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141.
The complex impact structure El'gygytgyn (age 3.6 Ma, diameter 18 km) in northeastern Russia was formed in ~88 Ma old volcanic target rocks of the Ochotsk‐Chukotsky Volcanic Belt (OCVB). In 2009, El'gygytgyn was the target of a drilling project of the International Continental Scientific Drilling Program (ICDP), and in summer 2011 it was investigated further by a Russian–German expedition. Drill core material and surface samples, including volcanic target rocks and impactites, have been investigated by various geochemical techniques in order to improve the record of trace element characteristics for these lithologies and to attempt to detect and constrain a possible meteoritic component. The bedrock units of the ICDP drill core reflect the felsic volcanics that are predominant in the crater vicinity. The overlying suevites comprise a mixture of all currently known target lithologies, dominated by felsic rocks but lacking a discernable meteoritic component based on platinum group element abundances. The reworked suevite, directly overlain by lake sediments, is not only comparatively enriched in shocked minerals and impact glass spherules, but also contains the highest concentrations of Os, Ir, Ru, and Rh compared to other El'gygytgyn impactites. This is—to a lesser extent—the result of admixture of a mafic component, but more likely the signature of a chondritic meteoritic component. However, the highly siderophile element contribution from target material akin to the mafic blocks of the ICDP drill core to the impactites remains poorly constrained.  相似文献   
142.
Abstract— Approximately 100 m of impactites were retrieved from the ICDP borehole Yaxcopoil‐1 (Yax‐1), located ~60 km south‐southwest from the center of the Chicxulub impact crater on the Yucatán Peninsula of Mexico. Here, we characterize and discuss this impact breccia interval according to its geochemical characteristics. Chemical analysis of samples from all five recognized breccia units reveals that the impactites are of heterogeneous composition with regard to both major and trace elements at the single sample (8–16 cm3) scale. This is primarily due to a strong mixing relationship between carbonate and silicate fractions. However, averaged compositions for suevitic units 1 to 3 are similar, and the silicate fraction (after removal of the carbonate component) indicates thorough mixing and homogenization. Analysis of the green melt breccia horizon, unit 4, indicates that it contains a distinct mafic component. Large brown melt particles (in units 2, 3, and 4) represent a mixture of feldspathic and mafic components, with high CaO abundances. Unit 5 shows the greatest compositional diversity, with highly variable abundances of SiO2, CaO, and MgO. Inter‐sample heterogeneity is the result of small sample size combined with inherent heterogeneous lithological compositions, highly variable particle size of melt and lithic components, and post‐depositional alteration. In contrast to samples from the Y6 borehole from closer to the center of the structure, Yax‐1 impactites have a strong carbonate component. Elevated loss on ignition, Rb, and Cs contents in the upper two impactite units indicate strong interaction with seawater. The contents of the siderophile elements, including Ni, Co, Ir, and Cr, do not indicate the presence of a significant extraterrestrial component in the Yax‐1 impactites.  相似文献   
143.
Abstract— The 15 km diameter Ames structure in northwestern Oklahoma is located 2.75 km below surface in Cambro‐Ordovician Arbuckle dolomite, which is overlain by Middle Ordovician Oil Creek Formation shale. The feature is marked by two concentric ring structures, with the inner ring of about 5 km diameter probably representing the collapsed remnant of a structural uplift composed of brecciated Precambrian granite and Arbuckle dolomite. Wells from both the crater rim and the central uplift are oil‐ and gas‐producing, making Ames one of the economically important impact structures. Petrographic, geochemical, and age data were obtained on samples from the Nicor Chestnut 18‐4 drill core, off the northwest flank of the central uplift. These samples represent the largest and best examples of impact‐melt breccia obtained so far from the Ames structure. They contain carbonate rocks, which are derived from the target sequence. The chemical composition of the impact‐melt breccias is similar to that of target granite, with variable carbonate admixture. Some impact‐melt rocks are enriched in siderophile elements indicating the possible presence of a meteoritic component. Based on stratigraphic arguments, the age of the crater was estimated at 470 Ma. Previous 40Ar‐39Ar dating attempts of impact‐melt breccias from the Dorothy 1–19 core yielded plateau ages of about 285 Ma, which is in conflict with the stratigraphic age. The new 40Ar‐39Ar age data obtained on the melt breccias from the Nicor Chestnut core by ultraviolet (UV) laser spot analysis resulted in a range of ages with maxima around 300 Ma. These data could reflect processes related either the regional Nemaha Uplift or resetting due to hot brines active on a midcontinent‐wide scale, perhaps related to the Alleghenian and Ouachita orogenies. The age data indicate an extended burial phase associated with thermal overprint during Late Pennsylvanian‐Permian.  相似文献   
144.
