A search for absorption of Mg and Ca compounds in molecular clouds towards Galactic continuum sources     

Seiichi Sakamoto    Glenn J. White    Kentarou Kawaguchi    Masatoshi Ohishi    Kumiko S. Usuda  & Tetsuo Hasegawa 《Monthly notices of the Royal Astronomical Society》1998,301(3):872-880

Absorption lines of MgH and CaH N  = 1 − 0 transitions were searched for in foreground molecular clouds towards the continuum sources associated with Sgr B2 (M) and W49A (N). None of these lines was detected with our sensitivity level of ∼20 mK. Millimetric absorption lines of MgO, MgOH, CaO and CaOH were also searched for towards Sgr B2 (M) without success. The fractional abundances relative to molecular hydrogen are ≲ 1.0 × 10⁻¹¹ for MgH, ≲ 7.9 × 10⁻¹³ for MgO, ≲ 1.6 × 10⁻¹⁰ for MgOH, ≲ 1.6 × 10⁻⁹ for CaH, ≲ 2.0 × 10⁻¹² for CaO, and ≲ 2.5 × 10⁻¹⁰ for CaOH, respectively. The low abundances measured in absorption indicate that a significant fraction of interstellar magnesium and calcium cannot be tied up in their monohydrides, monoxides and monohydroxides. The low abundance of MgH also implies that grain-surface chemistry involving magnesium is not efficient and that magnesium is depleted on to grains to a factor of ≳ 10^2.5 in well-shielded molecular clouds.  相似文献   

Prediction of slope water intrusion into the Kii channel in summer     

Toshinori Takashi  Tateki Fujiwara  Toshiaki Sumitomo  Wataru Sakamoto 《Journal of Oceanography》2006,62(1):105-113

Intrusions of the warm, oligotrophic surface slope water (SSW) and the cold, nutrient-rich bottom slope water (BSW) from the continental slope influence the annual variations in water temperature and nutrient concentrations in the Kii Channel in August. In order to evaluate the relationships between both these intrusions and the distance of the Kuroshio axis from Cape Shionomisaki (Kuroshio distance), a Distance-Intrusion-Diagram (DID) for temperature, which can reproduce the vertical temperature profile of the channel, was constructed by analyzing the temperature and Kuroshio distance records in August for 1967–2001. DIDs for nutrients (nitrate and phosphate) are also constructed by using the relationship between the nutrient concentration and water temperature. The only explanatory variable in the DIDs is the Kuroshio distance. The DID for temperature predicts that the SSW occupies almost the entire water column when the Kuroshio approaches Cape Shionomisaki (Kuroshio distance = 18.5 km). When the Kuroshio distance lies in the range 18.5–74 km, the BSW thickness increases proportionally to the Kuroshio distance increment while the SSW thickness decreases. The BSW occupies the largest portion of the channel when the Kuroshio distance is 74 km. Further, beyond 74 km, the BSW thickness reduces gradually. Yearly variations in the temperature and concentrations of nitrate and phosphate were hindcast with the DIDs. The results revealed that the Kuroshio distance contributes 70%, 35%, and 30% of the variances in temperature, nitrate concentration, and phosphate concentration, respectively.  相似文献   

Deep convection seesaw controlled by freshwater transport through the Denmark Strait   总被引：1，自引：0，他引：1  

Akira Oka  Hiroyasu Hasumi  Naosuke Okada  Takashi T. Sakamoto  Tatsuo Suzuki 《Ocean Modelling》2006,15(3-4):157

Observations of deep ocean temperature and salinity in the Labrador and Greenland Seas indicate that there is negative correlation between the activities of deep convection in these two sites. A previous study suggests that this negative correlation is controlled by the North Atlantic Oscillation (NAO). In this study, we discuss this deep convection seesaw by using a coupled atmosphere and ocean general circulation model. In this simulation, the deep convection is realistically simulated in both the Labrador and Greenland Seas and their negative correlation is also recognized. Regression of sea level pressure to wintertime mixed layer depth in the Labrador Sea reveals strong correlation between the convection and the NAO as previous studies suggest, but a significant portion of their variability is not correlated. On the other hand, the convection in the Greenland Sea is not directly related to the NAO, and its variability is in phase with changes in the freshwater budget in the GIN Seas. The deep convection seesaw found in the model is controlled by freshwater transport through the Denmark Strait. When this transport is larger, more freshwater flows to the Labrador Sea and less to the Greenland Sea. This leads to lower upper-ocean surface salinity in the Labrador Sea and higher salinity in the Greenland Sea, which produces negative correlation between these two deep convective activities. The deep convection seesaw observed in the recent decades could be interpreted as induced by the changes in the freshwater transport through the Denmark Strait, whose role has not been discussed so far.  相似文献   

