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Garnets in continentally derived high-pressure (HP) rocks ofthe Sesia Zone (Western Alps) exhibit three different chemicalzonation patterns, depending on sample locality. Comparisonof observed garnet zonation patterns with thermodynamicallymodelled patterns shows that the different patterns are causedby differences in the water content of the subducted protolithsduring prograde metamorphism. Zonation patterns of garnets inwater-saturated host rocks show typical prograde chemical zonationswith steadily increasing pyrope content and increasing XMg,together with bell-shaped spessartine patterns. In contrast,garnets in water-undersaturated rocks have more complex zonationpatterns with a characteristic decrease in pyrope and XMg betweencore and inner rim. In some cases, garnets show an abrupt compositionalchange in core-to-rim profiles, possibly due to water-undersaturationprior to HP metamorphism. Garnets from both water-saturatedand water-undersaturated rocks show signs of intervening growthinterruptions and core resorption. This growth interruptionresults from bulk-rock depletion caused by fractional garnetcrystallization. The water content during burial influences significantly thephysical properties of the subducted rocks. Due to enhancedgarnet crystallization, water-undersaturated rocks, i.e. thoselacking a free fluid phase, become denser than their water-saturatedequivalents, facilitating the subduction of continental material.Although water-bearing phases such as phengite and epidote arestable up to eclogite-facies conditions in these rocks, dehydrationreactions during subduction are lacking in water-undersaturatedrocks up to the transition to the eclogite facies, due to thethermodynamic stability of such hydrous phases at high P–Tconditions. Our calculations show that garnet zonation patternsstrongly depend on the mineral parageneses stable during garnetgrowth and that certain co-genetic mineral assemblages causedistinct garnet zonation patterns. This observation enablesinterpretation of complex garnet growth zonation patterns interms of garnet-forming reactions and water content during HPmetamorphism, as well determination of detailed P–T paths. KEY WORDS: dehydration; high-pressure metamorphism; Sesia Zone; subduction; thermodynamic modelling  相似文献   
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4.
The granulites of the Saxon Granulite Massif equilibrated athigh pressure and ultrahigh temperature and were exhumed inlarge part under near-isothermal decompression. This raisesthe question of whether P–T–t data on the peak metamorphismmay still be retrieved with confidence. Felsic and mafic granuliteswith geochronologically useful major and accessory phases haveprovided a basis to relate P–T estimates with isotopicages presented in a companion paper. The assemblage garnet +clinopyroxene in mafic granulite records peak temperatures of1010–1060°C, consistent with minimum estimates ofaround 967°C and 22·3 kbar obtained from the assemblagegarnet + kyanite + ternary feldspar + quartz in felsic granulite.Multiple partial overprint of these assemblages reflects a clockwiseP–T evolution. Garnet and kyanite in the felsic granulitewere successively overgrown by plagioclase, spinel + plagioclase,sapphirine + plagioclase, and biotite + plagioclase. Most ofthis overprinting occurred within the stability field of sillimanite.Garnet + clinopyroxene in the mafic granulite were replacedby clinopyroxene + amphibole + plagioclase + magnetite. Thehigh P–T conditions and the absence of thermal relaxationfeatures in these granulites require a short-lived metamorphismwith rapid exhumation. The ages of peak metamorphism (342 Ma)and shallow-level granitoid intrusions (333 Ma) constrain thetime span for the exhumation of the Saxon granulites to  相似文献   
5.
