黑龙江乌拉嘎金矿成矿热力学参数研究     

尹淑苹  李永兵  田会全  刘善琪 《岩石矿物学杂志》2014,33(4):720-725

本文通过对前人工作的总结,在研究矿物共生关系的基础上将乌拉嘎金矿床的成矿作用过程划分为3个成矿阶段,然后利用热力学数据计算出了各个阶段的成矿热力学参数。第1阶段:黄铁矿-早期白色玉髓状石英阶段,Eh范围在-0.5~+0.3 V之间,处于弱还原环境,硫逸度应大于10~(-23);第2阶段:烟灰色玉髓状石英-多金属硫化物阶段,在低温时成矿环境为中酸性(pH=4),弱还原环境(Eh值为-1.0~-0.3 V),硫逸度范围应大于10~(-40),但不会超过10~0。同前一阶段相比,硫逸度下限降低;第3阶段:碳酸盐-石英阶段,碳酸盐矿物的出现预示着成矿已接近尾声,成矿介质的pH值逐步从酸性(pH=3)向中酸性(pH=5)转变,成矿Eh值也从弱还原(-0.5 V)向弱氧化(+0.3 V)过渡,硫逸度下限范围大约在10~(-23)左右,不超过10~0,而氧逸度范围在10~(-20)加左右。这对于深入探讨热液成矿作用过程具有重要参考价值。  相似文献   

黄土高原渭河宝鸡段北岸大型深层滑坡动力学机制研究   总被引：3，自引：0，他引：3  

辛鹏  吴树仁  石菊松  王涛  石玲 《地质学报》2014,88(7):1341-1352

为研究渭河盆地黄土塬边大型深层滑坡运动机制,通过对渭河宝鸡段北岸斜坡构造地貌过程解析、滑体地质剖面平衡计算与运动过程的动态数值模拟,结合黏土岩滑动带发育的宏观力学背景、物理结构变化特征与剪切蠕变、滑动力学行为特征研究,确定了渭河北岸大型深层滑坡的几何学、运动学特征,初步揭示了黏土岩质滑带塑性流动挤出的控滑机制。研究表明:①大型深层滑坡的运动变形由后缘向坡脚传递,后缘下降、前缘隆起,整体变形由底部泥岩控制,具有一定的水平位移,是旋转-平移复活式滑坡;②黏土岩滑动带结构损伤形成蠕变变形带,滑动过程中,塑性变形区在滑体下方呈倾斜三角形状,产生塑性流动变形,逆冲向上运动中形成翻卷结构,滑体前缘以流动状态隆起挤出;③黏土岩的塑性流动变形是黏土矿物含量增加、活性增强的结果,滑带土内的粘粒含量(2μm)由初始的17.94%增加到50.22%,蒙脱石的绝对含量从初始的13.19%增加至26.38%,而其比表面积平均由124.55增加至215.08,从而降低滑动带的强度、恶化水理性质,引起滑体剧烈变形,而滑体内赋存的高孔隙水压力可推动滑体滑动。  相似文献   

