Modeling, parameterization and evaluation of monitoring methods for CO2 storage in deep saline formations: the CO2-MoPa project     

S. Bauer  H. Class  M. Ebert  V. Feeser  H. G?tze  A. Holzheid  O. Kolditz  Sabine Rosenbaum  W. Rabbel  D. Sch?fer  A. Dahmke 《Environmental Earth Sciences》2012,67(2):351-367

Capture and geological sequestration of CO₂ from large industrial sources is considered a measure for reducing anthropogenic emissions of CO₂ and thus mitigating climate change. One of the main storage options proposed are deep saline formations, as they provide the largest potential storage capacities among the geologic options. A thorough assessment of this type of storage site therefore is required. The CO₂-MoPa project aims at contributing to the dimensioning of CO₂ storage projects and to evaluating monitoring methods for CO₂ injection by an integrated approach. For this, virtual, but realistic test sites are designed geometrically and fully parameterized. Numerical process models are developed and then used to simulate the effects of a CO₂ injection into the virtual test sites. Because the parameterization of the virtual sites is known completely, investigation as well as monitoring methods can be closely examined and evaluated by comparing the virtual monitoring result with the simulation. To this end, the monitoring or investigation method is also simulated, and the (virtual) measurements are recorded and evaluated like real data. Application to a synthetic site typical for the north German basin showed that pressure response has to be evaluated taking into account the layered structure of the storage system. Microgravimetric measurements are found to be promising for detecting the CO₂ phase distribution. A combination of seismic and geoelectric measurements can be used to constrain the CO₂ phase distribution for the anticline system used in the synthetic site.  相似文献   

CLEAN: project overview on CO2 large-scale enhanced gas recovery in the Altmark natural gas field (Germany)     

Michael Kühn  Maja Tesmer  Peter Pilz  Robert Meyer  Kurt Reinicke  Andrea F?rster  Olaf Kolditz  Dirk Sch?fer 《Environmental Earth Sciences》2012,67(2):311-321

The joint research project CLEAN was conducted in the years 2008?C2011 by a German research and development (R&D) alliance of 16 partners from science and industry. The project was set-up as pilot project to investigate the processes relevant to enhanced gas recovery (EGR) by the injection of CO₂ into a subfield of the almost depleted Altmark natural gas field. Despite the setback that permission for active injection was not issued by the mining authority during the period of the project, important results fostering the understanding of processes linked with EGR were achieved. Work carried out led to a comprehensive evaluation of the EGR potential of the Altmark field and the Altensalzwedel subfield in particular. The calculated safety margins emphasize that technical well integrity of the 12 examined boreholes is given for EGR without a need for any further intervention. The laboratory and field tests confirm that the Altensalzwedel subfield is suitable for the injection of 100,000?t of CO₂. Numerical simulations provide sound predictions for the efficiency and safety of the EGR technology based on the CO₂ injection. The development and testing of different monitoring techniques facilitate an improved surveying of CO₂ storage sites in general. The CLEAN results provide the technological, logistic and conceptual prerequisites for implementing a CO₂-based EGR project in the Altmark and provide a benchmark for similar projects in the world.  相似文献   

Feasibility of geoelectrical monitoring and multiphase modeling for process understanding of gaseous CO2 injection into a shallow aquifer     

Hendrik Lamert  H. Geistlinger  U. Werban  C. Schütze  A. Peter  G. Hornbruch  A. Schulz  M. Pohlert  S. Kalia  M. Beyer  J. Gro?mann  A. Dahmke  P. Dietrich 《Environmental Earth Sciences》2012,67(2):447-462

