Titan's atmospheric chemistry: Photolysis of gas mixtures containing hydrogen cyanide and carbon monoxide at 185 and 254 nm     

Buu N. Tran  Robert G. Briggs  Peter Persans 《Icarus》2008,193(1):224-232

The formation of organic compounds in the atmosphere of Titan is an ongoing process of the generation of complex organics from the simplest hydrocarbon, methane. Solar radiation and magnetosphere electrons are the main energy sources that drive the reactions in Titan's atmosphere. Since energy from solar radiation is 200 times greater than that from magnetosphere electrons, we have investigated the products formed by the action of UV radiation (185 and 254 nm) on a mixture of gases containing nitrogen, methane, hydrogen, acetylene, ethylene, and cyanoacetylene, the basic gas mixture (BGM) that simulates aspects of Titan's atmosphere using a flow reactor [Tran, B.N., Ferris, J.P., Chera, J.J., 2003a. Icarus 162, 114-124; Tran, B.N., Joseph, J.C., Force, M., Briggs, R.G., Vuitton, V., Ferris, J.P., 2005. Icarus 177, 106-115]. The present research extends these studies by the addition of carbon monoxide and hydrogen cyanide to the BGM. Quantum yields for the loss of reactants and the formation of volatile products were determined and compared with those measured in the absence of the hydrogen cyanide and carbon monoxide. The GCMS analyses of the volatile photolysis products from the BGM, with added hydrogen cyanide, had a composition similar to that of the BGM while the photolysis products of the BGM with added carbon monoxide contained many oxygenated compounds. The infrared spectrum of the corresponding solid product revealed the absorption band of a ketone group, which was probably formed from the reaction of carbon monoxide with the free radicals generated by photolysis of acetylene and ethylene. Of particular interest was the observation that the addition of HCN to the gas mixture only resulted in a very small change in the C/N ratio and in the intensity of the CN frequency at 2210 cm⁻¹ in the infrared spectrum suggesting that little HCN is incorporated into the haze analog. The C/N ratio of the haze analogs was found to be in the 10-12 range. The UV spectra of the solid products formed when HCN or CO added to the BGM is similar to the UV absorption formed from the BGM alone. This result is consistent with absence of additional UV chromophores to the solid product when these mixtures are photolyzed. The following photoproducts, which were not starting materials in our photochemical studies, have been observed on Titan: acetonitrile, benzene, diacetylene, ethane, propene, propane, and propyne.  相似文献   

Assessment of earthquake hazard for the northwestern Vietnam from geological and geophysical data using an original program package     

Ngo?Thi?LuEmail author  M.?V.?Rodkin  Tran?Viet?Phuong  Nguyen?Quang  Phung?Thi?Thu Hang  Vu?Thi?Hoan 《Journal of Volcanology and Seismology》2017,11(2):164-171

The highest seismic activity in Vietnam is observed in the northwest of the country, hence the practical significance of more accurate assessment of the earthquake hazard for the area. The worldwide experience of seismicity, in particular, the recent Tohoku mega-earthquake (March 11, 2011, M _w = 9.0, Japan) shows that instrumental and historical data alone are insufficient to reliably estimate earthquake hazard. This is all the more relevant in relation to Vietnam where the period of instrumental observation is short and historical evidence is nearly lacking. In this connection we made an attempt to construct maps of earthquake hazard based on known seismicity data using the available geological and geophysical data and the method of G.I. Reisner and his associates for classification of areas by seismic potential. Since the question of what geological and geophysical parameters are to be used and with what weights remains unresolved, we developed a program package to estimate Mmax based on different options in the use of geological and geophysical data. In this paper we discuss the first results and the promise held by this program package.  相似文献   

An Application of HFE-D for Evaluating Sea Water Intrusion in Coastal Aquifers of Southern Vietnam     

Thi Thuy Van Le  Rungruang Lertsirivorakul  Tran Vuong Bui  Marcia K. Schulmeister 《Ground water》2020,58(6):1012-1022

The coastal aquifers and inland waters of the Long Xuyen Quadrangle and Ca Mau Peninsula of southern Vietnam have been significantly impacted by sea water intrusion (SI) as a result of recent anthropogenic activities. This study identified the evolution and spatial distribution of hydrochemical conditions in coastal aquifers at this region using Hydrochemical Facies Evolution Diagram (HFE-D) and Geographical Information System mapping. Hydraulic heads and water chemistry were measured at 31 observation wells in four layered aquifers during dry and rainy seasons in early (2005), and more recent (2016), stages of agricultural development. Hydrochemical facies associated with intrusion or freshening stages were mapped in each aquifer after assigning mixing index values to each facies. The position of groundwater freshening and SI phases differed in Holocene, Upper Pleistocene, Middle Pleistocene, and Lower Pleistocene aquifers. The geographic position of freshening and intrusion fronts differ in dry and rainy seasons, and shifted after 11 years of groundwater abstraction in all four aquifers. The spatial and temporal differences in hydrochemical facies distributions according to HFE-D reflect the relative impact of SI in the four aquifers. The study results provide a better understanding of the evolution of groundwater quality associated with SI in a peninsular coastal aquifer system, and highlight the need for improving groundwater quality and management in similar coastal regions.  相似文献   

Preliminary Results of Anthropogenic Seismicity Monitoring in the Region of Song Tranh 2 Reservoir,Central Vietnam     

Jan Wiszniowski  Nguyen Van Giang  Beata Plesiewicz  Grzegorz Lizurek  Dinh Quoc Van  Le Quang Khoi  Stanisław Lasocki 《Acta Geophysica》2015,63(3):843-862

