Analysis of labile form of aluminum and heavy metals in bottom sediments from Kongsfjord, Isfjord, Hornsund fjords     

Marcin Frankowski  Anetta Zioła-Frankowska 《Environmental Earth Sciences》2014,71(3):1147-1158

The paper presents study results obtained for the bottom sediment samples of fjords Kongsfjord, Isfjord, Hornsund in the form of surface samples and their core profiles. The concentrations of labile form of aluminum and heavy metals were determined using the single-stage extraction with 3 mol L^?1 HCl. The obtained results allowed defining the occurrence of variability of labile aluminum form in the samples of bottom sediments of the studied fjords depending on the point and depth of sample collection. The conducted chemometric analysis allowed for the study of spatial variability of aluminum occurrence in the area of the investigated fjords. Based on the analysis, the correlations between aluminum and heavy metals were determined.  相似文献   

Luminescence and other spectroscopic properties of purple and green Cr-clinochlore     

Maria Czaja  Mariola Kądziołka-Gaweł  Radosław Lisiecki  Sabina Bodył-Gajowska  Zbigniew Mazurak 《Physics and Chemistry of Minerals》2014,41(2):115-126

For the first time ever, the luminescence spectra of Cr³⁺ centers in two chlorite crystals are presented. Chromium ions occupy the strong crystal-field site M4 in the brucite sheet and the intermediate crystal-field site in the inner octahedral sheet for purple and green chlorite, respectively. We discuss the influence of an effective positive charge on the Cr³⁺ ion and an effective negative charge of ligands on the differences in the values of the Dq and B parameters. It is concluded that the presence of Fe²⁺ ions and other point defects, as well as concentration quenching, causes the very short luminescence lifetimes of chromium ions.  相似文献   

Numerical modeling and neural networks to identify model parameters from piezocone tests: I. FEM analysis of penetration in two‐phase continuum     

Rafał F. Obrzud  Andrzej Truty  Laurent Vulliet 《国际地质力学数值与分析法杂志》2011,35(16):1703-1730

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A simplified analysis of interface failure under compressive normal stress and monotonic or cyclic shear loading     

Zenon Mrz  Marcin Bia&#x;as 《国际地质力学数值与分析法杂志》2005,29(4):337-368

Interface damage and delamination is usually accompanied by frictional slip at contacting interfaces under compressive normal stress. The present work is concerned with an analysis of progressive interface failure using the cohesive crack model with the critical stress softening and frictional traction present at the contact. Both monotonic and cyclic loadings are considered for anti‐plane shear of an elastic plate bonded to a rigid substrate by means of cohesive interface. An analytical solution can be obtained by neglecting the effect of minor shear stress component. The analysis of progressive delamination process revealed three solution types, namely: short, medium and long plate solutions. The long plate solution was obtained under an assumption of quasistatic progressive growth of the delamination zone. In view of snap back response, the quasistatic deformation process cannot be executed by either traction or displacement control. The states of frictional slip accompanied by shake down or incremental failure are distinguished in the case of cyclic loading, related to load amplitude and structural dimensions. The analysis provides a reference solution for numerical treatment of more complex cases. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Lateral bearing performance and mechanism of piles in the transition zone due to pit-in-pit excavation     

Tong  Liyuan  Li  Hongjiang  Ha  Si  Liu  Songyu 《Acta Geotechnica》2022,17(5):1935-1948

Acta Geotechnica - Excavation types of foundation pits for large-scale or special-purpose urban construction have been more and more complex, and the environmental safety issues caused by pit...  相似文献   

Periglacial and Fluvial Factors Controlling the Sedimentation of Pleistocene Breccia in NW Poland          下载免费PDF全文

Piotr Weckwerth  Małgorzata Pisarska‐Jamroży 《Geografiska Annaler: Series A, Physical Geography》2015,97(2):415-430

Breccias were investigated on the terrace of the Toruń‐Eberswalde ice‐marginal valley at Rozwarzyn (NW Poland). Breccia layers include soft‐sediment clasts with diameters between 2 and 256 mm and soft‐sediment megaclasts with diameters from 256 mm to 7 m. The shape of the soft‐sediment clasts and megaclasts (derived from frozen sediments) in the breccia is diverse: from angular and irregular in the case of debris‐flow breccias to slightly rounded and tabular in fluvial breccias. These two types of breccias were developed during the Late Weichselian when the periglacial climate favored extensive lateral erosion by currents of frozen braided channels in the ice‐marginal valley. The dual presence of breccias of fluvial and debris‐flow origin in channel deposits is unique for Quaternary sediments. Zones of breccias existed in the channels where scours and obstacle marks related to megaclasts developed. The study of breccias shed new light on the fluvial processes in ice‐marginal valleys during the Pleistocene and can be considered as diagnostic for fluvio‐periglacial conditions.  相似文献   

Relationship between the environmental and hydrogeological elements characterizing groundwater-dependent ecosystems in central Poland     

Ewa Krogulec  Sebastian Zabłocki 《Hydrogeology Journal》2015,23(7):1587-1602

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Numerical simulation and evaluation of Asian dust events observed in Mongolia in spring 2011     