Decomposition of kyanite and solubility of Al2O3 in stishovite at high pressure and high temperature conditions     

Xi Liu  Norimasa Nishiyama  Takeshi Sanehira  Toru Inoue  Yuji Higo  Shizue Sakamoto 《Physics and Chemistry of Minerals》2006,33(10):711-721

In order to constrain the high-pressure behavior of kyanite, multi-anvil experiments have been carried out from 15 to 25 GPa, and 1,350 to 2,500°C. Both forward and reversal approaches to phase equilibria were adopted in these experiments. We find that kyanite breaks down to stishovite + corundum at pressures above ∼15 GPa, and stishovite + corundum should be the stable phase assemblage at the pressure–temperature conditions of the transition zone and the uppermost part of the lower mantle of the Earth, in agreement with previous multi-anvil experimental studies and ab initio calculation results, but in disagreement with some of the diamond-anvil cell experimental studies in the literature. The Al₂O₃ solubility in nominally dry stishovite has been tightly bracketed by forward and reversal experiments; it is slightly but consistently reduced by pressure increase. Its response to temperature increase, however, is more complicated: increases at low temperatures, maximizes at around 2,000°C, and perhaps decreases at higher temperatures. Consequently, the Al₂O₃ solubility in dry stishovite at conditions of high temperature–high pressure is very limited.  相似文献   

Enrichment of adsorbed methane in authigenic carbonate concretions of the Japan Trench     

Akira Ijiri  Urumu Tsunogai  Toshitaka Gamo  Fumiko Nakagawa  Tatsuhiko Sakamoto  Saneatsu Saito 《Geo-Marine Letters》2009,29(5):301-308

Substantial amounts of adsorbed methane were detected in authigenic carbonate concretions recovered from sedimentary layers from depths between 245 and 1,108 m below seafloor during Ocean Drilling Program Leg 186 to ODP sites 1150 and 1151 on the deep-sea terrace of the Japan Trench. Methane contents were almost two orders of magnitude higher in the concretions (291–4,528 nmol/g wet wt) than in the surrounding bulk sediments (5–93 nmol/g wet wt), whereas methane/ethane ratios and stable carbon isotopic compositions were very similar. Carbonate content of surrounding bulk sediments (0.02–3.2 wet wt%) and methane content of the surrounding bulk sediments correlated positively. Extrapolation of the carbonate contents of bulk sediments suggests that 100 wt% carbonate would correspond to 1,886±732 nmol methane per g bulk sediment, which is similar to the average value observed in the carbonate concretions (1,321±1,067 nmol/g wet wt, n = 13). These data support the hypothesis that, in sediments, adsorbed hydrocarbon gases are strongly associated with authigenic carbonates.  相似文献   

Time series of carbonate system variables off Otaru coast in Hokkaido, Japan     

Ai Sakamoto  Yutaka W. Watanabe  Masato Osawa  KazuoKido  Shinichiro Noriki 《Estuarine, Coastal and Shelf Science》2008,79(3):377-386

