Hydrogeophysical characterization of the porous and fractured media (chalk aquifer in the Beauvais,France)     

Lahcen Zouhri  Pascale Lutz 《Environmental Earth Sciences》2016,75(4):343

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Assessment of toxicological status of a SW Mediterranean segment population of striped dolphin (Stenella coeruleoalba) using skin biopsy     

M. Cristina Fossi  Letizia Marsili  Giancarlo Lauriano  Caterina Fortuna  Simone Canese  Stefania Ancora  Claudio Leonzio  Teresa Romeo  Ruben Merino  Esteban Abad  Begoa Jimnez 《Marine environmental research》2004,58(2-5):269

Various studies have revealed high concentrations of contaminants such as organochlorines (OCs) and heavy metals in Mediterranean cetaceans. A geographical trend of contamination (PCBs and DDTs) has been found for striped dolphin (Stenella coeruleoalba). In this study we used a non-lethal approach (skin biopsy) to investigate bioaccumulation of OCs, including polychlorobiphenyls (PCBs), DDTs, polychlorodibenzo-p-dioxins (PCDDs), polychlorodibenzofurans (PCDFs), trace elements (Hg, Cd, Pb) and CYP1A activity (BPMO) in nine striped dolphins sampled in the Aeolian area (Sicily – Italy) in summer 2002. The arithmetic mean value of BPMO activity in this group was 43.46 AUF/g tissue/h. This value is approximately 3 times and 5 times lower, respectively, than the value found in the Ionian and in the Ligurian groups. Skin biopsies of striped dolphins emerged as a suitable material for assessing the toxicological status of the various Mediterranean groups.  相似文献   

Antioxidant efficiency and detoxification enzymes in spotted dogfish Scyliorhinus canicula     

Gorbi S  Pellegrini D  Tedesco S  Regoli F 《Marine environmental research》2004,58(2-5):293-297

Although elasmobranchs are widely distributed species, commonly found on sandy, gravely or muddy bottoms, several biological aspects of their metabolism still remain poorly investigated. In this work the efficiency of antioxidant system and detoxification enzymes were investigated in the coastal spotted dogfish Scyliorhinus canicula and in the red mullet Mullus barbatus for comparison with a teleost species. Organisms were sampled during a bottom trawl survey and analyzed for the biotransformation activity (EROD), levels of metallothioneins, catalase, glutathione S-transferases and total oxyradical scavenging capacity (TOSC) toward peroxyl radicals and hydroxyl radicals. EROD activity in the elasmobranchs was more than one order of magnitude lower than in the red mullets, while similar levels of metallothioneins were measured in these species. S. canicula showed significantly lower antioxidant enzymes and a more reduced efficiency in neutralizing *OH; on the other hand the scavenging capability toward ROO* was comparable in S. canicula and M. barbatus.  相似文献   

Evaluation of ecotoxicological effects of endocrine disrupters during a four-year survey of the Mediterranean population of swordfish (Xiphias gladius)   总被引：2，自引：0，他引：2  

Fossi MC  Casini S  Marsili L  Ancora S  Mori G  Neri G  Romeo T  Ausili A 《Marine environmental research》2004,58(2-5):425-429

In this project we investigated the ecotoxicological effects of endocrine disrupters in a four-year survey of the Mediterranean population of swordfish (Xiphias gladius). In the Mediterranean environment, top predators, such as swordfish, accumulate high concentrations of polyhalogenated aromatic hydrocarbons (PHAHs) and toxic metals, potentially incurring high toxicological risk. The effects of organochlorines and trace elements (Hg, Cd and Pb) in 192 swordfish specimens, caught in the Strait of Messina, Sicily, Italy, were investigated using vitellogenin (Vtg), zona radiata proteins (Zrp) and CYP1A (BPMO, EROD) activities. Vtg and Zrp were found to be dramatically induced in some adult male specimens, suggesting that this species is highly exposed to estrogens in the Mediterranean Sea. A role of organochlorines in this induction phenomenon is suggested by the statistically significant correlations between Zrp in plasma and PCB concentrations in muscle (p<0.032) and Vtg in plasma and PCB concentrations in liver (p<0.034) of male specimens. Levels of trace elements in liver were in the following ranges: Hg 1-22, Cd 1-28 and Pb 0-1.6 ppm d.w. These data indicate potential reproductive alterations in large pelagic fish and suggest the need for continuous monitoring to avoid reductions in the population of this fish species of high commercial and ecological interest.  相似文献   

