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21.
The Bavanat Cu–Zn–Ag Besshi-type volcanogenic massive sulfide (VMS) deposit occurs within the Surian volcano-sedimentary complex in the Sanandaj–Sirjan zone (SSZ) of southern Iran. The Surian complex is comprised of pelite, sandstone, calcareous shale, basalt, gabbro sills, and thin-bedded limestone. Mineralization occurs as stratiform sheet-like and tabular orebodies hosted mainly by greenschist metamorphosed feldspathic and quartz feldspathic sandstone, basalt, and pelites. The basalts of the Surian complex show predominantly tholeiitic to transitional affinities, with a few samples that are alkalic in composition. Primitive mantle-normalized trace and rare earth element (REE) patterns of the Surian basalts display depletions in light REE, negative anomalies of Nb, Ta, and Ti, and positive anomalies of P. Positive P anomalies are indicative of minor crustal contamination. Furthermore, Th enrichments in the mid-ocean ridge basalt-normalized patterns of the Surian basalts are characteristic of rifted arc basalts emplaced in continental margin subduction zones. The high MgO content (>6?wt.%) of most Surian basalts and low TiO2 content of two samples (0.53 and 0.62?wt.%) are characteristic of boninites. The aforementioned features of the basalts indicate arc tholeiites emplaced in intra-arc rift environments and continental margin subduction zones. U–Pb dating by laser ablation- inductively coupled plasma mass spectrometry of detrital zircons extracted from the host feldspathic and quartz feldspathic sandstone yields various ages that are predominantly Permian and Triassic; however, the youngest zircons give a mean Early Jurassic concordant U–Pb age of 191?±?12?Ma. This age, together with geological and petrochemical data, indicate that VMS mineralization formed in the Early Jurassic in pull-apart basins within the SSZ. These basins and the VMS mineralization may be temporally related to an intra-arc volcano–plutonic event associated with Neo-Tethyan oblique subduction.  相似文献   
22.
The Jinshajiang orogenic belt (JOB) of southwestern China, located along the eastern margin of the Himalayan–Tibetan orogen, includes a collage of continental blocks joined by Paleozoic ophiolitic sutures and Permian volcanic arcs. Three major tectonic stages are recognized based on the volcanic–sedimentary sequence and geochemistry of volcanic rocks in the belt. Westward subduction of the Paleozoic Jinshajiang oceanic plate at the end of Permian resulted in the formation of the Chubarong–Dongzhulin intra-oceanic arc and Jamda–Weixi volcanic arc on the eastern margin of the Changdu continental block. Collision between the volcanic arcs and the Yangtze continent block during Early–Middle Triassic caused the closing of the Jinshajiang oceanic basin and the eruption of high-Si and -Al potassic rhyolitic rocks along the Permian volcanic arc. Slab breakoff or mountain-root delamination under this orogenic belt led to post-collisional crustal extension at the end of the Triassic, forming a series of rift basins on this continental margin arc. Significant potential for VHMS deposits occurs in the submarine volcanic districts of the JOB. Mesozoic VHMS deposits occur in the post-collisional extension environment and cluster in the Late Triassic rift basins.  相似文献   
23.
