Major and trace element geochemistry in Zeekoevlei, South Africa: A lacustrine record of present and past processes   总被引：2，自引：0，他引：2  

Supriyo Kumar Das  Joyanto Routh  Alakendra N. Roychoudhury  J. Val Klump 《Applied Geochemistry》2008,23(8):2496-2511

This study reports a multi-parameter geochemical investigation in water and sediments of a shallow hyper-eutrophic urban freshwater coastal lake, Zeekoevlei, in South Africa. Zeekoevlei receives a greater fraction of dissolved major and trace elements from natural sources (e.g., chemical weathering and sea salt). Fertilizers, agricultural wastes, raw sewage effluents and road runoff in contrast, constitute the predominant anthropogenic sources, which supply As, Cd, Cu, Pb and Zn in this lake. The overall low dissolved metal load results from negligible industrial pollution, high pH and elevated metal uptake by phytoplankton. However, the surface sediments are highly polluted with Pb, Cd and Zn. Wind-induced sediment resuspension results in increased particulate and dissolved element concentrations in bottom waters. Low C/N ratio (10) indicates primarily an algal source for the sedimentary organic matter. Variation in sedimentary organic C content with depth indicates a change in primary productivity in response to historical events (e.g., seepage from wastewater treatment plant, dredging and urbanization). Primary productivity controls the enrichment of most of the metals in sediments, and elevated productivity with higher accumulation of planktonic debris (and siltation) results in increased element concentration in surface and deeper sediments. Aluminium, Fe and/or Mn oxy-hydroxides, clay minerals and calcareous sediments also play an important role in adsorbing metals in Zeekoevlei sediments.  相似文献   

Bulk organic matter characteristics in the Pichavaram mangrove – estuarine complex,south-eastern India     

Rajesh Kumar Ranjan  Joyanto Routh  A.L. Ramanathan 《Applied Geochemistry》2010

The Pichavaram mangrove ecosystem is located between the Vellar and Coleroon Estuaries in south-eastern India. To document the spatial-depth-based variabilities in organic matter (OM) input and cycling, five sediment cores were collected. A comparative study was carried out of grain-size composition, pore water salinity, dissolved organic C (DOC), loss-on-ignition (LOI), elemental ratios (C/N and H/C), pigments (Chl a, Chl b, and total carotenoids), and humification indices. Sand is the major fraction in these cores ranging from 60% to 99% followed by silt and clay; cores from the estuarine margin have high sand content. In mangrove forests, pore-water DOC concentrations are high (32 ± 14 mg L⁻¹), whereas salinity levels are low (50 ± 5.5‰). Likewise, LOI, organic C and N, and pigment concentrations are high in mangroves. OM is mainly derived from upstream terrestrial matter and/or mangrove litter, and marine OM. The humification indices do not vary significantly with depth because of rapid OM turnover. The bulk parameters indicate that the Vellar and Coleroon Estuaries are more affected by anthropogenic processes than mangrove forests. Finally, greater variability and sometimes lack of specific trends in bulk parameters implies that the 2004 tsunami caused extensive mixing in sediments.  相似文献   

Biomarker evidence of macrophyte and plankton community changes in Zeekoevlei,a shallow lake in South Africa   总被引：1，自引：0，他引：1  

Supriyo Kumar Das  Joyanto Routh  Alakendra N. Roychoudhury 《Journal of Paleolimnology》2009,41(3):507-521

