Hydrogen incorporation into forsterite in Mg2SiO4–K2Mg(CO3)2–H2O and Mg2SiO4–H2O–C at 7.5–14.0 GPa     

K.D. Litasov  A.F. Shatskiy  Yu.N. Pal’yanov  A.G. Sokol  T. Katsura  E. Ohtani 《Russian Geology and Geophysics》2009,50(12):1129-1138

Experiments on water solubility in forsterite in the systems Mg₂SiO₄–K₂Mg(CO₃)₂–H₂O and Mg₂SiO₄–H₂O–C were conducted at 7.5–14.0 GPa and 1200–1600 °C. The resulting crystals contain 448 to 1480 ppm water, which is 40–70% less than in the forsterite–water system under the same conditions. This can be attributed to lower water activity in the carbonate-bearing melt. The water content of forsterite was found to vary systematically with temperature and pressure. For instance, at 14 GPa in the system forsterite–carbonate–H₂O the H₂O content of forsterite drops from 1140 ppm at 1200 °C to 450 ppm at 1600 °C, and at 8 GPa it remains constant or increases from 550 to 870 ppm at 1300–1600 °C. Preliminary data for D-H-bearing forsterite are reported. Considerable differences were found between IR spectra of D-H- and H-bearing forsterite. The results suggest that CO₂ can significantly affect the width of the olivine-wadsleyite transition, i.e., the 410-km seismic discontinuity, which is a function of the water content of olivine and wadsleyite.  相似文献   

Newly-generated Daliangshan Fault Zone—Shortcutting on the central section of Xianshuihe-Xiaojiang fault system   总被引：3，自引：0，他引：3  

HongLin He  Yasutaka Ikeda  YuLin He  Masayoshi Togo  Jie Chen  ChangYun Chen  Masayoshi Tajikara  Tomoo Echigo  Shinsuke Okada 《中国科学D辑(英文版)》2008,51(9):1248-1258

The Daliangshan fault zone is the eastern branch in the central section of Xianshuihe-Xiaojiang fault system. It has been neglected for a long time, partly because of no destructive earthquake records along this fault zone. On the other hand, it is located on the remote and inaccessible plateau. So far it was excluded as part of the Xianshuihe-Xiaojiang fault system. Based on the interpretation of aerophotographs and field investigations, we document this fault zone in detail, and give an estimation of strike-slip rate about 3 mm/a in Late Quaternary together with age dating data. The results suggest that the Daliangshan fault zone is a newly-generated fault zone resulted from shortcutting in the central section of Xianshuihe-Xiaojiang fault system because of the clockwise rotation of the Southeastern Tibetan Crustal Block, which is bounded by the Xianshuihe-Xiaojiang fault system. Moreover, the shortcutting may make the Daliangshan fault zone replace the Anninghe and Zemuhe fault zones gradually, and finally, the later two fault zones will probably die out with the continuous clockwise rotation.  相似文献   

Boron cycling by subducted lithosphere; insights from diamondiferous tourmaline from the Kokchetav ultrahigh-pressure metamorphic belt     

Tsutomu Ota  Katsura Kobayashi  Takuya Kunihiro  Eizo Nakamura 《Geochimica et cosmochimica acta》2008,72(14):3531-3541

Subduction of lithosphere, involving surficial materials, into the deep mantle is fundamental to the chemical evolution of the Earth. However, the chemical evolution of the lithosphere during subduction to depth remains equivocal. In order to identify materials subjected to geological processes near the surface and at depths in subduction zones, we examined B and Li isotopes behavior in a unique diamondiferous, K-rich tourmaline (K-tourmaline) from the Kokchetav ultrahigh-pressure metamorphic belt. The K-tourmaline, which includes microdiamonds in its core, is enriched in ¹¹B relative to ¹⁰B (δ¹¹B = −1.2 to +7.7) and ⁷Li relative to ⁶Li (δ⁷Li = −1.1 to +3.1). It is suggested that the K-tourmaline crystallized at high-pressure in the diamond stability field from a silicate melt generated at high-pressure and temperature conditions of the Kokchetav peak metamorphism. The heavy isotope signature of this K-tourmaline differs from that of ordinary Na-tourmalines in crustal rocks, enriched in the light B isotope (δ¹¹B = −16.6 to −2.3), which experienced isotope fractionation through metamorphic dehydration reactions. A possible source of the heavy B-isotope signature is serpentine in the subducted lithospheric mantle. Serpentinization of the lithospheric mantle, with enrichment of heavy B-isotope, can be produced by normal faulting at trench-outer rise or trench slope regions, followed by penetration of seawater into the lithospheric mantle. Serpentine breakdown in the lithospheric mantle subducted in subarc regions likely provided fluids with the heavy B-isotope signature, which was acquired during the serpentinization prior to subduction. The fluids could ascend and cause partial melting of the overlying crustal layer, and the resultant silicate melt could inherit the heavy B-isotope signature. The subducting lithospheric mantle is a key repository for modeling the flux of fluids and associated elements acquired at a near the surface into the deep mantle.  相似文献   