Porphyry-type Cu (Mo, Au) deposits have been discovered along the Gangdese magmatic arc in the southern Tibetan Plateau. Extensive field investigations and systematic studies of geochemistry, S–Pb isotopic tracing, together with Re–Os and 40Ar/39Ar isotopic dating indicate that the mineralisation of the copper belt is genetically related to emplacement of late orogenic granitic porphyries during the post-collisional crustal relaxation period of the Late Himalayan epoch. These porphyries are petrochemically K-enriched and belong to shoshonitic to high-K calc-alkaline series. They display enrichment of large ion lithophile elements (LILE) Rb, K, U, Th, Sr, Pb and depletion of high field strength elements (HFSE) Nb, Ta, Ti and the heavy rare earth elements (HREE) and Y without Eu anomalies. These characteristics demonstrate that subduction played a dominant role in their petrogenesis and residual garnet was left in the magma sources. Pb isotope data show a linear correlation in the plumbotectonic framework diagram ranging from orogenic Pb in the eastern segment of the copper belt to mantle Pb in the western segment. These constitute a mixing line of the Indian Oceanic MORB with Indian Oceanic sediments and suggest that the porphyry magmas were dominantly derived from partial melting of subducted oceanic crusts mixed with a minor quantity of sediments and mantle wedge components.The Gangdese porphyry copper polymetallic belt has alteration characteristics and zonation typical of porphyry-type copper deposits which include potassic alteration (K-feldspathisation and biotitisation), silicification, sericitisation, and propylitisation. Mineralisation mainly occurs in strongly altered granitic cataclasite at the exo-contact with veinlet-disseminated textures. The porphyries themselves are weakly mineralised with disseminated pyrite and chalcopyrite. The copper deposits contain simple ore mineral associations consisting of chalcopyrite, pyrite, bornite, molybdenite, sphalerite and oxidised minerals of malachite, covellite and molybdite. During supergene oxidation, primary ores underwent secondary enrichment to form economic orebodies with Cu grade ranging from 1% to 5%.Ore sulphides of the copper belt display S and Pb isotopic compositions identical to the ore-bearing porphyries. Their δ34S values vary between − 3.8‰ and + 2.4‰ and are typical of mantle sulphur. The 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb ratios vary in the ranges: 18.106 to 18.752, 15.501 to 15.638, and 37.394 to 39.058, respectively, and yielded radiogenetic lead-enriched signatures. Twelve molybdenite samples from the copper belt yielded isochron ages of 14.76 ± 0.22 Ma and 13.99 ± 0.16 Ma for the Nanmu and Chongjiang deposits and model ages of 13.5 to 13.6 Ma for the Lakang'e deposit. Meanwhile, 40Ar/39Ar isotopic dating of two biotite phenocrysts from the Chongjiang and Lakang'e deposits give plateau ages of 13.5 ± 1.0 Ma and 13.42 ±0.10 Ma, respectively. During the geodynamic evolution of the Gangdese collision-orogenic belt, intrusion of the ore-bearing porphyries took place just before the rapid uplift and E–W extension of the southern Plateau. And the ore-forming process may have occurred simultaneously with the uplift and extension (14 ± 0.1 Ma).  相似文献   
24.
Tectonically, the Sanjiang Tethyan Metallogenic Domain (STMD) is located within the eastern Himalayan–Tibetan Orogen in the Sanjiang Tethys, southwestern China. Although this metallogenic domain was initiated in the Early Palaeozoic, extensive metallogenesis occurred in the Late Palaeozoic, Late Triassic and Himalayan (Tertiary) epochs. Corresponding tectonic settings and environments in the domain are: an arc-basin system related to the subduction of the Palaeo-Tethyan oceanic slabs; a post-collision crustal extension setting caused by the lithospheric delamination or slab breakoff underneath the Sanjiang Tethys during the Late Triassic; large-scale strike-slip faulting and thrusting systems due to the Indo-Asian continent collision since the Palaeocene. In this metallogenic domain important gold, copper, base metals, rare metals and tin ore belts, incorporating a large number of giant deposits, were developed. The main types of deposits include: (1) porphyry copper deposits, controlled by a large-scale strike-slip fault system, (2) VHMS deposits, mainly occurring in intra-arc rift basins and post-collision crustal extensional basins, (3) shear-zone type gold deposits in the ophiolitic mélange zone along the thrusting–shearing system, (4) hydrothermal silver-polymetallic deposits in the Triassic intra-continental rift basins and Tertiary strike-slip pull-apart basins, and (5) Himalayan granite-related greisen-type tin and rare-metallic deposits. Within the metallogenic epochs of the Late Palaeozoic to Cenozoic, the styles and types of the ore deposits changed from VHMS types in the Late Palaeozoic through exhalative-sedimentary type deposits in the Late Triassic, to porphyry-type copper deposits, shear-zone type gold deposits, hydrothermal vein-type silver-polymetallic deposits, greisen-type tin and rare-metal deposits in the Cenozoic. Correspondingly, ore-forming metals also changed from a Pb–Zn–Cu–Ag association through Ag–Cu–Pb–Zn, Fe–Ag–Pb and Ag–Au–Hg associations, to Ag–Cu–Pb–Zn, Cu–Mo, Au, Sn, and Li–Rb–Cs–Nb–Zr–Hf–Y–Ce–Sc associations.  相似文献   
25.