We report several biogeochemical parameters (dissolved inorganic carbon (DIC), total alkalinity (TA), dissolved oxygen (DO), phosphate (PO₄), nitrate + nitrite (NO₃ + NO₂), silicate (Si(OH)₄)) in a region off Otaru coast in Hokkaido, Japan on a “weekly” basis during the period of April 2002–May 2003. To better understand the long-term temporal variations of the main factors affecting CO₂ flux in this coastal region and its role as a sink/source of atmospheric CO₂, we constructed an algorithm of DIC and TA using other hydrographic properties. We estimated the CO₂ flux across the air–sea interface by using the classical bulk method. During 1998–2003 in our study region, the estimated fCO_2sea ranged about 185–335 μatm. The maximum of fCO_2sea in the summer was primarily due to the change of water temperature. The minimum of fCO_2sea in the early spring can be explained not only by the change of water temperature but also the change of nutrients and chlorophyll-a. To clarify the factors affecting fCO_2sea (water temperature, salinity, and biological activity), we carried out a sensitivity analysis of these effects on the variation of fCO_2sea. In spring, the biological effect had the largest effect for the minimum of fCO_2sea (40%). In summer, the water temperature effect had the largest effect for the maximum of fCO_2sea (25%). In fall, the water temperature effect had the largest effect for the minimum of fCO_2sea (53%). In winter, the biological effect had the largest effect for the minimum of fCO_2sea (35%).We found that our study region was a sink region of CO₂ throughout a year (−0.78 mol/m²/yr). Furthermore, we estimated that the increase of fCO_2sea was about 0.56 μatm/yr under equilibrium with the atmospheric CO₂ content for the period 1998–2003, with the temporal changes in the variables (T, S, PO₄) on fCO_2sea, thus as the maximum trend of each variable on fCO_2sea was 0.22 μatm/yr, and the trend of residual fCO₂ including gas exchange was 0.34 μatm/yr. This result suggests that interaction among variables would affect gas exchange between air and sea effects on fCO_2sea. We conclude that this study region as a representative coastal region of marginal seas of the North Pacific is special because it was measured, but there is no particular significance in comparison to any other area.  相似文献   

Steric sea level changes estimated from historical ocean subsurface temperature and salinity analyses   总被引：13，自引：0，他引：13  

Masayoshi Ishii  Masahide Kimoto  Kenji Sakamoto  Sin-Iti Iwasaki 《Journal of Oceanography》2006,62(2):155-170

An historical objective analysis of subsurface temperature and salinity was carried out on a monthly basis from 1945 to 2003 using the latest observational databases and a sea surface temperature analysis. In addition, steric sea level changes were mainly examined using outputs of the objective analyses. The objective analysis is a revised version of Ishii et al. and is available at 16 levels in the upper 700 m depth. Artificial errors in the previous analysis during the 1990s have been worked out in the present analysis. The steric sea level computed from the temperature analysis has been verified with tide gauge observations and TOPEX/Poseidon sea surface height data. A correction for crustal movement is applied for tide gauge data along the Japanese coast. The new analysis is suitable for the discussion of global warming. Validation against the tide gauge reveals that the amplitude of thermosteric sea level becomes larger and the agreement improves in comparison with the previous analysis. A substantial part of local sea level rise along the Japanese coast appears to be explained by the thermosteric effect. The thermal expansion averaged in all longitudes from 60°S to 60°N explains at most half of recent sea level rise detected by satellite observation during the last decade. Considerable uncertainties remain in steric sea level, particularly over the southern oceans. Temperature changes within MLD make no effective contribution to steric sea level changes along the Antarctic Circumpolar Current. According to statistics using only reliable profiles of the temperature and salinity analyses, salinity variations are intrinsically important to steric sea level changes in high latitudes and in the Atlantic Ocean. Although data sparseness is severe even in the latest decade, linear trends of global mean thermosteric and halosteric sea level for 1955 to 2003 are estimated to be 0.31 ± 0.07 mm/yr and 0.04 ± 0.01 mm/yr, respectively. These estimates are comparable to those of the former studies.  相似文献   

Identification of the fronts from the Kuroshio Extension to the Subarctic Current using absolute dynamic topographies in satellite altimetry products     

Hideyuki Nakano  Hiroyuki Tsujino  Kei Sakamoto  Shogo Urakawa  Takahiro Toyoda  Goro Yamanaka 《Journal of Oceanography》2018,74(4):393-420