Geological structure of the marginal plateau off Tottori,Southern-West of Honshu,Japan     

Tadahiko Katsura  Shoji Kitahara 《Journal of Oceanography》1977,33(5):259-266

A geological and geophysical survey off Tottori, southern-west of Honshu, Japan, was carried out by the Hydrographic Department of Japan during May and June (26 days) of 1974.In the survey area, there is marginal plateau which lies under the slope of the continental shelf adjacent to the Sanin district. By the closely-spaced surveying the marginal plateau was divided into two different zones based on differences of genesis and structure, which are identified in this paper as marginal plateaus A (west side) and marginal plateau B (east side). The tectonic boundary between marginal plateaus A and B, previously believed to exist near Tottori City, was not confirmed. An erosional plane, beneath the horizontally bedded upper layer was found to be 75 m lower than the submerged surface of marginal plateau A. Marginal plateau B is hypothesized to have been generated by the sliding of the upper layer. This is suggested by the presence of prominent slumping directed toward the bottom of the Oki Trough. This result implies that the submergence of the Oki Trough area and formation of the marginal plateau are closely related.  相似文献   

Seismic response controlled structure with Active Variable Stiffness system     

Takuji Kobori  Motoichi Takahashi  Tadashi Nasu  Naoki Niwa  Katsura Ogasawara 《地震工程与结构动力学》1993,22(11):925-941

The Active Variable Stiffness (AVS) system is proposed as a seismic response control system. It actively controls structural characteristics, such as stiffness of a building, to establish a non-resonant state against earthquake excitations, thus suppressing the building's response. It consumes a relatively small amount of energy and maintains the safety of the building in moderate to severe earthquakes. In order to accumulate practical data and investigate them, a building has been constructed as a trial. This paper describes the applied system, the control algorithm, verification of stiffness selection, results of tests for verifying system characteristics, some observed earthquake records and simulation analyses. Responses in controlled and uncontrolled states have been compared to show the effectiveness of the proposed system.  相似文献   

Electrical conductivity measurement of granulite under mid- to lower crustal pressure–temperature conditions     

K. Fuji-ta  T. Katsura  Y. Tainosho 《Geophysical Journal International》2004,157(1):79-86

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Connectivity of molten Fe alloy in peridotite based on in situ electrical conductivity measurements: implications for core formation in terrestrial planets   总被引：1，自引：0，他引：1  

Takashi Yoshino  Tomoo Katsura 《Earth and Planetary Science Letters》2004,222(2):625-643

The connectivity of molten Fe-S in peridotite has been experimentally investigated by means of in situ electrical conductivity measurements at high temperatures and 1 GPa. Starting materials were powdered mixtures of peridotite KLB-1 with various amounts (0, 3, 6, 13, 19, 24 vol.%) of the 1 GPa eutectic composition in the Fe-FeS binary system. At temperatures above the eutectic point in the Fe-FeS system (∼980 °C) and below the solidus of KLB1 (∼1200 °C), molten Fe-S in a solid silicate matrix interconnects when the volume fraction is over ∼5%. Conductivity-temperature paths indicate that in the presence of partial silicate melting the connectivity of molten Fe-S in a peridotite matrix is inhibited. Based on observations of retrieved samples, the percolation threshold of Fe-S melts in the presence of low to moderate degrees of silicate melt is estimated at 13±2 vol.%. These results indicate that if the volume fraction of Fe-alloy in a planetesimal was initially greater than 5%, and if early heating by decay of radionuclides raised the temperature of the interior above the Fe-alloy melting point, initial metal segregation was controlled by permeable flow of molten iron alloy in a solid silicate matrix. These conditions were likely met by many terrestrial objects in the early solar nebula. Efficient removal of residual Fe-alloy (5 vol.%) from silicate requires high-degree melting of silicate so that metal can segregate as droplets. Giant impacts during the final stage of accretion of large planetary objects could supply the energy required for high-degrees of melting. Alternatively, if initial metal segregation were delayed until a planetary object grew to large size (∼1000 km in diameter), release of gravitational potential energy due to metal segregation could contribute enough heat to form a magma ocean.  相似文献   

