Predictions of the electrical conductivity and charging of the aerosols in Titan's atmosphere     

W.J. Borucki  R.C. Whitten  E. Barth 《Icarus》2006,181(2):527-544

The electrical conductivity and electrical charge on the aerosols in atmosphere of Titan are computed for altitudes between 0 and 400 km. Ionization of methane and nitrogen due to galactic cosmic rays (GCR) is important at night where these ions are converted to ion clusters such as CH⁺₅CH₄, C₇H⁺₇, C₄H⁺₇, and H₄C₇N⁺. The ubiquitous aerosols observed also play an important role in determining the charge distribution in the atmosphere. Because polycyclic aromatic hydrocarbons (PAHs) are expected in Titan's atmosphere and have been observed in the laboratory and found to be electrophilic, we consider the formation of negative ions. During the night, the very smallest molecular complexes accept free electrons to form negative ions. This results in a large reduction of the electron abundance both in the region between 150 and 350 km over that predicted when such aerosols are not considered. During the day time, ionization by photoemission from aerosols irradiated by solar ultraviolet (UV) radiation overwhelms the GCR-produced ionization. The presence of hydrocarbon and nitrile minor constituents substantially reduces the UV flux in the wavelength band from the cutoff of CH₄ at 155 to 200 nm. These aerosols have such a low ionization potential that the bulk of the solar radiation at longer wavelengths is energetic enough to produce a photoionization rate sufficient to create an ionosphere even without galactic cosmic ray (GCR) bombardment. At altitudes below 60 km, the electron and positive ion abundances are influenced by the three-body recombination of ions and electrons. The addition of this reaction significantly reduces the predicted electron abundance over that previously predicted. Our calculations for the dayside show that the peaks of the charge distributions move to larger values as the altitude increases. This variation is the result of the increased UV flux present at the highest altitudes. Clearly, the situation is quite different than that for the night where the peak of the distribution for a particular size is nearly constant with altitude when negative ions are not present. The presence of very small aerosol particles (embryos) may cause the peak of the distribution to decrease from about 8 negative charges to as little as one negative charge or even zero charge. This dependence on altitude will require models of the aerosol formation to change their algorithms to better represent the effect of charged aerosols as a function of altitude. In particular, the charge state will be much higher than previously predicted and it will not be constant with altitude during the day time. Charging of aerosol particles, whether on the dayside or nightside, has a major influence on both the electron abundance and electrical conductivity. The predicted conductivities are within the measurement range of the HASI PWA instrument over most but not all, of the altitude range sampled.  相似文献   

Influence of changed vegetations fields on regional climate simulations in the Barents Sea Region     

Holger Göttel  Jörn Alexander  Elke Keup-Thiel  Diana Rechid  Stefan Hagemann  Tanja Blome  Annett Wolf  Daniela Jacob 《Climatic change》2008,87(1-2):35-50

In the context of the EU-Project BALANCE () the regional climate model REMO was used for extensive calculations of the Barents Sea climate to investigate the vulnerability of this region to climate change. The regional climate model REMO simulated the climate change of the Barents Sea Region between 1961 and 2100 (Control and Climate Change run, CCC-Run). REMO on ~50 km horizontal resolution was driven by the transient ECHAM4/OPYC3 IPCC SRES B2 scenario. The output of the CCC-Run was applied to drive the dynamic vegetation model LPJ-GUESS. The results of the vegetation model were used to repeat the CCC-Run with dynamic vegetation fields. The feedback effect of the modified vegetation on the climate change signal is investigated and discussed with focus on precipitation, temperature and snow cover. The effect of the offline coupled vegetation feedback run is much lower than the greenhouse gas effect.  相似文献   

Trace element geochemistry and tectonic characterization of the granulite facies rocks from Southwest Obudu Plateau,southeastern Nigeria     

