A novel method for the study and classification of shales     

J.M. Cubitt  J.G. Wilkinson 《Chemical Geology》1974,13(1):57-61

The electron spin resonance spectra of a range of shales, from the Upper Pennsylvanian and Lower Permian of Kansas, U.S.A., have been recorded. Cluster analysis of the spectral data produced a four-group classification of the samples. The results compare well with a classification based on X-ray diffraction results.  相似文献   

Links between teleconnection patterns and mean temperature in Spain     

David Ríos-Cornejo  Ángel Penas  Ramón Álvarez-Esteban  Sara del Río 《Theoretical and Applied Climatology》2015,122(1-2):1-18

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Technologies for adaptation to climate change. Examples from the agricultural and water sectors in Lebanon     

Sara Trærup  Jean Stephan 《Climatic change》2015,131(3):435-449

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A petrological,mineralogical, and chemical analysis of the lunar mare basalt meteorite LaPaz Icefield 02205, 02224, and 02226     

Katherine H. Joy  Ian A. Crawford  Hilary Downes  Sara S. Russell  Anton T. Kearsley 《Meteoritics & planetary science》2006,41(7):1003-1025

Abstract— LaPaz Icefield (LAP) 02205, 02226, and 02224 are paired stones of a crystalline basaltic lunar meteorite with a low‐Ti (3.21–3.43% TiO₂) low‐Al (9.93–10.45% Al₂O₃), and low‐K (0.11–0.12% K₂O) composition. They consist mainly of zoned pyroxene and plagioclase grains, with minor ilmenite, spinel, and mesostasis regions. Large, possibly xenocrystic, forsteritic olivine grains (<3% by mode) contain small trapped multiphase melt inclusions. Accessory mineral and mesostasis composition shows that the samples have experienced residual melt crystallization with silica oversaturation and late‐stage liquid immiscibility. Our section of LAP 02224 has a vesicular fusion crust, implying that it was at one time located sufficiently close to the lunar surface environment to have accumulated solar‐wind‐implanted gases. The stones have a comparable major element composition and petrography to low‐Ti, low‐Al basalts collected at the Apollos 12 and 15 landing sites. However, the LAP stones also have an enriched REE bulk composition and are more ferroan (Mg numbers in the range of 31 to 35) than similar Apollo samples, suggesting that they represent members of a previously unsampled fractionated mare basalt suite that crystallized from a relatively evolved lunar melt.  相似文献   

Petrogenesis of post-collisional A-type granitoids from the Urumieh–Dokhtar magmatic assemblage,Southwestern Kerman,Iran: Constraints on the Arabian–Eurasian continental collision     

Sara Dargahi  Mohsen Arvin  Yuanming Pan  Abbed Babaei 《Lithos》2010,115(1-4):190-204

Three plutons (Deh-Siahan, Bande-Bagh and Baghe-Khoshk Sharghi, collectively referred to as the DBB hereafter) in southwestern Kerman, in the southeastern part of the Urumieh–Dokhtar magmatic assemblage (UDMA) of the Zagros orogenic belt differ from the typical calc-alkaline metaluminous, I-type intrusions of the region. The DBB intrusions have a distinct lithological assemblage varying from diorite through monzogranite and monzonite to alkali feldspar syenite and alkali granite. The DBB granitoids are metaluminous to slightly peraluminous, alkaline to shoshonitic in composition and have high total alkali contents with K₂O > Na₂O, high FeO_T/MgO values, and low CaO and MgO contents. They are enriched in some LILEs (such as Rb and Th) and HFSEs (such as Zr, Y and REEs except Eu) and depleted in Sr and Ba relative to primordial mantle, and have low concentrations of transitional metals. These features along with various geochemical discriminant diagrams suggest that the DBB granitoids are post-collisional A-type granitoids, which had not been recognized previously in the UDMA. The chondrite-normalized REE patterns of the DBB granitoids show slightly enriched light REEs [(La/Sm)_N = 2.26–4.13], negative Eu anomalies [(Eu/Eu*)_N = 0.19–0.74] and flat heavy REE patterns [(Gd/Yb)_N = 0.80–1.87]. The negative Eu anomaly indicates an important role for plagioclase and/or K-feldspar during fractional crystallization. Whole-rock Rb–Sr isotope analysis yields an isochron age of 33 ± 1 Ma with an initial ⁸⁷Sr/⁸⁶Sr value of 0.7049 ± 0.0001. Whole-rock Sm–Nd isotope analysis gives ε_Nd^t values from + 2.56 to + 3.62 at 33 Ma. The positive ε_Nd^t and low I_Sr values of the DBB granitoids together with their T_DM of 0.6–0.7 Ga suggest their formation from partial melting of a lithospheric mantle source, modified by fluids or melts from earlier subduction processes. Melting of lithospheric mantle occurred via a dehydration melting process at pressures below the garnet stability field, as a consequence of lithospheric mantle delamination or break-off of a subducted slab and melting of the lithospheric mantle by upwelling of hot asthenosphere. On the basis of Rb/Sr age dating and the post-collisional geochemical signatures of the DBB granitoids, along with extensive pre-collisional volcanic eruptions in Middle Eocene, we suggest Late Eocene for the time of collision between the Arabian and Central Iranian plates. This also implies that the calc-alkaline I-type intrusions in the southwestern Kerman and in other parts of the UDMA may have formed in a post-collisional context.  相似文献   