Relationship between the optical properties of chromophoric dissolved organic matter and total concentration of dissolved organic carbon in the southern Baltic Sea region   总被引：10，自引：0，他引：10  

Giovanni M. Ferrari  Mark D. Dowell  Stefania Grossi  Cristina Targa 《Marine Chemistry》1996,55(3-4)

Absorption and fluorescence of chromophoric dissolved organic matter (CDOM) and dissolved organic carbon (DOC) measurements were performed during three oceanographic surveys in 1994 in the southern Baltic Sea (Polish area of the Baltic Proper). DOC was measured both by high-temperature catalytic oxidation (HTCO) and low-temperature oxidation (LTO) conventional persulphate methods. CDOM fluorescence was shown to be highly correlated with absorption, with the same regression parameters, despite the seasonal change in different hydrographic conditions and the fluorescence quantum yield variations (1.23 ± 0.07 in April and 0.97 ± 0.12 in September). The results show a good correlation between the optical parameters and DOC although ˜ 70% of the DOC does not display significant absorption in the UV-visible range (350–750 nm). The non-absorbing DOC measured with HTCO method appears unaffected by seasonal changes. Consequently, total DOC can be predicted by optical methods using remote sensing techniques. The non-absorbing DOC measured by LTO method varies from 62% (April) to 76% (September), which implies that there is requirement for estimates on a seasonal basis.  相似文献   

Evaluation of ecotoxicological effects of endocrine disrupters during a four-year survey of the Mediterranean population of swordfish (Xiphias gladius)     

M. Cristina Fossi  Silvia Casini  Letizia Marsili  Stefania Ancora  Gabriele Mori  Giovanni Neri  Teresa Romeo  Antonella Ausili 《Marine environmental research》2004,58(2-5):425

In this project we investigated the ecotoxicological effects of endocrine disrupters in a four-year survey of the Mediterranean population of swordfish (Xiphias gladius). In the Mediterranean environment, top predators, such as swordfish, accumulate high concentrations of polyhalogenated aromatic hydrocarbons (PHAHs) and toxic metals, potentially incurring high toxicological risk. The effects of organochlorines and trace elements (Hg, Cd and Pb) in 192 swordfish specimens, caught in the Strait of Messina, Sicily, Italy, were investigated using vitellogenin (Vtg), zona radiata proteins (Zrp) and CYP1A (BPMO, EROD) activities. Vtg and Zrp were found to be dramatically induced in some adult male specimens, suggesting that this species is highly exposed to estrogens in the Mediterranean Sea. A role of organochlorines in this induction phenomenon is suggested by the statistically significant correlations between Zrp in plasma and PCB concentrations in muscle (p<0.032) and Vtg in plasma and PCB concentrations in liver (p<0.034) of male specimens. Levels of trace elements in liver were in the following ranges: Hg 1–22, Cd 1–28 and Pb 0–1.6 ppm d.w. These data indicate potential reproductive alterations in large pelagic fish and suggest the need for continuous monitoring to avoid reductions in the population of this fish species of high commercial and ecological interest.  相似文献   

Orbital imprint on Holocene palaeohydrological variations in west‐central Europe as reflected by lake‐level changes at Cerin (Jura Mountains,eastern France)     

Michel Magny  Gilles Bossuet  Pascale Ruffaldi  Aurélie Leroux  Jacques Mouthon 《第四纪科学杂志》2011,26(2):171-177

This paper presents a lake‐level record for the Holocene at Lake Cerin (Jura Mountains, eastern France). It is based on a range of sedimentological techniques validated in previous studies, with a combination of systematic lithostratigraphic investigations of the infillings accumulated in the lacustrine basin, and sediment analyses of two selected cores. The chronology is based on 10 radiocarbon dates and pollen stratigraphy. On a millennial scale, the Cerin lake‐level record shows three distinct successive phases characterised by higher lake‐level conditions until ca. 9000 cal. a BP, followed by a maximal lowering at ca. 9000–8500 cal. a BP, and a progressive rise until the present. This rise was punctuated by centennial‐scale fluctuations, with major events around 4000, 2800 and after 1500 cal. a BP. Considered on a multimillennial scale, the general pattern of palaeohydrological changes reconstructed at Cerin reflects the impact of orbitally driven summer insolation. This is in agreement with other regional and extra‐regional palaeoclimatic records, although every record shows peculiarities in timing and shape depending on the proxy used for reconstruction. In this general context, centennial to multicentennial oscillations appear to have been second‐order events in comparison with the major influence of the orbital factor. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

