During the past quarter century the study of air-sea interaction has evolved from a small branch of marine climatology to play a key role in the modelling of the coupled system of ocean and atmosphere. Knowledge of air- sea fluxes has grown, based on Monin-Obukhov similarity theory for surface boundary layers and on direct and indirect techniques of measuring the fluxes. This has been the basis for providing boundary conditions needed to couple atmospheric and oceanic circulation models that are used to forecast weather and climate. An overview of current understanding is followed by a discussion of parameterisation schemes and a chronicle of some of the experimental work that has tested theories and quantified their conclusions. 相似文献
53 local earthquakes recorded at 2.5 km depth in the Cajon Pass scientific borehole are analysed for shear-wave splitting. The time delays between the split shear waves can be positively identified for 32 of the events. Modelling these observations of polarizations and time delays using genetic algorithms suggests that the anisotropic structure near Cajon Pass has orthorhombic symmetry. The polarization of the shear waves and the inferred strike of the stress-aligned fluid-filled intergranular microcracks and pores suggests that the maximum horizontal compressional stress direction is approximately N13°W. This is consistent with previous results from earthquake source mechanisms and the right-lateral strike-slip motion on the nearby San Andreas Fault, but not with stresses measured within the uppermost 3 km of the borehole. This study suggests that the San Andreas Fault is driven by deeper tectonic stresses and the present understanding of a weak and frictionless San Andreas Fault may need to be modified. The active secondary faulting and folding close to the fault are probably driven by the relatively shallow stress as measured in the 3.5 km deep borehole. 相似文献
Peroxyacetyl nitrate (PAN,CH3C(O)O2NO2) has been measured inthe polluted boundary layer and free troposphere by thermal conversion tonitrogen dioxide (NO2) followed by detection of thedecomposition product with a Scintrex LMA-3 NO2-luminolinstrument. Following laboratory tests of the efficiency of PAN conversionand investigations of possible interferences, the technique was evaluated atthe West Beckham TOR (Tropospheric Ozone Research) Station near the northNorfolk coast in Eastern England between September 1989 and August 1990. PANmeasured by the new technique was reasonably well correlated with PANrecorded using electron capture gas chromatography (EC/GC). PAN was alsowell correlated with ozone (O3) in the summer months. Springand autumn episodes of simultaneously high concentrations of PAN andO3 were examined in conjunction with air parcelback-trajectories and synoptic- and local-scale meteorology in a study ofthe sources of photooxidants on the east coast of England. Spring-timemeasurements of PAN made in the free troposphere in a light aircraft ataltitudes up to 3.1 km showed the presence of 0.54 and 0.26 ppbv PAN inpolar maritime and mid-latitude oceanic air masses, respectively. Thetechnique is particularly suited to airborne applications because potentialinterferences are minimised and the frequency of measurements is higher thangenerally achieved with EC/GC methods. 相似文献
Eighty ferromanganese nodules from a wide variety of marine and fresh-water environments have been analyzed by electron spin resonance spectroscopy. The purpose has been to gain information on the forms in which the major constituents of manganese nodules are present. Contributions to ESR spectra of the nodules come mainly from Mn2+ and Fe3+. Deep-sea samples generally showed only broad resonance lines, and those with larger peaks close to g = 2.0 are believed to contain more Mn2+ than others. Some Antarctic and fresh-water nodules lack a strong Mn2+ resonance and have a peak around g = 4.0 which is most likely tetrahedral Fe3+. A number of smaller peaks in several samples could not be readily interpreted in terms of contributions from individual ionic species because of fundamental problems in preparing standards having the ion of interest in the same micro-environment as it experiences in the nodules. 相似文献
The mantle xenoliths included in Quaternary alkaline volcanics from the Manzaz-district (Central Hoggar) are proto-granular, anhydrous spinel lherzolites. Major and trace element analyses on bulk rocks and constituent mineral phases show that the primary compositions are widely overprinted by metasomatic processes. Trace element modelling of the metasomatised clinopyroxenes allows the inference that the metasomatic agents that enriched the lithospheric mantle were highly alkaline carbonate-rich melts such as nephelinites/melilitites (or as extreme silico-carbonatites). These metasomatic agents were characterized by a clear HIMU Sr–Nd–Pb isotopic signature, whereas there is no evidence of EM1 components recorded by the Hoggar Oligocene tholeiitic basalts. This can be interpreted as being due to replacement of the older cratonic lithospheric mantle, from which tholeiites generated, by asthenospheric upwelling dominated by the presence of an HIMU signature. Accordingly, this rejuvenated lithosphere (accreted asthenosphere without any EM influence), may represent an appropriate mantle section from which deep alkaline basic melts could have been generated and shallower mantle xenoliths sampled, respectively. The available data on lherzolite xenoliths and alkaline lavas (including He isotopes, Ra < 9) indicate that there is no requirement for a deep plume anchored in the lower mantle, and that sources in the upper mantle may satisfactorily account for all the geochemical/petrological/geophysical evidence that characterizes the Hoggar swell. Therefore the Hoggar volcanism, as well as other volcanic occurrences in the Saharan belt, are likely to be related to passive asthenospheric mantle uprising and decompression melting linked to tensional stresses in the lithosphere during Cenozoic reactivation and rifting of the Pan–African basement. This can be considered a far-field foreland reaction of the Africa–Europe collisional system since the Eocene. 相似文献
