Factor and cluster analysis of water quality data of the groundwater wells of Kushtia, Bangladesh: Implication for arsenic enrichment and mobilization     

Md. Golzar Hossain  A. H. M. Selim Reza  Mst. Lutfun-Nessa  Syed Samsuddin Ahmed 《Journal of the Geological Society of India》2013,81(3):377-384

The study area is located in the southwestern part of Bangladesh. Twenty-six groundwater samples were collected from both shallow and deep tube wells ranging in depth from 20 to 60 m. Multivariate statistical analyses including factor analysis, cluster analysis and multidimensional scaling were applied to the hydrogeochemical data. The results show that a few factors adequately represent the traits that define water chemistry. The first factor of Fe and HCO₃ is strongly influenced by bacterial Fe (III) reduction which would raise both Fe and HCO₃ concentrations in water. Na, Cl, Ca, Mg and PO₄ are grouped under the second factor representing the salinity sources of waters. The third factor, represented by As, Mn, SO₄ and K is related to As mobilization processes. Cluster analysis has been applied for the interpretation of the groundwater quality data. Initially Piper methods have been employed to obtain a first idea on the water types in the study area. Hierarchical cluster analysis was carried out for further classification of water types in the study area. Twelve components, namely, pH, Fe, Mn, As, Ca, Mg, Na, K, HCO₃, Cl, SO₄ and NO₃ have been used for this purpose. With hierarchical clustering analysis the water samples have been classified into 3 clusters. They are very high, high and moderately As-enriched groundwater as well as groundwater with elevated SO₄.  相似文献   

Simple and multiple regression models for relationship between electrical resistivity and various soil properties for soil characterization     

Fahad Irfan Siddiqui  Syed Baharom Azahar Bin Syed Osman 《Environmental Earth Sciences》2013,70(1):259-267

Precise determination of engineering properties of soil is essential for proper design and successful construction of any structure. The conventional methods for determination of engineering properties are invasive, costly and time-consuming. Electrical resistivity survey is an attractive tool for delineate subsurface properties without soil disturbance. Reliable correlations between electrical resistivity and other soil properties will enable us to characterize the subsurface soil without borehole sampling. This paper presents the correlations of electrical resistivity with various properties of soil. Soil investigations, field electrical resistivity survey and laboratory electrical resistivity measurements were conducted. The results from electrical resistivity tests (field and laboratory) and laboratory tests were analyzed together to understand the interrelation between electrical resistivity and various soil properties. The test results were evaluated using simple and multiple regression analysis. From the data analysis, significant quantitative and qualitative correlations have been obtained between resistivity and moisture content, friction angle and plasticity index. Weaker correlations have been observed for cohesion, unit weight of soil and effective size (D ₁₀).  相似文献   

Assessment of Trace Metal Contamination of Drinking Water in the Pearl Valley,Azad Jammu and Kashmir     

Saboor Javaid  Syed Ghulam Sarwar Shah  Abdul Jabbar Chaudhary  Mohammad Haleem Khan 《洁净——土壤、空气、水》2008,36(2):216-221

The aim of this study was to assess trace metal contamination of drinking water in the Pearl Valley, Azad Jammu and Kashmir (Pakistan). The objectives were to determine physical properties and the dissolved concentration of five trace metals, i. e., lead, copper, nickel, zinc, and manganese, in drinking water samples collected from various sites of municipal water supply, natural water springs and wells in the valley. Concentrations of the metals in the water samples were determined by flame atomic absorption spectrometry. Results showed physical parameters, i. e., appearance, taste and odor within acceptable limits and pH was between 5.5 and 7.0. The observed concentrations of the metals varied between sources of water samples and between sampling sites. Maximum dissolved concentration observed was 4.7 mg/L for Pb and Mn, 4.6 mg/L for Zn, 2.9 mg/L for Ni and 2.8 mg/L for Cu. The observed concentrations of the metals were compared with the World Health Organization's guideline values for drinking water. Overall, the quality of water samples taken from the water springs at Mutyal Mara and Bonjosa was good; however, the water quality was unsuitable for drinking in Kiraki, Kharick, and Pothi Bala localities particularly. Finally, the authors discuss possible causes for increased concentrations of the trace metals in drinking water in the study area.  相似文献   

