The provenance of northern Kalahari Basin sediments and growth history of the southern Congo Craton reconstructed by U–Pb ages of zircons from recent river sands     

Andreas Gärtner  Ulf Linnemann  Mandy Hofmann 《International Journal of Earth Sciences》2014,103(2):579-595

The southern Congo Craton is widely overlain by Meso- to Cenozoic sediments of the northern Kalahari Basin, which hamper any correlation of basement units. The latter are represented by the Archaean Angola and Kasai Blocks, while the southern cratonic margin is framed by several Meso- to Neoproterozoic orogenic belts. For provenance analysis of the sedimentary cover and reconstruction of the main zircon-forming events, we studied zircons from recent sediments of the largest rivers at the southern margin of the Congo Craton. U–Pb zircon ages suggest a major amount of the sediments to originate from E Lufilian and Kibaran Belts, while input from the S Damara Belt seems to increase to the W. Ages related to the Angola Block were only noticed in the westernmost parts of the working area, which is not in accordance with the SE-trending drainage pattern, proposed to have been onset during the Cretaceous. Thus, it is assumed that the Meso- to Cenozoic sedimentary cover extended further west than today prior to the Mesozoic to Neogene uplift of the Angola Block and that subsequent erosion exhumed the basement stepwise from west to east. A recurrent destabilisation of the southern margin of the Congo Craton at ~2.7, 1.9, 1.0 and 0.6 Ga is supposed to be represented by major peaks in the age distribution pattern of the total amount of concordant zircons. This is in accordance with similar studies in adjacent areas. Additionally, the obtained data fit well to several hypothesised major events during the supercontinent cycle.  相似文献   

Stable isotope study of the Archaean rocks of the Vredefort impact structure,central Kaapvaal Craton,South Africa     

Åke Fagereng  Chris Harris  Mandy La Grange  Gary Stevens 《Contributions to Mineralogy and Petrology》2008,155(1):63-78

The Vredefort dome in the Kaapvaal Craton was formed as a result of the impact of a large meteorite at 2.02 Ga. The central core of Archaean granitic basement rocks is surrounded by a collar of uplifted and overturned strata of the Witwatersrand Supergroup, exposing a substantial depth section of the Archaean crust. Orthogneisses of the core show little variation in whole-rock δ ¹⁸O value, with the majority being between 8 and 10‰, with a mean of 9.2‰ (n = 35). Quartz and feldspar have per mil differences that are consistent with O-isotope equilibrium at high temperatures, suggesting minimal interaction with fluids during subsequent cooling. These data refute previous suggestions that the Outer Granite Gneiss (OGG) and Inlandsee Leucogranofels (ILG) of the core represent middle and lower crust, respectively. Granulite-facies greenstone remnants from the ILG have δ ¹⁸O values that are on average 1.5‰ higher than the ILG host rocks and are unlikely, therefore, to represent the residuum from the partial melting event that formed the host rock. Witwatersrand Supergroup sedimentary rocks of the collar, which were metamorphosed at greenschist-to amphibolite-facies conditions, generally have lower δ ¹⁸O values than the core rocks with a mean value for metapelites of 7.7‰ (n = 45). Overall, through an ∼20 km thick section of crust, there is a general increase in whole-rock δ ¹⁸O value with increasing depth. This is the reverse of what is normal in the crust, largely because the collar rocks have δ ¹⁸O values that are unusually low in comparison with metamorphosed sedimentary rocks worldwide. The collar rocks have δD values ranging from −35 to −115‰ (average −62‰, n = 29), which are consistent with interaction with water of meteoric origin, having a δD of about −25 to −45‰. We suggest that fluid movement through the collar rocks was enhanced by impact-induced secondary permeability in the dome structure. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

Provenance of Holocene beach sand in the Western Iberian margin: the use of the Kolmogorov–Smirnov test for the deciphering of sediment recycling in a modern coastal system          下载免费PDF全文

Manuel Francisco Pereira  Luís Albardeiro  Cristina Gama  Martim Chichorro  Mandy Hofmann  Ulf Linnemann 《Sedimentology》2016,63(5):1149-1167