Ekere E. Ukwang  Barth N. Ekwueme 《中国地球化学学报》2009,28(3):248-257

The trace elements characteristics of the migmatitic gneisses (biotite-garnetand hornblende-biotite), granulite facies rocks (charnockitic gneisses) and meta-peridotite in the area of Southwest Obudu Plateau indicate that the area exhibits a high degree of geochemical variability. Compatible trace elements (Ni and Cr) are comparatively high in the granulite facies rocks and meta-peridotite. Ni ranges from 28×10-6 to 266×10-6 whilst Cr ranges from 62×10-6 to 481×10-6 for the granulite facies rocks (charnocki...  相似文献   

Hydrological analysis of Skradinski Buk tufa waterfall (Krka River,Dinaric karst,Croatia)     

Ognjen Bonacci  Ivo Andrić  Tanja Roje-Bonacci 《Environmental Earth Sciences》2017,76(19):669

The paper analyses complex hydrological behaviour of Skradinski Buk, the tufa waterfall, formed on the downstream part of the Krka River located in the coastal part of the Croatian Dinaric karst. This waterfall is the central point of the Krka National Park (KNP) proclaimed in 1985. Skradinski Buk is the seventh, final and the largest tufa barrier on the Krka River. Morphology of Skradinski Buk is composed of 17 unevenly distributed steps and dozens of small depressions. Natural waterfall morphology strongly influenced the complex waterfall hydrological regime. Additionally, hydrological regime is disturbed by the operation of the hydroelectric power plant (HEPP) Jaruga. This paper analyses characteristic (minimum, mean, maximum) annual water levels and discharges monitored at two hydrological stations (Skradinski Buk Gornji-SBG and Nacionalni Park-NP). SBG controls the inflow of water into the waterfall, while the NP is established in order to control the use of water from the HEPP Jaruga operation. It is concluded that the HEPP Jaruga does not comply with the agreement signed between the KNP and the HEPP Jaruga. The goal of the paper is to give detailed hydrological analysis of the Skradinski Buk, which should play the crucial role in the protection of this wonderful and very vulnerable phenomenon.  相似文献   

Suitability of linden and elder in the assessment of environmental pollution of Brestovac spa and Bor lake (Serbia)     

Tanja S. Kalinovic  Snezana M. Serbula  Jelena V. Kalinovic  Ana A. Radojevic  Jelena V. Petrovic  Mirjana M. Steharnik  Jelena S. Milosavljevic 《Environmental Earth Sciences》2017,76(4):178

The suitability of linden and elder as biomonitors was evaluated in the tourist zone of the Bor region well known for pyrometallurgical copper production. The concentrations of As, Cu, Pb and Zn in the soil, washed and unwashed leaves and roots of linden and elder were determined. The absorption of As, Cu, Pb and Zn from soil to roots and leaves, as well as the translocation of the studied elements from roots to leaves, was analysed. It was observed that the soil in the tourist zone of Bor (Bor lake and Brestovac spa) was greatly polluted with Cu and As. Linden and elder leaves can be used as a low-cost material for detection of As, Cu, Pb and Zn in the atmospheric deposition, which was concluded due to the amounts of these elements removed after a washing treatment. Thus, canopies of linden and elder might have an important role in the removal of the polluting substances from the air. The elder leaves were more suitable to be used for indication of environmental pollution with As, Cu and Pb than the linden leaves. The area of the Bor lake sampling site had higher air pollution with As and Pb than Brestovac spa, since greater amounts of As and Pb were washed off the linden and elder leaves from the Bor lake sampling site. The linden and elder used different adaptation strategies in conditions of the increased soil and air pollution. These strategies were based on different efficiencies of element absorption from the soil and on limited or efficient translocation of the studied elements from roots to leaves, and therefore, they have an important role in the biogeochemical cycling of the examined elements in the environment.  相似文献   

