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51.
Heavy metal pollution assessment in various industries of Pakistan   总被引:1,自引:0,他引:1  
Water pollution is a source of danger to the health of people living in developing countries such as Pakistan. The main industries located at various industrial zones of Pakistan cause water pollution, which ultimately result in various diseases. The aim of the present study was to study the concentrations of essential and toxic metals (Na, K, Cu, Zn, Fe, Ca, Pb and As) in the drained water of three main industrial estates of Pakistan, i.e., Industrial Estate No. 1 Peshawar, Small Industrial Estate No. 2 Gujranwala, Industrial Estate Hattar Haripur, and in Warsak Canal (industrially pure water) with the help of atomic absorption spectroscopy and flame emission spectroscopy. The study showed high Pb and As levels originating from industries. The concentrations of Pb and As ranged from 0.04 to 0.942 mg/L in all the samples. These have been extensively used for irrigation since the last five decades. The elevated concentrations of heavy metals are continuously entering into the food chain through agriculture leading to serious health hazards and a threat to the sustainability of local ecosystem.  相似文献   
52.
Prevailing trends of climatic extremes across Indus-Delta of Sindh-Pakistan   总被引:1,自引:0,他引:1  
This study examines the variability and change in the patterns of climatic extremes experienced in Indus-Delta of Sindh province of Pakistan, comprising regions of Karachi, Badin, Mohenjodaro, and Rohri. The homogenized daily minimum and maximum temperature and precipitation data for a 36-year period were used to calculate 13 and 11 indices of temperature and precipitation extremes with the help of RClimDex, a program written in the statistical software package R. A non-parametric Mann–Kendall test and Sen’s slope estimates were used to determine the statistical significance and magnitude of the calculated trend. Temperatures of summer days and tropical nights increased in the region with overall significant warming trends for monthly maximum temperature as well as for warm days and nights reflecting dry conditions in the study area. The warm extremes and nighttime temperature indices showed greater trends than cold extremes and daytime indices depicting an overall warming trends in the Delta. Historic decrease in the acreage of major crops and over 33% decrease in agriculture credit for Sindh are the indicators of adverse impacts of warmer and drier weather on Sindh agriculture. Trends reported for Karachi and Badin are expected to decrease rice cultivation, hatching of fisheries, and mangroves forest surrounding these cities. Increase in the prevailing temperature trends will lead to increasingly hotter and drier summers resulting to constraints on cotton, wheat, and rice yield in Rohri and Mohenjodaro areas due to increased crop water requirements that may be met with additional groundwater pumping; nonetheless, the depleted groundwater resources would have a direct impact on the region’s economy.  相似文献   
53.
Spatial objects can be interconnected and mutually dependent in complex ways. In Geographical Information Science, spatial objects’ topological relationships are not discussed together with their attributes’ dependencies, and the vagueness of spatial objects is often ignored during the spatial modelling process. To address this, a spatial fuzzy influence diagram (SFID) is introduced. Compared to the traditional statistical or fuzzy modelling approach, the influence diagram brings advantages in helping decision-makers structure complex interdependency problems. A questionnaire was developed to evaluate the applicability of using an influence diagram in modelling spatial objects’ dependencies. As a case study, an SFID is applied to tree-related electric outages. The result of the case study is represented as a vulnerability map of electrical networks. The map shows areas at risk due to tree-related electric outages. The results were first validated by using a visual comparison of the vulnerability map and electricity fault data. In the second validation step, the percentage of fault data, which has received values in different vulnerability categories, was calculated. The results of the case study can be used to support the decision-making process of electrical network maintenance and planning.  相似文献   
54.