Geotechnical Characterization by In situ and Lab Tests to the Back-Analysis of a Supported Excavation in Metro do Porto   总被引：1，自引：1，他引：0  

António Viana da Fonseca  Sara Rios Silva  Nuno Cruz 《Geotechnical and Geological Engineering》2010,28(3):251-264

This paper summarizes the geotechnical characterization conducted for the design and subsequent analysis of a strutted excavation in “Metro do Porto”. This region is geologically dominated by heterogeneous weathered granite masses with deep residual soil profiles. Local saprolitic soils exhibit, by their nature, a particular behavior characterized by very sensitive and weak relic micro-structures, due to their specific genesis. This study has included the interpretation of a significant volume of in situ test results, triaxial tests over undisturbed samples and monitoring data, giving rise to specific correlations between testing and design parameters. Real time monitoring enabled a back-analysis by FEM of a well instrumented section of the strutted excavation, which was calibrated taking into account the derived correlations and the deformability behavior of this specific geotechnical ambient. This geomaterial, although revealing very high initial stiffness values (for very small strain ranges) has shown low stiffness values for “medium to high” strain levels, reflecting a singular strong non-linearity in the stress-strain behavior.  相似文献   

Distribution and Abundance of Arsenic in the Soils and Sediments of O‘ahu,Hawai‘i     

Eric Heinen De Carlo  Michael S. Tomlinson  Laura E. deGelleke  Sara Thomas 《Aquatic Geochemistry》2014,20(2-3):87-113

Lack of high-spatial-resolution soil and sediment arsenic data for Hawai‘i has generated substantial disagreement between researchers and regulators regarding the magnitude of natural levels of arsenic in Hawai‘i and rendered difficult the defining of areas of anthropogenically elevated arsenic. Our earlier research into the occurrence of arsenic in terrestrial and marine environments revealed widely disparate concentrations of arsenic with no apparent spatial pattern. To better understand the distribution and abundance of arsenic in soils and sediments of O‘ahu, we collected an additional 64 samples at locations chosen to represent different environments with varying degrees of human impact. We found surface arsenic values that ranged from 0.28 to 740 ppm with a median concentration of 8.1 ppm, which is above the global median of 5 ppm and US soil median of 5.2 ppm. Higher concentrations of arsenic (up to 913 ppm) were encountered at depth in soil cores. The median arsenic in streambed sediments from one of our earlier studies of 6.1 ppm was comparable to the conterminous US median of 6.3 ppm; however, we encountered arsenic concentrations as high as 43.9 ppm (median = 8.60 ppm, n = 75) in marine sediments in recent work off the leeward coast of O‘ahu. Overall, arsenic in the soils and sediments of O‘ahu is elevated relative to world and national values, but there still is no readily discernible pattern in the distribution of arsenic to explain these elevated values.  相似文献   

Lateral variations in tectonic style across cross-strike discontinuities: an example from the Central Apennines belt (Italy)     

Sara Satolli  Paolo Pace  Mauro Gabriele Viandante  Fernando Calamita 《International Journal of Earth Sciences》2014,103(8):2301-2313

In foreland thrust belts, abrupt lateral changes in tectonic style, structural–stratigraphic features, and topography usually occur across cross-strike faults. The Central Apennines of Italy offer an exceptional scenario of lateral variations in tectonic setting. Here, the Sangro Volturno oblique thrust ramp (SVOTR) represents the outer thrust front of the Pliocene–Quaternary foreland thrust system, confining southward the axial culmination of the orogen that occurs in the Central Apennines. We present an interpretation of the Pliocene–Quaternary evolution of this cross-strike fault through an integrated dataset including structural-geological mapping and subsurface onshore seismic reflection profiles. The interpretation of the structural framework is augmented by the analysis of low-temperature thermochronometers from 32 new sites extending across the subsurface transverse structure. As evidenced by seismic line interpretation, the localization and development of the SVOTR have been influenced by inherited extensional faults within a positive inversion tectonics context. The regional distribution of the maximum paleotemperature values across the SVOTR constrains the original extent of the allochthonous thrust sheet over all its hanging-wall and footwall blocks. The Pliocene–Quaternary thrusting and inversion of SVOTR caused the strong hanging-wall uplift, which brought to the complete erosion of the allochthonous units and the exhumation of the Adria units. The integrated analysis of low-temperature thermochronometers and structural evidence as applied in the study case can define the role of major cross-strike discontinuities in foreland thrust belts, by constraining and verifying their tectonics inversion significance and the amount of related exhumation.  相似文献   