Competitive Sorption of Antimony with Zinc,Nickel, and Aluminum in a Seaweed Based Fixed‐bed Sorption Column     

Adil Bakir  Peter McLoughlin  Syed A. M. Tofail  Eddy Fitzgerald 《洁净——土壤、空气、水》2009,37(9):712-719

The removal of heavy metals such as Ni(II), Zn(II), Al(III), and Sb(III) from aqueous metal solutions was investigated using novel, cost effective, seaweed derived sorbents. Studies with a laboratory scale fixed‐bed sorption column, using a seaweed waste material (referred to as waste Ascophyllum product (WAP)) from the processing of Ascophyllum nodosum as biosorbent, demonstrated high removal efficiencies (RE) for a variety of heavy metals including Ni(II), Zn(II) and Al(III), with 90, 90 and 74% RE achieved from initial 10 mg/L metal solutions, respectively. The presence of Sb(III) in multi component metal solutions suppressed the removal of Ni(II), Zn(II) and Al(III), reducing the RE to 28, 17 and 24%, respectively. The use of Polysiphonia lanosa as a biosorbent showed a 67% RE for Sb(III), both alone and in combination with other metals. Potentiometric and conductometric titrations, X‐ray photoelectron and mid‐infrared spectroscopic analysis demonstrated that carboxyl, alcohol, sulfonate and ether groups were heavily involved in Sb(III) binding by P. lanosa. Only carboxyl and sulfonate groups were involved in Sb(III) binding by WAP. Furthermore, a greater amount of weak acidic groups (mainly carboxylic functions) were involved in Sb(III) binding by P. lanosa, compared to WAP which involved a greater concentration of strong acidic groups (mainly sulfonates).  相似文献   

Optimal site selection for an optical-astronomical observatory in Pakistan using Multicriteria Decision Analysis     

Daniyal  Syed Jamil Hassan Kazmi 《天文和天体物理学研究(英文版)》2019,(9)

An astronomical observatory is the core component of any astronomical research facility that connects astronomers with their lab: the Cosmos. The research quality of an astronomical facility is rooted in the precision of data, collected by its observatory. For optimal performance, an observatory is sited while considering certain astronomical, environmental, geological and social parameters. This study aims to identify the potential sites in Pakistan for locating an optical-astronomical observatory using the Multicriteria Decision Analysis(MCDA) technique. The study uses the Analytic Hierarchy Process(AHP) for deriving the influence weights of nine evaluation criteria: Photometric Night Fraction; Night-time Sky Brightness;Sky Transparency; Aerosol Concentration; Altitude; Terrain Slope; Accessibility; Seismic Vulnerability;and Landuse/Land Cover. On the basis of experts' opinions and previous studies, the evaluation criteria have been ordered in two possible preference sequences for identifying their influence weights with respect to each other for taking part in MCDA. Consequently, the process of MCDA identified certain areas with respect to each preference sequence, whereas some areas were found to be suitable according to both preference sequences. The study synchronizes the required eclectic data into an evaluation matrix that augments the process of astronomical site selection. In the future, this study will be useful for astronomical societies and for furthering astronomical research in the country.  相似文献   

A Major Geoeffective CME from NOAA 12371: Initiation,CME–CME Interactions,and Interplanetary Consequences     

Bhuwan Joshi  M. Syed Ibrahim  A. Shanmugaraju  D. Chakrabarty 《Solar physics》2018,293(7):107