The climatologies and variabilities of the fronts associated with the Kuroshio Extension (KE), the Kuroshio Extension Northern Branch (KENB), the flow along the Subarctic Boundary (SAB), and the Subarctic Current (SAC) are identified by a new method based on the absolute dynamic height product from the archiving, validation, and interpretation of satellite oceanographic data (the AVISO product). The fronts are detected by examining the specific contour values of the absolute dynamic topography (ADT) in the AVISO product. The (time-varying) specific contour values are decided from the local maxima of the averaged surface geostrophic velocity along the ADT. Assuming the specific contours as the front locations, we obtain an occurrence frequency map of the four front locations, and determine the monthly variability of the fronts over the 1993–2015 period. The results are validated by hydrographic observations. The KE and KENB east of the Shatsky Rise migrate southward several times at a speed of ~ 0.2 cm s^?1, while the SAB and SAC are mostly stationary.  相似文献   

Development of a new operational system for monitoring and forecasting coastal and open-ocean states around Japan     

Hirose  Nariaki  Usui  Norihisa  Sakamoto  Kei  Tsujino  Hiroyuki  Yamanaka  Goro  Nakano  Hideyuki  Urakawa  Shogo  Toyoda  Takahiro  Fujii  Yosuke  Kohno  Nadao 《Ocean Dynamics》2019,69(11):1333-1357

We developed a new system to monitor and forecast coastal and open-ocean states around Japan for operational use by the Japan Meteorological Agency. The system consists of an eddy-resolving analysis model based on four-dimensional variational assimilation and a high (2-km) resolution forecast model covering Japanese coastal areas that incorporates an initialization scheme with temporal and spatial filtering. Assimilation and forecast experiments were performed for 2008 to 2017, and the results were validated against various observation datasets. The assimilation results captured well the observed variability in sea surface temperature, coastal sea level, volume transport, and sea ice. Furthermore, the volume budget for the Japan Sea was significantly improved by the use of the 2-km resolution forecast model compared with the 10-km resolution analysis model. The forecast results indicate that this system has a predictive limit longer than 1 month in many areas, including in the Kuroshio current area south of Japan and the southern Japan Sea. In the forecast results of case studies, the 2017 Kuroshio large meander was well predicted, and warm water intrusions accompanying Kuroshio path variations south of Japan were also successfully reproduced. Sea ice forecasts for the Sea of Okhotsk largely captured the evolution of sea ice in late winter, but sea ice in early winter included relatively large errors. This system has high potential to meet operational requirements for monitoring and forecasting ocean phenomena at both meso- and coastal scales.

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26Al–26Mg chronology of high-temperature condensate hibonite in a fine-grained,Ca-Al-rich inclusion from reduced CV chondrite     

Noriyuki Kawasaki  Daiki Yamamoto  Sohei Wada  Changkun Park  Hwayoung Kim  Naoya Sakamoto  Hisayoshi Yurimoto 《Meteoritics & planetary science》2024,59(4):630-639

Al–Mg mineral isochron studies using secondary ion mass spectrometry (SIMS) have revealed the initial ²⁶Al/²⁷Al ratios, (²⁶Al/²⁷Al)₀, for individual Ca-Al-rich inclusions (CAIs) in meteorites. We find that the relative sensitivity factors of ²⁷Al/²⁴Mg ratio for SIMS analysis of hibonite, one of the major constituent minerals of CAIs, exhibit variations based on their chemical compositions. This underscores the critical need for using appropriate hibonite standards to obtain accurate Al−Mg data. We measured the Al−Mg mineral isochron for hibonite in a fine-grained CAI (FGI) from the Northwest Africa 8613 reduced CV chondrite by SIMS using synthesized hibonite standards with ²⁷Al/²⁴Mg of ~30, ~100, and ~400. The obtained mineral isochron of hibonite in the FGI yields (²⁶Al/²⁷Al)₀ of (4.73 ± 0.09) × 10⁻⁵, which is identical to that previously obtained from the mineral isochron of spinel and melilite in the same FGI (Kawasaki et al., 2020). The uncertainties of (²⁶Al/²⁷Al)₀ indicate that the constituent minerals in the FGI formed within ~0.02 Myr in the earliest solar system. The disequilibrium O-isotope distributions of the minerals in the FGI suggest that the O-isotope compositions of the nebular gas from which they condensed underwent a transitional change from ¹⁶O-rich to ¹⁶O-poor within ~0.02 Myr in the earliest solar system. Once formed, the FGI may have been removed from the forming region within ~0.02 Myr and transported to the accretion region of the parent body.  相似文献