Mantle xenoliths from the Olot volcanic district (NE Spain) comprise a bi-modal suite consisting of protogranular spinel lherzolites (cpx 12–14%) sometimes with pargasitic amphibole, and highly refractory spinel harzburgites (cpx ≤ 1%) with coarse-grained granular textures. The lherzolites range from slightly depleted to moderately LREE-enriched with flat HREE patterns between 1.5 and 2.7 × chondrite (Ch). In contrast, the harzburgites are extremely depleted in HREE (down to 0.2 × Ch) and strongly LREE-enriched (LaN/YbN = 12.3–17.2). LA-ICP-MS analyses of clinopyroxene and amphibole of the lherzolites highlight variable degrees of LREE depletion (HREE up to 13 × Ch, LaN/YbN down to 0.01), with the exception of a single sample in which both clinopyroxene and amphibole are LREE-enriched (LaN/YbN up to 19). In the harzburgites, clinopyroxenes display totally different REE distributions, characterized by extreme HREE depletion (down to 0.4 × Ch) and upward convex positively fractionated middle-light REE patterns (NdN/YbN up to 20.7 × Ch; LaN/YbN up to 12 × Ch). Sr–Nd–Hf isotopic data for both whole-rocks and cpx separates, coherently indicate depleted mantle (DM) compositions for the lherzolites (εSr = − 15 to − 26, εNd = + 9 to + 17, εHf = + 18 to + 68) and enriched mantle (EM) compositions for the harzburgites (εSr = − 10 to + 36, εNd = − 1 to − 6, εHf = + 3 to + 8). Modelling of the clinopyroxene REE data and isotopic systematics suggest that some lherzolites were affected by pre-Paleozoic (0.6–1 By) low-degree partial melting processes, while others probably reflect some extent of refertilization of the mantle protolith by metasomatizing melts similar to the Triassic rift-related tholeiites reported from several Pyrenean localities. The harzburgites represent extreme refractory residua, resulting from a complex depletion history due to multistage melt extraction as often observed in the cratonic mantle. The distinctive REE patterns and isotopic systematics of their clinopyroxenes suggest that the harzburgites were formed by the interaction of an ultra-depleted peridotite matrix with highly alkaline basic melts similar in composition to the Permo-Triassic alkaline lamprophyres which are widespread within the Iberian plate. Lherzolites possibly represent younger lithosphere (accreted asthenosphere?) up-lifted and juxtaposed to the older subcontinental lithospheric mantle (harzburgites) during the post-Variscan rifting of the Iberian margin. These two genetically different, but adjoining, mantle domains intimately mingled along the northern Iberian margin during the subsequent plate convergence processes, leading to the close association of harzburgites and lherzolites observed in the Olot mantle xenoliths and in some Pyrenean peridotite massifs. 相似文献
Major- and trace-element analyses of garnets from heavy-mineral concentrates have been used to derive the compositional and thermal structure of the subcontinental lithospheric mantle (SCLM) beneath 16 areas within the core of the ancient Laurentian continent and 11 areas in the craton margin and fringing mobile belts. Results are presented as stratigraphic sections showing variations in the relative proportions of different rock types and metasomatic styles, and the mean Fo content of olivine, with depth. Detailed comparisons with data from mantle xenoliths demonstrate the reliability of the sections.
In the Slave Province, the SCLM in most areas shows a two-layer structure with a boundary at 140–160 km depth. The upper layer shows pronounced lateral variations, whereas the lower layer, after accounting for different degrees of melt-related metasomatism, shows marked uniformity. The lower layer is interpreted as a subcreted plume head, added at ca. 3.2 Ga; this boundary between the layers rises to <100 km depth toward the northern and southern edges of the craton. Strongly layered SCLM suggests that plume subcretion may also have played a role in the construction of the lithosphere beneath Michigan and Saskatchewan.
Outside the Slave Province, most North American Archon SCLM sections are less depleted than similar sections in southern Africa and Siberia; this may reflect extensive metasomatic modification. In E. Canada, the degree of modification increases toward the craton margin, and the SCLM beneath the Kapuskasing Structural Zone is typical of that beneath Proterozoic to Phanerozoic mobile belts.
SCLM sections from several Proterozoic areas around the margin of the Laurentian continental core (W. Greenland, Colorado–Wyoming district, Arkansas) show discontinuities and gaps that are interpreted as the effects of lithosphere stacking during collisional orogeny. Some areas affected by Proterozoic orogenesis (Wyoming Craton, Alberta, W. Greenland) appear to retain buoyant, modified Archean SCLM. Possible juvenile Proterozoic SCLM beneath the Colorado Plateau is significantly less refractory. The SCLM beneath the Kansas kimberlite field is highly melt-metasomatised, reflecting its proximity to the Mid-Continent Rift System.
A traverse across the continent shows that the upper part of the cratonic SCLM is highly magnesian; the decrease in mg# with depth is interpreted as the cumulative effect of metasomatic modification through time. The relatively small variations in seismic velocity within the continental core largely reflect the thickness of this depleted layer. The larger drop in seismic velocity in the surrounding Proton and Tecton belts reflects the closely coupled changes in SCLM composition and geotherm. 相似文献