Dissolved organic matter variations in coastal plain wetland watersheds: The integrated role of hydrological connectivity,land use,and seasonality          下载免费PDF全文

Jacob D. Hosen  Alec W. Armstrong  Margaret A. Palmer 《水文研究》2018,32(11):1664-1681

Dissolved organic matter (DOM) is integral to fluvial biogeochemical functions, and wetlands are broadly recognized as substantial sources of aromatic DOM to fluvial networks. Yet how land use change alters biogeochemical connectivity of upland wetlands to streams remains unclear. We studied depressional geographically isolated wetlands on the Delmarva Peninsula (USA) that are seasonally connected to downstream perennial waters via temporary channels. Composition and quantity of DOM from 4 forested, 4 agricultural, and 4 restored wetlands were assessed. Twenty perennial streams with watersheds containing wetlands were also sampled for DOM during times when surface connections were present versus absent. Perennial watersheds had varying amounts of forested wetland (0.4–82%) and agricultural (1–89%) cover. DOM was analysed with ultraviolet–visible spectroscopy, fluorescence spectroscopy, dissolved organic carbon (DOC) concentration, and bioassays. Forested wetlands exported more DOM that was more aromatic‐rich compared with agricultural and restored wetlands. DOM from the latter two could not be distinguished suggesting limited recovery of restored wetlands; DOM from both was more protein‐like than forested wetland DOM. Perennial streams with the highest wetland watershed cover had the highest DOC levels during all seasons; however, in fall and winter when temporary streams connect forested wetlands to perennial channels, perennial DOC concentrations peaked, and composition was linked to forested wetlands. In summer, when temporary stream connections were dry, perennial DOC concentrations were the lowest and protein‐like DOM levels the highest. Overall, DOC levels in perennial streams were linked to total wetland land cover, but the timing of peak fluxes of DOM was driven by wetland connectivity to perennial streams. Bioassays showed that DOM linked to wetlands was less available for microbial use than protein‐like DOM linked to agricultural land use. Together, this evidence indicates that geographically isolated wetlands have a significant impact on downstream water quality and ecosystem function mediated by temporary stream surface connections.  相似文献   

New Reference Materials and Assessment of Matrix Effects for SIMS Measurements of Oxygen Isotopes in Garnet     

Alice Vho  Daniela Rubatto  Benita Putlitz  Anne‐Sophie Bouvier 《Geostandards and Geoanalytical Research》2020,44(3):459-471

Accurate ion microprobe analysis of oxygen isotope ratios in garnet requires appropriate reference materials to correct for instrumental mass fractionation that partly depends on the garnet chemistry (matrix effect). The matrix effect correlated with grossular, spessartine and andradite components was characterised for the Cameca IMS 1280HR at the SwissSIMS laboratory based on sixteen reference garnet samples. The correlations fit a second‐degree polynomial with maximum bias of ca. 4‰, 2‰ and 8‰, respectively. While the grossular composition range 0–25% is adequately covered by available reference materials, there is a paucity of them for intermediate compositions. We characterise three new garnet reference materials GRS2, GRS‐JH2 and CAP02 with a grossular content of 88.3 ± 1.2% (2s), 83.3 ± 0.8% and 32.5 ± 3.0%, respectively. Their micro scale homogeneity in oxygen isotope composition was evaluated by multiple SIMS sessions. The reference δ¹⁸O value was determined by CO₂ laser fluorination (δ¹⁸O_LF). GRS2 has δ¹⁸O_LF = 8.01 ± 0.10‰ (2s) and repeatability within each SIMS session of 0.30–0.60‰ (2s), GRS‐JH2 has δ¹⁸O_LF = 18.70 ± 0.08‰ and repeatability of 0.24–0.42‰ and CAP02 has δ¹⁸O_LF = 4.64 ± 0.16‰ and repeatability of 0.40–0.46‰.  相似文献   

Exsolution and shock microstructures of igneous pyroxene clasts in the Northwest Africa 7533 Martian meteorite          下载免费PDF全文

Hugues Leroux  Damien Jacob  Maya Marinova  Roger H. Hewins  Brigitte Zanda  Sylvain Pont  Jean‐Pierre Lorand  Munir Humayun 《Meteoritics & planetary science》2016,51(5):932-945