Gold-copper-bismuth mineralization in the Tennant Creek goldfield of the Northern Territory occurs in pipe-like, ellipsoidal, or lensoidal lodes of magnetite ± hematite ironstones which are hosted in turbiditic sedimentary rocks of Proterozoic age. Fluid inclusion studies have revealed four major inclusion types in quartz associated with mineralized and barren ironstones at Ten nant Creek; (1) liquid-vapour inclusions with low liquid/vapour ratios (Type I), (2) liquid-vapour inclusions with high liquid/vapour ratios or high vapour/liquid ratios and characteristic dark bubbles (Type II), (3) liquid-vapour-halite inclusions (Type III), and (4) liquid-vapour inclusions with variable liquid/vapour ratios (Type V). Type I inclusions are present in the barren ironstones and the unmineralized portions of fertile ironstones, whereas Types II and III inclusions are recognized in fertile ironstones. Trails of Types II and III inclusions cut trails of Type I inclusions. Type I fluid inclusions have homogenization temperatures of 100° to 350 °C with a mode at 200° to 250 °C. Type II inclusions in mineralized ironstones (e.g. Juno, White Devil, Eldorado, TC8 and Gecko K-44 deposits) have homogenization temperatures of 250 °C to 600 °C with a mode of 350 °C. Type I fluid inclusions have a salinity range of 10 to 30 NaCl equiv. wt %. Salinity measurements on fluid inclusions in the mineralized zones gave a range of 10 to 50 NaCl equiv. wt % with a mode of 35 NaCl equiv. wt %. Fluid inclusion studies indicate that the Tennant Creek ironstones were formed from a relatively low temperature and moderately saline fluid, where as gold and copper mineralization was deposited from later hydrothermal fluids of higher temperature and salin ity. Gas analysis indicates the presence of N2 and CO2, with very minor CH4 in Types II inclusions but no N2 or CH4 gases in Type I inclusions. Microprobe analysis of the fluid inclusion decrepitates indicates that the inclusions from Tennant Creek contain sodium and calcium as dominant cations and potassium in a subordinate amount. The high temperatures ( 350 °C), high salinities ( 35 NaCl equiv. wt. %) and cation composition of the Tennant Creek ore fluids suggest that the ore fluids were derived from upward migrating heated basinal brines, although contribution from a magmatic source cannot be ruled out. Close association of vapour-rich Type IIb and salt-rich Type III inclusions in the mineralized ironstones (e.g. Juno, White Devil, Eldorado, TC8 and Gecko K-44) indicates heterogeneous trapping of ore fluids. This heterogeneous trapping is interpreted to be due to unmixing (exsolution) of a gas-rich (e.g. N2) fluid during the upward migration of the metal bearing brines and/or due to degassing caused by reaction of oxidized ore fluids and host ironstones. Fluid inclusion data have important implications regarding the deposition of gold in the ironstones, and may have application in discriminating fertile from barren ironstones.  相似文献   
26.
Zusammenfassung Aus 19 Profilen der eisenoolith-führenden Minette (Toarcium-Aalenium), ihrem Liegenden (Toarcium) und Hangenden (Bajocium), sowie aus dem erzführenden Aalenium der Vorbergzone des Schwarzwaldes wurden an 1253 Proben folgende Elemente und der HCl/HNO3 — unlösliche Rückstand ( SiO2) bestimmt: Na, Mg, Al, P, S, K, Ca, Ti, V, Cr, Mn, Fe, Fe2+, Co, Ni, Cu, Zn, As, Sr, Ba und Pb. Die Auswertung des umfangreichen Datenmaterials erfolgte mit Hilfe verschiedener multivariater statistischer Verfahren. Es zeichnen sich stratigraphische und regionale Trends ab, die im Zusammenhang mit der Genese der Lagerstätte diskutiert werden. Die Eisenooide sind in Latosolen auf dem Festland entstanden und wie bei Lagerstätten des Salzgitter-Typs als klastische Abtragungsprodukte lateritischer Verwitterungsdecken ins Meer verfrachtet worden. Auf einem ausgedehnten Schelfareal wurden die Erzkörner in flachem Wasser mehrfach umgelagert, sortiert und schließlich als marine Seife konzentriert. Auch andere mesozoisch-känozoische Lagerstätten des Minette-Typs sind wahrscheinlich auf diese Weise entstanden. Das Modell erklärt Herkunft und Transport des Eisens auf aktualistische Weise und steht im Einklang mit bekannten geochemischen Befunden, wonach sowohl in Lateriten als auch in Minette-Erzen die Elemente Al, Si, Ti, V, Cr, Mn und P als Begleiter des Eisens auftreten.