Potential pathways in the subsurface may allow upwardly migrating gaseous CO₂ from deep geological storage formations to be released into near surface aquifers. Consequently, the availability of adequate methods for monitoring potential CO₂ releases in both deep geological formations and the shallow subsurface is a prerequisite for the deployment of Carbon Capture and Storage technology. Geoelectrical surveys are carried out for monitoring a small-scale and temporally limited CO₂ injection experiment in a pristine shallow aquifer system. Additionally, the feasibility of multiphase modeling was tested in order to describe both complex non-linear multiphase flow processes and the electrical behavior of partially saturated heterogeneous porous media. The suitability of geoelectrical methods for monitoring injected CO₂ and geochemically altered groundwater was proven. At the test site, geoelectrical measurements reveal significant variations in electrical conductivity in the order of 15?C30?%. However, site-specific conditions (e.g., geological settings, groundwater composition) significantly influence variations in subsurface electrical conductivity and consequently, the feasibility of geoelectrical monitoring. The monitoring results provided initial information concerning gaseous CO₂ migration and accumulation processes. Geoelectrical monitoring, in combination with multiphase modeling, was identified as a useful tool for understanding gas phase migration and mass transfer processes that occur due to CO₂ intrusions in shallow aquifer systems.  相似文献   

Precise ionosphere-free single-frequency GNSS positioning     

Torben Schüler  Herman Diessongo  Yaw Poku-Gyamfi 《GPS Solutions》2011,15(2):139-147

Ionospheric delays can be efficiently eliminated from single-frequency data using a combination of carrier phases and code ranges. Unfortunately, GPS and GLONASS ranges are relatively noisy which can limit the use of the positioning method. Nevertheless, position standard deviations are in the range of 6–8 cm (horizontal) and 7–9 cm (3d) obtained from diurnal data batches from selected IGS reference stations can be further reduced to 2–3 cm (3d) for weekly smoothed averages. GPS data sets collected in Ghana (Africa) reveal a typical level of 10 cm of deviation that must be anticipated under average conditions. Looking at the future of GNSS, the European Galileo system will, in contrast to GPS, provide the broadband signal E5 that is by far less affected by multipath thus providing rather precise range measurements. Simulated processing runs featuring both high ionospheric and tropospheric delay variations show a 3d position precision of 4 cm even for a data batch as short as just 1 h, whereas GPS L1/Galileo E1 performance is close to 13 cm for the same data set.  相似文献   

60Fe–60Ni systematics in the eucrite parent body: A case study of Bouvante and Juvinas     

Ghylaine Quitté  Christopher Latkoczy  Maria Schönbächler  Alex N. Halliday  Detlef Günther 《Geochimica et cosmochimica acta》2011,75(23):7698-7706

Eucrites are basaltic meteorites that cooled rapidly but are in many instances thermally metamorphosed and impact brecciated. The exact timing of these events remains unclear. In this study, Ni isotopic compositions and Fe/Ni elemental ratios are presented for two non-cumulate eucrites, Bouvante and Juvinas, including mineral separates from the latter. The samples are characterized by variable, well-resolved ⁶⁰Ni-excesses consistent with the former presence of live ⁶⁰Fe (t_1/2 = 2.62 Ma) at the time of eucrite crystallization. A significant fraction of Ni with a terrestrial-like composition appears to be surface correlated. This Ni may be the product of terrestrial contamination or was introduced by a chondritic impactor during brecciation. Altogether, the data provide evidence for a complex and probably multi-stage history of Fe and/or Ni redistribution, which impedes the interpretation of the chronological data.  相似文献   

Sex-specific biochemical and histological differences in gonads of sea urchins (Psammechinus miliaris) and their response to phenanthrene exposure     

Schäfer S  Abele D  Weihe E  Köhler A 《Marine environmental research》2011,71(1):70-78

Female and male individuals of the same species often differ with respect to their susceptibility to toxicant stress. In the present study, sea urchins (Psammechinus miliaris) of both sexes were exposed to high (150 μg L?1) and environmentally relevant (5 μg L?1) concentrations of phenanthrene over 10 days. While food intake was significantly decreased following exposure to 150 μg L?1 phenanthrene, histological indices (lipofuscin accumulation, fibrosis, oocyte atresia), energetic status (energy charge, sum adenylates, AMP/ATP ratio) as well as ascorbate levels in the gonads showed either little or no effect upon phenanthrene exposure. However, most parameters (vitamin C, energy charge, sum adenylates, AMP/ATP ratio, ATP and ADP concentrations, lipofuscin content, fibrosis) significantly differed between male and female animals. This study illustrates the difficulties to identify toxic injury in reproductive tissue as it may be superimposed by gametogenesis and spawning of gametes.  相似文献   