In this article, we present a multi-wavelength and multi-instrument investigation of a halo coronal mass ejection (CME) from active region NOAA 12371 on 21 June 2015 that led to a major geomagnetic storm of minimum \(\mathrm{Dst} = -204\) nT. The observations from the Atmospheric Imaging Assembly onboard the Solar Dynamics Observatory in the hot EUV channel of 94 Å confirm the CME to be associated with a coronal sigmoid that displayed an intense emission (\(T \sim6\) MK) from its core before the onset of the eruption. Multi-wavelength observations of the source active region suggest tether-cutting reconnection to be the primary triggering mechanism of the flux rope eruption. Interestingly, the flux rope eruption exhibited a two-phase evolution during which the “standard” large-scale flare reconnection process originated two composite M-class flares. The eruption of the flux rope is followed by the coronagraphic observation of a fast, halo CME with linear projected speed of 1366 km?s^?1. The dynamic radio spectrum in the decameter-hectometer frequency range reveals multiple continuum-like enhancements in type II radio emission which imply the interaction of the CME with other preceding slow speed CMEs in the corona within \(\approx10\)?–?\(90~\mbox{R} _{\odot}\). The scenario of CME–CME interaction in the corona and interplanetary medium is further confirmed by the height–time plots of the CMEs occurring during 19?–?21 June. In situ measurements of solar wind magnetic field and plasma parameters at 1 AU exhibit two distinct magnetic clouds, separated by a magnetic hole. Synthesis of near-Sun observations, interplanetary radio emissions, and in situ measurements at 1 AU reveal complex processes of CME–CME interactions right from the source active region to the corona and interplanetary medium that have played a crucial role towards the large enhancement of the geoeffectiveness of the halo CME on 21 June 2015.  相似文献   

A comprehensive study on the surface chemistry of particulate matter collected from Jeddah,Saudi Arabia     

Asim Jilani  Syed Zajif Hussain  Mohd Hafiz Dzarfan Othman  Usama Zulfiqar  Muhammad Bilal Shakoor  Imran Ullah Khan  Javed Iqbal  Attieh A. Al-Ghamdi  Ahmed Alshahrie 《Journal of Atmospheric Chemistry》2018,75(3):271-283

In this work, the X-ray Photoelectron Spectroscopy (XPS) technique is utilized to analyze the surface chemical composition of particulate matter (PM) which was collected from various locations at Jeddah, Saudi Arabia. The main elements found on the surface of PM are carbon (C), oxygen (O) and silicon (Si) with combined percentage of 89.4–94.9 while traces of nitrogen (N), calcium (Ca), aluminum (Al), sodium (Na), chlorine (Cl), manganese (Mg), and sulfur (S) were also present. The analyzed XPS chemical state of C, O and Si was further used to determine their bonding with other elements occurring over the surface of PM. Carbon was found in the form of carbides (18.86%), fluorides (2.39%) and carbonates (78.75%); oxygen was observed as oxides (21.05%) and hydroxides (73.42%) of other metals; and silicon was detected as silicones (12.16%), nitrides (82.53%) and silicates (5.25%). The particle size of a PM is also of great concern for health issues, and thus has been investigated by the Field Emission Scanning Electron Microscope (FESEM). The Energy Dispersive X-ray Spectroscopy (EDS) was employed for cross verification of detected elements by XPS.  相似文献   

Numerical simulation of groundwater flow in the Peshawar intermontane basin, northwest Himalayas     

Asim Yousafzai  Yoram Eckstein  Peter Dahl 《Hydrogeology Journal》2008,16(7):1395-1409