新疆二红洼镁铁—超镁铁岩体橄榄石成因及其对硫化物熔离的指示     

孙涛  钱壮志  张瑞  张江江  姜超  杨素红  王若梅 《地质学报》2014,88(8):1494-1503

二红洼岩体位于新疆东天山黄山镁铁—超镁铁岩带的西段,地表由南、北两个小岩体组成,北岩体出露面积约1.42km2,呈北东—南西向展布;南岩体在呈椭圆形,出露面积约为6.25km2。岩体可分为两个侵入期次:第一侵入期次岩性为(含长)二辉橄榄岩和橄榄辉长岩,第二侵入期次岩性为辉长苏长岩和淡色辉长岩,辉长苏长岩侵入于第一期次形成的含长二辉橄榄岩和橄榄辉长岩中。岩体橄榄石Fo值在80.9~89.7之间,为贵橄榄石;Ni含量变化范围较大,主要集中在102.19×10-6~4319.66×10-6之间。岩体母岩浆MgO含量为10.3%,FeO含量为10.8%;回归计算结果显示二红洼岩体的原始岩浆中MgO含量为15.73%,FeO含量为10.71%。在橄榄石的结晶过程中母岩浆达到硫饱和,并发生有硫化物的熔离作用;橄榄石与硫化物的晶出质量比(橄榄石:硫化物)为50~100∶1。通过岩石学、矿物学特征以及模拟计算结果表明,二红洼岩体具有形成铜镍矿床的基本条件,但是岩体在深部岩浆房已经达到硫饱和并发生了硫化物的熔离作用,导致母岩浆中亏损Ni、Cu等成矿元素,未能形成工业矿体;在以后找矿勘探中,需要寻找早期硫化物熔离所形成的那部分硫化物熔体,并进一步寻找成矿富集的有利地段。  相似文献   

琼东南盆地深水区中央峡谷天然气成藏条件与成藏模式   总被引：2，自引：0，他引：2  

杨金海  李才  李涛  宋爱学  王利杰  周刚 《地质学报》2014,88(11):2141-2149

利用钻井岩芯、岩屑地质化验资料及测井、二维、二维地震数据,综合分析了琼东南盆地深水区中央峡谷储层的发育特征、天然气成藏条件及成藏主控因素.结果表明,峡谷中、下部堆积的多期浊积砂岩,储集物性好,是该区带的优质储层;峡谷内发育的大量岩性、构造-岩性复合型圈闭为天然气聚集造就了重要场所;凹陷中的渐新统崖城组煤系烃源岩及广厚的半封闭浅海泥岩生气潜力大,提供了丰富的烃源基础;峡谷下方的底辟/微裂隙是深部崖城组烃源岩生成的天然气向上运移的重要通道.可见,中央峡谷成藏条件优越,圈闭有效性和运移是该区天然气成藏的关键要素;由于峡谷内圈闭大多数定型于上新世莺歌海组沉积时期,与下伏崖城组烃源岩主生气期形成合理配置,因此,天然气成藏较晚,L1、L2和L3气田的重大发现就是很好的例证.  相似文献   

玲珑金矿大开头矿区Bi特征及指示意义     

胡宝群  高海东  申玉科  郭涛  吕古贤  武际春 《物探与化探》2014,(6)

在金矿床中,金、铋常常相伴产出,在金矿体周围存在明显的铋异常,它可作为重要的指示元素。笔者研究了玲珑金矿不同岩石中铋与金含量之间的关系,比较了基岩地球化学剖面中两元素的相关性,采用电子探针分析了主要矿石矿物中铋和金的含量,发现不同类型岩石中铋含量差异明显,铋在矿体中含量远高于围岩,在矿区中铋与金呈幂函数正相关,铋原生晕规模大、衬度高,与金都是以独立矿物相形式存在。在玲珑金矿化探找矿中,铋含量高,与金呈较好的正相关关系,是最佳指示元素之一。  相似文献   

Erratum to: Prognostication of hydrocarbon generative potential in the onshore and offshore Niger Delta,Nigeria using TOC content and rock-eval pyrolysis techniques     

E. K. Nyantakyi  Tao Li  Wangshui Hu  J. K. Borkloe  R. D. Nagre 《中国地球化学学报》2014,33(3):324-324

  相似文献   

Trace element and REE geochemistry of the Zhewang gold deposit,southeastern Guizhou Province,China   总被引：1，自引：0，他引：1  

Kun Liu  Ruidong Yang  Wenyong Chen  Rui Liu  Ping Tao 《中国地球化学学报》2014,33(1):109-118