Lead and cadmium are the two widely recognized toxic metals, with known ecological risk to freshwater fish in contaminated ecosystems. However, their effect at environmentally realistic level in a mixture has been rarely investigated. In the present study, serum metabolic responses of Crucian carp exposed to Pb (30 µgL?1), Cd (100 µgL?1) and Pb+Cd (30 + 100 µgL?1) for 21 days were investigated by 1H NMR-based metabolomics. The metabolic responses were compared to control by multivariate techniques (PCA, PLS-DA and OPLS-DA), and metabolites that significantly contributed to the variation were identified. Metal dependent metabolic responses revealed a decline of alanine, lysine and tyrosine in Pb exposed fish, indicating changes in neurotransmitters, and amino acid metabolism, while fish exposed to Cd showed significant decrease in lysine, isoleucine, leucine, alanine and increase in 3-hydroxybutyrate, acetone, lactate, choline, inosine, guanosine and threonine. The coexposure of Pb and Cd had additive effect on metabolic profile with increase in pyruvate, guanosine and inosine. The overall metabolic changes due to Pb and Cd were characterized by disturbed energy metabolism, impaired osmotic regulation and a shift from aerobic to anaerobic respiration. Moreover, 1H NMR-based metabolomics was proved to be a powerful tool in elucidating the toxic effects of environmental pollutants and underlying mechanism.  相似文献   
55.
The presence of trace antibiotics in domestic and industrial effluents poses a risk of toxicity to fauna and flora. The application of floating treatment wetlands (FTWs) is a low-cost and sustainable approach to remediate wastewater. In this study, the performance of different macrophytes vegetated in FTWs for the remediation of ciprofloxacin (CIP)-contaminated water is investigated. Six macrophytes, Brachia mutica, Typha domingensis, Phragmites australis, Canna indica, Cyperus laevigatus, and Leptochloa fusca, are vegetated in FTWs for the removal of CIP (50 mg L−1) from water. The FTWs show the potential to remove 30–43.58 mg L−1 CIP from water in 28 days. They also reduce the chemical oxygen demand (118–138 mg L−1) and biochemical oxygen demand (35–45 mg L−1) of water. Among the macrophytes, C. indica removes maximum (43.58 mg L−1) and T. domingensis minimum (30 mg L−1) CIP. Canna indica and T. domingensis exhibit the maximum and minimum increase (30% and 12% of dry biomass) in growth, respectively. This study reveals that the FTWs vegetated with different plant species exhibit varying performances in removing CIP from water. This investigation is a step forward toward sustainable bioremediation of water contaminated with antibiotics.  相似文献   
56.
The Changjiang River Estuary(CRE) in the East China Sea suffers from seasonal hypoxia in summer. The vertical distributions and seasonal changes of microbial communities in the CRE were well documented. However, little is known about the diurnal changes of bacterial communities in the hypoxic zone of the CRE. Here, 16 S rRNA gene analysis was used to explore the changes of bacterial communities in the oxic surface and hypoxic middle seawater layers during 24 h in the CRE. Significant differences between the hypoxic and oxic layers were observed:the phyla Cyanobacteria, Bacteroidetes and Acidimicrobiia were enriched in the oxic layer, whereas the phylum SAR406 and the class Deltaproteobacteria were more abundant in the hypoxic layer. In addition, some subtle diurnal variations of the bacterial relative abundance were found in both two layers. The relative abundance of Synechococcus increased at night, and this change was more obvious in the hypoxic layer. The similar trend was also found in some phototrophic and several heterotrophic bacteria, such as Rhodobacteraceae, OM60 and Flavobacteriaceae. Their relative abundances peaked at 16:00 in the oxic layer, while the relative abundances peaked at around 7:00 and decreased until 13:00 in the hypoxic layer. Together, the results of the present study suggest that some photosynthetic bacteria and several heterotrophic bacteria have similar diurnal variations implying the light and physicochemical heterogeneity in the course of a day are important for bacterial diurnal changes in the CRE.  相似文献   
57.