Summary On 1253 samples of 19 vertical sections from the oolitic Minette ironstone (Toarcian — Aalenian, Luxemburg, Lorraine), its under- and overlying beds and from the aalenian oolitic ironstone of the Freiburg region, the following elements have been analysed: Na, Mg, Al, P, S, K, Ca, Ti, V, Cr, Mn, Fe, Fe2+, Co, Ni, Cu, Zn, As, Sr, Ba, Pb and the insoluble residu in HCI/HNO3. Data processing has been accomplished by different methods of multivariate statistics. The results show stratigraphical and regional trends which are discussed in connexion with the genesis of the ore deposit. We believe, that the iron oolites derive from latosols of continental areas. After erosion of the lateritic caprock the oolitic grains were transported into thes ea. The iron ore particles were then winnowed in shallow marine water to be finally concentrated as a marine placer — similar to the Lower Cretaceous iron ores of Salzgitter, Lower Saxony. Other mesozoic to cainozoic deposits of the Minette-type have probably been formed in the same manner. This model explains in a simple and actuogeological way the origin and transport of iron and is fully compatible with the wellknown occurence of the elements Al, Si, Ti, V, Cr, Mn and P, accompanying the iron in laterites as well as in Minette-type ores.

Résumé Les éléments Na, Mg, Al, P, S, K, Ca, Ti, V, Cr, Mn, Fe, Fe2+, Co, Ni, Cu, Zn, As, Sr, Ba, Pb et le résidu insoluble à HCl/HNO3 ont été analysés sur 1253 échantillons, soit 19 coupes du minerai de fer oolithique toarcien — aalénien de la minette, de son mur et de son toit ainsi que des couches aaléniennes de la région de Fribourg. Le grand nombre des données a été traité à l'aide de méthodes différentes de la statistique multivariable. Il en résulte des tendances stratigraphiques et régionales qui sont discutées en rapport avec la genèse du minerai. Les oolithes ont pris naissance dans des sols latéritiques sur le continent et ont été transportées ensuite au cours de l'érosion comme produits détritiques dans la mer (comparable aux minerais du type Salzgitter). Sur un vaste shelf peu profond les grains de minerai ont été déplacés plusieurs fois pour Être enfin concentrés à la faÇon de placers marins. Pendant les temps mésozoiques et cénozoiques d'autres gÎtes oolithiques stratiformes du type minette se sont peut-Être formés de la mÊme manière. Ce modèle de formation explique de faÇon simple et actuelle la provenance et le mode de transport du fer et correspond avec des résultats géochimiques connus d'après lesquels des éléments Al, Si, Ti, V, Cr, Mn et P accompagnent le fer aussi bien dans des latérites que dans des minerais de fer du type minette.

1253 19- ToarciumAalenium. (Toarcium) (Bajocium) Aafenium : Na, Mg, Al, , S, , , , V, Cr, Mn, Fe, Fe2+, , Ni, Cu, Zn, As, Sr, Pb , NCl/HNO3, .. . . ; . — — , . , , , . - . , , . : Al, Si, , V, Cr, Mn, P
  相似文献   
27.
