The removal kinetics of dissolved organic matter and the optical clarity of groundwater     

Francis H. Chapelle  Yuan Shen  Eric W. Strom  Ronald Benner 《Hydrogeology Journal》2016,24(6):1413-1422

Concentrations of dissolved organic matter (DOM) and ultraviolet/visible light absorbance decrease systematically as groundwater moves through the unsaturated zones overlying aquifers and along flowpaths within aquifers. These changes occur over distances of tens of meters (m) implying rapid removal kinetics of the chromophoric DOM that imparts color to groundwater. A one-compartment input-output model was used to derive a differential equation describing the removal of DOM from the dissolved phase due to the combined effects of biodegradation and sorption. The general solution to the equation was parameterized using a 2-year record of dissolved organic carbon (DOC) concentration changes in groundwater at a long-term observation well. Estimated rates of DOC loss were rapid and ranged from 0.093 to 0.21 micromoles per liter per day (μM d^?1), and rate constants for DOC removal ranged from 0.0021 to 0.011 per day (d^?1). Applying these removal rate constants to an advective-dispersion model illustrates substantial depletion of DOC over flow-path distances of 200 m or less and in timeframes of 2 years or less. These results explain the low to moderate DOC concentrations (20–75 μM; 0.26–1 mg L^?1) and ultraviolet absorption coefficient values (a ₂₅₄?<?5 m^?1) observed in groundwater produced from 59 wells tapping eight different aquifer systems of the United States. The nearly uniform optical clarity of groundwater, therefore, results from similarly rapid DOM-removal kinetics exhibited by geologically and hydrologically dissimilar aquifers.  相似文献   

Analysis of the contribution of multiple factors to the recent decrease in discharge and sediment yield in the Yellow River Basin,China   总被引：5，自引：1，他引：4  

Wenyi Yao  Peiqing Xiao  Zhenzhou Shen  Jinhua Wang  Peng Jiao 《地理学报(英文版)》2016,26(9):1289-1304

The Yellow River basin is well known for its high sediment yield. However, this sediment yield has clearly decreased since the 1980s, especially after the year 2000. The annual average sediment yield was 1.2 billion tons before 2000, but has significantly decreased to 0.3 billion tons over the last 10 years. Changes in discharge and sediment yield for the Yellow River have attracted the attention of both the Central Government and local communities. This study aimed to identify the individual contributions of changes in precipitation and human activities (e.g. water conservancy projects, terracing, silt dams, socio-economic and needs, and soil and water conservation measures) to the decrease in discharge and sediment yield of the Yellow River. The study used both improved the hydrological method and the soil and water conservation method. The study focused on discharge analysis for the upper reaches and the investigation of sediments for the middle reaches of the river. The results showed that discharge and sediment yield have both presented significant decreasing trends over the past 50 years. Precipitation showed an insignificant decreasing trend over the same period. The annual average discharge decreased by 5.68 billion m³ above Lanzhou reach of the Yellow River from 2000 to 2012; human activities (e.g. socio-economic water use) contributed 43.4% of the total reduction, whereas natural factors (e.g. evaporation from lakes, wetlands and reservoirs) accounted for 56.6%. The decrease in annual discharge and sediment yield of the section between Hekouzhen station and Tongguan station were 12.4 billion m³ and 1.24 billion tons, respectively. Human activities contributed 76.5% and 72.2% of the total reduction in discharge and sediment yield, respectively, and were therefore the dominant factors in the changes in discharge and sediment yield of the Yellow River.  相似文献   

Anthropogenic,detritic and atmospheric soil-derived sources of lead in an alpine poor fen in northeast China     

Kun-shan Bao  Ji Shen  Guo-ping Wang  Shurkhuu Tserenpil 《山地科学学报》2016,13(2):255-264

Ombrotrophic bogs are faithful archive of atmospheric metal deposition,but the potential for fens to reconstruct environmental change is often underestimated.In this study,some new data on the Pb depositional history in northeast China were provided using two 210Pb-dated peat sequences from a poor fen in the Fenghuang Mountain of Heilongjiang province.Anthropogenic,detritic and atmospheric soil sources were discriminated using a two-step sequential digestion(weak acid leaching to liberate mobile Pb which is often regarded as anthropogenic Pb,especially for recent samples)and a ratio of unsupported 210 Pb and supported 210 Pb with the logic of that the 214 Pb mainly represents the residual detritus(constant throughout the core)and the unsupported 210 Pb arises from atmospheric fallout.A higher 210Pb/214 Pb suggests more contributions from atmospheric deposition to the Pb content in the peat,and a ratio of 10 was defined to indicate the boundary between detritic input and atmospheric deposition.The detritic Pbwas estimated to be 10~(-1)3 mg·kg~(-1),the anthropogenic Pb ranged from 10-80 mg·kg~(-1),and the atmospheric soil-derived Pb ranged from 5 mg·kg~(-1) to 30mg·kg~(-1).The history of anthropogenic Pb pollution over the last 150 years was reconstructed,and the calculated Pb deposition rate(AR Pb) ranged from 5to 56 mg·m-2·yr~(-1).Using Ti as a reliable reference,the enrichment factor of Pb(EF Pb) relative to the upper continental crust was calculated.Both AR Pb and EF Pb increased with time,especially after the foundation of the People's Republic of China.This is consistent with increasing industrialization and coal burning in the last 60 years in northeast China.The present record of anthropogenic Pb deposition was consistent with the previous reports and an increasing trend of environmental pollution due to anthropogenic activities,in contrasts to Europe and North America which have experienced a major environmental cleanup.For the first time,this work estimates atmospheric Pb deposition via a minerotrophic peat core in China.This will enhance the use of peat archives for studies of environmental change.  相似文献   