The hypothesis that abnormal fluid pressure is generated in basins under tectonic compression is tested. The study site, between the Main Karakoram Thrust (MKT), Main Mantle Thrust (MMT), Main Central Thrust (MCT), Main Boundary Thrust (MBT) and Salt Range Thrust (SRT) in northwest Pakistan, is experiencing a tectonic compression of 90 MPa. The Peshawar basin is a broad, oval depression comprising a thick sequence of lacustrine, deltaic and fluvial sediments overlain by loess and alluvial deposits dated at 2.8–0.6 Ma. It is surrounded by the Precambrian and Tertiary intrusive and metamorphic rocks on the north and sedimentary rocks of Paleogene and Neogene to the south. The basin was divided into four hydrostratigraphic units for numerical simulations using the three-dimensional finite-element model FEMWATER within groundwater modeling system (GMS) ver. 5.1. Simulated pressure head data have been compared with the field measurements of hydraulic heads. Transient simulations indicate that topography alone is not sufficient to induce the pressure heads observed in the field, generating consistently positive residuals 0.98–2.90 m over the topography-driven flow. The residuals disappeared after inclusion of the elastic properties of the four hydrostratigraphic units in the model, suggesting the effect of tectonic compression.  相似文献   

Integrated geo-microbial and trace metal anomalies for detection of hydrocarbon microseepage in Ahmedabad block of Cambay basin,India     

M. A. Rasheed  P. L. Srinivasa Rao  Annapurna Boruah  Syed Zaheer Hasan  Bougi Mohamoud Mohamed Seddik  Disha Pandey  T. Harinarayana 《Journal of the Geological Society of India》2016,88(4):433-439

The aim of the present work is to define the geo-microbial signatures along with trace metals, and to investigate whether the geo-microbial anomalies have correlation with trace metal anomalies in Ahmedabad block of Cambay basin. The surface geochemical techniques are based on seepage of light hydrocarbon gases from the oil and gas pools to the shallow surface and can bring up near-surface oxidation reduction zones that favor the development of a diverse array of chemical and mineralogical changes. The paper reports the role of hydrocarbon microseepage in surface alterations of trace metal concentrations and hydrocarbon oxidizing bacteria and its interrelationship. For the purpose a total of 90 soil samples are collected in grid pattern of 2 x 2 km interval. The paper reports the chemical alterations associated with trace metals in soils that are related to hydrocarbon microseepages above some of the major oil and gas fields of this petroliferous region. The concentrations of V (0 to149 ppm), Cr (2 to 192 ppm), Cu (4 to 171 ppm), Se (98 to 440 ppm), Zn (56 to 1215 ppm) are obtained. It is observed that the concentrations of trace elements are tremendously increased when they are compared with their normal concentrations in soils. In this study the hydrocarbon oxidizing bacterial counts ranged between 1.0 x 10³ and 1.59 x 10⁶ cfu/g of soil sample respectively. The attempt has made for the first time, which revealed good correlation as both these anomalies are found as apical in relation. Integrated studies between trace elements and hydrocarbon oxidizing bacterial anomalies showed positive correlation with existing oil and gas wells in the study area.  相似文献   

Elimination of Interferences in the Determination of Palladium,Platinum and Rhodium Mass Fractions in Moss Samples using ICP‐MS/MS          下载免费PDF全文

Terhi Suoranta  Syed N. H. Bokhari  Thomas Meisel  Matti Niemelä  Paavo Perämäki 《Geostandards and Geoanalytical Research》2016,40(4):559-569

Moss samples (Pleurozium schreberi) exposed to traffic‐related emission of Pd, Pt and Rh were analysed in this study. Successful elimination of interferences was achieved in the determination of Pd, Pt and Rh mass fractions in these samples using inductively coupled plasma‐tandem mass spectrometry (ICP‐MS/MS). Based on the results, a reliable determination of Pd, Pt and Rh mass fractions in microwave‐digested moss samples was obtained using ammonia (10% NH₃ in He) in the collision/reaction cell when ¹⁰³Rh was measured either on‐mass (103→103) or with mass‐shift (103→171) and mass‐shifts for ¹⁰⁸Pd (108→159) and ¹⁹⁵Pt (195→229) were used. The ICP‐MS/MS procedure was validated using BCR‐723 (road dust) as a reference material. In addition, a good agreement between the ICP‐MS/MS results and the results obtained with cloud point extraction and quadrupole ICP‐MS was observed for the moss samples.  相似文献