Eun-Hee Lee  Erdenebayar Munkhtsetseg  Seung-Bum Kim  Jong-Chul Ha  Sang-Sam Lee  Youngsin Chun 《Asia-Pacific Journal of Atmospheric Sciences》2013,49(1):111-120

The Asian dust forecasting model, Mongolian Asian Dust Aerosol Model (MGLADAM), has been operated by the National Agency for Meteorology and Environmental Monitoring of Mongolia since 2010, for the forecast of Asian dust storms. In order to evaluate the performance of the dust prediction model, we simulated Asian dust events for the period of spring 2011. Simulated features were compared with observations from two sites in the dust source region of the Gobi desert in Mongolia, and in the downstream region in Korea. It was found that the simulated wind speed and friction velocity showed a good correlation with observations at the Erdene site (one of the sites in the Gobi desert). The results show that the model is proficient in the simulation of dust concentrations that are within the same order of magnitude and have similar start and end times, compared with PM₁₀ observed at two monitoring sites in the Gobi regions. Root Mean Square Error (RMSE) of the dust simulation ranges up to 200 μg m^?3 because of the high concentrations in source regions, which is three times higher than that in the downstream region. However, the spatial pattern of dust concentration matches well with dust reports from synoptic observation. In the downwind regions, it was found that the model simluated all reported dust cases successfully. It was also found that the RMSE in the downwind region increased when the model integration time increased, but that in the source regions did not show consistent change. It suggests that MGLADAM has the potential to be used as an operational dust forecasting model for predicting major dust events over the dust source regions as well as predicting transported dust concentrations over the downstream region. However, it is thought that further improvement in the emission estimation is necessary, including accurate predictions in surface and boundary layer meteorology. In the downwind regions, background PM₁₀ concentration is considerably affected by other aerosol species, suggesting that a consideration of anthropogenic pollutants will be required for accurate dust forecasting.  相似文献   

PM10 data assimilation over south Korea to Asian dust forecasting model with the optimal interpolation method     

Eun-Hee Lee  Jong-Chul Ha  Sang-Sam Lee  Youngsin Chun 《Asia-Pacific Journal of Atmospheric Sciences》2013,49(1):73-85

A data assimilation (DA) system using ground PM₁₀ observation for Asian Dust Aerosol Model version 2 (ADAM2), which is the operational dust forecasting model of Korea Meteorological Administration (KMA), has been developed with the optimal interpolation (OI) method. The observations are provided by the PM₁₀ network operated by KMA. Three DA experiments are performed to simulate a dust event observed in Korea from 1 March to 31 May 2009 with different assimilation cycles of 24 (DA24), 12 (DA12), and 06 hours (DA06). 48-hour forecasts from the adjusted Initial Condition (IC) of dust concentration are compared with control simulation (CTL) and observation from independent stations. It is found that CTL simulates spatial patterns of dust emitted and transported associated with a developing low pressure system over the dust source regions quite well, compared with satellite measurement. However, it appears that there is considerable uncertainty in estimating the concentration of dust. With IC adjustment, the model simulates improved dust concentration, showing considerably reduced RMSE, particularly for the prediction within 12 hours of forecast. At the same time, it is shown that the time interval of DA affects the predictability of ADAM2, so that DA06 appears to have better predictability within a 12-hour simulation, reducing RMSE by 50% compared with CTL. This suggests that assimilating PM₁₀ to the dust prediction model using OI has the potential to predict air quality in Korea when the cycle of assimilation is sufficiently short.  相似文献   

Integral Turbulence Statistics Over a Central European City Centre   总被引：2，自引：2，他引：0  

Krzysztof Fortuniak  Włodzimierz Pawlak  Mariusz Siedlecki 《Boundary-Layer Meteorology》2013,146(2):257-276

Atmospheric measurements over 5 years (2005–2010) at two sites in ?ód?, central Poland have been analyzed to develop a better understanding of turbulence in urban areas. Fast response wind velocity, temperature, humidity and CO₂ concentration were measured using sonic anemometers and gas analyzers, placed on narrow masts at 37 and 42 m above the ground. The measurements were used to calculate standard deviations of each parameter, and were then normalized according to local Monin–Obukhov similarity theory and plotted as a function of stability parameter ζ = z′/L. Results for the wind components show typical scaling with a power law with exponent ±1/3 in the free convection limit, and that approaches a constant value close to neutral stratification. For stable conditions, the constant value in the neutral limit remains the same for stability parameters lower than 0.1–0.2, then increases. The normalized standard deviation of temperature fits the ?1/3 law in the free convection limit, approaching a constant value within a stable limit. However, it exhibits hyperbolic characteristics for close to neutral stratification. The normalized standard deviations for humidity and CO₂ concentration exhibit scaling similar to the wind components in the unstable regime and remain constant in the stable domain. The results for the wind components and for temperature are in the range of various functions found in other studies. The absolute values for humidity and CO₂ concentration seem to be slightly higher, but only single examples of such investigations can be found in the literature.  相似文献