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11.
Two theoretical models, spherical and cylindrical, of propagation of shockwaves with varying energy in a rotating, magneto-radiative,self-gravitating non-uniform atmosphere have been developed. Subsequently,a comparison between the two models has been drawn with the aid ofvariation of flow variables with distance graphically. Significant is thedifference between two models, when one observes the variations of radialvelocity, pressure, mass, radiation flux, magnetic field and energy withdistance. Also, the respective influences of radiation flux, magneticfield and rotational velocity on the variations of the flow variables havebeen studied.  相似文献   
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This study investigated land use/land cover change (LULCC) dynamics using temporal satellite images and spatial statistical cluster analysis approaches in order to identify potential LULCC hot spots in the Pune region. LULCC hot spot classes defined as new, progressive and non-progressive were derived from Gi* scores. Results indicate that progressive hot spots have experienced high growth in terms of urban built-up areas (20.67% in 1972–1992 and 19.44% in 1992–2012), industrial areas (0.73% in 1972–1992 and 3.46% in 1992–2012) and fallow lands (4.35% in 1972–1992 and ?6.38% in 1992–2012). It was also noticed that about 28.26% of areas near the city were identified as new hot spots after 1992. Hence, non-significant change areas were identified as non-progressive after 1992. The study demonstrated that LULCC hot spot mapping through the integrated spatial statistical approach was an effective approach for analysing the direction, rate, spatial pattern and spatial relationship of LULCC.  相似文献   
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The 2.7–3 Ma Ertsberg East Skarn System (Indonesia), adjacent to the giant Grasberg Porphyry Copper deposit, is part of the world’s largest system of CuAu skarn deposits. Published fluid inclusion and stable isotope data show that it formed through the flux of magma-derived fluid through contact metamorphosed carbonate rock sequences at temperatures well above 600° C and pressures of less than 50 MPa. Under these conditions, the fluid has very low density and the properties of a gas. Combining a range of micro-analytical techniques, high-resolution QEMSCAN mineral mapping and computer-assisted X-ray micro-tomography, an array of coupled gas–solid reactions may be identified that controlled reactive mass transfer through the ~ 1 km3 hydrothermal skarn system. Vacancy-driven mineral chemisorption reactions are identified as a new type of reactive transport process for high-temperature skarn alteration. These gas–solid reactions are maintained by the interaction of unsatisfied bonds on mineral surfaces and dipolar gas-phase reactants such as SO2 and HCl that are continuously supplied through open fractures and intergranular diffusion. Principal reactions are (a) incongruent dissolution of almandine-grossular to andradite and anorthite (an alteration mineral not previously recognized at Ertsberg), and (b) sulfation of anorthite to anhydrite. These sulfation reactions also generate reduced sulfur with consequent co-deposition of metal sulfides. Diopside undergoes similar reactions with deposition of Fe-enriched pyroxene in crypto-veins and vein selvedges. The loss of calcium from contact metamorphic garnet to form vein anhydrite necessarily results in Fe-enrichment of wallrock, and does not require Fe-addition from a vein fluid as is commonly assumed.  相似文献   
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Detection and attribution methodologies have been developed over the years to delineate anthropogenic from natural drivers of climate change and impacts. A majority of prior attribution studies, which have used climate model simulations and observations or reanalysis datasets, have found evidence for human-induced climate change. This papers tests the hypothesis that Granger causality can be extracted from the bivariate series of globally averaged land surface temperature (GT) observations and observed CO2 in the atmosphere using a reverse cumulative Granger causality test. This proposed extension of the classic Granger causality test is better suited to handle the multisource nature of the data and provides further statistical rigor. The results from this modified test show evidence for Granger causality from a proxy of total radiative forcing (RC), which in this case is a transformation of atmospheric CO2, to GT. Prior literature failed to extract these results via the standard Granger causality test. A forecasting test shows that a holdout set of GT can be better predicted with the addition of lagged RC as a predictor, lending further credibility to the Granger test results. However, since second-order-differenced RC is neither normally distributed nor variance stationary, caution should be exercised in the interpretation of our results.  相似文献   
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Determination of thermal properties of soils (viz., thermal resistivity, thermal conductivity, thermal diffusivity and heat capacity), which primarily influence heat migration through the soil mass, is essential in situations where geomaterials are relentlessly subjected to higher temperatures and temperature variations. These properties of the soil mainly depend upon its type, mineralogy, particle size and gradational characteristics, density and water content. In this context, earlier researchers have determined thermal conductivity of soils by employing a thermal probe (a line heat source), which works on the principle of transient method (TM) of heat conduction. However, this methodology cannot be employed for establishing the heat flow (read thermal regime) through the soil. Hence, development of an alternate technique, which facilitates quantification of temporal and spatial variation of the heat flux and temperature in the soil mass, becomes essential. With this in mind, a methodology to determine thermal conductivity of soils by employing the concept of thermal flux measurement (TFM) has been developed and its details are presented in this paper. Results obtained from the TM and TFM have also been critically evaluated for the sake of validation and generating more confidence in the proposed methodology.  相似文献   
18.
