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381.
The conditions for energy flux, momentum flux and the resulting streaming velocity are analysed for standing waves formed in front of a fully reflecting wall. The exchange of energy between the outer wave motion and the near bed oscillatory boundary layer is considered, determining the horizontal energy flux inside and outside the boundary layer. The momentum balance, the mean shear stress and the resulting time averaged streaming velocities are determined. For a laminar bed boundary layer the analysis of the wave drift gives results similar to the original work of Longuet–Higgins from 1953. The work is extended to turbulent bed boundary layers by application of a numerical model. The similarities and differences between laminar and turbulent flow conditions are discussed, and quantitative results for the magnitude of the mean shear stress and drift velocity are presented. Full two-dimensional simulations of standing waves have also been made by application of a general purpose Navier–Stokes solver. The results agree well with those obtained by the boundary layer analysis. Wave reflection from a plane sloping wall is also investigated by using the same numerical model and by physical laboratory experiments. The phase shift of the reflected wave train is compared with theoretical and empirical models.  相似文献   
382.
383.
Columbite-tantalite LA-ICP-MS U-Pb dating is a fast and useful method to determine the age of rare-metal deposits and fingerprint the provenance of columbite-tantalite ore concentrates. Accurate LA-ICP-MS U-Pb dating requires matrix-matched reference materials. We analysed three columbite-tantalite samples (SN3, HND and RL2) from China using ID-TIMS and LA-ICP-MS to assess their potential as reference materials for in situ U-Pb dating. Coltan 139 and these three columbite-tantalite samples with variable compositions yielded internally consistent LA-ICP-MS U-Pb ages when using each other for calibration and the weighted mean 206Pb/238U ages are comparable to respective ID-TIMS ages. Composition-dependent U-Pb fractionation seems to be insignificant under the LA-ICP-MS conditions used. Sample SN3 has a low percentage of heterogeneity for 206Pb/238U ages (4%) with low common Pb contributions (f206 < 1%) and shows a good potential in calibrating unknown samples as primary reference material for LA-ICP-MS analysis. Samples RL2 and HND have altered sections characterised by high LREE contents, flat LREE patterns and old 206Pb/238U apparent ages, and are not suited as reference materials. The low 207Pb/206Pb intercepts for samples RL2 and HND lack geological meaning but provide strong evidence that the disturbed U-Pb systematics with anomalous apparent 206Pb/238U ages is a secondary feature.  相似文献   
384.
This paper is aimed at investigating whether there is ample support for the view that the acceptance criterion for evaluating measures for prevention of oil spills from tankers should be based on cost-effectiveness considerations. One such criterion can be reflected by the Cost of Averting a Tonne of oil Spilt (CATS) whereas its target value is updated by elaborating the inherent uncertainties of oil spill costs and establishing a value for the criterion’s assurance factor. To this end, a value of $80,000/t is proposed as a sensible CATS criterion and the proposed value for the assurance factor F = 1.5 is supported by the retrieved Protection and Indemnity (P&I) Clubs’ Annual Reports. It is envisaged that this criterion would allow the conversion of direct and indirect costs into a non-market value for the optimal allocation of resources between the various parties investing in shipping. A review of previous cost estimation models on oil spills is presented and a probability distribution (log-normal) is fitted on the available oil spill cost data, where it should be made abundantly clear that the mean value of the distribution is used for deriving the updated CATS criterion value. However, the difference between the initial and the updated CATS criterion in the percentiles of the distribution is small. It is found through the current analysis that results are partly lower than the predicted values from the published estimation models. The costs are also found to depend on the type of accident, which is in agreement with the results of previous studies. Other proposals on acceptance criteria are reviewed and it is asserted that the CATS criterion can be considered as the best candidate. Evidence is provided that the CATS approach is practical and meaningful by including examples of successful applications in actual risk assessments. Finally, it is suggested that the criterion may be refined subject to more readily available cost data and experience gained from future decisions.  相似文献   
385.
Dolomite Controls on Phanerozoic Seawater Chemistry   总被引:1,自引:0,他引:1  
We investigate the potential role of dolomite as a long-term buffer on Phanerozoic seawater composition. Using a comprehensive model of Phanerozoic geochemical cycling, we show how variations in the formation rate of sedimentary marine dolomite have buffered seawater saturation state. The total inventory of inorganic carbon reflects the sum of fluxes derived from continental weathering, basalt-seawater exchange, alumino-silicate diagenesis (reverse weathering), and global deposition of calcium carbonate. Although these fluxes are approximately balanced, model results indicate that seawater saturation state is sensitive to the marine dolomite depositional flux. This conclusion is consistent with and constrained by independent proxy data for seawater ion ratios, paleo-atmospheric CO2 concentrations, and paleo-pH data, and dolomite mass-age distribution through Phanerozoic time. Abundant research indicates that dolomite’s occurrence in marine sediments is sensitive to many factors: temperature, seawater composition, paleogeographic setting, continental organization, etc. Although the complexity of the process of dolomite formation prevents a complete understanding of the relative role of these factors, our model results clearly underscore the importance of this mineral in the chemical history of Phanerozoic seawater.  相似文献   
386.
Various finite element families for the Brinkman flow (or Stokes–Darcy flow) are tested numerically. Particularly, the effect of small permeability is studied. The tested finite elements are the MINI element, the Taylor–Hood element, and the stabilized equal order methods. The numerical tests include both a priori analysis and adaptive methods.  相似文献   
387.