Song Tranh 2 hydropower plant and the reservoir containing backed up water are located in the Quang Nam province (Central Vietnam). The region experiences unusual seismic activity related to the reservoir impoundment, with earthquakes of magnitude up to 4.7. In result of cooperation between the Institute of Geophysics, Vietnam Academy of Sciences and Technology and the Institute of Geophysics, Polish Academy of Sciences a seismic network has been built to facilitate seismic monitoring of the Song Tranh 2 area. The network, operating since August 2013, consists of 10 seismic stations. Here we show that the network is sufficient for advanced data processing. The first results of monitoring of the earthquake activity in Song Tranh 2 area in the period between 2012 and 2014, especially the completeness of catalogs, study and comparisons between water level and the seismic activity suggest direct connection between reservoir exploitation and anthropogenic seismicity.  相似文献   

Daily precipitation concentration in Central Coast Vietnam     

Benhamrouche  Aziz  Martin-Vide  Javier  Pham  Quoc Bao  Kouachi  Mostefa E.  Moreno-Garcia  M. Carmen 《Theoretical and Applied Climatology》2022,147(1-2):37-45

Theoretical and Applied Climatology - Empirical frequency distribution of daily precipitation amounts can be fitted by a negative exponential distribution, because anywhere there are many small...  相似文献   

Meshless BEM and overlapping Schwarz preconditioners for exterior problems on spheroids     

Adrian Costea  Quoc T. Le Gia  Ernst P. Stephan  Thanh Tran 《Studia Geophysica et Geodaetica》2011,55(3):465-477

We consider the exterior Neumann problem of the Laplacian with boundary condition on spheroids. We propose to use spherical radial basis functions in the solution of the boundary integral equation arising from the Dirichlet-to-Neumann map. Our meshless approach with radial basis functions is particularly suitable for handling scattered satellite data. We also propose a preconditioning technique based on an overlapping domain decomposition method to deal with ill-conditioned matrices arising from the approximation problem.  相似文献   

Geogene Versus Anthropogene Origin of Trace Metals in Sediments in Cua Luc Estuary and Ha Long Bay, Vietnam     

Huu Hieu Ho  Rudy Swennen  Valérie Cappuyns  Elvira Vassilieva  Gerda Neyens  Mustafa Rajabali  Tan Van Tran 《Estuaries and Coasts》2013,36(1):203-219

In the present study, the geochemistry of 49 surficial-bed and 101 core sediment samples is investigated to clarify the origin of trace metals in the Cua Luc Estuary and Ha Long Bay, which is a famous World Natural Heritage Site in Vietnam. Moreover, the potential mobility of trace metals is also assessed and their relationship with reference elements (Al, Fe, and Ca) and organic matter is established in order to make recommendations for sediment management and monitor future pollution. Generally, trace metals display higher concentrations in Ha Long Bay compared to the Cua Luc Estuary. However, this is controlled by the distribution of the fine (clay?+?silt) fraction, and hence the concentrations of Al, Fe, Ca, and organic matter (OM). The comparison of concentrations of trace metals (normalized towards Al) between the surficial sediments and the subsurface core sediments based on ¹³⁷Cs datings indicates that almost all surficial-sediment data fall inside or deviate slightly from the 95 % prediction interval of a background regression line. In addition, as determined by a Community Bureau of Reference three-step extraction, trace metals mainly dominate in the residual fraction (assumed to relate to crystal lattice of primary and secondary minerals), and this fraction does not change much in recent sediment layers. Therefore, trace metals are supposed to be derived from natural bio/geochemical processes and are characterized by a low potential mobility. Consequently, the established linear regression relationships of trace metal vs. Al or multiple regression relationships of trace metal vs. multi-elements (Al, Fe, Ca, and OM) are useful for the prediction of background levels of trace metals in sediments in future pollution monitoring and assessment programs.  相似文献   

Cenozoic basement structure of the South China Sea and adjacent areas by modeling and interpreting gravity data     

Tran Tuan Dung  Bui Cong Que  Nguyen Hong Phuong 《Russian Journal of Pacific Geology》2013,7(4):227-236

The South China Sea and adjacent areas is a large region with diversely complicated geological conditions. In spite of investigations carried out over the past many years, the marine geological structure in many places has remained poorly understood because of the deficient data, a thick seawater layer as well as of the sensitive areas among the countries in the region. In this paper, the authors study and apply a model-based methodology of the modeling and interpretation of the newest gravity data and others, which are 3D modeling, frequency filtering, horizontal gravity gradient and maximum horizontal gravity gradient, in order to determine clearly the basement structure. The basement features such as the main faults systems, uplift-depression zones and seafloor spreading axis, oceanic boundary in the region have been defined. The achieved results are checked by the seismic data available for the region. From the studied results, the authors have brought out some initial remarks on the structure and form of the basement in the South China Sea and adjacent areas.  相似文献   

Editorial introduction to the Geokarst hazards 2009 special issue     

Hai Thanh Tran 《Environmental Earth Sciences》2013,70(2):495-496

  相似文献   

围垦工程引起多年海岸冲淤演变的经验计算方法     

郑金海  HOANG Quoc Xuyen  张弛  陈可锋  董晓伟  王义刚  张清扬 《海洋学报(英文版)》2017,36(11):86-93

提出了一个改进的经验公式,用以计算围垦工程引起的淤泥质海岸多年冲淤演变。该经验公式假定在年时间尺度上,地形变化与潮流场变化具有密切联系。引入了一个冲刷折减系数,将传统公式的适用范围从淤积计算拓展到可以同时计算冲刷和淤积。建立了冲淤率年际变化与水深变化之间的关系式,可节省计算时间。将改进公式应用于江苏沿海小庙洪水道,较好地复演了边滩围垦工程影响下周边地形在3年时间内的演变,表明所改进的公式具有一定的可靠性。  相似文献