The aim of this study is to assess the performance of linear discriminate analysis, support vector machines (SVMs) with linear and radial basis, classification and regression trees and random forest (RF) in the classification of radionuclide data obtained from three different types of rocks. Radionuclide data were obtained for metamorphic, sedimentary and igneous rocks using gamma spectroscopic method. A P-type high-purity germanium detector was used for the radiometric study. For analysis purpose, we have determined activity concentrations of 232Th, 226Ra and 40K radionuclides, published elsewhere (Rafique et al. in Russ Geol Geophys 55:1073–1082, 2014), in different rock samples and built the classification model after pre-processing the data using three times tenfold cross-validation. Using this model, we have classified the new samples into known categories of sedimentary, igneous and metamorphic. The statistics depicts that RF and SVM with radial kernel outperform as compared to other classification methods in terms of error rate, area under the curve and with respect to other performance measures.  相似文献   
58.
Metamorphosed volcanic and sedimentary rocks of the Jaglot Group are exposed along the west bank of the Indus River near Thelichi. The structural bottom unit, the Thelichi Formation, is composed of metavolcaniclastic, metavolcanic, metapelitic, and metacalcareous rocks. Bedding planes of the Thelichi Formation trend E–W or NW–SE and dip steeply to the N. The middle unit, Gashu-Confluence Volcanics, is composed of metavolcaniclastic, metavolcanic, and metacalcareous rocks. Bedding planes trend NW–SE and dip moderately to the N. The top unit, the Gilgit Formation, is composed of interlayered metapsammitic and metapelitic rocks. Graded bedding, cross-bedding, and pillow structures are preserved in these metamorphic rocks of the Jaglot Group. Those indicate clastic sedimentary and volcanic origins. There is no major repetition of layers due to folding (so-called “the Jaglot syncline”) as is evidenced by the consistent northward younging of the beds. The three lithological units constitute a north-dipping tectonic stack. The tectonic stack was provably caused by the northward subduction of the back-arc basin under the Asian margin and subsequent collision between the Asia and the Kohistan (the closure of back-arc basin).  相似文献   
59.
In this study, sono-assisted dilute sulfuric acid process was evaluated for its viability of simultaneous pretreatment and saccharification of rice straw. Three critical factors for simultaneous pretreatment and saccharification process, such as sonication time (30–50 min), temperature (70–90 °C), and acid concentration (5–10 %), were optimized to maximize reducing sugar yield using Box-Behnken design and response surface methodology. The response surface methodology model was found to be adequately fitted to the obtained data. Simultaneous pretreatment and saccharification factors were optimized at sonication of 50 min, 80 °C and an acid concentration of 10 % yielding the maximum sugar content (31.78 g/100 g of biomass). Scanning electron microscopy revealed that the smooth surface of raw biomass was altered into a rough and porous surface as a result of sugar release, which showed the prospective feasibility of simultaneous pretreatment and saccharification process. This process integration may lead to develop economical bioethanol production facility. However, further research is required to make this process industrially viable.  相似文献   
60.
Cadmium (Cd) is the family member of toxic heavy metals, and its accumulation in food crops has become a global environmental constraint. Biochar potentially minimizes the metal contents in plants, but limited work has been reported on its residual effect on subsequent crops. The residual effect of various biochar levels (0, 1.5, 3.0, and 5.0% w/w) on Cd accumulation in rice has been investigated in this study. Biochar treatments enhanced the rice growth, photosynthesis, and antioxidant enzymes, whereas diminished the Cd contents and oxidative stress in rice. Cadmium concentration in shoots decreased by 24.4, 36.6, and 57.5% in 1.5, 3.0, and 5.0% biochar treatments over the control. Biochar supply enhanced the soil pH and electrical conductivity, whereas diminished the soil bioavailable Cd. Overall, the results depicted a significant residual impact of rice straw biochar on rice growth attributes and Cd uptake. However, studies are still needed to explore the long-term sustainability of biochars prepared from different feedstocks on bioavailability of toxic metals in soils and uptake by food crops under field conditions.  相似文献   
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