The northeastern high-latitude North Atlantic is characterised by the Bellsund and Isfjorden fans on the continental slope off west Svalbard, the asymmetrical ultraslow Knipovich spreading ridge and a 1,000 m deep rift valley. Recently collected multichannel seismic profiles and bathymetric records now provide a more complete picture of sedimentary processes and depositional environments within this region. Both downslope and alongslope sedimentary processes are identified in the study area. Turbidity currents and deposition of glacigenic debris flows are the dominating downslope processes, whereas mass failures, which are a common process on glaciated margins, appear to have been less significant. The slide debrite observed on the Bellsund Fan is most likely related to a 2.5–1.7 Ma old failure on the northwestern Barents Sea margin. The seismic records further reveal that alongslope current processes played a major role in shaping the sediment packages in the study area. Within the Knipovich rift valley and at the western rift flank accumulations as thick as 950–1,000 m are deposited. We note that oceanic basement is locally exposed within the rift valley, and that seismostratigraphic relationships indicate that fault activity along the eastern rift flank lasted until at least as recently as 1.5 Ma. A purely hemipelagic origin of the sediments in the rift valley and on the western rift flank is unlikely. We suggest that these sediments, partly, have been sourced from the western Svalbard—northwestern Barents Sea margin and into the Knipovich Ridge rift valley before continuous spreading and tectonic activity caused the sediments to be transported out of the valley and westward.  相似文献   
388.
Chemical and Sr, Nd and Pb isotopic compositions of Late Cenozoic to Quaternary small-volume phonolite, trachyte and related mafic rocks from the Darfur volcanic province/NW-Sudan have been investigated. Isotope signatures indicate variable but minor crustal contributions. Some phonolitic and trachytic rocks show the same isotopic composition as their primitive mantle-derived parents, and no crustal contributions are visible in the trace element patterns of these samples. The magmatic evolution of the evolved rocks is dominated by crystal fractionation. The Si-undersaturated strongly alkaline phonolite and the Si-saturated mildly alkaline trachyte can be modelled by fractionation of basanite and basalt, respectively. The suite of basanite–basalt–phonolite–trachyte with characteristic isotope signatures from the Darfur volcanic province fits the compositional features of other Cenozoic intra-plate magmatism scattered in North and Central Africa (e.g., Tibesti, Maghreb, Cameroon line), which evolved on a lithosphere that was reworked or formed during the Neoproterozoic.  相似文献   
389.
Besides the enormous improvement of air quality in Germany due to the reduction of sulphur dioxide emissions in the last decades, high immissions of nitrogen oxides and fine particulate matter are frequently observed at traffic-rich urban sites. The changed chemical composition of air pollution requires a new investigation of its impact on historic buildings constructed of natural stone. In a pilot study a multi-disciplinary approach was chosen to obtain information on the actual pollution situation of historic buildings and monuments at traffic hotspots in Germany. The study concentrated on the two German cities of Munich and Mainz of different size, traffic volume and stone inventory. Dose–response functions were calculated to demonstrate the change of impact of different pollutants over the last three decades, and for comparison of traffic hotspots and housing areas of both cities. Numeric modelling on a city-scale was used to identify the historic buildings and monuments affected by elevated traffic immissions. Because a relevant part of these pollutants is dominated by short-range transport, the differences of wind speed and deposition rates were calculated using a street-scale 3D flow and dispersion model regarding traffic volume, wind regime and adjacent buildings. Finally, particulate matter was sampled at different positions of two buildings heavily exposed to traffic emissions. Individual particles were investigated by environmental scanning electron microscopy. After classification of the particles into different chemical groups, the fraction of traffic-induced particulate matter was quantified. Summarizing the results, it must be stated that soiling by traffic-related particulate matter, deposition of nitrates deriving from exhaust emission and other diffusely emitted components bear a severe damage potential for natural building stone at least locally at traffic-rich urban sites.  相似文献   
390.
Abstract

The magnitudes of the largest known floods of the River Rhine in Basel since 1268 were assessed using a hydraulic model drawing on a set of pre-instrumental evidence and daily hydrological measurements from 1808. The pre-instrumental evidence, consisting of flood marks and documentary data describing extreme events with the customary reference to specific landmarks, was “calibrated” by comparing it with the instrumental series for the overlapping period between the two categories of evidence (1808–1900). Summer (JJA) floods were particularly frequent in the century between 1651–1750, when precipitation was also high. Severe winter (DJF) floods have not occurred since the late 19th century despite a significant increase in winter precipitation. Six catastrophic events involving a runoff greater than 6000 m 3 s‐1 are documented prior to 1700. They were initiated by spells of torrential rainfall of up to 72 h (1480 event) and preceded by long periods of substantial precipitation that saturated the soils, and/or by abundant snowmelt. All except two (1999 and 2007) of the 43 identified severe events (SEs: defined as having runoff > 5000 and < 6000 m 3 s ‐1) occurred prior to 1877. Not a single SE is documented from 1877 to 1998. The intermediate 121-year-long “flood disaster gap” is unique over the period since 1268. The effect of river regulations (1714 for the River Kander; 1877 for the River Aare) and the building of reservoirs in the 20th century upon peak runoff were investigated using a one-dimensional hydraulic flood-routing model. Results show that anthropogenic effects only partially account for the “flood disaster gap” suggesting that variations in climate should also be taken into account in explaining these features.

Citation Wetter, O., Pfister, C., Weingartner, R., Luterbacher, J., Reist, T., & Trösch, J. (2011) The largest floods in the High Rhine basin since 1268 assessed from documentary and instrumental evidence. Hydrol. Sci. J. 56(5), 733–758.  相似文献   
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