Genesis and emplacement of Vredefort Granophyre, the impact melt rock exposed on the Vredefort Dome, the erosional remnant of the central uplift of the Vredefort impact structure, South Africa, have long been debated. This debate was recently reinvigorated by the discovery that besides the previously known felsic variety of >66 wt% SiO2, a second, somewhat more mafic phase of <66 wt% SiO2 occurs along a Granophyre dike on farms Kopjeskraal and Eldorado in the northwest sector of the dome. Two hypotheses have been put forward to explain the genesis and emplacement of this second phase: (1) successive injections of impact melt into extensional fractures opened in the course of central uplift formation/crater modification, with melts of distinct compositions derived from a differentiating impact melt body in the crater, and (2) generation of the more mafic phase as a product of admixture/assimilation of a mafic country rock component, either the so-called epidiorite of possible Ventersdorp Supergroup affiliation or the Dominion Group meta-lava (DGL), to Felsic Granophyre. In the latter model, contamination with mafic country rock would have occurred during downward intrusion and stoping into and below the crater floor. The so-called Mafic Granophyre has previously only ever been sampled on a single site (Farm Kopjeskraal). In this study, samples of Granophyre occurring along the southerly extension of this dike on farm Rensburgdrif, and from a second dike on the Rietkuil property further southwest were investigated by field work, and petrographic, geochemical, and isotopic analysis. The mafic phase indeed occurs in the interior of the dike at Rensburgdrif, and also on Rietkuil. New geochemical and Sr-Nd isotope data support the hypothesis that the Mafic Granophyre composition represents a mixture between Felsic Granophyre and a mafic country rock. A 20% admixture of epidiorite or DGL to Felsic Granophyre provides an excellent match for the chemical composition of the Mafic Granophyre. The Sr-Nd isotope data indicate that this admixture likely involved the epidiorite component rather than DGL. Together with earlier Sr-Nd-Os-Se isotopic data, and other geochemical data, these results further support formation of the Mafic Granophyre by local assimilation/admixture of epidiorite to Felsic Granophyre.  相似文献   
145.
146.
Characterization of GPS/GIOVE sensor stations in the CONGO network   总被引:6,自引:4,他引:2  
The Cooperative Network for GIOVE Observation (CONGO) is a global network of real-time capable multi-constellation GNSS receivers, which has been established by the German Aerospace Center (DLR) and the German Federal Agency for Cartography and Geodesy (BKG) as a test bed for experimentation with the new Galileo signals. The CONGO network employs a variety of different antennas and receivers which have become available for public use over the last 2 years. Following an overview of the network and the employed user equipment, the paper discusses the achieved GPS/GIOVE tracking performance. This includes a characterization of antenna gain patterns as well as receiver noise and multipath errors. Special attention is given to the discussion of inter-system biases. The nature and variation of these biases is illustrated based on a set of three different receivers operated in a zero-baseline configuration at the Wettzell site.  相似文献   
147.
The link between the Pacific/North American pattern (PNA) and the North Atlantic Oscillation (NAO) is investigated in reanalysis data (NCEP, ERA40) and multi-century CGCM runs for present day climate using three versions of the ECHAM model. PNA and NAO patterns and indices are determined via rotated principal component analysis on monthly mean 500?hPa geopotential height fields using the varimax criteria. On average, the multi-century CGCM simulations show a significant anti-correlation between PNA and NAO. Further, multi-decadal periods with significantly enhanced (high anti-correlation, active phase) or weakened (low correlations, inactive phase) coupling are found in all CGCMs. In the simulated active phases, the storm track activity near Newfoundland has a stronger link with the PNA variability than during the inactive phases. On average, the reanalysis datasets show no significant anti-correlation between PNA and NAO indices, but during the sub-period 1973?C1994 a significant anti-correlation is detected, suggesting that the present climate could correspond to an inactive period as detected in the CGCMs. An analysis of possible physical mechanisms suggests that the link between the patterns is established by the baroclinic waves forming the North Atlantic storm track. The geopotential height anomalies associated with negative PNA phases induce an increased advection of warm and moist air from the Gulf of Mexico and cold air from Canada. Both types of advection contribute to increase baroclinicity over eastern North America and also to increase the low level latent heat content of the warm air masses. Thus, growth conditions for eddies at the entrance of the North Atlantic storm track are enhanced. Considering the average temporal development during winter for the CGCM, results show an enhanced Newfoundland storm track maximum in the early winter for negative PNA, followed by a downstream enhancement of the Atlantic storm track in the subsequent months. In active (passive) phases, this seasonal development is enhanced (suppressed). As the storm track over the central and eastern Atlantic is closely related to the NAO variability, this development can be explained by the shift of the NAO index to more positive values.  相似文献   
148.
