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81.
Since 1990s, various booster biocides have been increasingly used as substitutes of organotins. However, knowledge about their toxicities on tropical/sub-tropical marine species is significantly lacking. This study comprehensively investigated the acute toxicities of copper, tributyltin (TBT), and five commonly used booster biocides including Irgarol, diuron, zinc pyrithione (ZnPT), copper pyrithione (CuPT) and chlorothalonil on the growth or survival of 12 marine species in which eight of them are native species of subtropical Hong Kong. We found that Irgarol was more toxic than TBT on the growth of autotrophic species. The toxicity of CuPT was comparable to that of TBT on almost all test species, while it showed higher toxicity than TBT on medaka fish larvae. As the usage of these biocides is expected to further increase worldwide, accurate assessments of their ecological risks are required for better informed decision on their management. This study provided useful datasets for such purposes.  相似文献   
82.
Using the dogwhelk Nucella lapillus as a biomonitor, we evaluated the organotin contamination along the Icelandic coast over nearly two decades. In 2008, adult dogwhelks collected from 30 locations were examined for imposex status. In 2009, tissue concentrations of six organotin species in dogwhelks from 16 of the 30 locations were analysed using gas chromatography-mass spectrometry. Tributyltin was the most predominant residue ranging from 2.07 to 70.38 μg kg(-1) dw, while triphenyltin was also detected at concentrations up to 22.79 μg kg(-1) dw. Higher total organotin concentrations and imposex indices were observed at locations near large harbours (Reykjavík and Hafnarfj?reur). By comparing the current imposex results with those of previous surveys (1992-2003), we found that recovery was slow near the large harbours, but more apparent near the smaller harbours. We also observed a notable increase in imposex at several northwest sites implying incessant input of organotins.  相似文献   
83.
While much work has been done in investigating determinants of oil spillage attributed to vessel accidents, little research has been conducted on the effectiveness of ship hull design in reducing marine pollution. This paper addresses whether the double-hull requirement reduces vessel-accident oil spillage. The volume of oil spillage due to oil-cargo vessel accidents was investigated using tobit regressions and an empirical data set of individual vessel accident pollution incidents investigated by the US Coast Guard from 2001 to 2008. The results indicate that the double hull design on average reduces the size of oil spills by 20% and 62% in tank barge and tanker ship accidents, respectively.  相似文献   
84.
In this paper, we apply finite-mixture-model-based clustering algorithms to cluster post-landfall tracks of tropical cyclones (TCs) making landfall over China. Because existing studies find that landfall surfaces or elevations affect post-landfall TC movements, we also take account of elevations in addition to time orders in this model. Our study reveals three clusters, with cluster 1 making landfall in Hainan province and moving across the western coast of Guangdong province. Most of the TC tracks in cluster 1 move over the ocean and make secondary landfalls over Yunnan province of China and Vietnam. Cluster 1 finally dissipates inland and moves westward as a result of the westward-shift subtropical high, westward steering flow, easterly vertical wind shear and strong mountainous blocking. Cluster 2 makes landfall over Guangdong and Fujian provinces. TCs in cluster 2 subsequently move inland and disappear due largely to westward-shift subtropical high, easterly steering flow, easterly vertical wind shear and relatively strong mountainous blocking. Cluster 3 makes landfall along the Fujian and Zhejiang coast and sustains a long period of time, recurving mostly to the mid-latitude region owing to the surrounding eastward-shift subtropical high, westerly vertical wind shear, weak mountainous blocking and westerly steering flow. Because cluster 2 is significantly associated with La Niña events, TCs more likely make landfall over southeastern China coast and move westward or northwestward without recurving. Cluster 3 sustains a longer time than clusters 1 and 2 in spite of its weak horizontal and vertical water vapor supply. TCs in cluster 3 interact actively with westerlies during the post-landfall period. However, we cannot observe any analogous interactions with the mid-latitude westerlies in clusters 1 and 2. TCs of clusters 1 and 2 are influenced by summer monsoon flows. Moreover, summer monsoon exerts a greater influence on cluster 1 than cluster 2. The composite 200 hPa divergence of cluster 3 is stronger than that of clusters 1 and 2. This explains to some degree why cluster 3 sustains longer than clusters 1 and 2 after making landfall.  相似文献   
85.
In this paper, we use a neural network to carry out angle-of-arrival (AOA) estimation in a multipath oceanic environment. In particular, the AOA problem is considered as a mapping from the space of AOA to the space of the sensor output. A neural network is used to determine the inverse mapping from the sensor output space to the space of AOA and this inversion is realized using a radial basis function (RBF) network. We will present the development of the RBF approach for AOA estimation. Simulations are carried out to understand the efficiency and performance of this method. Furthermore, real data are used to evaluate the RBF approach and the results demonstrate the robustness and effectiveness of this neural network method  相似文献   
86.