Sedimentation in epithermal veins of the Bohemia mining district,Oregon, USA: Interpretations and significance     

J. Schieber  K. T. Katsura 《Mineralium Deposita》1986,21(4):322-328

Open spaces in epithermal veins of the Bohemia mining district, Oregon, USA, filled with sediments during hydrothermal activity. These sediments consist mainly of chalcedony, rock fragments, and vein quartz fragments. In addition, hematite is deposited during stage three of the vein development. Observed sedimentary features include draping laminae, erosion surfaces, slumping, and graded bedding. Such sediments can be used for reconstruction of the original orientation of vein systems, because the sediment laminae are initially deposited horizontally. Vein sediments record variations in fluid flow due to self-sealing, fracturing, and cessation of hydrothermal activity. Investigation of vein sediments therefore provides an additional tool to unravel the geologic history of epithermal systems. The chalcedonic vein sediments record large temperature drops and highly silica supersaturated waters, probably due to fracturing and pressure release. Hematitic vein sediments indicate sulfide deficient hydrothermal fluids.  相似文献   

Nonaqueous titration of functional groups in humic acid     

Koyo Yonebayashi  Tomoo Hattori 《Organic Geochemistry》1985,8(1):47-54

Humic acid was titrated by sodium methoxide in dimethylsulfoxide using platinum-calomel electrode systems. Adding benzoic acid and phenol as internal standards to humic acid yielded two inflections. The titer at the first inflection point was equivalent to the carboxyl groups whose pK_a (H₂O) values were less than 7. The difference between the titers at the two inflection points was equivalent to the phenolic hydroxyl groups whose pK_a (H₂O) values were 7–10. Calculated results for the carboxyl and phenolic hydroxyl groups in humic acid obtained by the nonaqueous titration method agreed closely with those obtained by conventional methods.  相似文献   

Determination of Chromium, Nickel, Copper and Zinc in Milligram Samples of Geological Materials Using Isotope Dilution High Resolution Inductively Coupled Plasma-Mass Spectrometry     

Akio Makishima  Katsura Kobayashi  Eizo Nakamura 《Geostandards and Geoanalytical Research》2002,26(1):41-51

A simple and accurate method for the determination of Cr, Ni, Cu and Zn at μg g^?1 levels in milligram‐sized bulk silicate materials is reported using isotope dilution high‐resolution inductively coupled plasma‐mass spectrometry (HR‐ICP‐MS) with a flow injection system. Silicate samples with Cr, Ni, Cu and Zn spikes were digested with HF‐HBr and Br₂, and subsequently decomposed at 518 K in a Teflon bomb. In this procedure, all sulfides and chromite, major hosts of these elements, were completely decomposed, thus allowing for isotope equilibration between the sample and spike. Magnesium and Al fluorides formed after the digestion of the sample were removed by centrifugation, and the supernatant was directly aspirated into a HR‐ICP‐MS at a mass resolution of 7500, where interfering oxide ions, ArO⁺, CaO⁺, TiO⁺, CrO⁺ and VO⁺, were separated from Cr⁺, Ni⁺, Cu⁺ and Zn⁺. No matrix effects were observed down to a dilution factor of 50. Detection limits for these elements in silicate samples were < 0.04 μg g^?1. The effectiveness of the technique was demonstrated by the analysis of 13 to 40 mg test portions of USGS and GSJ silicate reference materials with a major element composition ranging from andesite to peridotite, in addition to 8‐23 mg of the Smithsonian reference Allende. Both the reproducibility and the deviation from the reference value for most reference materials of various rock types were < 9%, and thus confirm that the method gives accurate analytical results for small sample sizes over a wide range of Cr, Ni, Cu and Zn contents. This method is, therefore, suitable for analysing small and/or precious bulk samples, such as meteorites, mantle peridotites and mineral separates, and for the characterisation of silicate and sulfide minerals for use as calibration samples in secondary ion mass spectrometry or laser ablation ICP‐MS.  相似文献