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11.
Kirsten Moeller Ronny Schoenberg Rolf‐Birger Pedersen Dominik Weiss Shuofei Dong 《Geostandards and Geoanalytical Research》2012,36(2):177-199
The commonly used, but no longer available, reference materials NIST SRM 976 (Cu) and ‘JMC Lyon’ (Zn) were calibrated against the new reference materials ERM®‐AE633, ERM®‐AE647 (Cu) and IRMM‐3702 (Zn), certified for isotope amount ratios. This cross‐calibration of new with old reference materials provides a continuous and reliable comparability of already published with future Cu and Zn isotope data. The Cu isotope amount ratio of NIST SRM 976 yielded δ65/63Cu values of ?0.01 ± 0.05‰ and ?0.21 ± 0.05‰ relative to ERM®‐AE633 and ERM®‐AE647, respectively, and a δ66/64ZnIRMM‐3702 value of ?0.29 ± 0.05‰ was determined for ‘JMC Lyon’. Furthermore, we separated Cu and Zn from five geological reference materials (BCR‐2, BHVO‐2, BIR‐1, AGV‐1 and G‐2) using a two‐step ion‐exchange chromatographic procedure. Possible isotope fractionation of Cu during chromatographic purification and introduction of resin‐ and/or matrix‐induced interferences were assessed by enriched 65Cu isotope addition. Instrumental mass bias correction for the isotope ratio determinations by MC‐ICP‐MS was performed using calibrator‐sample bracketing with internal Ni doping for Cu and a double spike approach for Zn. Our results for the five geological reference materials were in very good agreement with literature data, confirming the accuracy and applicability of our analytical protocol. 相似文献
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Insolubilized humic acid (IHA) was prepared in the laboratory by heating approach. Through the comparison between the endothermic
peaks, optimal heating temperature was determined to be 330°C. The modified IHA then was characterized by TG-DTA, SEM, FTIR,
element analysis, and nitrogen adsorption–desorption isotherms. The removal efficiency of p-nitrophenol from the aqueous solution by adsorption onto solid IHA surfaces was shown to be a function of pH, reaction temperature,
and p-nitrophenol concentration. Adsorption equilibrium data satisfactorily fitted the Langmuir adsorption isotherm. Under a certain
concentration range, the removal rate of p-nitrophenol at pH 3.5 could reach 24, 29, and 35 mg/g at a temperature of 25, 35, and 45±0.1°C. The results suggest that
IHA could play a role as a potential efficient absorbent to remove organic contaminants, e.g., utilized to purify water contaminated
by organic compounds. 相似文献
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Ronny Schoenberg Michael A.W. Marks Jan A. Schuessler Friedhelm von Blanckenburg Gregor Markl 《Chemical Geology》2009,258(1-2):65-77
The Ilímaussaq intrusion, South Greenland, provides an exceptional test case for investigating the changes of stable Fe isotope fractionation of solidus phases with changes in the Fe3+/∑Fe ratio of an evolving melt. The intrusion comprises a sequence of four melt batches that were fed from the same parental alkali basaltic magma. Differentiation produced cumulate rocks that range from augite syenite (phase I) over peralkaline granite (phase II) to agpaitic syenites (phases IIIa and IIIb). Fe3+/∑Fe ratios in amphiboles increase substantially from phase I to phase II and III rocks and mark a major change in the parental magma composition from augite syenites to peralkaline granites and agpaitic syenites. Before this transition, olivine, clinopyroxene, and amphibole in augite syenite, the most primitive rock type in the Ilímaussaq Complex, have a uniform Fe isotope composition that is identical to that of the bulk of igneous crustal rocks and approximated by the average isotopic composition of basalts (δ56/54FeIRMM-014 = 0.072 ± 0.046‰). After the transition, amphiboles in the peralkaline granites and agpaitic syenites yield significantly heavier Fe isotope compositions with δ56/54FeIRMM-014 values ranging from 0.123 to 0.237‰. Contamination of the Ilímaussaq magma by ongoing crustal assimilation as cause for this increase can be excluded on the grounds of Nd isotope data. Large-scale metasomatic overprint with an external fluid can also be dismissed based on amphibole O and Li isotope systematics. Rather, the increase towards heavy Fe isotope compositions most likely reflects the change in chemical compositions of amphiboles (calcic in augite syenite to sodic in the agpaitic syenites) and their Fe3+/ΣFe ratios that mirror changes in the chemical composition of the melt and its oxygen fugacity. A sensitive adjustment of equilibrium Fe isotope fractionation factors to amphibole ferric/ferrous ratios is also supported by beta-factors calculated from Mössbauer spetroscopy data. Comparison of the measured isotope fractionation between clinopyroxene and amphibole with that predicted from Mössbauer data reveal Fe isotope systematics close to equilibrium in augite syenites but Fe isotopic disequilibrium between these two phases in phase IIIa agpaitic syenites. These results are in agreement with O and Li isotope systematics. While amphiboles in all Ilímaussaq lithologies crystallized at temperatures between 650 and 850 °C, textural evidence reveals later clinopyroxene crystallization at temperatures as low as 300–400 °C. Therefore, isotopic equilibrium at crystallization conditions between these two phases can not be expected, but importantly, subsolidus reequilibration can also be dismissed. 相似文献
14.