Microfacies and diagenesis of older Pleistocene (pre‐last glacial maximum) reef deposits,Great Barrier Reef,Australia (IODP Expedition 325): A quantitative approach     

Eberhard Gischler  Alex L. Thomas  André W. Droxler  Jody M. Webster  Yusuke Yokoyama  Bernd R. Schöne 《Sedimentology》2013,60(6):1432-1466

During Integrated Ocean Drilling Program Expedition 325, 34 holes were drilled along five transects in front of the Great Barrier Reef of Australia, penetrating some 700 m of late Pleistocene reef deposits (post‐glacial; largely 20 to 10 kyr bp ) in water depths of 42 to 127 m. In seven holes, drilled in water depths of 42 to 92 m on three transects, older Pleistocene (older than last glacial maximum, >20 kyr bp ) reef deposits were recovered from lower core sections. In this study, facies, diagenetic features, mineralogy and stable isotope geochemistry of 100 samples from six of the latter holes were investigated and quantified. Lithologies are dominated by grain‐supported textures, and were to a large part deposited in high‐energy, reef or reef slope environments. Quantitative analyses allow 11 microfacies to be defined, including mixed skeletal packstone and grainstone, mudstone‐wackestone, coral packstone, coral grainstone, coralline algal grainstone, coral‐algal packstone, coralline algal packstone, Halimeda grainstone, microbialite and caliche. Microbialites, that are common in cavities of younger, post‐glacial deposits, are rare in pre‐last glacial maximum core sections, possibly due to a lack of open framework suitable for colonization by microbes. In pre‐last glacial maximum deposits of holes M0032A and M0033A (>20 kyr bp ), marine diagenetic features are dominant; samples consist largely of aragonite and high‐magnesium calcite. Holes M0042A and M0057A, which contain the oldest rocks (>169 kyr bp ), are characterized by meteoric diagenesis and samples mostly consist of low‐magnesium calcite. Holes M0042A, M0055A and M0056A (>30 kyr bp ), and a horizon in the upper part of hole M0057A, contain both marine and meteoric diagenetic features. However, only one change from marine to meteoric pore water is recorded in contrast with the changes in diagenetic environment that might be inferred from the sea‐level history. Values of stable isotopes of oxygen and carbon are consistent with these findings. Samples from holes M0032A and M0033A reflect largely positive values (δ¹⁸O: ?1 to +1‰ and δ¹³C: +1 to +4‰), whereas those from holes M0042A and M0057A are negative (δ¹⁸O: ?4 to +2‰ and δ¹³C: ?8 to +2‰). Holes M0055A and M0056A provide intermediate values, with slightly positive δ¹³C, and negative δ¹⁸O values. The type and intensity of meteroric diagenesis appears to have been controlled both by age and depth, i.e. the time available for diagenetic alteration, and reflects the relation between reef deposition and sea‐level change.  相似文献   

Cu- and Mn-bearing tourmalines from Brazil and Mozambique: crystal structures, chemistry and correlations     

Andreas Ertl  Gerald Giester  Ulrich Schüssler  Helene Brätz  Martin Okrusch  Ekkehart Tillmanns  Hermann Bank 《Mineralogy and Petrology》2013,107(2):265-279

Cu- and Mn-bearing tourmalines from Brazil and Mozambique were characterised chemically (EMPA and LA-ICP-MS) and by X-ray single-crystal structure refinement. All these samples are rich in Al, Li and F (fluor-elbaite) and contain significant amounts of CuO (up to ~1.8 wt%) and MnO (up to ~3.5 wt%). Structurally investigated samples show a pronounced positive correlation between the <Y-O> distances and the (Li + Mn²⁺ + Cu + Fe²⁺) content (apfu) at this site with R ² = 0.90. An excellent negative correlation exists between the <Y-O> distances and the Al₂O₃ content (R ² = 0.94). The samples at each locality generally show a strong negative correlation between the X-site vacancies and the (MnO + FeO) content. The Mn content in these tourmalines depends on the availability of Mn, on the formation temperature, as well as on stereochemical constraints. Because of a very weak correlation between MnO and CuO we believe that the Cu content in tourmaline is essentially dependent on the availability of Cu and on stereochemical constraints.  相似文献   

