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In‐situ aerosol measurements were performed in the northern hemispheric stratosphere up to altitudes of 21 km between 13 November 1996 and 14 January 1997, inside and outside of the polar vortex during the Airborne Polar Experiment (APE) field campaign. These are measurements of particle size distributions with a laser optical particle counter of the FSSP‐300 type operated during 9 flights on the Russian M‐55 high‐altitude research aircraft Geophysika. For specific flights, the FSSP‐300 measurements are compared with balloon‐borne data (launched from Kiruna, Sweden). It was found that the stratospheric aerosol content reached levels well below the background concentrations measured by the NASA operated ER‐2 in 1988/89 in the northern hemisphere. During the APE campaign, no PSC particle formation was observed at flight altitudes although the temperatures were below the NAT condensation point during one flight. The measured correlations between ozone and aerosol give an indication of the subsidence inside the 1996/97 polar vortex. Despite the lower aerosol content in the winter 1996/97 compared to the 1989 background, the heterogeneous reactivity of the aerosol (as calculated from the measured data with additional model input) is comparable. This is due to the dependency of the reactive uptake coefficients on the atmospheric water vapor content. Under the described assumptions the reaction rates on the background aerosol are significantly smaller than for competing gas phase chlorine activation, as can be expected for stratospheric background conditions especially inside the polar vortex.  相似文献   
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The occurrence of diatoms (both marine and freshwater) in sediments beneath the West Antarctic Ice Sheet (WAIS) is suggestive of past ice-sheet collapse. However, it is not the only model explaining such occurrences. We propose another mechanism for introducing diatoms beneath ice sheets by considering the fate of a diatom placed (by eolian processes) on top of an ice sheet. Mathematical modeling indicates that the route the diatom will take through the ice sheet is dictated by the basal melting rate. If no basal melting takes place, flowlines will crop out at the ice-sheet margin. However, if basal melting is as low as 0.01 m/yr the trajectories of all Howlines except for those nearest the margin will intersect the bed, with those diatoms deposited near the dome reaching the bed about halfway down the Howband. Larger values of basal melting lead to the diatoms reaching the bed even faster and closer to the point of origin. In light of these results, the presence of diatoms in sediments beneath the WAIS does not lead to a unique solution; it is not necessary to invoke past ice-sheet collapse to account for their presence.  相似文献   
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Abstract— Knowledge of regolith depth structure is important for a variety of studies of the Moon and other bodies such as Mercury and asteroids. Lunar regolith depths have been estimated using morphological techniques (i.e., Quaide and Oberbeck 1968; Shoemaker and Morris 1969), crater counting techniques (Shoemaker et al. 1969), and seismic studies (i.e., Watkins and Kovach 1973; Cooper et al. 1974). These diverse methods provide good first order estimates of regolith depths across large distances (tens to hundreds of kilometers), but may not clearly elucidate the variability of regolith depth locally (100 m to km scale). In order to better constrain the regional average depth and local variability of the regolith, we investigate several techniques. First, we find that the apparent equilibrium diameter of a crater population increases with an increasing solar incidence angle, and this affects the inferred regolith depth by increasing the range of predicted depths (from ~7–15 m depth at 100 m equilibrium diameter to ~8–40 m at 300 m equilibrium diameter). Second, we examine the frequency and distribution of blocky craters in selected lunar mare areas and find a range of regolith depths (8–31 m) that compares favorably with results from the equilibrium diameter method (8–33 m) for areas of similar age (~2.5 billion years). Finally, we examine the utility of using Clementine optical maturity parameter images (Lucey et al. 2000) to determine regolith depth. The resolution of Clementine images (100 m/pixel) prohibits determination of absolute depths, but this method has the potential to give relative depths, and if higher resolution spectral data were available could yield absolute depths.  相似文献   
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Measurements of  Δ14C  in atmospheric CO2 are an effective method of separating CO2 additions from fossil fuel and biospheric sources or sinks of CO2. We illustrate this technique with vertical profiles of CO2 and  Δ14C  analysed in whole air flask samples collected above Colorado, USA in May and July 2004. Comparison of lower tropospheric composition to cleaner air at higher altitudes (>5 km) revealed considerable additions from respiration in the morning in both urban and rural locations. Afternoon concentrations were mainly governed by fossil fuel emissions and boundary layer depth, also showing net biospheric CO2 uptake in some cases. We estimate local industrial CO2:CO emission ratios using in situ measurements of CO concentration. Ratios are found to vary by 100% and average 57 mole CO2:1 mole CO, higher than expected from emissions inventories. Uncertainty in CO2 from different sources was ±1.1 to ±4.1 ppm for addition or uptake of −4.6 to 55.8 ppm, limited by  Δ14C  measurement precision and uncertainty in background  Δ14C  and CO2 levels.  相似文献   
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Evaluation of the results of factor analysis of sets of spectroscopically detected chromatograms is carriedout by examining the shapes of the abstract factors.This is done either by visual inspection or by analysisof the power density spectra produced from them.Owing to constraints imposed by the column functionand the spectroscopic instrument function,the information content of the chromatograms necessarilyoccurs at low spatial frequencies.As a consequence,it appears as relatively broad features in the abstractchromatograms and as a peak in the low-frequency region of the corresponding power density plot.Onthe basis of examination of the power density distribution,a well-defined distinction is made betweenprimary and secondary abstract factors.The major uncertainty encountered in determining the numberof chemical components appears to arise from effects of contaminants in reagents.  相似文献   
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