Detrital zircons from Holocene beach sand and igneous zircons from the Cretaceous syenite forming Cape Sines (Western Iberian margin) were dated using laser ablation – inductively coupled plasma – mass spectrometry. The U–Pb ages obtained were used for comparison with previous radiometric data from Carboniferous greywacke, Pliocene–Pleistocene sand and Cretaceous syenite forming the sea cliff at Cape Sines and the contiguous coast. New U–Pb dating of igneous morphologically simple and complex zircons from the syenite of the Sines pluton suggests that the history of zircon crystallization was more extensive (ca 87 to 74 Ma), in contrast to the findings of previous geochronology studies (ca 76 to 74 Ma). The U–Pb ages obtained in Holocene sand revealed a wide interval, ranging from the Cretaceous to the Archean, with predominance of Cretaceous (37%), Palaeozoic (35%) and Neoproterozoic (19%) detrital‐zircon ages. The paucity of round to sub‐rounded grains seems to indicate a short transportation history for most of the Cretaceous zircons (ca 95 to 73 Ma) which are more abundant in the beach sand that was sampled south of Cape Sines. Comparative analysis using the Kolmogorov–Smirnov statistical method, analysing sub‐populations separately, suggests that the zircon populations of the Carboniferous and Cretaceous rocks forming the sea cliff were reproduced faithfully in Quaternary sand, indicating sediment recycling. The similarity of the pre‐Cretaceous ages (>ca 280 Ma) of detrital zircons found in Holocene sand, as compared with Carboniferous greywacke and Pliocene–Pleistocene sand, provides support for the hypothesis that detritus was reworked into the beach from older sedimentary rocks exposed along the sea cliff. The largest percentage of Cretaceous zircons (<ca 95 Ma) found in Holocene sand, as compared with Pliocene–Pleistocene sand (secondary recycled source), suggests that the Sines pluton was the one of the primary sources that became progressively more exposed to erosion during Quaternary uplift. This work highlights the application of the Kolmogorov–Smirnov method in comparison of zircon age populations used to identify provenance and sediment recycling in modern and ancient detrital sedimentary sequences.  相似文献   

Provenance analysis of the Paleozoic sequences of the northern Gondwana margin in NW Iberia: Passive margin to Variscan collision and orocline development     

Daniel Pastor-Galán  Gabriel Gutiérrez-Alonso  J. Brendan Murphy  Javier Fernández-Suárez  Mandy Hofmann  Ulf Linnemann 《Gondwana Research》2013,23(3):1089-1103

The Cantabrian Zone of NW Iberia preserves a voluminous, almost continuous, sedimentary sequence that ranges from Neoproterozoic to Early Permian in age. Its tectonic setting is controversial and recent hypotheses include (i) passive margin deposition along the northern margin of Gondwana or (ii) an active continental margin or (iii) a drifting ribbon continent. In this paper we present detrital zircon U–Pb laser ablation age data from 13 samples taken in detrital rocks from the Cantabrian Zone sequence ranging from Early Silurian to Early Permian in depositional age. The obtained results, together with previously published detrital zircon ages from Ediacaran–Ordovician strata, allow a comprehensive analysis of changing provenance through time. Collectively, these data indicate that this portion of Iberia was part of the passive margin of Gondwana at least from Ordovician to Late Devonian times. Zircon populations in all samples show strong similarities with the Sahara Craton and with zircons found in Libya, suggesting that NW Iberia occupied a paleoposition close to those regions of present-day northern Africa during this time interval. Changes in provenance in the Late Devonian are attributed to the onset of the collision between Gondwana and Laurussia.Additionally, the Middle Carboniferous to Permian samples record populations consistent with the recycling of older sedimentary sequences and exhumation of the igneous rocks formed before and during the Variscan orogeny. Late-Devonian to Permian samples yield zircon populations that reflect topographic changes produced during the Variscan orogeny and development of the lithospheric scale oroclinal buckling.  相似文献   

Application of sulphur isotope ratios to examine weaning patterns and freshwater fish consumption in Roman Oxfordshire, UK     

Olaf Nehlich  Benjamin T. Fuller  Mandy Jay  Alice Mora  Colin I. Smith  Michael P. Richards 《Geochimica et cosmochimica acta》2011,75(17):4963-4977

This study investigates the application of sulphur isotope ratios (δ³⁴S) in combination with carbon (δ¹³C) and nitrogen (δ¹⁵N) ratios to understand the influence of environmental sulphur on the isotopic composition of archaeological human and faunal remains from Roman era sites in Oxfordshire, UK. Humans (n = 83), terrestrial animals (n = 11), and freshwater fish (n = 5) were analysed for their isotope values from four locations in the Thames River Valley, and a broad range of δ³⁴S values were found. The δ³⁴S values from the terrestrial animals were highly variable (−13.6‰ to +0.5‰), but the δ³⁴S values of the fish were clustered and ³⁴S-depleted (−20.9‰ to −17.3‰). The results of the faunal remains suggest that riverine sulphur influenced the terrestrial sulphur isotopic signatures. Terrestrial animals were possibly raised on the floodplains of the River Thames, where highly ³⁴S-depleted sulphur influenced the soil. The humans show the largest range of δ³⁴S values (−18.8‰ to +9.6‰) from any archaeological context to date. No differences in δ³⁴S values were found between the males (−7.8 ± 6.0‰) and females (−5.3 ± 6.8‰), but the females had a linear correlation (R² = 0.71; p < 0.0001) between their δ¹⁵N and δ³⁴S compositions. These δ³⁴S results suggest a greater dietary variability for the inhabitants of Roman Oxfordshire than previously thought, with some individuals eating solely terrestrial protein resources and others showing a diet almost exclusively based on freshwater protein such as fish. Such large dietary variability was not visible by analysing only the carbon and nitrogen isotope ratios, and this research represents the largest and most detailed application of δ³⁴S analysis to examine dietary practices (including breastfeeding and weaning patterns) during the Romano-British Period.  相似文献   