Early concretionary and non-concretionary siderites are common in subsurface Triassic sandstones and mudrocks of the Rewan Group, southern Bowen Basin. A detailed petrological and stable isotopic study was carried out on these siderites in order to provide information on the depositional environment of the host rocks. The siderites are extremely pure, containing 85–97 mol% FeCO3, and are commonly enriched in manganese. δ13C (PDB) values are highly variable, ranging from - 18·4 to +2·9‰, whereas δ18O (PDB) values are very consistent, ranging from - 14·0 to - 10·2‰ (mean= - 11·9 ± 1·0‰). The elemental and oxygen isotopic composition of the siderites indicates that only meteoric porewaters were involved in siderite formation, implying that host rocks accumulated in totally non-marine environments. The carbon isotopic composition of the siderites is interpreted to reflect mixing of bicarbonate/carbon dioxide generated by methane oxidation and methanogenesis. Very low δ13C values demonstrate that, contrary to current views, highly 13C-depleted siderite can be produced at shallow burial depths in anoxic non-marine sediments.  相似文献   
6.
Geological mapping, definition of facies distributions and reconstruction of platform‐interior growth geometries of the Messinian Cariatiz carbonate platform (Sorbas basin, South Spain), were performed to evaluate the controlling factors in platform growth and to test a 3‐D computer simulation program. For the simulation with the program REPRO, five platform‐related facies were modelled: (1) the reef crest facies by the numerical solution of a Fisher equation; (2) the lagoonal facies by a function of water depth‐dependent carbonate production; (3) the proximal and middle slope facies (breccia and block facies, calcarenite facies) by a subroutine simulating gravity‐driven particle export from the reef crest; (4) a distal slope; and (5) a basinal facies by a pelagic rain function. Development of a fan delta conglomeratic system is simulated by using a siliciclastic point source and gravity‐driven particle redistribution. A best fit between the observed platform growth geometries and modelling results is achieved by assuming that high‐frequency sea‐level changes superimposed onto a longer term sea‐level fall controlled platform growth. For the modelling, a relative sea‐level curve was reconstructed, which is based on a deep‐sea benthic foraminiferal stable oxygen isotope record at ODP Site 926 with a 45 m eustatic sea‐level fall, and a tectonic uplift component of 20 m. The consistency of 3‐D simulation results is corroborated by the coral growth rates provided by the Fisher‐equation subroutine. These rates of 2–8 mm year−1 compare well to the coral growth rates in Recent fringing reefs. We propose that during the early stage of platform evolution the high‐frequency fluctuations were obliquity‐modulated precessional cycles, whereas precessional cycles control later stages of platform growth. REPRO provides a separate visualization of the different facies bodies as a function of time and space, showing the intrinsic pattern of facies distribution in the platform. This is the result of a combination of platform growth and syndepositional subaerial erosion. For example, only the youngest stages of reef framework facies in the development of the Cariatiz carbonate platform are preserved.  相似文献   
7.
In a polymetamorphic, felsic, biotite-bearing gneiss, biotite has reacted to form magnetite and microcline. The resulting structure is a magnetite core surrounded by a mantle of feldspar and quartz normally not exceeding 20mm in diameter. Measurements of oxygen isotope ratios disclose disequilibrium between mantle microcline and mantle quartz and also between mantle and matrix minerals of the same species. A clustering of temperature estimates from the oxygen isotope distribution between magnetite and quartz and between magnetite and microcline in the interval 550 to 600°C suggests an approach to oxygen isotope equilibrium. No signs of a re-equilibriation of the reacting biotite can be found.  相似文献   
8.