Zeekoevlei is the largest freshwater lake in South Africa and has a century-long history of anthropogenic impact that caused hyper-eutrophic conditions. We used biomarkers (alkanes and pigments), stable isotopes (δ¹³C and δ¹⁵N), rates of primary palaeoproduction and total inorganic carbon (TIC) accumulation rates in the lake sediments to investigate changes in plankton and macrophyte communities in response to anthropogenic activities in this shallow lake. Specific alkanes (ΣC_15,17,19, pristane, phytane and n-C₂₉/n-C₁₇ ratio) and pigment (chlorophyll a, β,β-carotene, echinenone, fucoxanthin and zeaxanthin) concentrations in lake waters indicated the present-day hyper-eutrophic condition and seasonal fluctuations of cyanobacteria, zooplankton and diatom populations. Eutrophic conditions were initiated in the lake with the start of recreational activities and construction of a sewage treatment plant in the early 1920s. The lake transformed from a eutrophic to a hyper-eutrophic waterbody following damming, pondweed eradication and accelerated catchment-derived nutrient input. The change in lake trophic state was recorded by a sharp decline in the terrestrial to aquatic ratio (TAR) of specific n-alkanes, low carbon preference index (CPI) and increased δ¹³C values in the sediment core. In addition, the aquatic macrophyte n-alkane proxy (P_aq) values (~1) indicated a slow takeover by floating macrophytes after the eradication of submerged pondweeds in 1951. Elevated n-alkane (ΣC_15,17,19), total alkane and pigment (chlorophyll a, β,β-carotene, zeaxanthin and zeaxanthin to β,β-carotene ratio) concentrations, low δ¹⁵N values and low TIC accumulation rates in the upper middle section of the core indicated the beginning of intense cyanobacterial blooms after the dredging in 1983. Although the cyanobacterial population has decreased in recent years, hyper-eutrophic conditions are reflected by low CPI <0.04 and TAR <1 values at the top of the sediment core.  相似文献   

Coupling Between Seismic Activity and Hydrogeochemistry at the Shillong Plateau, Northeastern India     

Alasdair Skelton  Lillemor Claesson  Govinda Chakrapani  Chandan Mahanta  Joyanto Routh  Magnus Mörth  Param Khanna 《Pure and Applied Geophysics》2008,165(1):45-61

Transient hydrogeochemical anomalies were detected in a granite-hosted aquifer, which is located at a depth of 110 m, north of the Shillong Plateau, Assam, India, where groundwater chemistry is mainly buffered by feldspar alteration to kaolinite. Their onsets preceded moderate earthquakes on December 9, 2004 (M_W = 5.3) and February 15, 2005 (M_W = 5.0), respectively, 206 and 213 km from the aquifer. The ratios [Na+K]/Si, Na/K and [Na+K]/Ca, conductivity, alkalinity and chloride concentration began increasing 3–5 weeks before the M_W = 5.3 earthquake. By comparison with field, experimental and theoretical studies, we interpret a transient switchover between source aquifers, which induced an influx of groundwater from a second aquifer, where groundwater chemistry was dominantly buffered by the alteration of feldspar to smectite. This could have occurred in response to fracturing of a hydrological barrier. The ratio Ba/Sr began decreasing 3–6 days before the M_W = 5.0 earthquake. We interpret a transient switchover to anorthite dissolution caused by exposure of fresh plagioclase to groundwater interaction. This could have been induced by microfracturing, locally within the main aquifer. By comparison with experimental studies of feldspar dissolution, we interpret that hydrogeochemical recovery was facilitated by groundwater interaction and clay mineralization, which could have been coupled with fracture sealing. The coincidence in timing of these two hydrogeochemical events with the only two M_W ≥ 5 earthquakes in the study area argues in favor of cause-and-effect seismic-hydrogeochemical coupling. However, reasons for ambiguity include the lack of similar hydrogeochemical anomalies coupled with smaller seismic events near the monitoring station, the >200 km length scale of inferred seismic-hydrogeochemical coupling, and the potential for far-field effects related to the Great Sumatra–Andaman Islands Earthquake of December 26, 2004.  相似文献   

Propagation of acoustic waves in the non‐isothermal solar atmosphere     

S. Routh  Z. E. Musielak 《Astronomische Nachrichten》2014,335(10):1043-1048

The acoustic cutoff frequency was originally introduced by Lamb in the study of the propagation of acoustic waves in a stratified, isothermal medium. In this paper, we use a new method to generalize Lamb's result for a stratified, non‐isothermal medium and obtain the local acoustic cutoff frequency, which describes the propagation of acoustic waves in such a medium. The main result is that the cutoff frequency is a local quantity and that its value at a given atmospheric height determines the frequency acoustic waves must have in order to propagate at this height. Application of this result to specific physical problems like the solar atmosphere is discussed. (© 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献