Numerical Simulation and Observational Analysis of the Bora of Pag’s Ribs     

Tanja Trošić  Živko Trošić 《Boundary-Layer Meteorology》2010,134(2):353-366

The severe bora case that lasted from 13 to 15 November 2004 has been selected for the analysis of the bora of Pag’s ribs, which occurs in the northern part of the eastern Adriatic coast over the Pag island area (Croatia). According to the measurements from automatic stations, the MM5 numerical model is successful in the 10-min mean wind speed prediction at 10-m height. The vertical analysis of the wind speed and potential temperature also gave satisfactory results. At the commencement of the bora the modelled wind had a magnitude of 20ms⁻¹ at 10-m height in the Pag island area, which sharply attenuated in the cross direction and to the open sea. In this way the model has proved successful in predicting the characteristics of the bora of Pag’s ribs. Potential vorticity (PV) at 600m has lower values within PV banners than during the developed bora. The consequence is a strong jet emanating from the nearest gap. The vertical cross-sections through the centre of the gap point out a permanent hydraulic-like flow. At the time of the bora of Pag’s ribs the highest modelled turbulent kinetic energy is found in the jump-like region above the inversion and within the boundary layer along the lower boundary, ranging from 6–8m² s⁻². It is concluded that the dissipation in the hydraulic jumps and the wave breaking regions are the reasons for PV generation.  相似文献   

The influence of cyanobacteria on oil polluted intertidal soils at the Saudi Arabian Gulf shores   总被引：3，自引：0，他引：3  

Barth HJ 《Marine pollution bulletin》2003,46(10):1245-1252

In 1991 the second Gulf War lead to the largest oil spill in human history. Over 770 km of coastline from southern Kuwait to Abu Ali Island (Saudi Arabia) were smothered with oil and tar, erasing most of the local plant and animal communities. In the following year cyanobacteria colonized most of the oil polluted shores. In the study area at the Saudi Arabian Gulf coast north of Jubail three different processes were observed that followed the extensive formation of cyanobacterial mats. The first one is desiccation, cracking, and peeling of the cyanobacterial mats, thereby removing the uppermost part of the oiled sediment. The second is the resettlement of burrowing macrofauna like crabs and benthic animals such as gastropods, which outcompete the cyanobacteria again. The third process is further extensive growth of cyanobacteria building thick laminated mats. These layers, completely seal the surface and hence produce an anaerobic milieu which inhibits oil degradation. As long as such cyanobacteria exist, they will prevent microbial oil degradation as well as any resettlement by macrofauna.  相似文献   

Copepod distribution as an indicator of epikarst system connectivity   总被引：2，自引：0，他引：2  

Tanja Pipan  David C. Culver 《Hydrogeology Journal》2007,15(4):817-822

The distribution of 27 copepod species was determined in 35 drips in four Slovenian caves (Dimnice, Postojna Planina Cave System, Škocjanske Jame, Županova Jama), and of ten species from 13 drips in one US cave (Organ Cave, West Virginia). The dripping water comes from epikarst, the skin of karst. A significant fraction of the copepod species found (nine species in Slovenia and three in West Virginia) occurred over a maximum linear extent of 100 m. These and other localized distributions probably resulted from colonization of epikarst by an ancestral surface population in a single location, with subsequent lateral spread in the direction of epikarst flow. This suggests that the distribution of copepods could potentially be used to trace major flow paths in epikarst without the need for the injection of dyes or other tracers.

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Résumé La distribution de 27 espèces de copépodes a été déterminée dans 35 zones de percolation de quatre grottes slovènes (Dimnice, système de grottes Postojna Planina, Škocjanske Jame, Županova Jama) et grace à dix espèces de 13 zones de percolation d’une grotte des Etats-Unis (Grotte Organ, Ouest de la Virginie). L’eau de percolation provient de l’épikarst, la partie supérieure du karst. Une fraction importante des espèces de copépodes trouvées (9 espèces en Slovénie et 3 dans l’Ouest de la Virginie) s’étendait sur une longueur maximum de 100 m. Ces dernières ainsi que d’autres distributions localisées étaient probablement issues de la colonisation par une population ancienne de surface, de zones localisées de l’épikarst, puis par une dispersion latérale dans la direction de l’écoulement dans l’épikarst. Ceci suggère que la distribution des copépodes pourrait potentiellement être utilisée pour identifier les principales trajectoires d’écoulement dans l’épikarst, sans utiliser l’injection de colorants ou d’autres traceurs.