Effect of benzo[a]pyrene on detoxification and the activity of antioxidant enzymes of marine microalgae     

Chen Shen  Jingjing Miao  Yun Li  Luqing Pan 《中国海洋大学学报(英文版)》2016,15(2):303-310

The objective of this study was to examine the effect of benzo[a]pyrene(Ba P) on the detoxification and antioxidant systems of two microalgae,Isochrysis zhanjiangensis and Platymonas subcordiformis.In our study,these two algae were exposed to Ba P for 4 days at three different concentrations including 0.5 μg~(L-1)(low),3 μg~(L-1)(mid) and 18 μg~(L-1)(high).The activity of detoxification enzymes,ethoxyresorufin O-deethylase(EROD) and glutathione S-transferase(GST) increased in P.subcordiformis in all Ba P-treated groups.In I.zhanjiangensis,the activity of these two enzymes increased at the beginning of exposure,and then decreased in the groups treated with mid-and high Ba P.The activity of antioxidant enzyme superoxide dismutase(SOD) increased in I.zhanjiangensis in all Ba P-treated groups,and then decreased in high Ba P-treated group,while no significant change was observed in P.subcordiformis.The activity of antioxidant enzyme catalase(CAT) increased in I.zhanjiangensis and P.subcordiformis in all Ba Ptreated groups.The content of malondialdehyde(MDA) in Isochrysis zhanjiangensis increased first,and then decreased in high Ba P-treated group,while no change occurred in P.subcordiformis.These results demonstrated that Ba P significantly influenced the activity of detoxifying and antioxidant enzymes in microalgae.The metabolic related enzymes(EROD,GST and CAT) may serve as sensitive biomarkers of measuring the contamination level of Ba P in marine water.  相似文献   

Effectiveness of vegetative filter strips in abating fecal coliform based on modified soil and water assessment tool     

J. Bai  Z. Shen  T. Yan 《International Journal of Environmental Science and Technology》2016,13(7):1723-1730

Pathogenic bacteria are a serious public health concern. Exposure to these microorganisms can result in illnesses or even death. Therefore, it is important to control pathogenic bacteria sources, transport mechanisms and fate. Best management practices proved to be very effective in the control of non-point source pollution. In this study, the soil and water assessment tool (SWAT) was modified and used to simulate the fecal coliform in Chao River of Miyun Reservoir watershed, China. The model was then used to explore the effectiveness of vegetative filter strips (VFS) in reducing fecal coliform abundance throughout the watershed. The water temperature equation within the SWAT was modified to align the model more closely with the characteristics of the study area and generate a more accurate simulation. The DAFS_ratio (20, 50, 80, 120 and 150) and DF_con (0.25, 0.4, 0.6 and 0.75) parameters were considered for VFS to see their effects on removal efficiency. The results show that calibration and validation results for fecal coliform and flow can be accepted. Different values for DAFS_ratio and DF_con have great influence on VFS. Increasing values resulted in a decrease in the removal efficiency of VFS.  相似文献   

Investigations on physical properties and ablation processes of snow cover during the spring snowmelt period in the headwater region of the Irtysh River,Chinese Altai Mountains   总被引：1，自引：0，他引：1  

Wei Zhang  Yongping Shen  Ninglian Wang  Jianqiao He  An’an Chen  Jian Zhou 《Environmental Earth Sciences》2016,75(3):199

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Microbial dechlorination of HCB,PCP, PCB180, HCH and PCE in a Yangtze Three Gorges Reservoir enrichment culture,China     

Irene Kranzioch-Seipel  Ulrike Beckert  Chaofeng Shen  Daqiang Yin  Andreas Tiehm 《Environmental Earth Sciences》2016,75(10):928

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Protection of neighbour buildings due to construction of shield tunnel in mixed ground with sand over weathered granite     

Qing-Long Cui  Huai-Na Wu  Shui-Long Shen  Zhen-Yu Yin  Suksun Horpibulsuk 《Environmental Earth Sciences》2016,75(6):458

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Geological formation and geo-hazards during subway construction in Guangzhou     

Dong-Jie Ren  Shui-Long Shen  Wen-Chieh Cheng  Ning Zhang  Zhi-Feng Wang 《Environmental Earth Sciences》2016,75(11):934

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Geohazards induced by anthropic activities of geoconstruction: a review of recent failure cases     

Khalid Elbaz  Jack S. Shen  Arul Arulrajah  Suksun Horpibulsuk 《Arabian Journal of Geosciences》2016,9(18):708

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