The freshwater lens of Benjamín Aceval,Chaco, Paraguay: a terrestrial analogue of an oceanic island lens     

Georg Houben  Ursula Noell  Sara Vassolo  Christoph Grissemann  Mebus Geyh  Susanne Stadler  Eduardo J. Dose  Sofia Vera 《Hydrogeology Journal》2014,22(8):1935-1952

The occurrence of a freshwater lens in the Paraguayan Chaco, 900 km away from the ocean, is reported. It is located underneath sandstone hills, surrounded by lowlands with predominantly saline groundwater. Its geometry was delineated using geoelectrical and electromagnetic investigations. The unusual height of the fresh groundwater level can be attributed to the presence of a confining layer at depth. The lens receives its recharge exclusively from rainfall during the hot and humid summer months. It predominantly contains water predating the atmospheric atomic bomb tests, some of it probably up to a thousand or more years old. The water balance shows that extraction currently does not exceed recharge in normal years. However, the available volume of groundwater leaves little room for a further increase of extraction in the future. Recharge is augmented by return flow from thousands of latrines and cess pits, and this has lead to widespread contamination of the groundwater by faecal bacteria.  相似文献   

Permian volcanic rocks from the Apuseni Mountains (Romania): Geochemistry and tectonic constraints     

Ionel Nicolae  Ioan Seghedi  Iuliu Boboş  Maria do Rosário Azevedo  Sara Ribeiro  Mihai Tatu 《Chemie der Erde / Geochemistry》2014

An Early Permian volcanic assemblage is well exposed in the central-western part of the Apuseni Mountains (Romania). The rocks are represented by rhyolites, basalts and subordinate andesites suggesting a bimodal volcanic activity that is intimately associated with a post-orogenic (Variscan) syn-sedimentary intra-basinal continental molasse sequences. The mafic and mafic-intermediate rocks belong to sub-alkaline tholeiitic series were separated in three groups (I–III) showing a high Th and Pb abundances, depletion in Nb, Ta and Sr, and slightly enriched in LREE patterns (La_N/Yb_N = 1.4–4.4). Isotopically, the rocks of Group I have the initial ratios ⁸⁷Sr/⁸⁶Sr_(i) = 0.709351–0.707112, ¹⁴³Nd/¹⁴⁴Nd_(i) = 0.512490–0.512588 and high positive ?_Nd270 values from 3.9 to 5.80; the rocks of Group II present for the initial ratios values ⁸⁷Sr/⁸⁶Sr_(i) = 0.709434–0.710092, ¹⁴³Nd/¹⁴⁴Nd_(i) = 0.512231–0.512210 and for ?_Nd270 the negative values from −1.17 to −1.56; the rocks of Group III display for the initial ratios the values ⁸⁷Sr/⁸⁶Sr_(i) = 0.710751–0.709448, ¹⁴³Nd/¹⁴⁴Nd_(i) = 0.512347–0.512411 and for ?_Nd270 the positive values from 1.64 to 2.35. The rocks resembling continental tholeiites, suggest a mantle origin and were further affected by fractionation and crustal contamination. In addition, the REE geochemistry (1 > Sm_N/Yb_N < 2.5; 0.9 > La_N/Sm_N < 2.5) suggests that these rocks were generated by high percentage partial melting of a metasomatized mantle in the garnet peridotite facies. The felsic rocks are enriched in Cs, Rb Th and U and depleted in Nb, Ta, Sr, Eu, and Ti. The REE fractionation patterns show a strong negative Eu anomaly (Eu/Eu* = 0.23–0.40). The felsic rocks show the initial ratios the values: ⁸⁷Sr/⁸⁶Sr_(i) = 0.704096–0.707805, ¹⁴³Nd/¹⁴⁴Nd_(i) = 0.512012–0.512021 and for ?_Nd270 the negative values from −5.27 to −5.44. They suggest to be generated within the lower crust during the emplacement of mantle-derived magmas that provided necessary heat to crustal partial melting.  相似文献