Effects of temperature on scope for growth and accumulation of Cd, Co, Cu and Pb by the marine bivalve Mytilus edulis 总被引：7，自引：0，他引：7
In many aquatic organisms including Mytilus edulis, the role of temperature on bioaccumulation of metals is still not clearly understood. In this study, uptake and accumulation of Cu, Co, Cd and Pb in mussels were investigated at different temperatures (6-26 degrees C). Results from exposure of isolated gills showed a positive relationship between temperature and metal uptake. But in whole organism experiments, only the accumulations of non-essential metals (Cd, Pb) showed a similar trend while the two essential metals Co and Cu were independent and inversely related to temperature, respectively. With exception of Cu, elimination process appeared to be independent of temperature. The study also showed that neither changes in scope for growth (SFG) of mussels nor chemical speciation could fully account for the observed temperature-effects. Overall, these results suggest that fundamentally (i.e. at epithelial membranes), temperature-effects on uptake are largely due to changes in solution chemistry and physical kinetics, which favours higher uptake at high temperature. But at whole organism level, complex physiological responses appears to mask the relationship, particularly for biologically essential metals like copper. 相似文献
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Schubert H Feuerpfeil P Marquardt R Telesh I Skarlato S 《Marine pollution bulletin》2011,62(9):1948-1956
Remane’s species-minimum concept, which states that the lowest number of taxa occurs at the horohalinicum (5-8 psu), was tested by investigating macroalgal diversity on hard substrates along the natural salinity gradient in the Baltic Sea. Field data on species occurrence and abundance were collected by SCUBA diving along 10 transects of the Finnish, Swedish and German coasts, covering a salinity range from 3.9 to 27 psu. Macroalgal species numbers declined steadily with salinity, decreasing until 7.2 psu was reached, but in the horohalinicum, a marked reduction of species number and a change in diversity were indicated by the Shannon index and evenness values. The non-linear decrease in macroalgal diversity at 5-8 psu and the lack of increase in species numbers at salinities below 5 psu imply a restricted applicability of Remane’s species-minimum concept to macroalgae. 相似文献
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Feifei Yuan Hiroshi Yasuda Ronny Berndtsson Cintia Bertacchi Uvo Linus Zhang Zhenchun Hao 《水文科学杂志》2013,58(8):1383-1394
ABSTRACTThe summer precipitation (June–September) in the source region of the Yellow River accounts for about 70% of the annual total, playing an important role in water availability. This study divided the source region of the Yellow River into homogeneous zones based on precipitation variability using cluster analysis. Summer precipitation trends and teleconnections with global sea-surface temperatures (SST) and the Southern Oscillation Index (SOI) from 1961 to 2010 were investigated by Mann-Kendall test and Pearson product-moment correlation analysis. The results show that the northwest part (Zone 1) had a non-significantly increasing trend, and the middle and southeast parts (zones 2 and 3) that receive the most precipitation displayed a statistically significant decreasing trend for summer precipitation. The summer precipitation in the whole region showed statistically significant negative correlations with the central Pacific SST for 0–4 month lag and with the Southern Indian and Atlantic oceans SST for 5–8 month lag. Analyses of sub-regions reveal intricate and complex correlations with different SST areas that further explain the summer precipitation variability. The SOI had significant positive correlations, mainly for 0–2 months lag, with summer precipitation in the source region of the Yellow River. It is seen that El Niño Southern Oscillation (ENSO) events have an influence on summer precipitation, and the predominant negative correlations indicate that higher SST in equatorial Pacific areas corresponding to El Niño coincides with less summer precipitation in the source region of the Yellow River.
Editor Z.W. Kundzewicz; Associate editor D. Gerten 相似文献
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Sonja Schuh Roberto Silvotti Ronny Lutz Björn Loeptien Elizabeth M. Green Roy H. Østensen Silvio Leccia Seung-Lee Kim Gilles Fontaine Stéphane Charpinet Myriam Francœur Suzanna Randall Cristina Rodríguez-López Valerie van Grootel Andrew P. Odell Margit Paparó Zsófia Bognár Péter Pápics Thorsten Nagel Benjamin Beeck Markus Hundertmark Thorsten Stahn Stefan Dreizler Frederic V. Hessman Massimo Dall’Ora Dario Mancini Fausto Cortecchia Serena Benatti Riccardo Claudi Rimvydas Janulis 《Astrophysics and Space Science》2010,329(1-2):231-242
In 2007, a companion with planetary mass was found around the pulsating subdwarf B star V391 Pegasi with the timing method, indicating that a previously undiscovered population of substellar companions to apparently single subdwarf B stars might exist. Following this serendipitous discovery, the EXOTIME (http://www.na.astro.it/~silvotti/exotime/) monitoring program has been set up to follow the pulsations of a number of selected rapidly pulsating subdwarf B stars on time scales of several years with two immediate observational goals:
- determine $\dot{P}$ of the pulsational periods P
- search for signatures of substellar companions in O–C residuals due to periodic light travel time variations, which would be tracking the central star’s companion-induced wobble around the centre of mass