Northwest Africa (NWA) 7533 is a Martian regolith breccia. This meteorite (and its pairings) offers a good opportunity to study (near‐) surface processes that occurred on early Mars. Here, we have conducted a transmission electron microscope study of medium‐ and coarse‐grained (a few tens to hundreds of micrometers) Ca‐rich pyroxene clasts in order to define their thermal and shock histories. The pyroxene grains have a high‐temperature (magmatic) origin as revealed by the well‐developed pigeonite–augite exsolution microstructure. Exsolution lamella characteristics (composition, thickness, and spacing) indicate a moderately slow cooling. Some of the pyroxene clasts display evidence for local decomposition into magnetite and silica at the submicron scale. This phase decomposition may have occurred at high temperature and occurred at high oxygen fugacity at least 2–3 log units above the QFM buffer, after the formation of the exsolution lamellae. This corresponds to oxidizing conditions well above typical Martian magmatic conditions. These oxidizing conditions seem to have prevailed early and throughout most of the history of NWA 7533. The shock microstructure consists of (100) mechanical twins which have accommodated plastic deformation. Other pyroxene shock indicators are absent. Compared with SNC meteorites that all suffered significant shock metamorphism, NWA 7533 appears only mildly shocked. The twin microstructure is similar from one clast to another, suggesting that the impact which generated the (100) twins involved the compacted breccia and that the pyroxene clasts were unshocked when they were incorporated into the NWA 7533 breccia.  相似文献   

The meteoritic origin of Tutankhamun's iron dagger blade          下载免费PDF全文

Daniela Comelli  Massimo D'orazio  Luigi Folco  Mahmud El‐Halwagy  Tommaso Frizzi  Roberto Alberti  Valentina Capogrosso  Abdelrazek Elnaggar  Hala Hassan  Austin Nevin  Franco Porcelli  Mohamed G. Rashed  Gianluca Valentini 《Meteoritics & planetary science》2016,51(7):1301-1309

Scholars have long discussed the introduction and spread of iron metallurgy in different civilizations. The sporadic use of iron has been reported in the Eastern Mediterranean area from the late Neolithic period to the Bronze Age. Despite the rare existence of smelted iron, it is generally assumed that early iron objects were produced from meteoritic iron. Nevertheless, the methods of working the metal, its use, and diffusion are contentious issues compromised by lack of detailed analysis. Since its discovery in 1925, the meteoritic origin of the iron dagger blade from the sarcophagus of the ancient Egyptian King Tutankhamun (14th C. BCE) has been the subject of debate and previous analyses yielded controversial results. We show that the composition of the blade (Fe plus 10.8 wt% Ni and 0.58 wt% Co), accurately determined through portable x‐ray fluorescence spectrometry, strongly supports its meteoritic origin. In agreement with recent results of metallographic analysis of ancient iron artifacts from Gerzeh, our study confirms that ancient Egyptians attributed great value to meteoritic iron for the production of precious objects. Moreover, the high manufacturing quality of Tutankhamun's dagger blade, in comparison with other simple‐shaped meteoritic iron artifacts, suggests a significant mastery of ironworking in Tutankhamun's time.  相似文献   

Vorticity analysis of the Palmi shear zone mylonites: new insights for the Alpine tectonic evolution of the Calabria–Peloritani terrane (southern Italy)     

Vincenzo Festa  Giacomo Prosser  Alfredo Caggianelli  Antonietta Grande  Antonio Langone  Daniela Mele 《Geological Journal》2016,51(4):670-681

New microstructural data on the mylonites from the well‐exposed Palmi shear zone (southern Calabria) are presented with the aim to shed light on both the kinematics and the geometry of the southwestern branch of the Alpine belt during Eocene. In the study area, located between the Sardinia–Corsica block and the Calabria–Peloritani terrane, previous large‐scale geodynamic reconstructions suggest the presence of strike–slip or transform fault zones dissecting the southwestern branch of the Alpine belt. However, there are no field data supporting the occurrence of these structures. This paper uses vorticity analysis technique based on the aspect ratio and the long axis orientation of rigid porphyroclasts in mylonitic marbles and mylonitic granitoids, to estimate the contribution of pure and simple shear of deformation during the movement of the Palmi shear zone. Porphyroclasts aspect ratio and orientation were measured on thin sections using image analysis. Estimates of the vorticity number, W_m, indicate that the Palmi shear zone recorded general shear with a contribution of pure shear of c. 65%. Then, the Palmi shear zone can be interpreted as a segment of a left‐lateral transpressive bend along the southern termination of the Eocene Alpine front. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Midnight reversal of ionospheric plasma bubble eastward velocity to westward velocity during geomagnetically quiettime: Climatology and its model validation     