Turbulence is defined as an eddy-like state of fluid motion where the inertial-vortex forces of the eddies are larger than any of the other forces that tend to damp the eddies out. Energy cascades of irrotational flows from large scales to small are non-turbulent, even if they supply energy to turbulence. Turbulent flows are rotational and cascade from small scales to large, with feedback. Viscous forces limit the smallest turbulent eddy size to the Kolmogorov scale. In stratified fluids, buoyancy forces limit large vertical overturns to the Ozmidov scale and convert the largest turbulent eddies into a unique class of saturated, non-propagating, internal waves, termed fossil-vorticity-turbulence. These waves have the same energy but different properties and spectral forms than the original turbulence patch. The Gibson (1980, 1986) theory of fossil turbulence applies universal similarity theories of turbulence and turbulent mixing to the vertical evolution of an isolated patch of turbulence in a stratified fluid as its growth is constrained and fossilized by buoyancy forces. Quantitative hydrodynamic-phase-diagrams (HPDs) from the theory are used to classify microstructure patches according to their hydrodynamic states. When analyzed in HPD space, previously published oceanic datasets showed their dominant microstructure patches are fossilized at large scales in all layers. Laboratory and field measurements suggested phytoplankton species with different swimming abilities adjust their growth strategies by pattern recognition of tur-bulence-fossil-turbulence dissipation and persistence times that predict survival-relevant surface layer sea changes. New data collected near a Honolulu waste-water outfall showed the small-to-large evolution of oceanic turbulence microstructure from active to fossil states, and revealed the ability of fossil-density-turbulence patches to absorb, and vertically radiate, internal wave energy, information, and enhanced turbulent-mixing-rates toward the sea surface so that the submerged waste-field could be detected from a space satellite (Bondur and Filatov, 2003).  相似文献   
87.
Numerous field monitoring programs have been conducted to investigate the performance of an unsaturated soil slope subjected to rainfalls in wet seasons. Most case histories focus on the response of matric suction, which is one of the two stress-state variables governing unsaturated soil behaviour. However, effects due to another variable, net normal stress, are often ignored. Also, slope performance under alternative wet and dry seasons is rarely reported and analysed. In this study, a saprolitic hillslope situated in Hong Kong was instrumented heavily to investigate its seasonal movement due to changes of the two variables and also groundwater flow mechanism. Two-year seasonal variations of matric suction and net normal stress were monitored by tensiometers together with heat dissipation matric water potential sensors and earth pressure cells, respectively. During heavy rainstorms in wet season, there was a substantial recharge of the main groundwater table, causing a significant increase of positive pore-water pressure in deeper depths. Rupture surface likely developed at depths between 5.5 and 6 m, hence resulting in a “deep-seated” mode of downslope movement. The downslope movement resulted in a peak increase of horizontal stress. In dry seasons, matric suction of up to 190 kPa was recorded, and the associated soil shrinkage led to substantial upslope rebounds. The stress built up in wet seasons hence reduced. After monitoring period of 2 years, downslope ratcheting is identified. Up to 40 % of the downslope displacements were recovered by the upslope rebounds.  相似文献   
88.
Radon and its progenies have been ranked second of being responsible for lung cancer in humans. Hong Kong has four major groups of uranium-rich plutonic and volcanic rocks and is suffering from radon emanated therefrom. However, there is a lack of radon potential maps in Hong Kong to resolve the spatial distribution of radon-prone areas. A ten-point radon potential system was developed in Germany (2005) to predict radon potential using both the in situ geogenic and geographic parameters under hierarchical ranking. Primarily, the ten-point system requires the desk study of the geological environment of sampling sites, which has an advantage of saving resources and manpower in extensive radon potential mapping over the traditional soil radon concentration sampling method. This paper presents a trial of radon potential mapping in Hong Kong to further verify the system. Despite some slight departures, the system demonstrates an acceptable correlation with soil radon concentrations (R 2 = 0.62–0.66) from 768 samples of mainly intermediate radon potential. Hong Kong has a mean soil radon concentrations of 58.9 kBqm?3, while the radon potential from the ten-point system achieves an average of 4.93 out of 10 over the territory. The vicinity of fault zone showed high soil radon concentrations and potentials, which were conducive to uranium enrichment and rapid soil-gas diffusion near faults. High uranium-238 content in soil was found to cause high soil radon concentration with a large R 2, 0.84. The Jurassic granite and volcanic crystal tuff cover more than 85 % of the whole Hong Kong area, and they show relatively high radon concentrations (Geometric mean 83 and 49 kBqm?3, respectively) which are associated with their high uranium contents (Geometric mean 234 and 197 Bqkg?1, respectively). While indoor radon concentration is an important factor for radon risk assessment, this study has not considered the correlation between indoor radon concentration and radon potential. The reason is that almost all buildings in Hong Kong are high-rise buildings where indoor radon concentrations are governed only by the radium content in the building materials and the ventilation conditions.  相似文献   
89.
Can saltwater toxicity be predicted from freshwater data?   总被引:3,自引:0,他引:3  
The regulation of substances discharged to estuarine and coastal environments relies upon data derived from ecotoxicity tests. Most such data are generated for freshwater rather than saltwater species. If freshwater toxicity data are related to saltwater toxic effects in a systematic and predictable way, the former can be used to predict the latter. This would have economic advantages due to a reduction in toxicity testing of saltwater species. If toxicity data are plotted as species sensitivity distributions, four theoretical relationships between freshwater and saltwater can be envisaged. Examples show that each one of these relationships is supported by empirical data. These examples show that although there is considerable potential for freshwater to saltwater prediction, species parity and representativeness need to be examined for each chemical substance to avoid bias.  相似文献   
90.
This paper is about the development of a decision‐support system for water‐pollution management and environmental planning. More specifically, the paper first presents the overall concept and the system architecture of a generic environmental decision‐support system (EDSS) and then develops an EDSS especially for analysing the tidal flow pattern and water quality of China's Pearl River Delta. The EDSS developed here employs the object‐oriented approach to design the environmental database and utilizes the system integration technology to develop the overall user‐friendly system that operates in the Windows environment. Furthermore, the system can be expanded to facilitate automated model selection and analysis. The EDSS should be of value for managing water quality of river networks with complicated flow patterns, such as that found in the Pearl River Delta.  相似文献   
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