A Common Reference Material for Cadmium Isotope Studies – NIST SRM 3108     

Wafa Abouchami  Stephen J. G. Galer  Tristan J. Horner  Mark Rehkämper  Frank Wombacher  Zichen Xue  Myriam Lambelet  Melanie Gault‐Ringold  Claudine H. Stirling  Maria Schönbächler  Alyssa E. Shiel  Dominique Weis  Philip F. Holdship 《Geostandards and Geoanalytical Research》2013,37(1):5-17

Research into natural mass‐dependent stable isotope fractionation of cadmium has rapidly expanded in the past few years. Methodologies are diverse with MC‐ICP‐MS favoured by all but one laboratory, which uses thermal ionisation mass spectrometry (TIMS). To quantify the isotope fractionation and correct for instrumental mass bias, double‐spike techniques, sample‐calibrator bracketing or element doping has been used. However, easy comparison between data sets has been hampered by the multitude of in‐house Cd solutions used as zero‐delta reference in different laboratories. The lack of a suitable isotopic reference material for Cd is detrimental for progress in the long term. We have conducted a comprehensive round‐robin assay of NIST SRM 3108 and the Cd isotope offsets to commonly used in‐house reference materials. Here, we advocate NIST SRM 3108 both as an isotope standard and the isotopic reference point for Cd and encourage its use as ‘zero‐delta’ in future studies. The purity of NIST SRM 3108 was evaluated regarding isobaric and polyatomic molecular interferences, and the levels of Zn, Pd and Sn found were not significant. The isotope ratio ¹¹⁴Cd/¹¹⁰Cd for NIST SRM 3108 lies within ～ 10 ppm Da^?1 of best estimates for the Bulk Silicate Earth and is validated for all measurement technologies currently in use.  相似文献   

Late Variscan “Basin and Range” magmatism and tectonics in the Central Alps: evidence from U-Pb geochronology     

Urs Schaltegger  Fernando Corfu 《Geodinamica Acta》2013,26(2):82-98

Abstract

Towards the end of the Variscan orogeny, volcano-sedimentary basins were formed within the mountain hell. U-Pb age determinations on zircons of volcanic and plutonic rocks from intramontane basins of the Central Alps allows us to define the age of two volcano-sedimentary units: The former one was dated older than 333 Ma (probably Visean), the younger one was deposited in a short time span between 303 and 298 Ma (Stephanien). The latter contains tuffs (303 ± 4 Ma), ignimbrites and microgranites (299 ± 2 Ma) and intrusive rhyolites (300 ± 2 Ma) that are all coeval within analytical precision. Granitoid rocks intruded into the volcano-sedimentary rocks at 333 ± 2 Ma, 310 ± 3 Ma and 298 ± 2 Ma. An angular unconformity between the older and the younger units in the Tö di area (Aar massif) indicates uplift and erosion between 310 and 303 Ma.

Our results suggest the existence of two periods of late Variscan extension (or transtension) in the Alpine realm, both combined with magmatic activity. The extensional event of Stephaniun age is characterized by a short duration of only a few million years, between 303 and 298 Ma, comprising tectonic activity, volcanism and plutonism. The plutonic rocks are characterized by a dominant lithospheric mantle component, which was contaminated by different amounts of crostai material and might have been increasingly influenced by aslhcnos-pherie mantle melts in the course of crostai thinning. The ealc-alkaline geochemical characteristics of the granites may be explained as an inherited source feature.

The overall tectonic style and the mode of magmatism resembles the situation of the Basin-and-Kange Province (eastern USA). Consequently there is no need to invoke a late-Variscan Andean-type subduction to explain the geochemical composition of the magmatic rocks. We conclude that late-orogenic extension is an important tectonic stage of the Variscan orogeny, which lasted for some 50 million years. The extension led to thinning of the crust and upwelling of hot mantle, causing high heat flow, intrusion of mantle melts and formation of huge volumes of acid melts.  相似文献