Numerous dykes of ultramafic lamprophyre (aillikite, mela-aillikite,damtjernite) and subordinate dolomite-bearing carbonatite withU–Pb perovskite emplacement ages of 590–555 Ma occurin the vicinity of Aillik Bay, coastal Labrador. The ultramaficlamprophyres principally consist of olivine and phlogopite phenocrystsin a carbonate- or clinopyroxene-dominated groundmass. Ti-richprimary garnet (kimzeyite and Ti-andradite) typically occursat the aillikite type locality and is considered diagnosticfor ultramafic lamprophyre–carbonatite suites. Titanianaluminous phlogopite and clinopyroxene, as well as comparativelyAl-enriched but Cr–Mg-poor spinel (Cr-number < 0.85),are compositionally distinct from analogous minerals in kimberlites,orangeites and olivine lamproites, indicating different magmageneses. The Aillik Bay ultramafic lamprophyres and carbonatiteshave variable but overlapping 87Sr/86Sri ratios (0·70369–0·70662)and show a narrow range in initial Nd (+0·1 to +1·9)implying that they are related to a common type of parentalmagma with variable isotopic characteristics. Aillikite is closestto this primary magma composition in terms of MgO (15–20wt %) and Ni (200–574 ppm) content; the abundant groundmasscarbonate has 13CPDB between –5·7 and –5,similar to primary mantle-derived carbonates, and 18OSMOW from9·4 to 11·6. Extensive melting of a garnet peridotitesource region containing carbonate- and phlogopite-rich veinsat 4–7 GPa triggered by enhanced lithospheric extensioncan account for the volatile-bearing, potassic, incompatibleelement enriched and MgO-rich nature of the proto-aillikitemagma. It is argued that low-degree potassic silicate to carbonatiticmelts from upwelling asthenosphere infiltrated the cold baseof the stretched lithosphere and solidified as veins, therebycrystallizing calcite and phlogopite that were not in equilibriumwith peridotite. Continued Late Neoproterozoic lithosphericthinning, with progressive upwelling of the asthenosphere beneatha developing rift branch in this part of the North Atlanticcraton, caused further veining and successive remelting of veinsplus volatile-fluxed melting of the host fertile garnet peridotite,giving rise to long-lasting hybrid ultramafic lamprophyre magmaproduction in conjunction with the break-up of the Rodinia supercontinent.Proto-aillikite magma reached the surface only after coatingthe uppermost mantle conduits with glimmeritic material, whichcaused minor alkali loss. At intrusion level, carbonate separationfrom this aillikite magma resulted in fractionated dolomite-bearingcarbonatites (13CPDB –3·7 to –2·7)and carbonate-poor mela-aillikite residues. Damtjernites maybe explained by liquid exsolution from alkali-rich proto-aillikitemagma batches that moved through previously reaction-lined conduitsat uppermost mantle depths. KEY WORDS: liquid immiscibility; mantle-derived magmas; metasomatism, Sr–Nd isotopes; U–Pb geochronology  相似文献   
9.
Granulite-facies metamorphism in the structurally lower partof the Saxon Granulite Massif culminated at 1010–1060°Cand  相似文献   
10.
A multiproxy analysis of Hole 911A (Ocean Drilling Program (ODP) Leg 151) drilled on the Yermak Plateau (eastern Arctic Ocean) is used to investigate the behaviour of the Svalbard/Barents Sea ice sheet (SBIS) during late Pliocene and early Pleistocene (~3.0-1.7 Ma) climate changes. Contemporary with the 'Mid-Pliocene (~3 Ma) global warmth' (MPGW), a warmer period lasting ~300 kyr with seasonally ice-free conditions in the marginal eastern Arctic Ocean is assumed to be an important regional moisture source, and possibly one decisive trigger for intensification of the Northern Hemisphere glaciation in the Svalbard/Barents Sea area at ~2.7 Ma. An abrupt pulse of ice-rafted debris (IRD) to the Yermak Plateau at ~2.7 Ma reflects distinct melting of sediment-laden icebergs derived from the SBIS and may indicate the protruding advance of the ice sheet onto the outer shelf. Spectral analysis of the total organic carbon (TOC) record being predominantly of terrigenous/fossil-reworked origin indicates SBIS and possibly Scandinavian Ice Sheet response to incoming solar radiation at obliquity and precession periodicities. The strong variance in frequencies near the 41 kyr obliquity cycle between 2.7 and 1.7 Ma indicates, for the first time in the Arctic Ocean, a close relationship of SBIS growth and decay patterns to the Earth's orbital obliquity amplitudes, which dominated global ice volume variations during late Pliocene/early Pleistocene climate changes.  相似文献   
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