We have experimentally determined the tracer diffusion coefficients (D*) of 44Ca and 26Mg in a natural diopside (~Di96) as function of crystallographic direction and temperature in the range of 950–1,150 °C at 1 bar and f(O2) corresponding to those of the WI buffer. The experimental data parallel to the a*, b, and c crystallographic directions show significant diffusion anisotropy in the a–c and b–c planes, with the fastest diffusion being parallel to the c axis. With the exception of logD*(26Mg) parallel to the a* axis, the experimental data conform to the empirical diffusion “compensation relation”, converging to logD ~ −19.3 m2/s and T ~ 1,155 °C. Our data do not show any change of diffusion mechanism within the temperature range of the experiments. Assuming that D* varies roughly linearly as a function of angle with respect to the c axis in the a–c plane, at least within a limited domain of ~20° from the c-axis, our data do not suggest any significant difference between D*(//c) and D*(⊥(001)), the latter being the diffusion data required to model compositional zoning in the (001) augite exsolution lamellae in natural clinopyroxenes. Since the thermodynamic mixing property of Ca and Mg is highly nonideal, calculation of chemical diffusion coefficient of Ca and Mg must take into account the effect of thermodynamic factor (TF) on diffusion coefficient. We calculate the dependence of the TF and the chemical interdiffusion coefficient, D(Ca–Mg), on composition in the diopside–clinoenstatite mixture, using the available data on mixing property in this binary system. Our D*(Ca) values parallel to the c axis are about 1–1.5 log units larger than those Dimanov et al. (1996). Incorporating the effect of TF, the D(Ca–Mg) values calculated from our data at 1,100–1,200 °C is ~0.6–0.7 log unit greater than the experimental quasibinary D((Ca–Mg + Fe)) data of Fujino et al. (1990) at 1 bar, and ~0.6 log unit smaller than that of Brady and McCallister (1983) at 25 kb, 1,150 °C, if our data are normalized to 25 kb using activation volume (~4 and ~6 cm3/mol for Mg and Ca diffusion, respectively) calculated from theoretical considerations.  相似文献   
19.
Inter-annual variations of phytoplankton abundance and community organization were observed over a two-decade period along with the ancillary parameters at the land–ocean boundary associated with the Sundarban mangrove forest (21°32′ and 22°40′ N and 88°05′ and 89° E), along the NE Coast of the Bay of Bengal. The number of definable Bacillariophyceae species exceeded Dinophyceae taxa, and the total number of bloom-forming species declined from a maximum of ten in 2000 and a minimum of two in 2007. Blooms of the diatom Coscinodiscus radiatus were common in 2000 and 2007. Tide cycles and the onset of the monsoon season played important roles in diurnal and seasonal variability of phytoplankton. Phytoplankton biovolume showed seasonality, with the highest levels during post-monsoon periods and lowest levels during the monsoon period. Phytoplankton abundance was correlated to rainfall patterns, which may be altered by long-term changes in climate.  相似文献   
20.
Approximate mixing properties of the dominant calcium silicate end-member components of natural garnets, namely grossularite, andradite and uvarovite, have been derived through theoretical thermodynamic and crystal chemical analysis, and appropriate reduction of the available experimental data. The stability of the solid solution with respect to phase separation in the ternary system has been analyzed. Finally, a general model is presented as to the approximate mixing properties of multicomponent natural garnet solid solution involving substitutions in both eight and six coordinated sites.  相似文献   
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