Tracking an upper limit of the “Carnian Crisis” and/or Carnian stage in the Western Carpathians (Slovakia)     

Kohút  Milan  Hofmann  Mandy  Havrila  Milan  Linnemann  Ulf  Havrila  Jakub 《International Journal of Earth Sciences》2018,107(1):321-335

International Journal of Earth Sciences - The Late Triassic timescale, especially the Carnian–Norian boundary, is poorly constrained mainly due to a paucity of high-precision radio-isotopic...  相似文献   

A new U–Pb zircon age and a volcanogenic model for the early Permian Chemnitz Fossil Forest     

Luthardt  Ludwig  Hofmann  Mandy  Linnemann  Ulf  Gerdes  Axel  Marko  Linda  Rößler  Ronny 《International Journal of Earth Sciences》2018,107(7):2465-2489

International Journal of Earth Sciences - The Chemnitz Fossil Forest depicts one of the most completely preserved forest ecosystems in late Paleozoic Northern Hemisphere of tropical Pangaea. Fossil...  相似文献   

DNA technologies for monitoring waterborne pathogens: A revolution in water pollution monitoring     

Richard Y.C. Kong  Mandy M.H. Mak  Rudolf S.S. Wu 《Ocean & Coastal Management》2009,52(7):355-358

Due to increasing population growth and anthropogenic pollution in the coastal zone, contamination of water and seafood with pathogens is probably responsible for the greatest number of human morbidities and mortalities worldwide. Hence, regular monitoring of waterborne pathogens is required to safeguard public health. Current techniques rely on the culturing of nonpathogenic indicator organisms (e.g. Escherichia coli or coliforms) for detection by inference. However, recent epidemiological evidence shows poor correlation between concentrations of E. coli/coliform and waterborne pathogens. Moreover, traditional methods are slow, not cost-effective, unable to distinguish harmful from benign strains, and fail to detect viable but nonculturable pathogens. The use of the polymerase chain reaction (PCR) has provided rapid and highly sensitive methods for the specific detection of pathogenic microorganisms. This paper briefly reviews some DNA-based technologies for waterborne pathogen detection, and describes our recent development of two new DNA-based technologies—quantitative multiplex PCR (Q-mPCR) and DNA microarray—that allow simultaneous and cost-effective detection and quantification of numerous pathogens in a single sample, which is superior to the culture methods currently in use.  相似文献   

Induction of DNA strand breaks in the mussel (Mytilus trossulus) and clam (Protothaca staminea) following chronic field exposure to polycyclic aromatic hydrocarbons from the Exxon Valdez spill   总被引：1，自引：0，他引：1  

Thomas RE  Lindeberg M  Harris PM  Rice SD 《Marine pollution bulletin》2007,54(6):726-732

In 2002, 13 years after the Exxon Valdez spill, mussels and clams were examined for lingering oil exposure and damage. Known oil patches were sampled at four locations, and compared to nearby reference areas (same bay), and were also compared to "hot reference" sites to verify the methods used (Cordova harbor and fresh diesel spill at Port Chalmers). Passive samplers deployed for a month at the sites, along with tissue samples, confirmed that the oiled sites were oiled (fingerprinting back to Exxon Valdez oil) and that reference sites were clean. The highest PAH loads were detected in sub-surface interstitial waters at oiled sites. Exposure at the surface was generally low level, and probably intermittent. DNA damage was assessed in blood cells using sensitive comet analyses. DNA strand breakage was detected in both mussels and clams, with the highest level of damage detected at "hot reference" sites of Cordova harbor and Port Chalmers. Bioavailability and DNA damage at the oiled sties was low, indicating there has been substantial progress in recovery from the spill 13 years before, yet low level bioavailability and damage were still detectable.  相似文献   

The Blackspring Ridge Flute Field, south-central Alberta, Canada: : evidence for subglacial sheetflow erosion     

Mandy J. Munro-Stasiuk  John Shaw 《Quaternary International》2002,90(1)

The Blackspring Ridge (BSR), located in south-central Alberta, Canada, is dominated by a prominent flute field. Flutes (elongated streamlined depressions) and ridges (elongate streamlined hills) are up to 15 km long and are composed of two material types: in situ bedrock, and in situ pre-Laurentide glaciation fluvial sand and gravel beds. The preglacial beds are Tertiary or early Quaternary in age. The beds are undisturbed, maintain primary bedding structures, and even maintain clast imbrication. No till overlies the gravel beds, although in places large granite boulder erratics lie on the surface, indicating that ice was present in the region in the past. Because the ridges are composed of preglacial materials, they are remnant erosional landforms rather than constructional landforms. Geomorphic and sedimentary evidence favor subglacial meltwater as the erosional agent, rather than ice. We suggest that the elevation of the BSR relative to basal ice would have resulted in confined subglacial meltwater flow, with associated flow acceleration and increased scouring resulting in flute formation. This meltwater stripped away any till cover, leaving behind only a few boulders. Observations at the BSR flute field preclude the possibility that flutes and remnant ridges are the result of deformation of soft clayey beds.  相似文献