An assessment of large-scale flood modelling based on LiDAR data     

Guénolé Choné  Pascale M. Biron  Thomas Buffin-Bélanger  Iulia Mazgareanu  Jeff C. Neal  Christopher C. Sampson 《水文研究》2021,35(8):e14333

Large-scale flood modelling approaches designed for regional to continental scales usually rely on relatively simple assumptions to represent the potentially highly complex river bathymetry at the watershed scale based on digital elevation models (DEMs) with a resolution in the range of 25–30 m. Here, high-resolution (1 m) LiDAR DEMs are employed to present a novel large-scale methodology using a more realistic estimation of bathymetry based on hydrogeomorphological GIS tools to extract water surface slope. The large-scale 1D/2D flood model LISFLOOD-FP is applied to validate the simulated flood levels using detailed water level data in four different watersheds in Quebec (Canada), including continuous profiles over extensive distances measured with the HydroBall technology. A GIS-automated procedure allows to obtain the average width required to run LISFLOOD-FP. The GIS-automated procedure to estimate bathymetry from LiDAR water surface data uses a hydraulic inverse problem based on discharge at the time of acquisition of LiDAR data. A tiling approach, allowing several small independent hydraulic simulations to cover an entire watershed, greatly improves processing time to simulate large watersheds with a 10-m resampled LiDAR DEM. Results show significant improvements to large-scale flood modelling at the watershed scale with standard deviation in the range of 0.30 m and an average fit of around 90%. The main advantage of the proposed approach is to avoid the need to collect expensive bathymetry data to efficiently and accurately simulate flood levels over extensive areas.  相似文献   

Data analysis pipeline for EChO end-to-end simulations     

Ingo P. Waldmann  E. Pascale 《Experimental Astronomy》2015,40(2-3):639-654

Atmospheric spectroscopy of extrasolar planets is an intricate business. Atmospheric signatures typically require a photometric precision of 1×10^?4 in flux over several hours. Such precision demands high instrument stability as well as an understanding of stellar variability and an optimal data reduction and removal of systematic noise. In the context of the EChO mission concept, we here discuss the data reduction and analysis pipeline developed for the EChO end-to-end simulator EChOSim. We present and discuss the step by step procedures required in order to obtain the final exoplanetary spectrum from the EChOSim ‘raw data’ using a simulated observation of the secondary eclipse of the hot-Neptune 55 Cnc e.  相似文献   

Field study and laboratory experiments of bubble plumes in shallow seas as analogues of sub-seabed CO₂ leakages     

Stefania Espa  Giorgio Caramanna  Vanda Bouché 《Applied Geochemistry》2010

To understand the effects of increased levels of CO₂ on the marine realm, it is possible to study areas where, for natural reasons, there are emissions of CO₂ from the seabed. One of these areas is located east of Panarea Island (Aeolian Islands – Southern Tyrrhenian Sea – Italy). Here, the volcanic activity that characterizes the Aeolian archipelago causes a continuous release of CO₂ (up to 98% of the total gas) from several vents on the seafloor in shallow water. This area was studied by means of surface techniques and direct SCUBA diving surveys; the data presented refers to a field campaign performed in 2008. To collect the necessary data, some dedicated sampling and measuring techniques were developed for use in an underwater environment. The chemistry of the fluids and their influence on the water body was determined via logs and transects in the field and by gas-chromatographic and liquid-chromatographic laboratory analysis. The flux from some of the main gas vents was also measured directly underwater. Furthermore, some laboratory experiments in a two-layer stratified fluid were conducted to understand the main features of the physical interaction of a gas plume with the surrounding environment. Both field and laboratory experiments show that there is a development of a pseudo-convective cell around the rising plume with the formation of vortices that act as a physical barrier thus reducing the interaction between the plume and the surrounding water.  相似文献