The quartz vein-type gold deposits are widely hosted by the Neoproterozoic （Xiajiang Group） epimeta- morphic clastic rock series in southeastern Guizhou Province, China. The Zhewang gold deposit studied in this paper occurs in the second lithologieal member of the Pinglue Formation of the Xiajiang Group. Trace element geochemis- try of host rocks, quartz veins and arsenopyrite has revealed that ore-forming fluid was enriched in sulphophile ele- ments such as Au, Ag, As, Sb, Pb and Zn, and simultaneously concentrated some magmaphile elements such as W and Mo, which probably provides some evidence for multi-stage mineralization or overprinting of magmatic hydro- therm. Quartz veins and arsenopyrite were characterized by depletion in HFSE and enrichment in LREE. Hf/Sm, Nb/La and Th/La imply that the ore-forming fluid was probably a NaC1-H20 solution system enriched in more C1 than F; Th/U values reflect the strong reducibility of the ore-forming fluid, coincident with the sulfide assemblages. The values of Co/Ni reflect that magmatic fluids may have partly participated in the ore-forming process and Y/Ho values have proved that the ore-forming fluid was associated with metamorphism and exotic hydrotherm which has reformed former quartz veins during late mineralization. The concentrations of REE, Eu anomalies and Ce anomalies of this deposit display that ore-forming elements mainly were derived from host rocks and possibly from a mixed deep source, and the ore-forming fluid was mixed by dominant metamorphic fluid and minor other sources. The physical-chemical conditions of ore-forming fluid changed from the initial stage to the late stage. The metamorphic fluid is responsible for the mineralization. Therefore, the Zhewang gold deposit is classified as a quartz vein-type gold deposit which may have been reformed by magmatic fluids during the late stage.  相似文献   

The Insect Oviposition Firstly Discovered on the Middle Jurassic Ginkgoales Leaf from Inner Mongolia,China     

NA Yuling  SUN Chunlin  LI Tao  LI Yunfeng 《《地质学报》英文版》2014,88(1):18-28

Although the evidence of insect oviposition on plant organs has been reported from the late Paleozoic to the Miocene, record from the middle Jurassic is still blank. This paper reports a significant evidence of insect oviposition on plant leaf from the middle Jurassic for the first time. The ovipositional scar is distributed on the abaxial surface of Sphenobaiera leaf（Ginkgoales） from the middle Jurassic Daohugou Formation of Inner Mongolia, China. A new ichnospecies Paleoovoidus venustus sp. nov. is described. The scar is elliptic to oval, arranged in longitudinal rows between leaf veins with almost regular distance, with its long axis paralleling to the leaf venation. This discovery adds new information to the morphology of insect endophytic oviposition probably produced by Odonata existed in a terrestrial ecosystem ~165 Ma ago. The new materials also provide important data for the study of insect reproductive biology, plant-insect interaction and coevolution, as well as understanding the paleoclimate and palaeoenvironment during that time in northeast China.  相似文献   

Arsenic Distribution Pattern in Different Sources of Drinking Water and their Geological Background in Guanzhong Basin,Shaanxi, China     