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Resumen Se determina la distribución de 27 especies de copépodo en 35 gotas de cuatro cavernas de Eslovenia (Dimnice, Sistema de Caverna Planina Postojna, Jame Škocjanske, y Jama Županova), y de diez especies en 13 gotas de una caverna de Estados Unidos (Caverna órgano, Virginia Occidental). El agua que gotea se deriva del epikarst, la piel del karst. Una fracción significativa de las especies de copépodos encontradas (9 especies en Eslovenia y 3 en Virginia Occidental) se presentaron en una extensión linear máxima de 100 m. Estas y otras distribuciones localizadas resultaron probablemente de colonización del epikarst por poblaciones superficiales ancestrales en una sola localización, con una expansión lateral subsiguiente en la dirección de flujo epikárstico. Esto sugiere que la distribución de copépodos podría tener un uso potencial para trazar rutas de flujo principales en epikarst sin tener la necesidad de inyectar colorantes u otros trazadores.

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Water fluxes and their control on the terrestrial carbon balance: Results from a stable isotope study on the Clyde Watershed (Scotland)     

J.A.C. Barth  H. Freitag  H.J. Fowler  A.P. Smith  C. Ingle  A. Karim 《Applied Geochemistry》2007,22(12):2684

The gradients between precipitation and runoff quantities as well as their water isotopes were used to establish a water balance in the Clyde River Basin (Scotland). This study serves as an example for a European extreme with poorly vegetated land cover and high annual rainfall and presents novel water stable isotope techniques to separate evaporation, interception and transpiration with annual averages of 0.029 km³ a⁻¹, 0.220 km³ a⁻¹ and 0.489 km³ a⁻¹, respectively. Transpiration was further used to determine CO₂ uptake of the entire basin and yielded an annual net primary production (NPP) of 352 × 10⁹ g C (Giga gram) or 185.2 g C m⁻². Compared to other temperate areas in the world, the Clyde Basin has only half the expected NPP. This lower value likely results from the type of vegetation cover, which consists mostly of grasslands. Subtracting the annual heterotrophic soil respiration flux (R_h) of 392 Gg (206.1 g C m⁻² a⁻¹) from the NPP yielded an annual Net Ecosystem Productivity (NEP) of −40 Gg C, thus showing the Clyde Watershed as a source of CO₂ to the atmosphere. Despite the unusual character of the Clyde Watershed, the study shows that areas with predominant grass and scrub vegetation still have transpirational water losses that by far exceed those of pure evaporation and interception. This infers that vegetation can influence the continental water balances on time scales of years to decades.  相似文献   

Indications for pedogenic formation of perylene in a terrestrial soil profile: Depth distribution and first results from stable carbon isotope ratios     

Tilman Gocht  Johannes A.C. Barth  Michaela Epp  Maik Jochmann  Michaela Blessing  Torsten C. Schmidt  Peter Grathwohl 《Applied Geochemistry》2007,22(12):2652

Concentrations and isotope compositions of polycyclic aromatic hydrocarbons (PAHs) were determined in natural soils of Southern Germany. In selected profiles perylene concentrations increased with soil depth when compared to the other PAH compounds present. However, its low solubility made vertical transport by seepage water unlikely. Therefore two mechanisms are discussed that could have caused the unusual distribution of perylene in these soils:

(a) Atmospheric deposition of combustion-derived (i.e. pyrogenic) perylene in the top-soil and

(b) in situ generation in the sub-soil of these specific terrestrial environments. This could have been caused by microbial activities or other catalytic processes yet unknown.

In order to distinguish between pyrogenic and natural generation compound-specific ¹³C/¹²C ratios (δ¹³C) were compared between perylene and other PAHs in samples from the top-soil and sub-soil. Despite successful clean-up of the extracts, low perylene concentrations and peak overlaps with benzo(e)pyrene and benzo(a)pyrene prevented determination of a unique δ¹³C value for perylene in the upper horizon. However, the δ¹³C value of perylene in the sub-soil was 5.7 permille more negative than other equal-mass PAHs (with m/z of 252) in the top-soil, which rather supports in situ generation of perylene in the sub-soil.  相似文献