The Geological Institute of Bonn University since 1975 investigates in connection with DSDP/IPOD the Cretaceous of the Atlantic coastal basin in south-western Morocco. 30 main stratigraphic sections and numerous auxiliary ones were taken along several traverses, running along distances of 150 to 200 km in west-east direction. The recognized epicontinental facies-pattern along the traverse of the southern High Atlas mountain range depicts clearly, that we cut here the critical region of intertonguing marine, fine-clastic-carbonaceous sediments and continental detritic deposits. The littoral zone successively progrades with three major transgressions (Neocomian, Upper Aptian, Turonian) towards the African Continent. Sedimentation processes, stratigraphy, paleomagnetics, geochemistry, sedimentology and paleogeography are investigated, taking selected horizons on one hand and complete stratigraphic columns on the other. A new sedimentation model reflecting transgression and regression events in the Cretaceous “Atlas Gulf” show some probabilities of eustatic sea-level changes. There are similarities between the Atlas Gulf and other coastal basins on both sides of the Atlantic Ocean. There are certain relations between the sedimentary record of the proand regrading littoral zone on the continent and in the nearby deep sea deposits. There is an exciting coincidence between the stratigraphie succession of the downwarping Atlas Gulf and the sedimentary cover of the interior of Africa, especially the Mesozoic Sahara Basin.  相似文献   
28.
Whole‐rock geochemical and Sr–Nd isotopic data are presented for late Miocene volcanic rocks associated with the Chah Zard epithermal Au–Ag deposit in the Urumieh‐Dokhtar Magmatic Arc (UDMA), Iran, to investigate the magma source, petrogenesis and the geodynamic evolution of the study area. The Chah Zard andesitic to rhyolitic volcanic rocks are characterized by significant Large Ion Lithophile Element (LILE) and Light Rare Earth Element (LREE) enrichment coupled with High Field Strength Element (HFSE) depletion. Our geochemical data indicate an adakitic‐like signature for the volcanic rocks (e.g. SiO2 > 62 wt%, Al2O3 > 15 wt%, MgO < 1.5 wt%, Sr/Y > 70, La/Yb > 35, Yb < 1 ppm, and Y < 18 ppm, and no significant Eu anomalies), distinguishing them from the other volcanic rocks of the UDMA. The Chah Zard volcanic rocks have similar Sr and Nd isotopic compositions; the 87Sr/86Sr(i) ratios range from 0.704 902 to 0.705 093 and the εNd(i) values are from +2.33 to +2.70. However, the rhyolite porphyry represents the final stage of magmatism in the area and has a relatively high 87Sr/86Sr ratio (0.705 811). Our data suggest that the andesitic magmas are from a heterogeneous source and likely to result from partial melting of a metasomatized mantle wedge associated with a mixture of subducted oceanic crust and sediment. These melts subsequently underwent fractional crystallization along with minor amounts of crustal assimilation. Our study is consistent with the model that the volcanic host rocks to epithermal gold mineralization in the UDMA are genetically related to late Miocene Neo‐Tethyan slab break‐off beneath Central Iran.  相似文献   
29.
Lead isotope data of sulfides and host volcanic rocks from the Bukit Botol and Bukit Ketaya deposits, the two representative deposits of the Tasik Chini volcanic‐hosted massive sulfide (VHMS) deposit, Central Belt of Peninsular Malaysia, are reported. Lead isotope compositions of the associated sulfide minerals and volcanic rocks from the Bukit Botol deposit exhibit homogeneous and less radiogenic values (206Pb/204Pb showing a range of composition from 18.14 to 18.20, 207Pb/204Pb between 15.52 and 15.59 and 208Pb/204Pb from 37.96 to 38.35). Similarly, the Pb isotopic compositions of the host volcanic rocks from the Bukit Ketaya deposit yielded a narrow range to those of the sulfide samples (206Pb/204Pb from 18.04 to 18.20, 207Pb/204Pb between 15.43 and 15.57 and 208Pb/204Pb of 37.96 to 38.30). The uniform Pb‐isotope compositions of the sulfides in the ore horizon and the host volcanic rocks from both deposits suggest a derivation from a similar source reservoir and mineralization processes. In the framework of the tectonic model for the Central Belt of Peninsular Malaysia, both deposits display a range of lead isotopic compositions originated from mixing of bulk crust/juvenile arc and minor mantle sources, which are typical for VHMS deposits in an island arc–back arc setting.  相似文献   
30.
Introduction The Rheinisches Schiefergebirge, the northern,non metamorphic part of the Hercynian orogen in Middle Europe is one of the most excellent examples of a stable continental area, deeply weathered under a tropical to subtropical climate during upper Mesozoic and especially Paleogene periods.  相似文献   
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