Nine SHRIMP U/Pb ages on zircon and two Pb/Pb single zircon ages have been determined from Late Paleozoic volcanic rocks from Saxony and northern Bohemia. Samples came from the Teplice-Altenberg Volcanic Complex, the Meissen Volcanic Complex, the Chemnitz Basin, the Döhlen Basin, the Brandov-Olbernhau Basin, and the North Saxon Volcanic Complex. The Teplice-Altenberg Volcanic Complex is subdivided into an early Namurian phase (Mikulov Ignimbrite, 326.8 ± 4.3 Ma), thus older than assumed by previous studies, and a late caldera-forming phase (Teplice Ignimbrite, 308.8 ± 4.9 Ma). The age of the latter, however, is not well constrained due to a large population of inherited zircon and possible hydrothermal overprint. The Leutewitz Ignimbrite, product of an early explosive volcanic episode of the Meissen Volcanic Complex yielded an age of 302.9 ± 2.5 Ma (Stephanian A). Volcanic rocks intercalated in the Brandov-Olbernhau Basin (BOB, 302 ± 2.8 Ma), Chemnitz Basin (CB, 296.6 ± 3.0 Ma), Döhlen Basin (DB, 296 ± 3.0 Ma), and the North Saxon Volcanic Complex (NSVC, c. 300–290 Ma) yielded well-constrained Stephanian to Sakmarian ages. The largest Late Paleozoic ignimbrite-forming eruption in Central Europe, the Rochlitz Ignimbrite, has a well-defined middle Asselian age of 294.4 ± 1.8 Ma. Ages of palingenic zircon revealed that the Namurian-Westphalian magmatism assimilated larger amounts of crystalline basement that formed during previous Paleozoic geodynamic phases. The Precambrian inherited ages support the chronostratigraphic structure assumed for the Saxo-Thuringian Zone of the Variscan Orogen. The present results help to improve the chronostratigraphic allocation of the Late Paleozoic volcanic zones in Central Europe. At the same time, the radiometric ages have implications for the interbasinal correlation and for the geodynamic evolution of the Variscan Orogeny.  相似文献   
149.
Abstract

This paper investigates the relationship between expert judgement and numerical criteria when evaluating hydrological model performance by comparing simulated and observed hydrographs. Using a web-based survey, we collected the visual evaluations of 150 experts on a set of high- and low-flow hydrographs. We then compared these answers with results from 60 numerical criteria. Agreement between experts was found to be more frequent in absolute terms (when rating models) than in relative terms (when comparing models), and better for high flows than for low flows. When comparing the set of 150 expert judgements with numerical criteria, we found that most expert judgements were loosely correlated with a numerical criterion, and that the criterion that best reflects expert judgement varies from expert to expert. Overall, we identified two groups of 10 criteria yielding an equivalent match with the expertise of the 150 participants in low and high flows, respectively. A single criterion common to both groups (the Hydrograph Matching Algorithm with mean absolute error) may represent a good indicator for the overall evaluation of models based on hydrographs. We conclude that none of the numerical criteria examined here can fully replace expert judgement when rating hydrographs, and that both relative and absolute evaluations should be based on the judgement of multiple experts.
Editor D. Koutsoyiannis  相似文献   
150.
Documenting the processes that control the variations in stream geochemistry at different streamflows is important for being able to use chemical tracers to understand catchment functioning. The concentrations of most solutes, including reactive cations (e.g., Na, Ca, K, and Mg) and anions that are primarily derived from precipitation (Cl and Br), in five headwater streams from southeast Australia vary little with streamflow and are close to being chemostatic. By contrast, NO3 and SO4 concentrations are higher at high streamflows. There is also a systematic increase of 3H activities from as low as 1.1 to as high as 2.6 TU with increasing streamflow. The changes in geochemistry cannot be explained solely by increased mineral dissolution at high streamflows or enhanced baseflow driven by hydraulic loading. They are best explained by an increased baseflow input augmented by water mobilized from shallower stores as the catchments wet up. The mean transit times of the water sustaining streamflow varies from 35 to 70 years at low streamflows to <7 years at high streamflows. The use of a range of geochemical tracers, including radioactive isotopes, allows the different possible causes of chemostatic behaviour to be assessed and improves our understanding of catchment functioning.  相似文献   
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