normal pressures (1013 mb). The primary implications of these results are (a) that greater than 99.9% of bacterial populations on sun-exposed surfaces of spacecraft are likely to be inactivated within a few tens of seconds to a few minutes on the surface of Mars, and (b) that within a single Mars day under clear-sky conditions bacterial populations on sun-exposed surfaces of spacecraft will be sterilized. Furthermore, these results suggest that the high UV fluence rates on the martian surface can be an important resource in minimizing the forward contamination of Mars.  相似文献   

Moisture source in the Hyblean Mountains region (south-eastern Sicily, Italy): Evidence from stable isotopes signature     

Fausto Grassa  Rocco Favara  Mariano Valenza 《Applied Geochemistry》2006,21(12):2082-2095

Here the authors present results of an isotope study on precipitation collected during a 2-a period from a rain-gauge network consisting of 6 stations located at different elevations in the Hyblean Mountains (HM) region, in south-eastern Sicily. The slope of the local meteoric water line (δD = 6.50 δ¹⁸O + 9.87) obtained for the region suggests that precipitation is affected by evaporation during rainfall events. The main variations in rainwater isotope composition are due to seasonal effects and elevation. An average ²H excess value of +21.2‰ was found for precipitation events less affected by evaporation (i.e. when the rainfall was >65 mm/month). The spatial distribution of O isotope composition of precipitation shows a negative gradient from east and south to the inner areas. The depositional rate of Cl, used as a tracer of the origin of air masses, is highest at the coastal rain-gauges (SR and MRG stations) and lowest on the northern flank of the HM region (SC station). Based on these findings, a model is proposed for the origin of precipitation in the HM region, which assumes that a Mediterranean-derived component is the main source of moisture in the studied area. D/H and ¹⁸O/¹⁶O ratios of inferred meteoric recharge waters were also compared with the isotope composition of waters collected from the main local springs and wells. The best linear fit of the δ¹⁸O vs δD relationship for Hyblean groundwater is δD = 4.85 δ¹⁸O–2.01. The enrichment of heavy isotopes in Hyblean groundwater is probably due to evaporation occurring after precipitation events or to a recharging contribution from surface waters (lakes or rivers) enriched in heavy isotopes.  相似文献