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A total of 113 samples of waste and soil were collected from a site in the state of San Luis Potosi, Mexico, that was occupied for several years by the metallurgical industry. Specific magnetic susceptibility (MS), electrical conductivity (EC) and pH were determined, as well as the total and available concentrations of potentially toxic elements (PTEs) such as As, Cd, Cu, Fe, Pb and Zn, which may cause a health risk for humans, animals and ecosystems, and the concentrations of major ions in aqueous extracts of soils and wastes. The solid phases of the samples were also characterized. The results revealed that the soils and wastes exhibited elevated values of PTEs, MS and EC. For soils these values decreased with increasing distance from the waste storage sites. The MS values were elevated primarily due to the presence of Fe-oxyhydroxides, such as magnetite, hematite and goethite, which contain PTEs in their structure leading to a high correlation between the value of MS and the As, Cd, Fe and Pb contents (r = 0.57–0.91) as well as between the PTEs values (r = 0.68–0.92). The elevated EC values measured in the metallurgical wastes were the result of presence of the sulfate minerals of Ca, Mg and Fe. The pollution index, which indicates the levels of simultaneous toxicity from elements such as As, Cd and Pb, was determined, with extreme hazard zones corresponding to areas that exhibit high MS values (0.91 correlation). In conclusion, MS measurements can be used as an indirect indicator to evaluate the PTE contamination in metallurgical areas, and EC measurements can aid in the identification of pollution sources.  相似文献   
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A multivariable approach utilising bulk sediment, planktonic Foraminifera and siliceous phytoplankton has been used to reconstruct rapid variations in palaeoproductivity in the Peru–Chile Current System off northern Chile for the past 19 000 cal. yr. During the early deglaciation (19 000–16 000 cal. yr BP), our data point to strongest upwelling intensity and highest productivity of the past 19 000 cal. yr. The late deglaciation (16 000–13 000 cal. yr BP) is characterised by a major change in the oceanographic setting, warmer water masses and weaker upwelling at the study site. Lowest productivity and weakest upwelling intensity are observed from the early to the middle Holocene (13 000–4000 cal. yr BP), and the beginning of the late Holocene (<4000 cal. yr BP) is marked by increasing productivity, mainly driven by silicate‐producing organisms. Changes in the productivity and upwelling intensity in our record may have resulted from a large‐scale compression and/or displacement of the South Pacific subtropical gyre during more productive periods, in line with a northward extension of the Antarctic Circumpolar Current and increased advection of Antarctic water masses with the Peru–Chile Current. The corresponding increase in hemispheric thermal gradient and wind stress induced stronger upwelling. During the periods of lower productivity, this scenario probably reversed. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   
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Population studies of EGRET gamma-ray sources indicate that there is a distinctive population of bright sources at low galactic latitudes. The sources have a distribution consistent with that of young galactic objects, with a concentration toward the inner spiral arms. There is a subgroup that displays strong variability with timescales from days to months. Following an earlier suggestion by Kaufman Bernadó et al. (2002), we explore the possibility that these sources could be high-mass microquasars. Detailed models for the gamma-ray emission that include inverse Compton interactions of electrons in the relativistic jets and photons from all local fields (stellar UV photons, synchrotron photons, soft X-ray photons from the accretion disk, and hard X-ray photons from a corona) are presented. We conclude that microquasars are excellent candidates for the parent population of the subgroup of variable low-latitude EGRET sources.  相似文献   
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Landslides - An extreme precipitation event produced catastrophic debris flows in central Chile during 29–31 January 2021 (austral summer). Our study focuses on the triggering factors and...  相似文献   
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Romero DM  Silver SE 《Ground water》2006,44(6):797-802
The ground water flow model MODFLOW inherently implements a nongeneralized integrated finite-difference (IFD) numerical scheme. The IFD numerical scheme allows for construction of finite-difference model grids with curvilinear (piecewise linear) rows. The resulting grid comprises model cells in the shape of trapezoids and is distorted in comparison to a traditional MODFLOW finite-difference grid. A version of MODFLOW-88 (herein referred to as MODFLOW IFD) with the code adapted to make the one-dimensional DELR and DELC arrays two dimensional, so that equivalent conductance between distorted grid cells can be calculated, is described. MODFLOW IFD is used to inspect the sensitivity of the numerical head and velocity solutions to the level of distortion in trapezoidal grid cells within a converging radial flow domain. A test problem designed for the analysis implements a grid oriented such that flow is parallel to columns with converging widths. The sensitivity analysis demonstrates MODFLOW IFD's capacity to numerically derive a head solution and resulting intercell volumetric flow when the internal calculation of equivalent conductance accounts for the distortion of the grid cells. The sensitivity of the velocity solution to grid cell distortion indicates criteria for distorted grid design. In the radial flow test problem described, the numerical head solution is not sensitive to grid cell distortion. The accuracy of the velocity solution is sensitive to cell distortion with error <1% if the angle between the nonparallel sides of trapezoidal cells is <12.5 degrees. The error of the velocity solution is related to the degree to which the spatial discretization of a curve is approximated with piecewise linear segments. Curvilinear finite-difference grid construction adds versatility to spatial discretization of the flow domain. MODFLOW-88's inherent IFD numerical scheme and the test problem results imply that more recent versions of MODFLOW 2000, with minor modifications, have the potential to make use of a curvilinear grid.  相似文献   
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Image network geometry, including the number and orientation of images, impacts the error, coverage, and processing time of 3D terrain mapping performed using structure-from-motion and multiview-stereo (SfM-MVS). Few studies have quantified trade-offs in error and processing time or ways to optimize image acquisition in diverse topographic conditions. Here, we determine suitable camera locations for image acquisition by minimizing the occlusion produced by topography. Viewshed analysis is used to select the suitable images, which requires a preliminary digital elevation model (DEM), potential camera locations, and sensor parameters. One aerial and two ground-based image collections were used to analyse differences between SfM-MVS models produced using: (1) all available images (ALL); (2) images selected using conventional methods (CON); and (3) images selected using the viewshed analysis (VIEW). The resulting models were compared with benchmark point clouds acquired by a terrestrial laser scanner (TLS) and TLS-derived DEMs. The VIEW datasets produced denser point clouds (28–32% more points) and DEMs with up to 66% reduction in error compared with CON datasets due to reduction of gaps in the DEM. VIEW datasets reduced processing time by 37–76% compared with ALL, with no reduction in coverage or increase in error. DEMs produced with ALL and VIEW datasets had similar slope and roughness, while slight differences that may be locally important were observed for the CON dataset. The new method helps optimize SfM-MVS image collection strategies that significantly reduce the number of images required with minimal loss in coverage or accuracy over complex surfaces. © 2020 John Wiley & Sons, Ltd.  相似文献   
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