José H.A. Sobral  Vivian M. de Castilho  M.A. Abdu  Hisao Takahashi  I. Paulino  Ulisses A.C. Gasparelo  Daniela C.S. Arruda  Matheus Mascarenhas  C.J. Zamlutti  C.M. Denardini  Daiki Koga  A.F. de Medeiros  R.A. Buriti 《Journal of Atmospheric and Solar》2011,73(11-12):1520-1528

In an effort to better understand the dynamics of westward velocities of the nocturnal F-region plasma, the climatology of the westward traveling plasma bubbles – WTB – occurring during quiettime is studied here. The climatology of the WTB is analyzed here based on airglow images obtained during 14 quiet days between 2001 and 2006 at the Brazilian station São João do Cariri (Geographic 7.45°S, 36.5°W, dip ～20°S). The frequency of occurrence of the WTB maximizes in the descending phase of the solar cycle. The WTB velocities ranged between ～20 and 40 ms^?1. The frequency of occurrence had a peak value of only 3.65% at 2345 LT. The maximum occurrence of the WTB was in July–September. No WTB have been observed from November until April in all years 2001–2006. We show for the first time theoretically that the WTB dominant forcing mechanisms during geomagnetically quiet days are westward thermospheric winds.  相似文献   

Multiplatform observation of the surface circulation in the Gulf of Naples (Southern Tyrrhenian Sea)   总被引：1，自引：1，他引：0  

Marco Uttieri  Daniela Cianelli  Bruno Buongiorno Nardelli  Berardino Buonocore  Pierpaolo Falco  Simone Colella  Enrico Zambianchi 《Ocean Dynamics》2011,61(6):779-796

The Gulf of Naples (Southern Tyrrhenian Sea) is a highly urbanised area, where human activities and natural factors (e.g. river runoff, exchanges with adjacent basins) can strongly affect the water quality. In this work we show how surface transport can influence the distribution of passively drifting surface matter, and more in general if and how the circulation in the basin can promote the renovation of the surface layer. To this aim, we carried out a multiplatform analysis by putting together HF radar current fields, satellite images and modelling tools. Surface current fields and satellite images of turbidity patterns were used to initialise and run model simulations of particle transport and diffusion. Model results were then examined in relation to the corresponding satellite distributions. This integrated approach permits to investigate the concurrent effects of surface dynamics and wind forcing in determining the distribution of passive tracers over the basin of interest, identifying key mechanisms supporting or preventing the renewal of surface waters as well as possible areas of aggregation and retention.  相似文献   

Developing coastal adaptation to climate change in the New York City infrastructure-shed: process, approach, tools, and strategies   总被引：1，自引：0，他引：1  

Cynthia Rosenzweig  William D. Solecki  Reginald Blake  Malcolm Bowman  Craig Faris  Vivien Gornitz  Radley Horton  Klaus Jacob  Alice LeBlanc  Robin Leichenko  Megan Linkin  David Major  Megan O��Grady  Lesley Patrick  Edna Sussman  Gary Yohe  Rae Zimmerman 《Climatic change》2011,106(1):93-127

While current rates of sea level rise and associated coastal flooding in the New York City region appear to be manageable by stakeholders responsible for communications, energy, transportation, and water infrastructure, projections for sea level rise and associated flooding in the future, especially those associated with rapid icemelt of the Greenland and West Antarctic Icesheets, may be outside the range of current capacity because extreme events might cause flooding beyond today??s planning and preparedness regimes. This paper describes the comprehensive process, approach, and tools for adaptation developed by the New York City Panel on Climate Change (NPCC) in conjunction with the region??s stakeholders who manage its critical infrastructure, much of which lies near the coast. It presents the adaptation framework and the sea-level rise and storm projections related to coastal risks developed through the stakeholder process. Climate change adaptation planning in New York City is characterized by a multi-jurisdictional stakeholder?Cscientist process, state-of-the-art scientific projections and mapping, and development of adaptation strategies based on a risk-management approach.  相似文献   

A comment on the article “A collinearity diagnosis of the GNSS geocenter determination” by P. Rebischung,Z. Altamimi,and T. Springer     

Michael Meindl  Gerhard Beutler  Daniela Thaller  Rolf Dach  Stefan Schaer  Adrian Jäggi 《Journal of Geodesy》2015,89(2):189-194

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Time variable Earth’s gravity field from SLR satellites   总被引：4，自引：4，他引：0  

Krzysztof Sośnica  Adrian Jäggi  Ulrich Meyer  Daniela Thaller  Gerhard Beutler  Daniel Arnold  Rolf Dach 《Journal of Geodesy》2015,89(10):945-960

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