LUO Kunli  ZHANG Shixi  TIAN Yuan  GAO Xing 《《地质学报》英文版》2014,88(3):984-994

To study arsenic(As) content and distribution patterns as well as the genesis of different kinds of water, especially the different sources of drinking water in Guanzhong Basin, Shaanxi province, China, 139 water samples were collected at 62 sampling points from wells of different depths, from hot springs, and rivers. The As content of these samples was measured by the intermittent flowhydride generation atomic fluorescence spectrometry method(HG-AFS). The As concentrations in the drinking water in Guanzhong Basin vary greatly(0.00–68.08 μg/L), and the As concentration of groundwater in southern Guanzhong Basin is different from that in the northern Guanzhong Basin. Even within the same location in southern Guanzhong Basin, the As concentrations at different depths vary greatly. As concentration of groundwater from the shallow wells(50 m deep, 0.56–3.87 μg/L) is much lower than from deep wells(110–360 m deep, 19.34–62.91 μg/L), whereas As concentration in water of any depth in northern Guanzhong Basin is 10 μg/L. Southern Guanzhong Basin is a newly discovered high-As groundwater area in China. The high-As groundwater is mainly distributed in areas between the Qinling Mountains and Weihe River; it has only been found at depths ranging from 110 to 360 m in confined aquifers, which store water in the Lishi and Wucheng Loess(Lower and Middle Pleistocene) in the southern Guanzhong Basin. As concentration of hot spring water is 6.47–11.94 μg/L; that of geothermal water between 1000 and 1500 m deep is 43.68–68.08 μg/L. The high-As well water at depths from 110 to 360 m in southern Guanzhong Basin has a very low fluorine(F) value, which is generally 0.10 mg/L. Otherwise, the hot springs of Lintong and Tangyu and the geothermal water in southern Guanzhong Basin have very high F values(8.07–14.96 mg/L). The results indicate that highAs groundwater in depths from 110 to 360 m is unlikely to have a direct relationship with the geothermal water in the same area. As concentration of all reservoirs and rivers(both contaminated and uncontaminated) in the Guanzhong Basin is 10 μg/L. This shows that pollution in the surface water is not the source of the high-As in the southern Guanzhong Basin. The partition boundaries of the high- and low-As groundwater area corresponds to the partition boundaries of the tectonic units in the Guanzhong Basin. This probably indicates that the high-As groundwater areas can be correlated to their geological underpinning and structural framework. In southern Guanzhong Basin, the main sources of drinking water for villages and small towns today are wells between 110–360 m deep. All of their As contents exceed the limit of the Chinese National Standard and the International Standard(10 μg/L) and so local residents should use other sources of clean water that are 50 m deep, instead of deep groundwater(110 to 360 m) for their drinking water supply.  相似文献   

胶东控矿断裂断层泥形成与演化:以新立金矿床为例     

杨林  王庆飞  刘学飞  张尧  管涛  潘瑞广  冯跃文 《大地构造与成矿学》2014,(4)

胶东半岛中生代金矿床具有重要的经济价值,其蚀变和矿化均受北东向断裂控制。例如,位于胶东半岛西北部的新立金矿床受区域三山岛-仓上断裂(F1)和次级断裂(F2)控制,其中F1广泛地控制蚀变和矿化,F2仅分割黄铁绢英岩化蚀变和钾化蚀变。本文选取新立金矿床F1和F2的断层泥为研究对象,通过显微观察,矿物组成测定,激光粒度分析等多种手段,探讨断层泥物质组成、矿物成因、演化阶段及其在成矿过程中的作用。矿物学分析表明F1断层泥主要成分为高岭石和石英,含少量黄铁矿、伊利石和石膏;F2断层泥含有大量的石英和绢云母以及少量高岭石和伊蒙混层。根据矿物共生关系和相图分析得出,高岭石是绢云母反应形成的,伊利石由高岭石转化所致,伊蒙混层是高岭石转化为伊利石的中间产物,这些矿物之间的转化反映了aK+或aK+/aH+连续减小。F1断层泥中黄铁矿和F2断层泥中石英和绢云母可能为围岩残留,石膏是次生风化的产物。F1断层泥的粒度分布曲线呈单峰型、复式双峰和三峰型,其粒度分布分维值为2.61~2.82;而F2断层泥仅呈简单双峰型,分维值为2.46~2.52,表明F1断层泥组份经历颗粒旋转磨蚀阶段,F2断层泥组份处于约束碾磨阶段。综上所述,水岩反应和构造磨蚀在断层泥的形成过程中扮演重要角色,两者在主断裂F1中更强烈、复杂。鉴于F2产出位置和断层泥特征,我们推断F2为成矿后构造。断层泥中大量的黏土矿物、高度分化的颗粒粒度以及定向的显微构造导致低的横向渗透性,使断层作为障碍层阻隔成矿流体并形成差异的蚀变矿化带。  相似文献