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71.
Clasts of the Late Devonian Keepit Conglomerate of northeastern New South Wales, Australia, are predominantly andesites of isotropic nature that lack any apparent initial shape controls. Given adequate time in a particular environment, these clasts could be reasonably expected to develop shapes characteristic of abrasion within that environment.Clasts from both fluvial and marine resedimented conglomerates of the Keepit Conglomerate possess shape characteristics indicative of shaping within a fluvial environment. Maximum projection sphericity, and a plot of sphericity against either the oblate-prolate index or the flatness parameter C/A, were the most useful in indicating fluvial shaping processes. In addition, the OP Index and the dominant form classes of the Sneed and Folk Sphericity-Form diagram were in support of a fluvial history for the clasts.The occurrence of clasts exhibiting typical fluvial shapes in marine resedimented conglomerates indicates a lack of time and/or insufficient energy in a beach environment for reshaping of the clasts prior to resedimentation into deeper-water submarine-fan environments. This interpretation is consistent with and lends support to the interpretation, based on all other available data, for the Keepit Conglomerate of a history of rapid progradation of fluvial gravels into a relatively low-energy coastline environment, with periodic resedimentation of coarse sediment into deeper water.  相似文献   
72.
The reaction coefficients of nitrogen dioxide and nitrous acid with monodisperse sodium chloride and ammonium sulphate aerosols have been measured in a flow reactor at atmospheric pressure. These experiments were performed at relative humidities above and below the deliquescence points of both aerosols (r.h. 50 and 85%) at 279 K. The results for NO2 afford a reaction coefficient in the range (2.8–10) × 10-4 and for HONO, (2.8–4.6) × 10-3. For both species, there appears to be an enhancement of the reaction coefficient on sodium chloride aerosol at 50% r.h. The results are compared with reaction coefficients determined by other experimental methods. A good agreement is found for both gases between this method and the coated denuder method previously developed in our research laboratories (Msibi et al., 1993) and with the majority of other published data for NO2. In the case of HONO, our estimate of reaction coefficient is smaller than, or at the lower limits of the ranges reported by other published studies.  相似文献   
73.
 The economic and environmental consequences of soil nitrogen tests can have significant impacts on agricultural production. Some of these are explored here. The pre-side-dress soil N-test is evaluated for a hypothetical farmer growing corn at the ARS Sustainable Agriculture Demonstration Farm site in southern Maryland. For a farmer not currently using a soil N-test, adoption of this technology can lead to the enhancement of net farm income and the reduction in nitrogen loss to the environment. This will transpire only if the farmer is currently underestimating nitrogen carryover by more than 25% or applying nitrogen fertilizer based solely on an expected plateau-yield goal. Received: 13 February 1997 · Accepted: 13 May 1997  相似文献   
74.
