An EELS study of near edge structures of the oxygen K-edge in spinels     

Susanne Nyquist  Ulf Hålenius 《Physics and Chemistry of Minerals》2014,41(4):255-265

Spectra of seven aluminate, ferrite and chromate spinels were collected at the oxygen K-edge in order to examine the effect of octahedral ion composition on the near edge structures and explore whether these may shed some light on previously reported major variations in the optical absorption coefficient (ε) for the spin-allowed d–d band transitions due to tetrahedrally coordinated Fe²⁺ in optical spectra of oxide spinels. Interpretation of the energy loss near edge structure (ELNES) spectra was aided using the multiple scattering code FEFF8.40. For the chromate samples spin polarised calculations were included. Gold’s iterative deconvolution method was utilized to improve on energy resolution, resulting in spectra equal in merit to those recorded by technically superior instruments. Results include absolute energy positions and interpretation of ELNES features in terms of transitions to available states. We conclude that the major causes of differences in the optical absorption coefficient mentioned above are hybridization between oxygen p- and octahedral metal orbitals. Our study does not support the idea presented by other authors that there exists a local antiferromagnetic ordering in MgCr₂O₄ at room temperature.  相似文献   

First U–Pb geochronology on detrital zircons from Early-Middle Cambrian strata of the Torgau-Doberlug Syncline (eastern Germany) and palaeogeographic implications     

Abubaker  Atnisha  Hofmann  Mandy  Gärtner  Andreas  Linnemann  Ulf  Elicki  Olaf 《International Journal of Earth Sciences》2017,106(7):2445-2459

International Journal of Earth Sciences - LA-ICP-MS U–Pb data from detrital zircons of the Ediacaran to Cambrian siliciclastic sequence of the Torgau-Doberlug Syncline (TDS, Saxo-Thuringia,...  相似文献