Entrapped biogenic gas in peat can greatly affect peatland biogeochemical and hydrological processes by altering volumetric water content, peat buoyancy, and ‘saturated’ hydraulic conductivity, and by generating over‐pressure zones. These over‐pressure zones further affect hydraulic gradients which influence water and nutrient flow direction and rate. The dynamics of entrapped gas are of global interest because the loss of this gas to the atmosphere via ebullition (bubbling) is likely the dominant transport mechanism of methane (CH4) to the atmosphere from peatlands, which are the largest natural terrestrial source per annum of atmospheric CH4. We investigated the relationship between atmospheric pressure and temperature on volumetric gas content (VGC) and CH4 ebullition using a laboratory peat core incubation experiment. Peat cores were incubated at three temperatures (one core at 4 °C, three cores at 11 °C, and one core at 20 °C) in sealed PVC cylinders, instrumented to measure VGC, pore‐water CH4 concentrations, and ebullition (volume and CH4 concentrations). Ebullition events primarily occurred (71% of the time) during periods of falling atmospheric pressure. The duration of the drop in atmospheric pressure had a larger control on ebullition volume than the magnitude of the drop. VGC in the 20 °C core increased from the onset of the experiment and reached a fluctuating but time‐averaged constant level between experiment day 30 and 115. The change in VGC was low for the 11 °C cores for the initial period of the experiment but showed large increases when the growth chamber temperature increased to 20 °C due to a malfunction. The core maintained at 4 °C showed only a small increase in entrapped gas content throughout the experiment. The 20 °C core showed the largest increase in VGC. The increases in VGC occurred despite pore‐water concentrations of CH4 being below the equilibrium solubility level. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   
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A maximum a posteriori (MAP) technique is developed to identify solar features in cotemporal and cospatial images of line-of-sight magnetic flux, continuum intensity, and equivalent width observed with the NASA/National Solar Observatory (NSO) Spectromagnetograph (SPM). The technique facilitates human understanding of patterns in large data sets and enables systematic studies of feature characteristics for comparison with models and observations of long-term solar activity and variability. The method uses Bayes’ rule to compute the posterior probability of any feature segmentation of a trio of observed images from per-pixel, class-conditional probabilities derived from independently-segmented training images. Simulated annealing is used to find the most likely segmentation. New algorithms for computing class-conditional probabilities from three-dimensional Gaussian mixture models and interpolated histogram densities are described and compared. A new extension to the spatial smoothing in the Bayesian prior model is introduced, which can incorporate a spatial dependence such as center-to-limb variation. How the spatial scale of training segmentations affects the results is discussed, and a new method for statistical separation of quiet Sun and quiet network is presented.  相似文献   
79.
We introduce a technique for U–Pb dating of baddeleyite using secondary ion mass spectrometry (SIMS) in situ analysis of ng-mass crystals that cannot be efficiently extracted by conventional mineral separation techniques. Average 207Pb/206Pb ages for Precambrian baddeleyite crystals are within < 0.3% of the respective isotope dilution thermal ionization mass spectrometry (ID-TIMS) ages. 206Pb/238U ratios are corrected for instrumental fractionation calibrated through linear regression in a Pb/U relative sensitivity vs. UO2+/U+ calibration plot. Calibration is performed on separated baddeleyite crystals (~ 100–200 μm in maximum dimension) mounted in random crystallographic orientation. 206Pb/238U ages for baddeleyite from Duluth gabbro (FC4b) and Kovdor are accurate within 1–2% when averaging 15–30 individual spot analyses and relative sensitivities calibrated on Phalaborwa baddeleyite. The relative difference of 206Pb/238U between large crystals and micro-baddeleyite from FC4b is within ~ 1%. Comparison between silicate glass and baddeleyite, as well as replicate analysis of the same grains in different orientations relative to the incidence direction of the primary beam support previous evidence for bias in Pb/U sensitivity in baddeleyite due to variable crystal orientations. We successfully utilized oxygen flooding and a UO2+/U+-based calibration to significantly reduce orientation dependent bias.  相似文献   
80.
An in situ U–Pb SIMS (IN-SIMS) method to date micro-baddeleyite crystals as small as 3 μm is presented with results from three samples that span a variety of ages and geologic settings. The method complements ID-TIMS geochronology by extending the range of dateable crystals to sizes smaller than can be recovered by physical separation. X-ray mapping and BSE imaging are used to locate target grains in thin section, followed by SIMS analysis on a CAMECA ims 1270, using the field aperture in the transfer column to screen out ions from host phases. Internal age precisions for the method are anticipated to range from 0.1% for Precambrian rocks to 3–7% for Phanerozoic rocks. Results establish a 2689 ± 5 Ma age for mafic dikes in the Wyoming craton, USA, a 1540 ± 30 Ma age for a subaerial lava flow from the Thelon Basin of northern Canada, and a 457 ± 34 Ma age for mafic dikes in the platform sequence of southeastern Siberia. The method is ideal for relatively non-destructive dating of small samples such as extraterrestrial rocks and precious terrestrial samples.  相似文献   
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